FR2862004B3 - Procede et installation d'enrichissement d'un flux gazeux en l'un de ses constituants - Google Patents

Procede et installation d'enrichissement d'un flux gazeux en l'un de ses constituants

Info

Publication number
FR2862004B3
FR2862004B3 FR0350819A FR0350819A FR2862004B3 FR 2862004 B3 FR2862004 B3 FR 2862004B3 FR 0350819 A FR0350819 A FR 0350819A FR 0350819 A FR0350819 A FR 0350819A FR 2862004 B3 FR2862004 B3 FR 2862004B3
Authority
FR
France
Prior art keywords
enriching
constituents
installation
gaseous flow
gaseous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
FR0350819A
Other languages
English (en)
French (fr)
Other versions
FR2862004A1 (fr
Inventor
Bot Patrick Le
Xavier Pontone
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0350819A priority Critical patent/FR2862004B3/fr
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Priority to BRPI0416327-3A priority patent/BRPI0416327A/pt
Priority to JP2006538907A priority patent/JP2007512491A/ja
Priority to EP04805813A priority patent/EP1697690A2/fr
Priority to PCT/FR2004/050570 priority patent/WO2005047790A2/fr
Priority to CN200480033075.4A priority patent/CN100543388C/zh
Priority to US10/577,621 priority patent/US20080034790A1/en
Publication of FR2862004A1 publication Critical patent/FR2862004A1/fr
Application granted granted Critical
Publication of FR2862004B3 publication Critical patent/FR2862004B3/fr
Anticipated expiration legal-status Critical
Priority to US13/046,141 priority patent/US20110192193A1/en
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/0446Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using the heat generated by mixing two different phases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04248Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
    • F25J3/04284Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
    • F25J3/0429Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
    • F25J3/04303Lachmann expansion, i.e. expanded into oxygen producing or low pressure column
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/0446Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using the heat generated by mixing two different phases
    • F25J3/04466Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using the heat generated by mixing two different phases for producing oxygen as a mixing column overhead gas by mixing gaseous air feed and liquid oxygen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04521Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
    • F25J3/04527Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general
    • F25J3/04551Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the metal production
    • F25J3/04557Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the metal production for pig iron or steel making, e.g. blast furnace, Corex
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04521Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
    • F25J3/04593The air gas consuming unit is also fed by an air stream
    • F25J3/046Completely integrated air feed compression, i.e. common MAC
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04769Operation, control and regulation of the process; Instrumentation within the process
    • F25J3/04812Different modes, i.e. "runs" of operation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00Processes or apparatus using separation by rectification
    • F25J2200/04Processes or apparatus using separation by rectification in a dual pressure main column system
    • F25J2200/06Processes or apparatus using separation by rectification in a dual pressure main column system in a classical double column flow-sheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2235/00Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams
    • F25J2235/42Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams the fluid being nitrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2235/00Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams
    • F25J2235/50Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams the fluid being oxygen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00Processes or apparatus involving steps for expanding of process streams
    • F25J2240/40Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval
    • F25J2240/42Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval the fluid being air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2250/00Details related to the use of reboiler-condensers
    • F25J2250/30External or auxiliary boiler-condenser in general, e.g. without a specified fluid or one fluid is not a primary air component or an intermediate fluid
    • F25J2250/40One fluid being air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2250/00Details related to the use of reboiler-condensers
    • F25J2250/30External or auxiliary boiler-condenser in general, e.g. without a specified fluid or one fluid is not a primary air component or an intermediate fluid
    • F25J2250/42One fluid being nitrogen

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Blast Furnaces (AREA)
  • Sampling And Sample Adjustment (AREA)
FR0350819A 2003-11-10 2003-11-10 Procede et installation d'enrichissement d'un flux gazeux en l'un de ses constituants Expired - Lifetime FR2862004B3 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR0350819A FR2862004B3 (fr) 2003-11-10 2003-11-10 Procede et installation d'enrichissement d'un flux gazeux en l'un de ses constituants
JP2006538907A JP2007512491A (ja) 2003-11-10 2004-11-05 気体流の一成分を濃縮する方法及び装置
EP04805813A EP1697690A2 (fr) 2003-11-10 2004-11-05 Procede et installation d enrichissement d'un flux gazeux en l'un de ses constituants
PCT/FR2004/050570 WO2005047790A2 (fr) 2003-11-10 2004-11-05 Procede et installation d'enrichissement d'un flux gazeux en l'un de ses constituants
BRPI0416327-3A BRPI0416327A (pt) 2003-11-10 2004-11-05 método e instalação para enriquecimento de uma corrente de gás com um dos componentes do mesmo
CN200480033075.4A CN100543388C (zh) 2003-11-10 2004-11-05 用于富集空气流中的氧的方法和设备
US10/577,621 US20080034790A1 (en) 2003-11-10 2004-11-05 Method And Installation For Enriching A Gas Stream With One Of The Components Thereof
US13/046,141 US20110192193A1 (en) 2003-11-10 2011-03-11 Method And Installation For Enriching A Gas Stream With One Of The Components Thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0350819A FR2862004B3 (fr) 2003-11-10 2003-11-10 Procede et installation d'enrichissement d'un flux gazeux en l'un de ses constituants

Publications (2)

Publication Number Publication Date
FR2862004A1 FR2862004A1 (fr) 2005-05-13
FR2862004B3 true FR2862004B3 (fr) 2005-12-23

Family

ID=34508749

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0350819A Expired - Lifetime FR2862004B3 (fr) 2003-11-10 2003-11-10 Procede et installation d'enrichissement d'un flux gazeux en l'un de ses constituants

Country Status (7)

Country Link
US (2) US20080034790A1 (pt)
EP (1) EP1697690A2 (pt)
JP (1) JP2007512491A (pt)
CN (1) CN100543388C (pt)
BR (1) BRPI0416327A (pt)
FR (1) FR2862004B3 (pt)
WO (1) WO2005047790A2 (pt)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2884305A1 (fr) * 2005-04-08 2006-10-13 Air Liquide Procede de recuperation et liquefaction du co2 contenu dans un gaz pauvre en co2
CZ302279B6 (cs) * 2005-07-04 2011-01-26 Cervenka@Jan Zpusob zrovnomernení kolísající koncentrace složky nebo složek v proudícím plynu
FR2960555A1 (fr) * 2010-05-31 2011-12-02 Air Liquide Installation integree comprenant un appareil de separation d'air et au moins un haut fourneau et son procede d'operation
US20130000352A1 (en) * 2011-06-30 2013-01-03 General Electric Company Air separation unit and systems incorporating the same
US9920987B2 (en) * 2015-05-08 2018-03-20 Air Products And Chemicals, Inc. Mixing column for single mixed refrigerant (SMR) process

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3126265A (en) * 1964-03-24 Process and apparatus for separating
US3731495A (en) * 1970-12-28 1973-05-08 Union Carbide Corp Process of and apparatus for air separation with nitrogen quenched power turbine
IT961138B (it) * 1971-02-01 1973-12-10 Air Liquide Impianto per comprimere un fluido mediante espansione di un altro fluido
LU70847A1 (pt) * 1973-09-25 1975-01-02
JPS61139609A (ja) * 1984-12-13 1986-06-26 Kawasaki Steel Corp 工業炉の酸素富化方法
FR2677667A1 (fr) * 1991-06-12 1992-12-18 Grenier Maurice Procede d'alimentation d'un haut-fourneau en air enrichi en oxygene, et installation de reduction de minerai de fer correspondante.
FR2680114B1 (fr) * 1991-08-07 1994-08-05 Lair Liquide Procede et installation de distillation d'air, et application a l'alimentation en gaz d'une acierie.
FR2712383B1 (fr) * 1993-11-12 1995-12-22 Air Liquide Installation combinée d'une unité de production de métal et d'une unité de séparation de l'air.
US5454227A (en) * 1994-08-17 1995-10-03 The Boc Group, Inc. Air separation method and apparatus
FR2753638B1 (fr) * 1996-09-25 1998-10-30 Procede pour l'alimentation d'une unite consommatrice d'un gaz
FR2758621B1 (fr) * 1997-01-22 1999-02-12 Air Liquide Procede et installation d'alimentation d'une unite consommatrice d'un gaz de l'air
FR2774159B1 (fr) * 1998-01-23 2000-03-17 Air Liquide Installation combinee d'un four et d'un appareil de distillation d'air et procede de mise en oeuvre
FR2774158B1 (fr) * 1998-01-23 2000-03-17 Air Liquide Installation combinee d'un four et d'un appareil de distillation d'air et procede de mise en oeuvre
US5979183A (en) * 1998-05-22 1999-11-09 Air Products And Chemicals, Inc. High availability gas turbine drive for an air separation unit
FR2814178B1 (fr) * 2000-09-18 2002-10-18 Air Liquide Alimentation en air enrichi en oxygene d'une unite de production de metal non-ferreux
US6568207B1 (en) * 2002-01-18 2003-05-27 L'air Liquide-Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude Integrated process and installation for the separation of air fed by compressed air from several compressors
US20060266048A1 (en) * 2005-05-27 2006-11-30 Bell Leonard E Fluid catalytic cracking flue gas utility optimizing system and process

Also Published As

Publication number Publication date
WO2005047790A3 (fr) 2005-08-11
WO2005047790A8 (fr) 2006-06-01
WO2005047790A2 (fr) 2005-05-26
FR2862004A1 (fr) 2005-05-13
US20110192193A1 (en) 2011-08-11
CN100543388C (zh) 2009-09-23
EP1697690A2 (fr) 2006-09-06
CN1878999A (zh) 2006-12-13
JP2007512491A (ja) 2007-05-17
BRPI0416327A (pt) 2007-01-09
US20080034790A1 (en) 2008-02-14

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