FR2869612A1 - Preparation of highly pure fatty acid ester and glycerin, useful as fuel, comprises reaction of vegetable or animal oil with 1-18C aliphatic monoalcohol in the presence of catalyst e.g. titanium oxide and/or zinc oxide - Google Patents

Preparation of highly pure fatty acid ester and glycerin, useful as fuel, comprises reaction of vegetable or animal oil with 1-18C aliphatic monoalcohol in the presence of catalyst e.g. titanium oxide and/or zinc oxide

Info

Publication number
FR2869612A1
FR2869612A1 FR0404730A FR0404730A FR2869612A1 FR 2869612 A1 FR2869612 A1 FR 2869612A1 FR 0404730 A FR0404730 A FR 0404730A FR 0404730 A FR0404730 A FR 0404730A FR 2869612 A1 FR2869612 A1 FR 2869612A1
Authority
FR
France
Prior art keywords
titanium oxide
glycerin
vegetable
catalyst
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR0404730A
Other languages
French (fr)
Other versions
FR2869612B1 (en
Inventor
Gerard Hillion
Bruno Delfort
Christophe Lendresse
Pennec Dominique Le
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR0404730A priority Critical patent/FR2869612B1/en
Priority to EP05290798A priority patent/EP1593732A1/en
Priority to US11/118,776 priority patent/US7151187B2/en
Priority to BRPI0501601-0A priority patent/BRPI0501601B1/en
Publication of FR2869612A1 publication Critical patent/FR2869612A1/en
Application granted granted Critical
Publication of FR2869612B1 publication Critical patent/FR2869612B1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Abstract

Preparation of an ester of fatty acid and glycerin (I) with a high degree of purity comprises reaction of a vegetable or animal oil with 1-18C aliphatic monoalcohol (a) in the presence of a catalyst (b) (combination of: titanium oxide and zinc oxide; zinc oxide, titanium oxide and alumina; titanium oxide and bismuth oxide; or bismuth oxide, titanium oxide and alumna).
FR0404730A 2004-05-03 2004-05-03 PROCESS FOR THE TRANSESTERIFICATION OF VEGETABLE OR ANIMAL OILS USING HETEROGENEOUS CATALYSTS BASED ON ZINC, TITANIUM AND ALUMINUM Expired - Fee Related FR2869612B1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
FR0404730A FR2869612B1 (en) 2004-05-03 2004-05-03 PROCESS FOR THE TRANSESTERIFICATION OF VEGETABLE OR ANIMAL OILS USING HETEROGENEOUS CATALYSTS BASED ON ZINC, TITANIUM AND ALUMINUM
EP05290798A EP1593732A1 (en) 2004-05-03 2005-04-11 Process for the transesterification of plant or animal oil using a catalyst based on zinc or bismuth, titanium and aluminium
US11/118,776 US7151187B2 (en) 2004-05-03 2005-05-02 Process for transesterification of vegetable oils or animal oils by means of heterogeneous catalysts based on zinc or bismuth, titanium and aluminium
BRPI0501601-0A BRPI0501601B1 (en) 2004-05-03 2005-05-03 PROCESS FOR TRANSESTERIFICATION OF VEGETABLE OR ANIMAL OILS IN A MEDIUM OF ZINC OR BISMUTE, TITANIUM AND ALUMINUM HYPEROGENIC CATALYZERS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0404730A FR2869612B1 (en) 2004-05-03 2004-05-03 PROCESS FOR THE TRANSESTERIFICATION OF VEGETABLE OR ANIMAL OILS USING HETEROGENEOUS CATALYSTS BASED ON ZINC, TITANIUM AND ALUMINUM

Publications (2)

Publication Number Publication Date
FR2869612A1 true FR2869612A1 (en) 2005-11-04
FR2869612B1 FR2869612B1 (en) 2008-02-01

Family

ID=34949289

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0404730A Expired - Fee Related FR2869612B1 (en) 2004-05-03 2004-05-03 PROCESS FOR THE TRANSESTERIFICATION OF VEGETABLE OR ANIMAL OILS USING HETEROGENEOUS CATALYSTS BASED ON ZINC, TITANIUM AND ALUMINUM

Country Status (1)

Country Link
FR (1) FR2869612B1 (en)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7557253B2 (en) 2005-05-20 2009-07-07 Solvay (Societe Anonyme) Method for converting polyhydroxylated aliphatic hydrocarbons into chlorohydrins
WO2010029228A1 (en) * 2008-09-15 2010-03-18 Ifp Method for preparing alcohol esters from triglycerides and alcohols using a heterogeneous catalyst containing a mesostructured zinc silicic solid
EP2336279A1 (en) 2009-12-16 2011-06-22 IFP Energies nouvelles Method for producing alkyl esters using vegetable or animal oil and an aliphatic mono-alcohol with hot purification in a fixed bed
WO2011149754A1 (en) 2010-05-26 2011-12-01 Dow Global Technologies Llc Process for hydrochlorination of multihydroxylated aliphatic hydrocarbons
US8124814B2 (en) 2006-06-14 2012-02-28 Solvay (Societe Anonyme) Crude glycerol-based product, process for its purification and its use in the manufacture of dichloropropanol
US8197665B2 (en) 2007-06-12 2012-06-12 Solvay (Societe Anonyme) Aqueous composition containing a salt, manufacturing process and use
US8258350B2 (en) 2007-03-07 2012-09-04 Solvay (Societe Anonyme) Process for the manufacture of dichloropropanol
US8273923B2 (en) 2007-06-01 2012-09-25 Solvay (Societe Anonyme) Process for manufacturing a chlorohydrin
US8314205B2 (en) 2007-12-17 2012-11-20 Solvay (Societe Anonyme) Glycerol-based product, process for obtaining same and use thereof in the manufacturing of dichloropropanol
US8378130B2 (en) 2007-06-12 2013-02-19 Solvay (Societe Anonyme) Product containing epichlorohydrin, its preparation and its use in various applications
US8471074B2 (en) 2007-03-14 2013-06-25 Solvay (Societe Anonyme) Process for the manufacture of dichloropropanol
US8507643B2 (en) 2008-04-03 2013-08-13 Solvay S.A. Composition comprising glycerol, process for obtaining same and use thereof in the manufacture of dichloropropanol
US8536381B2 (en) 2008-09-12 2013-09-17 Solvay Sa Process for purifying hydrogen chloride
US8715568B2 (en) 2007-10-02 2014-05-06 Solvay Sa Use of compositions containing silicon for improving the corrosion resistance of vessels
US8795536B2 (en) 2008-01-31 2014-08-05 Solvay (Societe Anonyme) Process for degrading organic substances in an aqueous composition
US9309209B2 (en) 2010-09-30 2016-04-12 Solvay Sa Derivative of epichlorohydrin of natural origin
US9663427B2 (en) 2003-11-20 2017-05-30 Solvay (Société Anonyme) Process for producing epichlorohydrin

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20080037618A (en) 2005-05-20 2008-04-30 솔베이(소시에떼아노님) Method for making a chlorhydrine by reaction between a polyhydroxylated aliphatic hydrocarbon and a chlorinating agent
CN101068761B (en) 2005-11-08 2011-11-23 索尔维公司 Process for the manufacture of dichloropropanol by chlorination of glycerol

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5908946A (en) * 1996-08-08 1999-06-01 Institut Francais Du Petrole Process for the production of esters from vegetable oils or animal oils alcohols
EP0924185A1 (en) * 1997-12-18 1999-06-23 Institut Français du Pétrole Process for the preparation of fatty acid esters and thus obtained high purity esters

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5908946A (en) * 1996-08-08 1999-06-01 Institut Francais Du Petrole Process for the production of esters from vegetable oils or animal oils alcohols
EP0924185A1 (en) * 1997-12-18 1999-06-23 Institut Français du Pétrole Process for the preparation of fatty acid esters and thus obtained high purity esters

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PETERSON G R ET AL: "Rapeseed oil transesterification by heterogenous catalysis", JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY, AMERICAN OIL CHEMISTS' SOCIETY. CHAMPAIGN, US, vol. 61, no. 10, October 1984 (1984-10-01), pages 1593 - 1597, XP002170978, ISSN: 0003-021X *

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9663427B2 (en) 2003-11-20 2017-05-30 Solvay (Société Anonyme) Process for producing epichlorohydrin
US7615670B2 (en) 2005-05-20 2009-11-10 Solvay (Société Anonyme) Method for making chlorohydrin in liquid phase in the presence of heavy compounds
EP2275417A2 (en) 2005-05-20 2011-01-19 SOLVAY (Société Anonyme) Process for producing dichloropropanol
EP2284162A2 (en) 2005-05-20 2011-02-16 SOLVAY (Société Anonyme) Process for producing dichloropropanol
EP2284163A2 (en) 2005-05-20 2011-02-16 SOLVAY (Société Anonyme) Process for producing dichloropropanol
US7557253B2 (en) 2005-05-20 2009-07-07 Solvay (Societe Anonyme) Method for converting polyhydroxylated aliphatic hydrocarbons into chlorohydrins
US8124814B2 (en) 2006-06-14 2012-02-28 Solvay (Societe Anonyme) Crude glycerol-based product, process for its purification and its use in the manufacture of dichloropropanol
US8258350B2 (en) 2007-03-07 2012-09-04 Solvay (Societe Anonyme) Process for the manufacture of dichloropropanol
US8471074B2 (en) 2007-03-14 2013-06-25 Solvay (Societe Anonyme) Process for the manufacture of dichloropropanol
US8273923B2 (en) 2007-06-01 2012-09-25 Solvay (Societe Anonyme) Process for manufacturing a chlorohydrin
US8378130B2 (en) 2007-06-12 2013-02-19 Solvay (Societe Anonyme) Product containing epichlorohydrin, its preparation and its use in various applications
US8399692B2 (en) 2007-06-12 2013-03-19 Solvay (Societe Anonyme) Epichlorohydrin, manufacturing process and use
US8197665B2 (en) 2007-06-12 2012-06-12 Solvay (Societe Anonyme) Aqueous composition containing a salt, manufacturing process and use
US8715568B2 (en) 2007-10-02 2014-05-06 Solvay Sa Use of compositions containing silicon for improving the corrosion resistance of vessels
US8314205B2 (en) 2007-12-17 2012-11-20 Solvay (Societe Anonyme) Glycerol-based product, process for obtaining same and use thereof in the manufacturing of dichloropropanol
US8795536B2 (en) 2008-01-31 2014-08-05 Solvay (Societe Anonyme) Process for degrading organic substances in an aqueous composition
US8507643B2 (en) 2008-04-03 2013-08-13 Solvay S.A. Composition comprising glycerol, process for obtaining same and use thereof in the manufacture of dichloropropanol
US8536381B2 (en) 2008-09-12 2013-09-17 Solvay Sa Process for purifying hydrogen chloride
FR2935983A1 (en) * 2008-09-15 2010-03-19 Inst Francais Du Petrole PROCESS FOR THE PREPARATION OF ALCOHOLIC ESTERS FROM TRIGLYCERIDES AND ALCOHOLS USING A HETEROGENEOUS CATALYST BASED ON A ZINC-CONTAINING SILICIC MESOSTRUCTURE SOLID
WO2010029228A1 (en) * 2008-09-15 2010-03-18 Ifp Method for preparing alcohol esters from triglycerides and alcohols using a heterogeneous catalyst containing a mesostructured zinc silicic solid
EP2336279A1 (en) 2009-12-16 2011-06-22 IFP Energies nouvelles Method for producing alkyl esters using vegetable or animal oil and an aliphatic mono-alcohol with hot purification in a fixed bed
WO2011149754A1 (en) 2010-05-26 2011-12-01 Dow Global Technologies Llc Process for hydrochlorination of multihydroxylated aliphatic hydrocarbons
US9067845B2 (en) 2010-05-26 2015-06-30 Dow Global Technologies Llc Process for hydrochlorination of multihydroxylated aliphatic hydrocarbons
US9309209B2 (en) 2010-09-30 2016-04-12 Solvay Sa Derivative of epichlorohydrin of natural origin

Also Published As

Publication number Publication date
FR2869612B1 (en) 2008-02-01

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Effective date: 20160129