FR2826573A1 - COMPOSITIONS CONTAINING A HYDROXYDIPHENYL ETHER DERIVATIVE INHIBITING THE DEVELOPMENT OF BODY ODORS - Google Patents

Abstract

The invention relates to a cosmetic composition or dermopharmaceutical composition comprising at least one hydroxydiphenyl ether derivative and at least one specific conditioning agent. The invention also relates to a method for treating human body odours, particulary axillary odours, using said compositions.

Description

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COMPOSITIONS CONTAINING HYDROXYDIPHENYL ETHER DERIVATIVE
The present invention relates to a dermopharmaceutical cosmetic composition comprising at least one hydroxydiphenyl ether derivative and, in addition, at least one particular conditioning agent. BACKGROUND OF THE INVENTION

The present invention also relates to a method for treating human body odor and especially axillary with these compositions.

In the cosmetic field, it is well known to use, in topical application, deodorant products containing active substances, antiperspirant type or bactericidal type, to reduce or eliminate axillary odors generally unpleasant.

Antiperspirant substances have the effect of limiting the flow of sweat. They generally consist of aluminum salts which, on the one hand, are irritating to the skin and on the other hand, reduce the flow of sweat by modifying the cutaneous physiology, which is not satisfactory.

Bactericidal substances inhibit the development of cutaneous flora responsible for axillary odors.

Of the bactericidal products, the most commonly used is Triclosan (2,4,4'-trichloro-2'-hydraziniphenyl ether).

In order to achieve long-term effectiveness, new products with a deodorant action, that is, products that are capable of modifying, reducing and / or removing or preventing the development, are sought. body odor (this definition is given in "Cosmetic Science and Technology Series" -1988 / Volume 7, Chapter 10-lilc).

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In the patent application EP1053989, mention has been made of the cosmetic use of hydroxydiphenyl ether derivatives as antimicrobial active agents, in particular for deodorizing the skin, the mucous membranes, the hair, and various materials such as paper and paint. However the effectiveness of these products is limited and insufficient to ensure a lasting inhibition of the development of body odors.

After much research on the subject, the Applicant has now discovered, unexpectedly and surprisingly, that compositions associating hydroxydiphenyl ether derivatives with particular conditioning agents have the property of preventing the development of body sweat odors, without the disadvantages of the active substances previously used in the deodorant compositions.

This discovery is the basis of the present invention.

The present invention thus has as its first object, a cosmetic or dermopharmaceutical composition containing: a) at least one hydroxydiphenyl ether derivative of formula (1):

2 4 dans laquelle R\ R2, R3 et R4, identiques ou différentes, désignent Z, OZ, COZ, COOZ, CONZZ', aryle en C6-C30 ou aralkyl en C7-C40 ou alkyaryle en C7-C40 éventuellement substitués par un ou plusieurs groupements choisis parmi OH, NH2, halogène, carboxy, ou alcoxy C1-C30 carbonyle ; Z et Z', identiques ou différentes, désignent H, un radical hydrocarboné C1-C30 linéaire ou ramifié, cyclique ou acyclique, saturé ou insaturé, interrompu ou non par un plusieurs hétéroatomes ou groupements carbonyles, substitué ou non par un ou plusieurs groupements choisis parmi OH, NH2, halogène, carboxy ou alcoxy C1-C30 carbonyle ; b) au moins un agent conditionneur choisi parmi :

Wherein R 1, R 2, R 3 and R 4, which may be identical or different, denote Z, OZ, COZ, COOZ, CONZZ ', C 6 -C 30 aryl or C 7 -C 40 aralkyl or C 7 -C 40 alkylaryl optionally substituted with one or a plurality of groups selected from OH, NH2, halogen, carboxy, or C1-C30 alkoxycarbonyl; Z and Z ', which may be identical or different, denote H, a linear or branched, cyclic or acyclic, saturated or unsaturated, C1-C30 hydrocarbon radical, interrupted or not by one or more heteroatoms or carbonyl groups, substituted or unsubstituted by one or more chosen groups from OH, NH2, halogen, carboxy or C1-C30 alkoxycarbonyl; b) at least one conditioning agent chosen from:

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 cationic or amphoteric conditioning polymers ceramides esters of fatty acids and of short-chain alcohols cyclic volatile silicones synthetic oils vegetable waxes.

The second subject of the present invention is a method of using such a composition to prevent or attenuate the development of body sweat odors.

Among the compounds of formula (1) that can be used according to the present invention, it is preferred:
2,4'-Dihydroxy diphenyl ether
2-hydroxy 2'-ethyl diphenyl ether
2-hydroxy 2'-isopropyl diphenyl ether
2-hydroxy 2'-methyl diphenyl ether
2-hydroxy 2'-sec. butyl diphenyl ether
2-hydroxy 2'-tert. butyl diphenyl ether
2-hydroxy-3-butanoyl diphenyl ether
2-hydroxy-3-propanoyl diphenyl ether
2-hydroxy-4-formyl diphenyl ether
2-hydroxy-4'-methyl-5-formyl diphenyl ether
2-hydroxy-5-butanoyl diphenyl ether
2-hydroxy-5-formyl diphenyl ether
2-Hydroxy diphenyl ether
3-hydroxy 2'-methyl diphenyl ether
3-hydroxy 2'-sec. butyl diphenyl ether
3-hydroxy 2'-methyl-4-propyl diphenyl ether
3-hydroxy 3'-methyl diphenyl ether
3-hydroxy 3'-methyl 4-n-propyl diphenyl ether
3-hydroxy-4- (1-hydroxy-2-methylpropyl) diphenyl ether

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 3-hydroxy-4-butanoyl-diphenyl ether 3-hydroxy-4-butyl-diphenyl ether 3-hydroxy-4-dimethylpropyl-diphenyl ether 3-hydroxy-4-dimethylpropyl-3'-methyl-diphenyl ether 3-hydroxy-4-hexyl-diphenyl ether 3-hydroxy-4-hexanoyl-diphenyl ether 3-hydroxy-4-dodecyl-diphenyl ether 3-hydroxy-4-isobutanol diphenyl ether 3-hydroxy-4-isobutyl diphenyl ether 3-hydroxy-4-isopentanoyl-diphenyl ether 3-hydroxy-4- isopropyl diphenyl ether 3-hydroxy 4'-isopropyl diphenyl ether 3-hydroxy 4-n-butyl diphenyl ether 3-hydroxy 4-n-butyl diphenyl ether 3-hydroxy 4-n-pentyl diphenyl ether 3-hydroxy 4-n-propyl diphenyl ether 3-hydroxy 4-pentanoyl diphenyl ether 3-hydroxy 4-pentyl diphenyl ether 3-hydroxy 4-phenylethyl diphenyl ether 3-hydroxy 2'-methyl-4-phenylethyl diphenyl ether 3-hydroxy 3'-methyl 4-phenylethyl diphenyl ether 3-hydroxy 4-propanoyl diphenyl ether 3-hydroxy diphenyl ether 3,4'-di Hydroxy diphenyl ether 4,4'-Dihydroxy diphenyl ether 4-hydroxy 2'-methyl 5'-isopropyl diphenyl ether 4-hydroxy 2'-tert. butyl 5'-methyl diphenyl ether 4-hydroxy 2 ', 5'-dimethyl diphenyl ether 4-hydroxy 2'-cyclohexyl 5'-methyl diphenyl ether 4-hydroxy 2'-isopropyl 4'-ethyl diphenyl ether 4 2'-isopropyl-4'-propyl diphenyl ether 4-hydroxy 2'-isopropyl 5'-methyl diphenyl ether 4-hydroxy 2'-isopropyl diphenyl ether

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4-hydroxy 2'-isopropyl-4-phenylethyl diphenyl ether
4-hydroxy-3- (3-methylbutyl) -4'- (3-methylbutyl) diphenyl ether
4-hydroxy-4'-dimethylpropyl diphenyl ether
4-hydroxy 4'-ethyl diphenyl ether
4-hydroxy-4'-nonyl diphenyl ether
4-hydroxy-4'-phenylethyl diphenyl ether
4-hydroxy-4'-propyl diphenyl ether
4-hydroxy 4'-trifluoromethyl diphenyl ether
4-hydroxy 4'-propanol diphenyl ether
4-Hydroxy-diphenyl ether Even more preferentially, 4,4'-dihydroxydiphenyl ether will be used.

In the compositions of the invention, the concentration of compound (s) of formula (1) preferably ranges from 0.001 to 20% by weight, more preferably from 0.01 to 15% by weight and even more preferably from 0.1 to 10% by weight. weight relative to the total weight of the composition.

The cationic polymer type conditioning agents that may be used in accordance with the present invention may be chosen from all those already known per se as improving the cosmetic properties of the hair treated with detergent compositions, namely in particular those described in the patent application EP-A- 0 337 354 and in the French patent applications FR-A-2 270 846, 2 383 660, 2 598 611, 2 470 596 and 2 519 863.

Even more generally, within the meaning of the present invention, the expression "cationic polymer" denotes any polymer containing cationic groups and / or ionizable groups in cationic groups.

The preferred cationic polymers are chosen from those containing units containing primary, secondary, tertiary and / or quaternary amine groups that may either be part of the main polymer chain or may be carried by a lateral substituent directly connected thereto.

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 The cationic polymers used generally have a number-average molecular weight of from about 500 to about 5, and preferably from about 10 3 to about 10.

Among the cationic polymers, mention may be made more particularly of the polyamine, polyaminoamide and quaternary polyammonium type polymers. These are known products.

The polymers of the polyamine, polyamidoamide or quaternary polyammonium type which can be used in accordance with the present invention, which may be mentioned in particular, are those described in French patents Nos. 2,505,348 or 2,542,997. Among these polymers, mention may be made of: (1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the following units of formulas:

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 in which: Ru, which may be identical or different, denote a hydrogen atom or a CH3 radical; A, which may be identical or different, represent a linear or branched alkyl group of 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms or a hydroxyalkyl group of 1 to 4 carbon atoms; R, Rg, Rg, which may be identical or different, represent an alkyl group having from 1 to 18 carbon atoms or a benzyl radical and preferably an alkyl group having from 1 to 6 carbon atoms; R1 and R12, identical or different, represent hydrogen or an alkyl group having from 1 to 6 carbon atoms and preferably methyl or ethyl; X- denotes an anion derived from a mineral or organic acid such as a methosulphate anion or a halide such as chloride or bromide.

The copolymers of the family (1) may further contain one or more units derived from comonomers which may be chosen from the family of acrylamides, methacrylamides, diacetones acrylamides, acrylamides and methacrylamides substituted on the nitrogen by lower alkyls (C1-C4) , acrylic or methacrylic acids or their esters, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, vinyl esters.

vendus sous la dénomination BINA QUAT P 100 par la société CIBA GEIGY, - le copolymère d'acrylamide et de méthosulfate de méthacryloyloxyéthyltriméthylammonium vendu sous la dénomination RETEN par la société HERCULES, - les copolymères vinylpyrrolidone 1 acrylate ou méthacrylate de dialkylaminoalkyle quaternisés ou non, tels que les produits vendus sous la dénomination "GAFQUAT"par la société ISP comme par exemple "GAFQUAT 734" ou Thus, among these copolymers of the family (1), mention may be made of: the copolymers of acrylamide and of dimethylaminoethyl methacrylate quaternized with dimethyl sulphate or with a dimethyl hologenide, such as that sold under the name HERCOFLOC by the company Hercules, the copolymers of acrylamide and of methacryloyloxyethyltrimethylammonium chloride described for example in the patent application EP-A-080976 and

sold under the name BINA QUAT P 100 by the company CIBA GEIGY, - the copolymer of acrylamide and methacryloyloxyethyltrimethylammonium methosulfate sold under the name RETEN by the company HERCULES, - vinylpyrrolidone copolymers 1 acrylate or dialkylaminoalkyl methacrylate quaternized or otherwise, such that the products sold under the name "GAFQUAT" by the company ISP such as "GAFQUAT 734" or

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 "GAFQUAT 755" or the products referred to as "COPOLYMER 845,958 and 937".

These polymers are described in detail in French Patents 2,077. 143 and 2.393. 573, - dimethylaminoethyl methacrylate / vinylcaprolactam / vinylpyrrolidone terpolymers such as the product sold under the name GAFFIX VC 713 by the company ISP, - the vinylpyrrolidone / methacrylamidopropyl dimethylamine copolymers sold in particular under the name STYLEZE CC 10 by ISP.

 and the quaternized vinylpyrrolidone 1 dimethylaminopropyl methacrylamide copolymers such as the product sold under the name "GAFQUAT HS 100" by the company ISP.

(II) The cellulose ether derivatives comprising quaternary ammonium groups described in French Patent 1,492,597, and in particular the polymers sold under the names "JR" (JR 400, JR 125, JR 30M) or "LR" (LR 400, LR 30M) by Union Carbide Corporation. These polymers are also defined in the CTFA dictionary as quaternary ammoniums of hydroxyethylcellulose reacted with an epoxide substituted by a trimethylammonium group.

(III) Cationic cellulose derivatives such as cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer, and described in particular in US Pat. No. 4,131,576, such as hydroxyalkyl celluloses, such as hydroxymethyl- hydroxyethyl or hydroxypropyl celluloses grafted in particular with a salt of methacryloylethyl trimethylammonium, methacrylmidopropyl trimethylammonium, dimethyldiallylammonium salt.

The marketed products corresponding to this definition are more particularly the products sold under the name "Celquat L 200" and "Celquat H 100" by the company National Starch.

(IV) The cationic polysaccharides described more particularly in US Pat. Nos. 3,589,578 and 4,031,307, such as guar gums containing

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 cationic trialkylammonium groups. For example, guar gums modified with a salt (eg chloride) of 2,3-epoxypropyltrimethylammonium are used.

Such products are marketed in particular under the trade names JAGUAR C13 S, JAGUAR C 15, JAGUAR C 17 or JAGUAR C162 by the company MEYHALL.

(V) polymers consisting of piperazinyl units and straight or branched chain alkylene or hydroxyalkylene divalent radicals, optionally interrupted by oxygen, sulfur, nitrogen or aromatic or heterocyclic rings, as well as oxidation and / or quaternization of these polymers. Such polymers are in particular described in French Patents 2.162. 025 and 2.280. 361; (VI) water-soluble polyaminoamides prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides can be crosslinked by an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bisazetidinium, a bis-haloacyldiamine, an alkyl bis-halide or a oligomer resulting from the reaction of a bifunctional compound reactive with a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, an alkyl bishalide, an epilhalohydrin, a diepoxide or a bisunsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.35 moles per amine group of the polymaoamide; these polyaminoamides can be alkylated or if they contain one or more tertiary amine functions, quaternized. Such polymers are in particular described in French Patents 2,252. 840 and 2.368. 508; (Vil) polyaminoamide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation with difunctional agents. Mention may be made, for example, of adipic acid-diacoylaminohydroxyalkyidialoylene triamine polymers in which the alkyl radical contains from 1 to 4 carbon atoms and preferably denotes

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 methyl, ethyl, propyl. Such polymers are described in particular in French Patent 1,583. 363.

Among these derivatives, mention may be made more particularly of the adipic acid / dimethylaminohydroxypropyl / diethylene triamine polymers sold under the name "Cartaretine F, F4 or F8" by the company Sandoz.

(VIII) polymers obtained by reacting a polyalkylene polyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms. The molar ratio between the polyalkylene polylamine and the dicarboxylic acid being between 0.8: 1 and 1.4: 1; the polyaminoamide resulting therefrom being reacted with epichlorohydrin in a molar ratio of epichlorohydrin relative to the secondary amine group of the polyaminoamide of between 0.5: 1 and 1.8: 1. Such polymers are described in particular in the patents US 3,227. 615 and 2.961. 347.

Polymers of this type are in particular sold under the name "Hercosett 57" by the company Hercules Inc. or under the name "PD 170" or "Delsette 101" by the company Hercules in the case of the adipic acid copolymer / epoxypropyl / diethylenetriamine.

(IX) cyclopolymers of alkyl diallyl amine or of dialkyl diallyl ammonium, such as homopolymers or copolymers comprising, as main constituent of the chain, units of formula (2) or (3):

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inférieur (C1-C4) ou R10 et R11 peuvent désigner conjointement avec l'atome d'azote auquel ils sont rattachés, des groupement hétérocycliques, tels que pipéridinyle ou morpholinyl ; Y- est un anion tel que bromure, chlorure, acétate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate. Ces polymères sont notamment décrits dans le brevet français 2.080. 759 et dans son certificat d'addition 2.190. 406. formulas in which k and t are 0 or 1, the sum k + t being equal to 1; R12 denotes a hydrogen atom or a methyl radical; R10 and R11! independently of each other, denote an alkyl group having 1 to 22 carbon atoms, a hydroxyalkyl group in which the alkyl group preferably has 1 to 5 carbon atoms, an amidoalkyl group

lower (C1-C4) or R10 and R11 may designate together with the nitrogen atom to which they are attached, heterocyclic groups, such as piperidinyl or morpholinyl; Y- is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate. These polymers are described in particular in French Patent 2,080. 759 and in his certificate of addition 2.190. 406.

R10 and R11, independently of one another, preferably denote an alkyl group having 1 to 4 carbon atoms.

Among the polymers defined above, mention may be made more particularly of the homopolymer of dimethyldiallylammonium chloride sold under the name "Merquat 100" by the company Calgon (and its homologues of low molecular weight average) and the chloride copolymers diallyldimethylammonium and acrylamide sold under the name "MERQUAT 550".

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formule (4) dans laquelle :

R. g, R, R. g et R. g, identiques ou différents, représentent des radicaux aliphatiques, alicycliques, ou arylaliphatiques contenant de 1 à 20 atomes de carbone ou des radicaux hydroxyalkylaliphatiques inférieurs, ou bien Rg, R, R et R. g, ensemb) e ou séparément, constituent avec les atomes d'azote auxquels ils sont rattachés des hétérocycles contenant éventuellement un second hétéroatome autre que l'azote ou bien R13' R14' R15 et R16 représentent un radical alkyle en C1-C6 linéaire ou ramifié substitué par un groupement nitrile, ester, acyle, amide ou -CO-0-R17-Q ou -CO-NH-R17-Q où R17 est un alkylène et Q un groupement ammonium quaternaire ; A1 et 81 représentent des groupements polyméthyléniques contenant de 2 à 20 atomes de carbone pouvant être linéaires ou ramifiés, saturés ou insaturés, et pouvant contenir, liés à ou intercalés dans la chaîne principale, un ou plusieurs cycles aromatiques, ou un ou plusieurs atomes d'oxygène, de soufre ou des groupements sulfoxyde, sulfone, disulfure, amino, alkylamino, hydroxyle, ammonium quaternaire, uréido, amide ou ester, et X- désigne un anion dérivé d'un acide minéral ou organique ; A1, R13 et R15 peuvent former avec les deux atomes d'azote auxquels ils sont rattachés un cycle pipérazinique ; en outre si A1 désigne un radical alkylène ou hydroxyalkylène linéaire ou ramifié, saturé ou insaturé, Bi peut également désigner un groupement (CH2) n-CO-D-OC- (CH2) n- dans lequel D désigne : a) un reste de glycol de formule :-0-Z1-O-, où Z1 désigne un radical hydrocarboné linéaire ou ramifié ou un groupement répondant à l'une des formules suivantes :

(X) the quaternary diammonium polymer containing recurring units having the formula:

formula (4) in which:

R.sub.g, R.sub.1, R.sub.1 and R.sub.6, which may be identical or different, represent aliphatic, alicyclic or arylaliphatic radicals containing from 1 to 20 carbon atoms or lower hydroxyalkylaliphatic radicals, or Rg, R, R and R g, together or separately, together with the nitrogen atoms to which they are attached, form heterocycles optionally containing a second heteroatom other than nitrogen, or R13 'R14' R15 and R16 represent a linear C1-C6 alkyl radical. or branched substituted with a nitrile, ester, acyl, amide group or -CO-O-R17-Q or -CO-NH-R17-Q where R17 is alkylene and Q is a quaternary ammonium group; A1 and 81 represent polymethylene groups containing from 2 to 20 carbon atoms which may be linear or branched, saturated or unsaturated, and may contain, bound to or intercalated in the main chain, one or more aromatic rings, or one or more atoms of oxygen, sulfur or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and X- denotes an anion derived from a mineral or organic acid; A1, R13 and R15 can form with the two nitrogen atoms to which they are attached a piperazine ring; in addition, if A1 denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, Bi can also denote a (CH 2) n -CO-D-OC- (CH 2) n- group in which D denotes: a) a residue of glycol of formula: -O-Z1-O-, where Z1 denotes a linear or branched hydrocarbon radical or a group corresponding to one of the following formulas:

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d) un groupement uréylène de formule :-NH-CO-NH- ; De préférence, X- est un anion tel que le chlorure ou le bromure. where x and y denote an integer from 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing an average degree of polymerization; b) a bis-secondary diamine residue such as a piperazine derivative; c) a bis-primary diamine residue of formula: -NH-Y1-NH-, where Y1 denotes a linear or branched hydrocarbon radical, or the divalent radical

d) a ureylene group of formula: -NH-CO-NH-; Preferably, X- is an anion such as chloride or bromide.

These polymers have a number average molecular weight generally between 1000 and 100000.

Polymers of this type are described in French patents 2,320. 330.2. 270,846, 2.316. 271.2. 336,434 and 2,413. 907 and US Patents 2,273. 780.2. 375.853, 2.388. 614.2. 454,547, 3.206. 462.2. 261.002, 2.271. 378, 3.874. 870.4. 001.432, 3.929. 990.3. 966.904, 4.005. 193.4. 025,617, 4,025. 627, 4.025. 653.4. 026,945 and 4,027,020.

It is more particularly possible to use polymers which consist of recurring units corresponding to the formula:

dans taque))eR,R,RetR identiques ou différents, désignent un radical alkyle ou hydroxyalkyl ayant de 1 à 4 atomes de carbone environ, n et p sont des nombres entiers variant de 2 à 20 environ et, X- est un anion dérivé d'un acide minéral ou organique.

in each of the same or different radicals, denote an alkyl or hydroxyalkyl radical having from 1 to 4 carbon atoms, n and p are integers ranging from 2 to approximately 20 and X- is a derived anion. a mineral or organic acid.

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A particularly preferred compound of formula (5) is that for which R 5, R 6, R 7 and R 8, represent a methyl radical and n = 3, p = 6 and X = Cl, referred to as Hexadimethrine chloride according to the INCI nomenclature (CTFA). .

formule dans laquelle :

Rg,RR et R, identiques ou différents, représentent un atome d'hydrogène ou un radical méthyle, éthyle, propyle, ss-hydroxyéthyle, ss-hydroxypropyle ou - CHCHOCHCH) OH où p est égal à 0 ou à un nombre entier compris entre 1 et 6, sous réserve que Rg, Rg, R et R21 ne représentent pas simultanément un atome d'hydrogène, r et s, identiques ou différents, sont des nombres entiers compris entre 1 et 6, q est égal à 0 ou à un nombre entier compris entre 1 et 34, X-désigne un anion tel qu'un halogènure, A désigne un radical d'un dihalogénure ou représente de préférence

De tels composés sont notamment décrits dans la demande de brevet EP-A-122 324. (XI) quaternary polyammonium polymers consisting of units of formula (6):

formula in which:

Rg, RR and R, which may be identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, ss-hydroxyethyl, ss-hydroxypropyl or -CHCHOCHCH) OH radical where p is equal to 0 or to an integer between 1 and 6, provided that Rg, Rg, R and R21 do not simultaneously represent a hydrogen atom, r and s, which are identical or different, are integers between 1 and 6, q is 0 or a integer between 1 and 34, X-denotes an anion such as a halide, A denotes a radical of a dihalide or is preferably

Such compounds are described in particular in patent application EP-A-122 324.

For example, mention may be made of "Mirapol # A 15", "Miapol # AD1", "Mirapol # AZ1" and "Miapol # 175" products sold by Miranol.

(XII) Quaternary polymers of vinylpyrrolidone and vinylimidazole, such as, for example, the products sold under the names Luviquat &commat; FC 905, FC 550 and FC 370 by the company B. A. S. F.

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(XIII) Polyamines such as Polyquart &commat; H sold by HENKEL, referenced under the name POLYETHYLENEGLYCOL (15) TALLOW POLYAMINE in the CTFA dictionary.

sous les noms de SALCARE SC 95 et SALCARE SC 96 par la Société ALLIED COLLOIDS. (XIV) Crosslinked polymers of methacryloyloxy (C 1 -C 4) tri-alkyl (C 1 -C 4) ammonium salts, such as the polymers obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized with methyl chloride, or by copolymerization of acrylamide with dimethylaminoethyl methacrylate quaternized with chloride of methyl, the homo or copolymerization being followed by crosslinking with an olefinically unsaturated compound, in particular methylenebisacrylamide. It is more particularly possible to use a crosslinked acrylamide / methacryloyloxyethyltrimethylammonium chloride copolymer (20/80 by weight) in the form of a dispersion containing 50% by weight of said copolymer in mineral oil. This dispersion is sold under the name SALCARE SC 92 by the company ALLIED COLLOIDS. It is also possible to use a crosslinked homopolymer of methacryloyloxyethyltrimethylammonium chloride containing about 50% by weight of the homopolymer in mineral oil or in a liquid ester. These dispersions are marketed

under the names SALCARE SC 95 and SALCARE SC 96 by the company ALLIED COLLOIDS.

Other cationic polymers which can be used in the context of the invention are cationic proteins or hydrolysates of cationic proteins, polyalkyleneimines, in particular polyethyleneimines, polymers containing vinylpyridine or vinylpyridinium units, condensates of polyamines and of epichlorohydrin, quaternary polyureylenes and chitin derivatives.

quaternaires tels que les produits vendus sous la dénomination JR 400 par la Société UNION CARBIDE CORPORATION, les cyclopolymères cationiques, en particulier les homopolymères ou copolymères de chlorure de Among all the cationic polymers that may be used in the context of the present invention, it is preferred to use cellulose ether derivatives.

quaternary products such as the products sold under the name JR 400 by UNION CARBIDE CORPORATION, cationic cyclopolymers, in particular homopolymers or copolymers of

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diméthyidiallylammonium, vendus sous les dénominations MERQUAT 100 , MERQUAT 550 et MERQUAT S par la société CALGON, les polymères quaternaires de vinylpyrrolidone et de vinylimidazol et leurs mélanges.

dimethylidallylammonium, sold under the names Merquat 100, Merquat 550 and Merquat S by the company Calgon, the quaternary polymers of vinylpyrrolidone and vinylimidazole and mixtures thereof.

The amphoteric polymers that may be used in accordance with the present invention may be chosen from polymers comprising K and M units statistically distributed in the polymer chain, where K denotes a unit derived from a monomer comprising at least one basic nitrogen atom and M denotes a unit derived from an acidic monomer having one or more carboxylic or sulphonic groups, or K and M may denote groups derived from zwitterionic monomers of carboxybetaines or sulfobetaines; K and M may also denote a cationic polymer chain comprising primary, secondary, tertiary or quaternary amine groups, in which at least one of the amine groups carries a carboxylic or sulphonic group connected via a hydrocarbon radical, or Well K and M are part of a chain of an ethylene-patterned polymer. p-dicarboxylic agent in which one of the carboxylic groups has been reacted with a polyamine containing one or more primary or secondary amine groups.

The amphoteric film-forming polymers corresponding to the definition given above, which are more particularly preferred, are chosen from the following polymers: (A) The polymers resulting from the copolymerization of a monomer derived from a vinyl compound carrying a carboxylic group such as, more particularly, the acrylic acid, methacrylic acid, maleic acid, alpha-chloro acrylic acid, and a basic monomer derived from a substituted vinyl compound containing at least one basic atom such as, more particularly, dialkylaminoalkyl methacrylate and acrylate, dialkylaminoalkylmethacrylamide and acrylamide. Such compounds are described in U.S. Patent No. 3,836,537.

Mention may also be made of the sodium acrylate / acrylamidopropyltrimethylammonium chloride copolymer sold under the name Polyquart KE 3033 by the company Henkel.

The vinyl compound may also be a dialkyldiallylammonium salt such as diethyldiallylammonium chloride. Copolymers of acrylic acid and

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 of the latter monomer are proposed under the names MERQUAT 280, MERQUAT 295 and MERQUAT PLUS 3330 by the company CALGON.

(B) polymers comprising units derived from: a) at least one monomer chosen from acrylamides or methacrylamides substituted on the nitrogen with an alkyl radical; b) with at least one acidic comonomer containing one or more carboxylic groups reagents, and c) at least one basic comonomer such as primary, secondary, tertiary and quaternary amine substituent esters of acrylic and methacrylic acids and the quaternization product of dimethylaminoethyl methacrylate with dimethyl or diethyl sulfate.

The N-substituted acrylamides or methacrylamides which are more particularly preferred according to the invention are the groups in which the alkyl radicals contain from 2 to 12 carbon atoms and more particularly N-ethylacrylamide, N-tert-butyl-acrylamide and N-tert-octyl-acrylamide. N-octylacrylamide, Ndecylacrylamide, N-dodecylacrylamide and the corresponding methacrylamides.

The acidic comonomers are chosen more particularly from acrylic, methacrylic, crotonic, itaconic, maleic and fumaric acids as well as alkyl monoesters having 1 to 4 carbon atoms of maleic or fumaric acids or anhydrides.

Preferred basic comonomers are aminoethyl, butylaminoethyl, N, N'-dimethylaminoethyl, and N-tert-butylaminoethyl methacrylates.

The copolymers whose CTFA (4th Ed., 1991) name is octylacrylamide / acrylates / butylaminoethylmethacrylate copolymer, such as the products sold under the name AMPHOMER or LOVOCRYL 47 by the company National Starch, are particularly used.

(C) Polyamino amide crosslinked and alkylated partially or totally derived from polyaminoamide of general formula:

<Desc / Clms Page number 18>

dans laquelle R19 représente un radical divalent dérivé d'un acide dicarboxylique saturé, d'un acide aliphatique mono ou dicarboxylique à double liaison éthylénique, d'un ester d'un alcanol inférieur ayant 1 à 6 atomes de carbone de ces acides ou d'un radical dérivant de l'addition de l'un quelconque desdits acides avec une amine bis primaire ou bis secondaire, et Z2 désigne un radical d'une polyalkylène-polyamine bis-primaire, mono ou bis-secondaire et de préférence représente : a) dans les proportions de 60 à 100 moles %, le radical

où x=2 et p=2 ou 3, ou bien x=3 et p=2

ce radical dérivant de la diéthylène triamine, de la triéthylène tétraamine ou de la dipropylène triamine ; b) dans les proportions de 0 à 40 moles % le radical (8) ci-dessus, dans lequel x=2 et p=1 et qui dérive de l'éthylènediamine, ou le radical dérivant de la pipérazine :

wherein R19 represents a divalent radical derived from a saturated dicarboxylic acid, an ethylenically double bonded mono or dicarboxylic aliphatic acid, an ester of a lower alkanol having 1 to 6 carbon atoms of these acids or a radical derived from the addition of any one of said acids with a primary bis or secondary bis amine, and Z2 denotes a radical of a bis-primary, mono or bis-secondary polyalkylene polyamine and preferably represents: a) in the proportions of 60 to 100 mol%, the radical

where x = 2 and p = 2 or 3, or x = 3 and p = 2

this radical derived from diethylene triamine, triethylene tetraamine or dipropylene triamine; b) in the proportions of 0 to 40 mol%, the radical (8) above, in which x = 2 and p = 1 and which is derived from ethylenediamine, or the radical derived from piperazine:

c) dans les proportions de 0 à 20 moles % le radica)-NH- (CH) g-NH- dérivant de l'hexaméthylènediamine, ces polyaminoamines étant réticulées par addition d'un agent réticulant bifonctionnel choisi parmi les épihalohydrines, les diépoxydes, les dianhydrides, les dérivés bis insaturés, au moyen de 0, 025 à 0, 35 mole d'agent réticulant par groupement amine du polyaminoamide et alcoylés par action d'acide acrylique, d'acide chloracétique ou d'une alcane sultone ou de leurs sels.

c) in the proportions of 0 to 20 mole% of the radica) -NH- (CH) g -NH- derived from hexamethylenediamine, these polyaminoamines being crosslinked by addition of a bifunctional crosslinking agent chosen from epihalohydrins, diepoxides, dianhydrides, bis unsaturated derivatives, by means of from 0.025 to 0.30 moles of crosslinking agent per amine group of the polyaminoamide and alkylated by the action of acrylic acid, chloroacetic acid or an alkane sultone or their salts.

The saturated carboxylic acids are preferably chosen from acids having 6 to 10 carbon atoms, such as adipic acid, trimethyl-2,2,4-adipic acid and trimethyl-2,4,4-adipic acid, terephthalic acid, ethylenic double bond such as acrylic acid, methacrylic acid, itaconic acid.

<Desc / Clms Page number 19>

The alkanesultones used in the alkylation are preferably propane or butane sultone, the salts of the alkylating agents are preferably the sodium or potassium salts.

dans laquelle R20 désigne un groupement insaturé polymérisable tel qu'un groupement acrylate, méthacrylate, acrylamide ou méthacrylamide, y et z représentent un nombre entier de 1 à 3, R21 et R22 représentent un atome d'hydrogène, méthyle, éthyle ou propyl, R23 et R24 représentent un atome d'hydrogène ou un radical alkyle de telle façon que la somme des atomes de carbone dans R23 et R24 ne dépasse pas 10. (D) polymers having zwitterionic units of formula:

in which R 20 denotes a polymerizable unsaturated group such as an acrylate, methacrylate, acrylamide or methacrylamide group, y and z represent an integer of 1 to 3, R 21 and R 22 represent a hydrogen, methyl, ethyl or propyl atom, R 23 and R24 represents a hydrogen atom or an alkyl radical such that the sum of the carbon atoms in R23 and R24 does not exceed 10.

Polymers comprising such units may also comprise units derived from non-zwitterionic monomers such as dimethyl or diethylaminoethyl acrylate or methacrylate or alkyl acrylates or methacrylates, acrylamides or methacrylamides or vinyl acetate.

By way of example, the product sold under the name DIAFORMER Z301 by SANDOZ may be used.

(E) polymers derived from chitosan having monomeric units corresponding to the following formulas (10), (11), (12):

<Desc / Clms Page number 20>

dans laquelle : q=0 et R26' R26 et R28'identiques ou différents, représentent chacun un atome d'hydrogène, un reste méthyle, hydroxyle, acétoxy ou amino, un reste monoalcoylamine ou un reste dialcoylamine éventuellement interrompus par un ou plusieurs atomes d'azote et/ou éventuellement substitués par un ou plusieurs groupes amine, hydroxyle, carboxyle, alcoylthio, sulfonique, un reste alcoylthio dont le groupe alcoyle porte un reste amino, l'un au moins des radicaux Rg, R et R28 étant dans ce cas un atome d'hydrogène ; ou bien q=1 et R26' R27 et R28 représentent chacun un atome d'hydrogène, ainsi que les sels formés par ces composés avec des bases ou des acides. the unit (10) being present in proportions between 0 and 30%, the unit (11) in proportions of between 5 and 50% and the unit F in proportions of between 30 and 90%, it being understood that in this R25 represents a radical of formula

in which: q = 0 and R26 'R26 and R28'idental or different, each represent a hydrogen atom, a methyl, hydroxyl, acetoxy or amino residue, a monoalkylamine residue or a dialkylamine residue optionally interrupted by one or more carbon atoms; nitrogen and / or optionally substituted with one or more amine, hydroxyl, carboxyl, alkylthio, sulphonic groups, an alkylthio radical whose alkyl group carries an amino residue, at least one of the radicals Rg, R and R28 being in this case a hydrogen atom; or q = 1 and R26 'R27 and R28 each represent a hydrogen atom, as well as the salts formed by these compounds with bases or acids.

(F) The polymers derived from the N-carboxyalkylation of chitosan, such as N-carboxymethylchitosan or N-carboxybutylchitosan sold under the name "Evalsan" by the company Jan Dekker.

<Desc / Clms Page number 21>

dans laquelle R29 représente un atome d'hydrogène, un radical CH3O, CH3CH2O, phényle, R30 désigne l'hydrogène ou un radical alkyle en Ci-Ce tel que méthyle, éthyle, R31 désigne l'hydrogène ou un radical alkyle en C1-C6 tel que méthyle, éthyle, R32 désigne un radical alkyle en C1-C6 tel que méthyle, éthyle ou un radical

répondant à ! a formuie :-Rgg-N (R) 2, R33 représentant un groupement-CH-CH- ,-CH-CH-CH-,-CH-CH (CHg)-, Rg ayant les significations mentionnées ci- dessus, ainsi que les homologues supérieurs de ces radicaux et contenant jusqu'à 6 atomes de carbone. (G) The polymers corresponding to the general formula (13) such as those described for example in the French patent 1,400,366:

in which R29 represents a hydrogen atom, a CH3O, CH3CH2O radical, phenyl, R30 denotes hydrogen or a C1-C6 alkyl radical such as methyl, ethyl, R31 denotes hydrogen or a C1-C6 alkyl radical; such as methyl, ethyl, R32 denotes a C1-C6 alkyl radical such as methyl, ethyl or a radical

responding to ! has the formula: -Rgg-N (R) 2, R33 representing a-CH-CH-, -CH-CH-CH-, -CH-CH (CHg) -, Rg group having the meanings mentioned above, as well as the higher homologues of these radicals and containing up to 6 carbon atoms.

où A'désigne un radical

et B'désigne le symbole E ou E', E ou E'identiques ou différents désignent un radical bivalent qui est un radical alkylène à chaîne droite ou ramifiée comportant jusqu'à 7 atomes de carbone dans la chaîne principale non substituée ou (H) Amphoteric polymers of the type -A'-B'-A'-B'-selected from: a) the polymers obtained by the action of chloroacetic acid or sodium chloroacetate on compounds comprising at least one unit of formula :

where A'designs a radical

and B 'denotes the symbol E or E', E or E 'the same or different denotes a divalent radical which is a straight or branched chain alkylene radical having up to 7 carbon atoms in the unsubstituted main chain or

<Desc / Clms Page number 22>

où A"désigne un radical

et B"désigne le symbole E ou E'et au moins une fois E' ; E ayant la signification indiquée ci-dessus et E'est un radical bivalent qui est un radical alkylène à chaîne droite ou ramifiée ayant jusqu'à 7 atomes de carbone dans la chaîne principale, substitué ou non par un ou plusieurs radicaux hydroxyle et comportant un ou plusieurs atomes d'azote, l'atome d'azote étant substitué par une chaîne alkyle interrompue éventuellement par un atome d'oxygène et comportant obligatoirement une ou plusieurs fonctions carboxyle ou une ou plusieurs fonctions hydroxyle et bétaïnisées par réaction avec l'acide chloracétique ou du chloracétate de soude. substituted with hydroxyl groups and which may further comprise oxygen, nitrogen, sulfur, 1 to 3 aromatic and / or heterocyclic rings; the oxygen, nitrogen and sulfur atoms being present in the form of ether, thioether, sulfoxide, sulfone, sulfonium, alkylamine, alkenylamine, hydroxyl groups, benzylamine, amine oxide, quaternary ammonium, amide, imide groups, alcohol, ester and / or urethane; b) polymers of formula:

where A "denotes a radical

and B "denotes the symbol E or E 'and at least once E'; E having the meaning indicated above; and E 'is a divalent radical which is a straight or branched chain alkylene radical having up to 7 carbon atoms. carbon in the main chain, substituted or unsubstituted by one or more hydroxyl radicals and comprising one or more nitrogen atoms, the nitrogen atom being substituted by an alkyl chain optionally interrupted by an oxygen atom and having obligatorily one or several carboxyl functions or one or more hydroxyl functions and betainized by reaction with chloroacetic acid or sodium chloroacetate.

(J) (C1-C5) alkyl vinyl ether / maleic anhydride copolymers partially modified by semiamidation with an N, N-dialkylaminoalkylamine such as N, N-dimethylaminopropylamine or by semi-esterification with N, Ndialcanolamine. These copolymers may also comprise other vinylic comonomers such as vinylcaprolactam.

The amphoteric polymers that are particularly preferred according to the invention are those of the family (A).

<Desc / Clms Page number 23>

Selon la présente invention, les composés de type céramide sont notamment les céramides et/ou les glycocéramides et/ou les pseudocéramides et/ou les néocéramides, naturelles ou synthétiques.

According to the present invention, the ceramide-type compounds are in particular ceramides and / or glycoceramides and / or pseudoceramides and / or neoceramides, natural or synthetic.

Ceramide-type compounds are described, for example, in patent applications DE4424530, DE4424533, DE4402929, DE4420736, WO95 / 23807, WO94 / 07844, EP-A-0646572, WO95 / 16665, FR-2 673 179, EP-A- 0227994 and WO 94/07844, WO94 / 24097, WO94 / 10131, the teachings of which are hereby incorporated by reference.

- le 2-N-linoléoylamino-octadécane-1, 3-diol, - le 2-N-oléoylamino-octadécane-1, 3-diol, - le 2-N-palmitoylamino-octadécane-1, 3-diol, - le 2-N-stéaroylamino-octadécane-1, 3-diol, - le 2-N-béhénoylamino-octadécane-1, 3-diol, - le 2-N-[2-hydroxy-palmitoyl]-amino-octadécane-1, 3-diol, - le 2-N-stéaroyl amino-octadécane-1,3, 4 triol et en particulier la N-stéaroyl phytosphingosine,

- le 2-N-palmitoylamino-hexadécane-1, 3-diol - le (bis- (N-hydroxyéthyl N-cétyl) malonamide), - le N- (2-hydroxyéthyl)-N- (3-cétyloxy-2-hydroxypropyl) amide d'acide cétylique. Particularly preferred ceramide-type compounds according to the invention are, for example:

2-N-linoleoylamino-octadecane-1,3-diol, 2-N-oleoylamino-octadecane-1,3-diol, 2-N-palmitoylamino-octadecane-1,3-diol, 2-N-stearoylamino-octadecane-1,3-diol, 2-N-behenoylamino-octadecane-1,3-diol, 2-N- [2-hydroxy-palmitoyl] -aminooctadecane-1, 3-diol, 2-N-stearoyl aminooctadecane-1,3,4 triol and in particular N-stearoyl phytosphingosine,

2-N-palmitoylamino-hexadecane-1,3-diol (bis (N-hydroxyethyl-N-cetyl) malonamide), N- (2-hydroxyethyl) -N- (3-cetyloxy) -2- cetyl hydroxypropyl) amide.

 N-docosanoyl N-methyl-D-glucamine or mixtures of these compounds.

The carboxylic acid esters may be mono, di, tri or tetracarboxylic acid esters.

The acid esters according to the invention are especially saturated or unsaturated, linear or branched C 1 -C 26 aliphatic acid esters and saturated or unsaturated, linear or branched C 1 -C 6 aliphatic or monohydric alcohols.

<Desc / Clms Page number 24>

Among the monoacid esters, mention may be made of octyl octanoate; octyl isononanoate; 2-ethylhexyl isononate; octyl palmitate; octyl pelargonate; octyl stearate; oleyl eructe; ethyl palmitates and isopropyl palmitate, ethyl-2-hexyl palmitate, 2-octyldecyl palmitate, alkyl myristates such as isopropyl myristate, butyl, hexyl stearate, butyl stearate, isobutyl stearate; dioctyl malate, hexyl laurate ,.

Among the esters of di or tricarboxylic acids, there may be mentioned in particular: diethyl sebacate; diisopropyl sebacate; diisopropyl adipate di-propyl adipate; dioctyl adipate; dioctyl maleate, glyceryl undecylenate, dicaprylate or propylene glycol dicaprate; triisopropyl citrate, glyceryl trilactate; glyceryl trioctanoate.

Among the esters mentioned above, it is preferred to use ethyl and isopropyl palmitates, ethyl-2-hexyl palmitate, alkyl myristates such as isopropyl, butyl or cetyl myristate. 2-octyldodecyl, hexyl stearate, butyl stearate, isobutyl stearate; dioctyl malate, hexyl laurate.

The volatile cyclic silicones are more particularly chosen from those having a boiling point between 60 ° C. and 2600 ° C., and even more particularly from cyclic silicones containing from 3 to 7 silicon atoms and preferably from 4 to 5. It is is, for example, octamethylcyclotetrasiloxane sold in particular under the name "VOLATILE SILICONE 7207" by UNION CARBIOE or "SILBIONE 70045 V 2" by RHONE POULENC, decamethylcyclopentasiloxane marketed under the name "VOLATILE SILICONE 7158" by UNION CARBIDE, "SILBIONE 70045 V 5" by RHONE POULENC, as well as their mixtures.

Mention may also be made of cyclocopolymers of the dimethylsiloxane / methylakylsiloxane type, such as the "VOLATILE SILICONE FZ 3109" marketed by UNION CARBIDE, of chemical structure:

<Desc / Clms Page number 25>

CH-G'-----G-G'- 1 1 avec G :-St-0-avec G'-Si-0avec G : avec Gs-Si-O CH3 CgH,,

On peut également citer les mélanges de silicones cycliques avec des composés organiques dérivés du silicium, tels que le mélange d'octaméthylcyclotétrasiloxane et de tétratriméthylsilylpentaérythritol (50/50) et le mélange d'octaméthylcyclotétrasiloxane et d'oxy-1, 1' (hexa-2, 2,2', 2', 3, 3'-triméthylsilyloxy) bis-néopentane ; Les huiles de synthèse sont notamment les polyoléfines en particulier les poly-aoléfines et plus particulièrement de type polybutène, hydrogéné ou non, et de préférence polyisobutène, hydrogéné ou non.

CH-G '----- G-G'-1 1 with G: -St-O-with G'-Si-0 with G: with Gs-Si-O CH3 CgH ,,

Cyclic silicone mixtures with organic compounds derived from silicon may also be mentioned, such as the mixture of octamethylcyclotetrasiloxane and tetramethylsilylpentaerythritol (50/50) and the mixture of octamethylcyclotetrasiloxane and oxy-1,1 '(hexamethylcyclotetrasiloxane). 2,2,2 ', 2', 3,3'-trimethylsilyloxy) bis-neopentane; The synthetic oils are in particular polyolefins, in particular polyolefins and more particularly polybutene type, hydrogenated or otherwise, and preferably polyisobutene, hydrogenated or otherwise.

Isobutylene oligomers with a molecular weight of less than 1000 and their mixtures with polyisobutylenes with a molecular weight greater than 1000 and preferably between 1000 and 15000 are preferably used.

par la Société PRESPERSE Inc, ou bien encore les produits vendus sous le nom de ARLAMOL HD (n=3) par la Société ICI (n désignant le degré de polymérisation), de type polydécène, hydrogéné ou non. As examples of poly-α-olefins that may be used in the context of the present invention, mention may be made more particularly of the polyisobutenes sold under the name Perrmyl 99 A, 101 A, 102 A, 104 A (n = 16) and 106 A (n = 38)

by the company PRESPERSE Inc., or even the products sold under the name ARLAMOL HD (n = 3) by the company ICI (n denoting the degree of polymerization), polydecene type, hydrogenated or not.

Such products are sold, for example, under the names ETHYLFLO by the company ETHYL CORP., And ARLAMOL PAO by the company ICI.

Vegetable waxes are natural substances that are solid at room temperature (20-25 C). They can be optionally hydrogenated. They are insoluble in water, soluble in oils and are capable of forming a water-repellent film.

<Desc / Clms Page number 26>

On the definition of waxes, for example, D. Dorgan, Drug and Cosmetic Industry, December 1983, pp. 30-33.

The wax or vegetable waxes are chosen in particular from carnauba wax, candelilla wax, olive wax, rice wax, hydrogenated jojoba wax or absolute waxes of flowers such as essential flower wax. blackcurrant.

According to the invention, the conditioning compound (s) may represent from 0.01% to 10% by weight, preferably from 0.05% to 5% by weight, and still more preferably from 0.1% to 3% by weight. relative to the total weight of the composition.

Advantageously, the compositions of the invention may additionally contain one or more deodorant active agents and / or antiperspirant active agents.

2, 4, 4'-trichloro-2'-hydroxydiphényléther (Triclosan), le 2, 4-dichloro-2'hydroxydiphényléther, le 3', 4', 5'-trichlorosalicylanilide, la 1- (3', 4'-dichlorophenyl)-3- (4'-chlorophenyl) urée (triclocarban) ou le 3, 7, 11-triméthyldodéca-2, 5, 10-triénol (Farnesol). Among the deodorant active agents, mention may be made, for example, of zinc pyrrolidone carboxylate (more commonly known as zinc pidolate), zinc sulphate, zinc chloride, zinc lactate, zinc gluconate and zinc phenolsulfonate.

2,4,4'-trichloro-2'-hydroxydiphenyl ether (Triclosan), 2,4-dichloro-2-hydroxydiphenyl ether, 3 ', 4', 5'-trichlorosalicylanilide, 1- (3 ', 4') dichlorophenyl) -3- (4'-chlorophenyl) urea (triclocarban) or 3, 7, 11-trimethyldodeca-2,5,10-trienol (Farnesol).

Among the antiperspirant active agents that may be mentioned for example aluminum chlorohydrate, chlorohydrex aluminum, chlorohydrex aluminum PEG, aluminum chlorohydrex PG, aluminum dichlorohydrate, aluminum dichlorohydrex PEG, aluminum dichlorohydrex PG, l aluminum sesquichlorohydrate, aluminum sesquichlorohydrex PEG, aluminum sesquichlorohydrex PG, aluminum sulfate, aluminum zirconium octachlorohydrate, aluminum zirconium pentachlorohydrate, aluminum zirconium tetrachlorohydrate, aluminum zirconium trichlorohydrate, metal complexes ( as aluminum or zirconium) with an amino acid and as described in US-3792068. Such complexes are generally known as ZAG. The complexes

<Desc / Clms Page number 27>

 ZAG usually have a quotient AI / Zr ranging from about 1.67 to 12.5 and a quotient Metal / CI ranging from about 0.73 to 1.93.

The preferred amino acid for preparing such ZAG complexes is glycine. Among these products, mention may be made of aluminum zirconium octachlorohydrex GLY, aluminum zirconium pentachlorohydrex GLY, aluminum zirconium tetrachlorohydrate GLY and aluminum zirconium trichlorohydrate-GLY.

These deodorant or antiperspirant active agents are present in the composition according to the invention in a proportion of approximately 0 to 20% by weight relative to the total weight of the composition and preferably in a proportion of approximately 0.1 to 10% by weight.

The composition according to the invention is formulated conventionally according to the form of presentation for which it is intended.

It is more particularly formulated in a cosmetically acceptable vehicle which can be especially essentially aqueous, or contain organic solvents and in particular C 1 -C 4 monoalcohols, preferably ethanol to accelerate the evaporation of the product, or propylene glycol, dipropylene glycol or their ethers.

The composition according to the invention may also be formulated in emulsion water-in-oil, oil-in-water, or triple water-in-oil-in-water emulsion (such emulsions are known and described for example by C. FOX in "Cosmetics and You" etries "-November 1986-Vo) 101-pages 101-112).

The composition according to the invention may further comprise cosmetic adjuvants chosen from fats other than those of the invention, gelling agents, emollients, antioxidants, opacifiers, stabilizers, moisturizing agents, vitamins, perfumes preservatives, surfactants, fillers, sequestering agents, polymers other than those of the invention, propellants, basifying or acidifying agents, perfumes, dyes, pigments, polymeric or non-polymeric thickeners, or any other ingredient usually used in cosmetics for this type of application.

<Desc / Clms Page number 28>

 Of course, those skilled in the art will take care to choose this or these optional additional compounds in such a way that the advantageous properties intrinsically attached to the cosmetic composition in accordance with the invention are not, or substantially, impaired by the addition or additions envisaged. .

The surfactants are preferably chosen from anionic, amphoteric or nonionic surfactants.

d'alcools gras tels que les benzoates d'alcools gras en C12-C15 (Finsolv TN de FINETEX), l'alcool myristique polyoxypropyléné à 3 moles d'oxyde de propylène (WITCONOL APM de WITCOLes huiles sont choisies parmi les huiles animales, végétales, minérales ou de synthèse et notamment l'huile de palme hydrogénée, l'huile de ricin hydrogénée, l'huile de vaseline, l'huile de paraffine, l'huile de Purcellin (octanoate de stéaryle), les huiles de silicone et les isoparaffines. The additional fatty substances may consist of a vegetable or animal oil or a synthetic or animal wax, petrolatum, paraffin, lanolin, hydrogenated lanolin, acetylated lanolin; they also include fatty acids, fatty alcohols such as auric, cetyl, myristic, stearic, palmitic, oleic alcohol as well as 2-octyldodecanol, fatty acid esters and

fatty alcohols such as C12-C15 fatty alcohol benzoates (Finsolv TN FINETEX), polyoxypropylene myristic alcohol 3 moles of propylene oxide (WITCONOL APM WITCOLes oils are selected from animal oils, vegetable , mineral or synthetic and in particular hydrogenated palm oil, hydrogenated castor oil, liquid petrolatum, paraffin oil, purcellin oil (stearyl octanoate), silicone oils and isoparaffins.

The additional waxes may be chosen from beeswaxes, ozokerites, microcrystalline waxes, paraffins, waxes and silicone resins.

The non-polymeric thickeners may be chosen from silicas such as, for example, the Bentone Gel MiO sold by the company NL Industries or the Veegum Ultra, sold by the company Polyplastic.

The composition according to the invention may comprise emollients, which contribute to a soft, dry, non-sticky feel when the composition is applied to the skin. These emollients can be chosen from non-volatile silicones and other non-volatile emollients.

<Desc / Clms Page number 29>

Nonvolatile silicones are defined in a known manner as compounds with low vapor pressure at ambient temperature. Among these compounds are included: polyalkylsiloxanes, in particular linear polyalkylsiloxanes, for example linear polydimethylsiloxanes, or dimethicones, marketed by Dow Corning under the name "Dow Corning 200 Fluid"; polyalkylarylsiloxanes, for example polymethylphenylsiloxanes, marketed by Dow Corning under the name "Dow Corning 556 Fluid"; polyether and siloxane copolymers, for example dimethicone copolyols.

Among the non-volatile emollients that can be used in the present invention, there may be mentioned, for example: hydrocarbon derivatives, mineral oils, fatty alcohols.

The amounts of these various constituents that may be present in the cosmetic composition according to the invention are those conventionally used for the presentation forms considered.

The composition according to the invention may thus be in the form of a lotion, a cream or a fluid gel dispensed in an aerosol spray, in a pump bottle or in a roll-on, in the form of a thick cream distributed in a tube and in the form of a stick or a powder, and contain in this respect the ingredients and propellants generally used in this type of products and well known to those skilled in the art.

Concrete but non-limiting examples illustrating the invention will now be given.

<Desc / Clms Page number 30>

Example 1

<Tb>
<tb> Alcohol <SEP> cetylstearyl alcohol <SEP> (NAFOL <SEP> 1618F <SEP> of <SEP> CONDEA) <SEP> 2.5 <SEP> g
<tb> Alcohol <SEP> cetylstearyl alcohol <SEP> to <SEP> 33 <SEP> moles <SEP> of OE <SEP> (EMULDAC <SEP> AS <SEP> 25 <SEP> of <SEP> CONDEA) <SEP > 1.25 <SEP> g
<tb> Monostearate <SEP> of <SEP> sorbitan <SEP> (TWEEN <SEP> 60 <SEP> of <SEP> HERE) <SEP> 2.2 <SEP> g
<tb> Alcohol <SEP> Stearyl <SEP> (ACILOL <SEP> 18 <SEP> from <SEP> AEGIS <SEP> CHEMICAL) <SEP> 0.3 <SEP> g
<tb> Isohexadecane <SEP> 6.0 <SEP> g
<tb> Propylene <SEP> Glycol <SEP> 3.0 <SEP> g
<tb>4,4'-dihydroxy<SEP> diphenyl <SEP> ether <SEP> 2.0 <SEP> g
<tb> Homopolymer
<tb> chloride <SEP> of <SEP> dimethylamilylammonium <SEP> (SEQUAR <SEP> 100 <SEP> of <SEP> CALGON) <SEP> 0.5 <SEP> g <SEP> MA
<tb> Conservatives <SEP> qs
<tb> Demineralized <SEP> water <SEP> qsp <SEP> 100, <SEP> 0g
<Tb>
Example 2

<Tb>
<tb> Alcohol <SEP> cetylstearyl alcohol <SEP> (NAFOL <SEP> 1618F <SEP> of <SEP> CONDEA) <SEP> 2.5 <SEP> g
<tb> Alcohol <SEP> cetylstearyl alcohol <SEP> to <SEP> 33 <SEP> moles <SEP> of OE <SEP> (EMULDAC <SEP> AS <SEP> 25 <SEP> of <SEP> CONDEA) <SEP > 1.25 <SEP> g
<tb> Monostearate <SEP> of <SEP> sorbitan <SEP> (TWEEN <SEP> 60 <SEP> of <SEP> HERE) <SEP> 2.2 <SEP> g
<tb> Alcohol <SEP> Stearyl <SEP> (ACILOL <SEP> 18 <SEP> from <SEP> AEGIS <SEP> CHEMICAL) <SEP> 0.3 <SEP> g
<tb> Propylene <SEP> Glycol <SEP> 3.0 <SEP> g
<tb>4,4'-dihydroxy<SEP> diphenyl <SEP> ether <SEP> 2.0 <SEP> g
<tb> Myristate <SEP> isopropyl <SEP> 5.0 <SEP> g
<tb> Conservatives <SEP> qs
<tb> Demineralized <SEP> water <SEP> qsp <SEP> 100, <SEP> 0g
<Tb>

<Desc / Clms Page number 31>

Example 3

<Tb>
<tb> Alcohol <SEP> cetylstearyl alcohol <SEP> (NAFOL <SEP> 1618F <SEP> of <SEP> CONDEA) <SEP> 2, <SEP> 5 <SEP> g
<tb> Alcohol <SEP> cetylstearyl alcohol <SEP> to <SEP> 33 <SEP> moles <SEP> of OE <SEP> (EMULDAC <SEP> AS <SEP> 25 <SEP> of <SEP> CONDEA) <SEP > 1,25g
<tb> Monostearate <SEP> of <SEP> sorbitan <SEP> (TWEEN <SEP> 60 <SEP> of <SEP> HERE) <SEP> 2.2 <SEP> g
<tb> Alcohol <SEP> Stearyl <SEP> (ACILOL <SEP> 18 <SEP> from <SEP> AEGIS <SEP> CHEMICAL) <SEP> 0.3 <SEP> g
<tb> Isohexadecane <SEP> 6.0 <SEP> g
<tb> Propylene <SEP> Glycol <SEP> 3.0 <SEP> g
<tb>4,4'-dihydroxy<SEP> diphenyl <SEP> ether <SEP> 2.0 <SEP> g
<tb> Octamethylcyclotetrasiloxane
<tb> (VOLATILE <SEP> SILICONE7207 <SEP> of UNION <SEP> CARBIDE) <SEP> 5.0 <SEP> g
<tb> Conservatives <SEP> qs
<tb> Demineralized <SEP> Water <SEP> qsp <SEP> 100, <SEP> 0 <SEP> g
<tb> MA <SEP> meaning <SEP> active <SEP> materials.
<Tb>

Claims (35)

1. Cosmetic or dermopharmaceutical composition, characterized in that it contains: a) at least one hydroxydiphenyl ether derivative of formula (1):

 Wherein R1, R2, R3 and R4, which may be identical or different, denote Z, OZ, COZ, COOZ, CONZZ ', C6-C30 aryl or C7-C40 aralkyl or C7-C40 alkylaryl optionally substituted by a or more groups selected from OH, NH2, halogen, carboxy, or C1-C30 alkoxycarbonyl; Z and Z ', which may be identical or different, denote H, a linear or branched, cyclic or acyclic, saturated or unsaturated, C1-C30 hydrocarbon radical, interrupted or not by one or more heteroatoms or carbonyl groups, substituted or unsubstituted by one or more chosen groups from OH, NH2, halogen, carboxy or C1-C30 alkoxycarbonyl; b) at least one conditioning agent chosen from: - cationic or amphoteric conditioning polymers - ceramides - esters of fatty acids and short chain alcohols - cyclic volatile silicones - synthetic oils - vegetable waxes 2. Composition according to Claim 1, characterized in that the compound of formula (1) is chosen from the following compounds: 2,4'-Dihydroxy diphenyl ether 2-hydroxy 2'-ethyl diphenyl ether 2-hydroxy 2'-isopropyl diphenyl ether 2-hydroxy 2'-methyl diphenyl ether 2-hydroxy 2'-sec. butyl diphenyl ether 2-hydroxy 2'-tert. butyl diphenyl ether <Desc / Clms Page number 33>  2-hydroxy-3-butanoyl-diphenyl ether 2-hydroxy-3-propanol diphenyl ether 2-hydroxy-4-formyl-diphenyl ether 2-hydroxy-4'-methyl-5-formyl diphenyl ether 2-hydroxy-5-butanoyl diphenyl ether 2-hydroxy-5-formyl-diphenyl ether 2-Hydroxy-diphenyl ether 3-hydroxy-2'-methyl-diphenyl ether 3-hydroxy 2'-sec. butyl diphenyl ether 3-hydroxy 2'-methyl 4-n-propyl diphenyl ether 3-hydroxy 3'-methyl diphenyl ether 3-hydroxy 3'-methyl 4-n-propyl diphenyl ether 3-hydroxy-4 ( 1-hydroxy-2-methylpropyl) diphenyl ether 3-hydroxy-4-butanoyl-diphenyl ether 3-hydroxy-4-butyl-diphenyl ether 3-hydroxy-4-dimethylpropyl-diphenyl ether 3-hydroxy-4-dimethylpropyl-3'-methyl-diphenyl ether 3-hydroxy 4-hexyl diphenyl ether 3-hydroxy 4-hexanoyl diphenyl ether 3-hydroxy 4-dodecyl diphenyl ether 3-hydroxy 4-isobutanol diphenyl ether 3-hydroxy 4-isobutyl diphenyl ether 3-hydroxy-4 isopentanol diphenyl ether 3-hydroxy 4-isopropyl diphenyl ether 3-hydroxy 4'-isopropyl diphenyl ether 3-hydroxy 4-n-butyl diphenyl ether 3-hydroxy 4-n-butyl diphenyl ether 3-hydroxy-4- n-pentyl diphenyl ether 3-hydroxy 4-n-propyl diphenyl ether 3-hydroxy 4-pentanoyl diphenyl ether 3-hydroxy 4-pentyl diphenyl ether 3-Hydro xy 4-phenylethyl diphenyl ether 3-hydroxy 2'-methyl 4-phenylethyl diphenyl ether <Desc / Clms Page number 34> 4-hydroxy diphenyl ether 3. Composition according to claim 1 or 2, characterized in that the concentration of compound (s) of formula (1) ranges from 0.001 to 20% by weight, preferably from 0.01 to 15% by weight and more preferably deO. 1 to 10% by weight relative to the total weight of the composition. 4-hydroxy 4'-propanoyl diphenyl ether 4-hydroxy 4'-trifluoromethyl diphenyl ether 4-hydroxy-4'-propyl diphenyl ether 4-hydroxy-4'-phenylethyl diphenyl ether 4-hydroxy-4'-nonyl diphenyl ether 4-hydroxy 4'-ethyl diphenyl ether 4-hydroxy-4'-dimethylpropyl diphenyl ether 4-hydroxy-3- (3-methylbuthyl) -4 '- (3-ethylbuthyl) diphenyl ether 4-hydroxy 2'-isopropyl-4-phenylethyl diphenyl ether 4-hydroxy 2'-isopropyl diphenyl ether 4-hydroxy 2'-isopropyl 5'-methyl diphenyl ether 4-hydroxy 2'-isopropyl-4'-propyl diphenyl ether 4-hydroxy 2'-isopropyl 4'-ethyl diphenyl ether 4-hydroxy 2'-cyclohexyl 5'-methyl diphenyl ether 4-hydroxy 2 ', 5'-dimethyl diphenyl ether 4-hydroxy 2'-tert. butyl 5'-methyl diphenyl ether 4-hydroxy 2'-methyl 5'-isopropyl diphenyl ether 4,4'-dihydroxy diphenyl ether 3,4'-Dihydroxy diphenyl ether 3-hydroxy diphenyl ether 3-hydroxy-4-propanol diphenyl ether 3-hydroxy-3'-methyl-4-phenylethyl diphenyl ether 4. Composition according to any one of claims 1 to 3, characterized in that the cationic polymers are chosen from those containing units containing primary, secondary, tertiary and / or quaternary amine groups that can be part of the chain. main polymer, to be carried by a lateral substituent directly connected thereto. <Desc / Clms Page number 35> 5. Composition according to any one of claims 1 to 4, characterized in that the cationic polymers used have a number-average molecular mass ranging from about 500 to about 5 × 10 6 and preferably ranging from about 10 3 to about 10 6. . 6. Composition according to any one of claims 1 to 5, characterized in that the cationic polymers are of the polyamine, polyaminoamide and quaternary polyammonium type.  in which :

7. Composition according to Claim 6, characterized in that the cationic polymers are chosen from: (1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the following units of formulas: <Desc / Clms Page number 36>  Ru, identical or different, denote a hydrogen atom or a CH3 radical; A, which may be identical or different, represent a linear or branched alkyl group of 1 to 6 carbon atoms or a hydroxyalkyl group of 1 to 4 carbon atoms; R, R, Rg, which may be identical or different, represent an alkyl group having from 1 to 18 carbon atoms or a benzyl radical; R1 and R2, which may be identical or different, represent hydrogen or an alkyl group having from 1 to 6 carbon atoms; X denotes an anion derived from a mineral or organic acid or a halide.

(II) cellulose ether derivatives having hydroxyethylcellulose ammonium groups that have reacted with a trimethylammonium-substituted epoxide. (III) cationic cellulose derivatives (IV) guar gums containing cationic trialkylammonium groups. (V) polymers consisting of piperazinyl units and straight or branched chain alkylene or hydroxyalkylene divalent radicals, optionally interrupted by oxygen, sulfur, nitrogen or aromatic or heterocyclic rings, as well as oxidation and / or quaternization of these polymers.  (VI) water-soluble polyaminoamides prepared in particular by polycondensation of an acidic compound with a polyamine; (Vil) polyaminoamide derivatives resulting from the condensation of polyalkylene olyalkylenes with polycarboxylic acids followed by alkylation with difunctional agents. (VIII) polymers obtained by reacting a polyalkylene polyamine containing two primary amine groups and at least one amine group <Desc / Clms Page number 37>  Wherein R13 'R14' R15 and R16 ', which are the same or different, represent aliphatic, alicyclic, or arylaliphatic radicals containing from 1 to 15 carbon atoms; 20 carbon atoms or lower hydroxyalkylaliphatic radicals, or Rg, R, R and R1g, together or separately, together with the nitrogen atoms to which they are attached, form heterocycles optionally containing a second heteroatom other than nitrogen or R13. R14 'R15 and R16 represent a linear or branched C1-C6 alkyl radical substituted with a nitrile, ester, acyl, amide group orCO-O-R17-Q or -CO-NH-RyQ where R17 is alkylene and Q is an ammonium group quaternary; A1 and 81 represent polymethylene groups containing from 2 to 20 carbon atoms which may be linear or branched, saturated or unsaturated, and may contain, bound to or intercalated in the main chain, one or more aromatic rings, or one or more atoms of oxygen, sulfur or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and X- denotes an anion derived from a mineral or organic acid; Ai, R13 and R15 can form with the two nitrogen atoms to which they are attached a piperazine ring; furthermore, if A1 denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, Bi can also denote a (CH 2) n -CO-D-OC- (CH 2) n-group;

 secondary with a dicarboxylic acid; the resulting polyaminoamide being reacted with epichlorohydrin (IX) cyclopolymers of alkyl diallyl amine or dialkyl diallyl ammonium (X) quaternary diammonium polymer containing recurring units having the formula: <Desc / Clms Page number 38>  (XII) quaternary polymers of vinylpyrrolidone and vinylimidazole;

 Where p is 0 or an integer between 1 and 6, provided that R18 'R19' R20 and R21 do not simultaneously represent a hydrogen atom, r and s, which are identical or different, are integers between 1 and 6, q is 0 or an integer of 1 to 34, X- is an anion such as halogen, A is a radical of a dihalide or is preferably

 wherein R18'R19'20 and R21'identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, ss-hydroxyethyl, ss-hydroxypropyl or

 where x and y denote an integer from 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing an average degree of polymerization; b) a bis-secondary diamine residue such as a piperazine derivative; c) a bis-primary diamine residue of formula: -NH-Y1-NH-, where Y1 denotes a linear or branched hydrocarbon radical, or the divalent radical -CH2-CH2-S-S-CH2-CH2-; d) a ureylene group of formula: -NH-CO-NH-;

 in which D denotes: a) a glycol residue of formula: -O-Z1-O-, where Z1 denotes a linear or branched hydrocarbon radical or a group corresponding to one of the following formulas: <Desc / Clms Page number 39>  wherein R19 represents a divalent radical derived from a saturated dicarboxylic acid, an ethylenically double bonded mono or dicarboxylic aliphatic acid, a lower alkanol ester having 1 to 6 carbon atoms, and

 (XIV) cross-linked polymers of methacryloyloxy (C 1 -C 6) alkyl salts; kyt (Ci- C4) ammonium 8. Composition according to any one of claims 1 to 5, characterized in that the cationic polymers are chosen from proteins or hydrolysates of cationic proteins 9. Composition according to any one of claims 1 to 3, characterized in that the amphoteric polymers are chosen from: (A) The polymers resulting from the copolymerization of a monomer derived from a vinyl compound carrying a carboxylic group and a basic monomer derived from a substituted vinyl compound containing at least one basic atom; (B) polymers comprising units derived from: a) at least one monomer chosen from acrylamides or methacrylamides substituted on the nitrogen with an alkyl radical; b) with at least one acidic comonomer containing one or more carboxylic groups reagents, and c) at least one basic comonomer such as primary, secondary, tertiary and quaternary amine substituent esters of acrylic and methacrylic acids and the quaternization product of dimethylaminoethyl methacrylate with dimethyl or diethyl sulfate; (C) Polyamino amides crosslinked and alkylated partially or totally derived from polyamino amides of general formula:

 (XIII) polyamines <Desc / Clms Page number 40>  in which R 20 denotes a polymerizable unsaturated group such as an acrylate, methacrylate, acrylamide or methacrylamide group, y and z represent an integer of 1 to 3, R 21 and R 22 represent a hydrogen, methyl, ethyl or propyl atom, R 23 and R24 represents a hydrogen atom or an alkyl radical such that the sum of the carbon atoms in R23 and R24 does not exceed 10.

 these acids or a radical derived from the addition of any one of said acids with a primary bis or secondary bis amine, and Z2 denotes a radical of a bis-primary, mono or bis-secondary polyalkylene polyamine (D ) polymers having zwitterionic units of formula:

 the unit (10) being present in proportions between 0 and 30%, the unit (11) in proportions of between 5 and 50% and the unit F in proportions of between 30 and 90%, it being understood that in this R25 represents a radical of formula

(E) polymers derived from chitosan having monomeric units corresponding to the following formulas (10), (11), (12): <Desc / Clms Page number 41>

 in which: q = 0 and Rg, R and R28'identical or different, each represent a hydrogen atom, a methyl, hydroxyl, acetoxy or amino residue, a monoalkylamine residue or a dialkylamine residue optionally interrupted by one or more carbon atoms; nitrogen and / or optionally substituted with one or more amine, hydroxyl, carboxyl, alkylthio, sulfonic acid, an alkylthio radical whose alkyl group carries an amino residue, at least one of R26'R27 and R28 being in this case a hydrogen atom; or q = 1 and Rg, R and R28 each represent a hydrogen atom, as well as the salts formed by these compounds with bases or acids; (F) polymers derived from the N-carboxyalkylation of chitosan (G) polymers corresponding to the general formula (13):  in which R29 represents a hydrogen atom, a radical CH3O, CH3CH2O, phenyl, R30 denotes hydrogen or a C1-C6 alkyl radical, Rdésigne the hydrogen or a C1-C6 alkyl radical, R32 denotes an alkyl radical; in Ci-Ce or a radical responding to! has the formula: -Rgg-N (Rg, R representing a group -CH-CH-, -CH-CH-CH-, -CH-CH (CHg) -, Rg having the meanings mentioned above, as well as the homologues higher of these radicals and containing up to 6 carbon atoms;

<Desc / Clms Page number 42>  and B "denotes the symbol E or E 'and at least once E'; E having the meaning indicated above; and E 'is a divalent radical which is a straight or branched chain alkylene radical having up to 7 carbon atoms. carbon in the main chain, substituted or unsubstituted by one or more hydroxyl radicals and comprising one or more nitrogen atoms, the nitrogen atom being substituted by an alkyl chain optionally interrupted by an oxygen atom and having obligatorily one or several carboxyl functions or one or more hydroxyl functional groups and betainized by reaction with chloroacetic acid or sodium chloroacetate;

 where A "denotes a radical

 and B 'denotes the symbol E or E', E or E 'the same or different denotes a divalent radical which is a straight or branched chain alkylene radical having up to 7 carbon atoms in the unsubstituted or substituted main chain. hydroxyl groups and may further comprise oxygen, nitrogen, sulfur, 1 to 3 aromatic and / or heterocyclic rings; the oxygen, nitrogen and sulfur atoms being present in the form of ether, thioether, sulfoxide, sulfone, sulfonium, alkylamine, alkenylamine, hydroxyl groups, benzylamine, amine oxide, quaternary ammonium, amide, imide groups, alcohol, ester and / or urethane; b) polymers of formula:

 where A'designs a radical

 (H) amphoteric polymers of the type -A'-B'-A'-B'-selected from: a) the polymers obtained by the action of chloroacetic acid or sodium chloroacetate on compounds comprising at least one unit of formula : <Desc / Clms Page number 43>  (J) (C 1 -C 4) alkyl vinyl ether / maleic anhydride copolymers partially modified by semiamidation with N, N-dialkylaminoalkylamine or by semi-esterification with N, N-dialkanolamine. 10. Composition according to any one of claims 1 to 3, characterized in that the ceramide-type compounds include ceramides and / or glycoceramides and / or pseudoceramides and / or neoceramides, natural or synthetic.  2-N-palmitoylamino-hexadecane-1,3-diol (bis (N-hydroxyethyl-N-cetyl) malonamide), N- (2-hydroxyethyl) -N- (3-cetyloxy) -2- cetyl hydroxypropyl) amide.

 Ceramide-type compounds are chosen from: 2-N-linoleoylamino-octadecane-1,3-diol, 2-N-oleoylamino-octadecane-1,3-diol, 2-N-palmitoylamino-octadecane; 1,3-diol, 2-N-stearoylaminooctadecane-1,3-diol, 2-N-behenoylaminooctadecane-1,3-diol, 2-N- [2-hydroxy-palmitoyl] ] -amino-octadecane-1,3-diol, 2-N-stearoyl aminooctadecane-1,3,4-triol and in particular N-stearoyl phytosphingosine,

11. Composition according to claim 10, characterized in that the  N-docosanoylN-methyl-D-glucamine or mixtures of these compounds. 12. Composition according to any one of claims 1 to 3, characterized in that the carboxylic acid esters are mono, di, tri or tetracarboxylic acid esters. <Desc / Clms Page number 44> 13. Composition according to Claim 12, characterized in that the carboxylic acid esters are chosen from linear or branched C 1 -C 26 saturated or unsaturated aliphatic acid esters and linear or saturated aliphatic or unsaturated aliphatic or polyalcohols. or branched C 1 -C 8. 14. Composition according to Claim 13, characterized in that the carboxylic acid esters are chosen from ethyl and isopropyl palmitates, ethyl-2-hexyl palmitate, alkyl myristates such as isopropyl, butyl, cetyl, 2-octyldodecyl myristate, hexyl stearate, butyl stearate, isobutyl stearate; dioctyl malate, hexyl laurate.  15. Composition according to any one of claims 1 to 3, characterized in that the volatile cyclic silicones are chosen from those having a boiling point between 600 C and 260 C. 16. Composition according to Claim 15, characterized in that the volatile cyclic silicones are chosen from cyclic silicones containing from 3 to 7 silicon atoms and preferably from 4 to 5. 17. Composition according to any one of claims 1 to 3, characterized in that the synthetic oils are chosen from poly-α-olefins 18. Composition according to Claim 17, characterized in that the polyolefins are chosen from: polyisobutenes, hydrogenated or otherwise. polydecenes, hydrogenated or not.  Candelila, olive wax, rice wax, hydrogenated jojoba wax or absolute waxes of flowers such as blackcurrant essential wax.

19. Composition according to any one of claims 1 to 3, characterized in that the vegetable waxes are chosen from carnauba wax, the wax of <Desc / Clms Page number 45>  20. Composition according to any one of claims 1 to 19, characterized in that the conditioning agent or agents represent from 0.01% to 10% by weight relative to the total weight of the composition. 21. Composition according to Claim 20, characterized in that the conditioning agent or agents represent from 0.05% to 5% by weight relative to the total weight of the composition. 22. Composition according to Claim 21, characterized in that the conditioning agent or agents represent from 0.1% to 3% by weight relative to the total weight of the composition. 23. Composition according to any one of claims 1 to 22, characterized in that it further contains at least one deodorant active and / or at least one antiperspirant active.  (4'-chlorophenyl) urea (triclocarban) or 3, 7, 11-trimethyldodeca-2,5,10-trienol (Farnesol).

24. Composition according to Claim 23, characterized in that the deodorant active agent is chosen from zinc pyrrolidone carboxylate, zinc sulphate, zinc chloride, zinc lactate, zinc gluconate and zinc phenolsulfonate. 2,4,4'-trichloro-2'-hydroxydiphenyl ether (Triclosan), 2,4-dichloro-2-hydroxydiphenyl ether, 3 ', 4', 5'-trichlorosalicylanilide, 1- (3 ', 4') 'dichlorophenyl) -3- 25. A composition according to claim 24, characterized in that the antiperspirant active is selected from aluminum chlorohydrate, aluminum chlorohydrex, aluminum chlorohydrex PEG, aluminum chlorohydrex PG, aluminum dichlorohydrate, aluminum dichlorohydrex PEG, aluminum dichlorohydrex PG, aluminum sesquichlorohydrate, aluminum sesquichlorohydrex PEG, aluminum sesquichlorohydrex PG, aluminum sulfate, aluminum zirconium octachlorohydrate, aluminum zirconium pentachlorohydrate, aluminum zirconium tetrachlorohydrate, aluminum zirconium trichlorohydrate, metal complexes (such as aluminum or zirconium) with an amino acid <Desc / Clms Page number 46>  26. Composition according to claim 25, characterized in that the amino acid used with the metal complexes is glycine. 27. Composition according to Claim 26, characterized in that the complexes are chosen from aluminum zirconium octachlorohydrex GLY, aluminum zirconium pentachlorohydrex GLY, aluminum zirconium tetrachlorohydrate GLY and aluminum zirconium trichlorohydrate-GLY. 28. Composition according to any one of Claims 24 to 27, characterized in that the deodorant or antiperspirant active agents are present in the composition according to the invention in a proportion of approximately 0.001 to 20% by weight relative to the total composition. . 29. Composition according to any one of claims 1 to 28, characterized in that it is formulated in a cosmetically acceptable vehicle which contains water and / or one or more organic solvents. 30. Composition according to claim 29, characterized in that the organic solvent is chosen from C1-C4 monoalcohols, propylene glycol, dipropylene glycol or their ethers. 31. Composition according to claim 30, characterized in that the organic solvent is ethanol. 32. A composition according to any one of claims 1 to 31, characterized in that it is formulated as a water-in-oil emulsion, oil-ineau, or triple emulsion water-in-oil-in -water <Desc / Clms Page number 47>  33. Composition according to any one of claims 1 to 32, characterized in that it contains one or more cosmetic adjuvants chosen from fatty substances other than those of the invention, emollients, antioxidants, opacifiers, stabilizers, moisturizers, vitamins, perfumes, preservatives, surfactants, fillers, sequestering agents, polymers other than those of the invention, propellants, basifying or acidifying agents, perfumes, dyes, pigments, polymeric or non-polymeric thickeners, or any other ingredient usually used in cosmetics. 34. Composition according to any one of claims 1 to 33, characterized in that it is in the form of lotion, cream or fluid gel dispensed aerosol spray, pump bottle or roll-on, in the form of thick cream distributed in tube and in the form of stick or powder. 35. A method for preventing or reducing the development of body sweat odors, characterized in that it consists in using a composition according to any one of claims 1 to 34.