FR2802807A1 - Decorative cosmetic composition for coloring lips, eyes and nails comprises plant extracts and oils - Google Patents

Abstract

A cosmetic decorative composition comprises: (a) plant extracts selected from Pterocarpus, Vaccinium and Glycyrrhiza; and (b) an oil.

Description

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 The present invention relates to the field of make-up cosmetology and relates to new preparations which, in addition to fatty substances, contain special plant extracts, as well as the use of extracts to make cosmetic make-up preparations.

 The desire to look beautiful and attractive has been rooted in men for millennia. Although the agents or products with which this objective was to be achieved have been constantly modified, modern beauty care products contain a greater or lesser proportion of dyes to modify the face, the area of the eyes, the lips and nails through the color. In addition, special components exert additional actions of skin care or skin protection. Dyes used are white pigments such as talc, zinc oxide, kaolin, titanium dioxide, inorganic dye pigments, such as iron oxides, chromium oxides, ultramarine pigment, manganese violet, and organic coloring pigments. In addition, pigments such as bismuth oxychloride, mica, titanium dioxide-coated mica and pearl essence, which generates a pearly luster, are also often used. In the area of the eyes and the lips, only dyes which have a corresponding tolerance of the mucous membranes must be used according to the law. The great diversity of dyes, which is made all the more important by the number of skincare products, makes the formulation of makeup cosmetics costly and problematic. It is not uncommon that materials can not be homogeneously mixed, so that separation, which certainly does not deteriorate the product immediately, occurs particularly during prolonged storage or thermal load. but gives it an unfavorable appearance. It is immediately clear that a consumer whose lipstick is hot or whose

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 nail separates after a few weeks will not renew its purchase decision.

The object of the present invention has therefore been to provide new makeup cosmetic preparations as a rule, in particular new dyes, which are characterized in that they combine a high dyeing power with a particular stability and optimal cosmetic compatibility for the skin. At the same time, dyes should meet the expectations of consumers wishing products of plant origin
The subject of the present invention relates to cosmetic makeup preparations which are characterized in that they comprise (a) at least one plant extract selected from the group which is formed by the Pterocarpus, Vaccinium and Glycyrrhiza families, and (b) at least one fatty substance.

 Surprisingly, it has been discovered that the named plant extracts have not only a high dyeing power, but that they themselves possess certain emulsifying properties, which not only facilitates their mixing in formulations containing oil, but also considerably improves the stability of the products obtained - as long as it is oil-in-water or water-in-oil emulsions.

Another advantage lies in the fact that the extracts are of vegetable origin and that they meet the high requirements for compatibility with the skin and the mucous membranes of the eye.

Vegetable extracts

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Extracts of the plants of the family Pterocarpus represent the first group of appropriate extracts. Concrete examples are the extracts of Pterocarpus macrocarpus, P. santalinus (red sandalwood), P. angolensis, P. indicus, P. soyaauxii; in view of the technique of use, it is the extract of Pterocarpus marsupium which has proved especially interesting. In this respect, reference is made, for example, to the French patent FR-B1-2483228 (Pierre Fabre), by which hair dyes based on extracts of Pterocarpus are known. The use of Pterocarpus extracts as hair oxidative dyes is also disclosed in Japanese Patent Application JP-A1 Hei 10/182372 (Lion). The subject of international patent application WO 98/44902 (L'Oreal) is finally a self-tanning agent having a content of sandalwood extract and a cosmetically acceptable fatty substance. J. Verghese, in Cosm. Toil. 101 (4), 69 (1986) deals with the use of sandalwood extract as a general rule. The main components of Pterocarpus extracts are santalines (see formula 1), sterols and flavonoids.

 Similarly, plant extracts of the family Vaccinium (blueberry), which forms the second group, are essentially known. In particular, the extract of Vaccinium myrtillus was found in this respect

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particularly appropriate. The topical use of extracts of this type is for example the subject of French patents FR-B1 2612775 (Thorel), FR-B1-2659556 (Mu Lab Eurl) and FR-B1 2695318 (Metsada). Bilberry extracts are characterized by a particular content of anthocyanosides, proanthocyanidins and flavonoids
A third group of extracts relates to plant extracts of the species Glycyrrhiza (licorice), such as Glycyrrhiza uralensis or in particular Glycyrrhiza glabra. The corresponding extracts have also long been known for topical application. Thus, for example, DE-A1 19654508 (Lancaster) and WO 98/34591 (Procter & Gambia) disclose skin care products comprising licorice extracts. The subject of the international patent application WO 98/17293 (Indena) relates to acne agents which also contain extracts of Glycyrrhiza. The anti-inflammatory action of the extracts, for example in case of sunburn, is also described in Japanese Patent Application JP-A1 Hei 05/070349 (Maruzen). The extracts are recommended as depigmenting agents in Japanese Patent Application JP-A1 Hei 06/263624 (Mochida). The main components of the extracts are glycerhretic acids (3p-hydroxy-11-oxoolean-12-ene-30, II acid) and glycyrrhizin (III):

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The preparation of plant extracts can be carried out in a manner known per se, namely by aqueous extraction, but preferably alcoholic. After separation of the extraction product, the extracts are collected in the usual manner in a cosmetic oil, silicone oils, for example dimethicone copolyol, having proved particularly advantageous for the manufacture of cosmetic makeup preparations precisely.

Fat body
Suitable fatty substances are, for example, 6 to 18, preferably 8 to 10 carbon, fatty alcohol Guerbet alcohols, linear C 6 to C 22 fatty acid esters with alcohols. C6 to C22 linear fatty acids, C6 to C13 branched chain carboxylic esters with linear C6 to C22 fatty alcohols, such as, for example, myristyl myristate, myristyl palmitate, myristyl stearate, isostearate, myristyl, myristyl oleate, myristyl behenate, myristyl erucate, cetyl myristate, cetyl palmitate, cetyl stearate, cetyl isostearate, cetyl oleate, cetyl behenate , cetyl erucate, stearyl myristate, stearyl palmitate, stearyl stearate, stearyl isostearate, stearyl oleate, stearyl behenate, stearyl erucate, isostearyl myristate , isostearyl palmitate, sté isostearyl arate, isostearyl isostearate, isostearyl oleate, isostearyl behenate, isostearyl erucate, oleyl myristate, oleyl palmitate, oleyl stearate, oleyl isostearate, oleyl oleate, oleyl behenate, oleyl erucate, behenyl myristate, behenyl palmitate, behenyl stearate, behenyl isostearate, behenyl oleate, behenyl behenate, behenyl erucate, myristate

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 erucyl, erucyl palmitate, erucyl stearate, erucyl isostearate, erucyl oleate, erucyl behenate and erucyl erucate.

Also suitable are esters of linear C 6 -C 22 fatty acids with branched alcohols, particularly 2-ethylhexanol, hydroxycarboxylic acid esters with linear or branched C 6 -C 22 fatty alcohols, particularly dioctyl malate, linear fatty acid esters and / or branched with polyols (such as for example propylene glycol, dimer diol or trimer diol) and / or Guerbet alcohols, triglycerides based on C6 fatty acids to C10, liquid mixtures of mono- / di-tri-glycerides based on C6-C18 fatty acids, C6-C22 fatty alcohol esters and / or Guerbet alcohol with aromatic carboxylic acids, particularly benzoic acid, esters of C 2 to C 12 dicarboxylic acids with linear or branched alcohols having 1 to 22 carbon atoms or polyols having 2 to 10 carbon atoms and 2 to 6 hydroxyl groups, vegetable oils, alcohols branched primers, substituted cyclohexanes, linear or branched C6 to C22 fatty alcohol carbonates, Guerbet carbonates, esters of benzoic acid with linear and / or branched C6 to C22 alcohols (eg Finsolv # TN), linear or branched, symmetrical or asymmetric dialkyl ethers having 6 to 22 carbon atoms per alkyl group, ring-opening products of epoxidized fatty acid esters with polyols, silicone oils and / or hydrocarbons aliphatic or naphthenic, such as squalane, squalene or dialkylcyclohexanes.

 Preferably, the new makeup preparations contain silicones which are selected from the group consisting of dimethylpolysiloxanes, methylphenylpolysiloxanes, cyclic silicones as well as silicone compounds modified with an amino, a fatty acid, an alcohol, a polyether, an epoxy , a fluorine, a glucoside and / or

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alkyl, which can be at room temperature both in liquid form and in resin form Also suitable are simethicones, which are dimethicone mixtures with an average chain length of between 200 and 300 units of dimethylsiloxane and hydrogenated silicates . A detailed summary of suitable volatile silicones, by Todd et al., Can be found in Cosm. Toil. 91,27 (1976) Cosmetic make-up preparations
Typically, cosmetic make-up preparations according to the present invention comprise: (a) 0.01 to 7.5, preferably 0.5 to 5% by weight of plant extracts, and (b) 1 to 99 , 9, preferably 5 to 92.5, and particularly 10 to 35% by weight of fat.

 In the simplest case, the vegetable extracts in the fats already represent the final preparations directly. Usually, however, there are also auxiliary agents and additives which form the difference at 100% by weight. In a preferred embodiment of the present invention, the preparations contain other natural or synthetic colored dyes or pigments, for example in amounts of between 1 and 15, and preferably 2 and 10% by weight.

 The plant extracts described above have a high cosmetic compatibility with the skin and a strong dyeing power. At the same time, they support the formation of emulsions. Another object of the present invention therefore relates to the use of extracts of Pterocarpus, Vaccinium and Glycyrrhiza, and especially extracts of Pterocarpus marsupium, Vaccinium myrtillus and / or

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 Glycyrrhiza glabra for the manufacture of cosmetic makeup preparations, in which they may be contained in amounts of between 0.01 and 7.5, preferably between 0.5 and 5% by weight, based on the final preparations.

Makeup cosmetic preparations
Plant extracts can be used to make cosmetic make-up preparations, such as make-up, reds, lipsticks, Cajal tubes, eyeshadow, mascaras or nail polish. These agents or products may furthermore comprise, as other auxiliary agents or additives, mild surfactants, emulsifiers, superfatting agents, polishing waxes, consistency agents, thickening agents, polymers, greases, waxes, Lecithins, phospholipids, stabilizers, biogenic substances, deodorants, film-forming agents, blowing agents, UV protection factors, antioxidants, hydrotropes, preservatives, self-tanners, inhibitors thyrosine (depigmenting agents), solubilizing agents, perfume oils, dyes and the like.

 Typical examples of mild surfactants, that is to say having a good skin tolerance, are fatty alcohol polyglycol ether sulfates, monoglyceride sulphates, mono- and / or dialkyl sulphosuccinates, acid isethionates. fatty acid sarcosinates, fatty acid taurides, fatty acid glutamates, α-olefinsulfonates, ether carboxylic acids, alkyl oligoglucosides, fatty acid glucamides, alkylamidobetaines and / or the protein fatty acid condensates, the latter being preferably based on wheat proteins.

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 For example, nonionic surfactants are considered as emulsifiers from at least one of the following groups: adducts of from 2 to 30 moles of ethylene oxide and / or from 0 to 5 moles of propylene on linear fatty alcohols having 8 to 22 carbon atoms, on fatty acids having 12 to 22 carbon atoms, on alkylphenols having 8 to 15 carbon atoms in the alkyl group and alkylamines containing 8 to 22 carbon atoms in the alkyl residue; alkyl or alkenyl oligoglucosides having 8 to 22 carbon atoms in the alkyl (alkenyl) residue and their ethoxylated analogs, the adducts of 1 to 15 moles of ethylene oxide on ethylene oxide; castor oil and / or hardened castor oil (hydrogenated); adducts of 15 to 60 moles of ethylene oxide on castor oil and / or hardened (hydrogenated) castor oil; the partial esters of glycerin and / or of sorbitan with unsaturated and linear or saturated, branched fatty acids containing 12 to 22 carbon atoms and / or hydroxycarboxylic acids containing 3 to 18 carbon atoms, as well as their addition products with 1 to 30 moles of ethylene oxide; partial esters of polyglycerin (average degree of clean condensation 2 to 8), polyethylene glycol (molecular weight 400 to 5,000), trimethylolpropane, pentaerythritol, sugar alcohols (for example sorbitol), alkylglucosides (by for example methylglucoside, butylglucoside, laurylglucoside) and polyglucosides (for example cellulose) with saturated and / or unsaturated, linear or branched fatty acids containing 12 to 22 carbon atoms and / or hydroxycarboxylic acids containing 3 to 18 atoms carbon, as well as their adducts with 1 to 30 moles of ethylene oxide;

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 the mixed esters of pentaerythritol, fatty acids, citric acid and fatty alcohol according to DE 1165574 B and / or mixed esters of fatty acids containing 6 to 22 carbon atoms, of methylglucose and of polyols, preferably glycerin or polyglycerin; mono-, di- and trialkylphosphates, as well as mono-, di- and / or trialkylphosphates of PEG and their salts; * alcohols of wool wax; polysiloxane - polyalkylpolyether copolymers or their corresponding derivatives; polyalkylene glycols and glycerine carbonate.

 Addition products of ethylene oxide and / or propylene oxide to fatty alcohols, fatty acids, alkylphenols or castor oil are known commercially available products. It is in this respect mixtures of homologues whose average degree of alkoxylation corresponds to the ratio between quantities of ethylene oxide and / or of propylene oxide and of the substrate with which the addition reaction is conducted. . C12 / 18 fatty acid mono- and di-esters of the ethylene oxide adducts on glycerin are known from DE 2024051 B as relipidants for cosmetic preparations.

 The oligoglucosides of alkyl and / or alkenyl, their manufacture and their use are known from the state of the art. Their manufacture is carried out particularly by conversion of glucose or oligosaccharides with primary alcohols having 8 to 18 carbon atoms. With regard to the glucoside residue, both the monoglucoside, in which a cyclic glucose residue is glycosidically bonded to the fatty alcohol, and the oligomeric glucoside having an oligomerization degree of preferably up to about 8, are suitable.

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 The degree of oligomerization is in this respect a mean statistical value resulting from a usual residual distribution of the homologues for such technical products.

 Typical examples of suitable partial glycerides are hydroxystearic acid monoglyceride, hydroxystearic acid diglyceride, isostearic acid monoglyceride, isostearic acid diglyceride, oleic acid monoglyceride, oleic acid diglyceride, ricinolic acid monoglyceride, ricinolic acid diglyceride, linoleic acid monoglyceride, linoleic acid diglyceride, linolenic acid monoglyceride, linolenic acid diglyceride, erucic acid monoglyceride, erucic acid diglyceride, tartaric acid monoglyceride, tartaric acid diglyceride, citric acid monoglyceride, citric acid diglyceride, malic acid monoglyceride, malic acid diglyceride, and their technical mixtures which, depending on the manufacturing process, may still contain small amounts of triglyceride. Also suitable are adducts of from 1 to 30, preferably 5 to 10, moles of ethylene oxide to the named partial glycerides.

 Sorbitan monoisostearate, sorbitan sesquiisostearate, sorbitan diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan dioleate, sorbitan trioleate, sorbitan monoerucate are considered as sorbitan esters. sorbitan sesquiérucate, sorbitan dierucate, sorbitan trierucate, sorbitan monoricinoleate, sorbitan sesquiricinoleate, sorbitan diricinoleate, sorbitan triricinoleate, sorbitan monohydroxystearate, sorbitan sesquihydroxystearate, sorbitan dihydroxystearate , sorbitan trihydroxystearate, sorbitan monotartrate, sorbitan sesquitartrate, sorbitan ditartrate, tritartrate,

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 sorbitan, sorbitan monocitrate, sorbitan sesquicitrate, sorbitan dicitrate, sorbitan tricitrate, sorbitan monomaleate, sorbitan sesquimaleate, sorbitan dimaleate, sorbitan trimaleate, and their technical mixtures. Also suitable are adducts of 1 to 30, preferably 5 to 10, moles of ethylene oxide on the named sorbitan esters.

dipolyhydroxystéarate de polyglycéryle-2 (Dehymuls PGPH), le diisostéarate de polyglycérine-3 (Lameform@ TGI), l'isostéarate de polyglycéryle-4 (Isolan# GI 34), l'oléate de polyglycéryle-3, le polyglycéryl- 3-diisostéarate de diisostéaroyle (Isolan# PDI), le polyglycéryl-3distéarate de méthylglucose (Tego Care@ 450), la cire d'abeille de polyglycéryle-3 (Cera Bellina), le caprate de polyglycéryle-4 (caprate de polyglycérol T2010/90), le cétyléther de polyglycéryle-3 (Chimexane@ NL), le distéarate de polyglycéryle-3 (Cremophor GS 32), le polyricinoléate de polyglycéryle (Admul# WOL 1403) et le dimérate-isostéarate de polyglycéryle, ainsi que leurs mélanges. Typical examples of suitable polyglycerin esters are

polyglyceryl dipolyhydroxystearate (Dehymuls PGPH), polyglycerin-3 diisostearate (Lameform® TGI), polyglyceryl-4 isostearate (Isolan # GI 34), polyglyceryl-3 oleate, polyglyceryl-3-diisostearate diisostearoyl (Isolan # PDI), methylglucose polyglyceryl-3-steareate (Tego Care® 450), polyglyceryl-3 bee wax (Cera Bellina), polyglyceryl-4 caprate (polyglycerol caprate T2010 / 90), polyglyceryl-3-cetyl ether (Chimexane® NL), polyglyceryl-3-distearate (Cremophor GS 32), polyglyceryl polyricinoleate (Admul # WOL 1403) and polyglyceryl dimerate-isostearate, and mixtures thereof.

 Examples of other suitable polyol esters optionally are the mono-, di- and triester of trimethylolpropane converted with from 1 to 30 moles of ethylene oxide, or pentaerythritol with lauric acid, coconut fatty acid, tallow fatty acid, palmitic acid, stearic acid, oleic acid, behenic acid and the like.

 In addition, amphoteric surfactants can be used as emulsifiers. Amphoteric (zwitterionic) surfactants are surface-active compounds which comprise in the molecule at least one quaternary ammonium group and at least one carboxylate group and a sulfonate group. Particularly suitable zwitterionic surfactants are the so-called betaine agents, such as N-alkyl-N, N-

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 dimethylammoniumglycinates, for example cocoalkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinates, for example cocoacylaminopropyldimethylammonium glycinate, and 2-alkyl-3-carboxymethyl-3-hydroxyethylimidazolines containing respectively 8 to 18 carbon atoms in the alkyl group. or acyl, as well as cocoacylaminoethylhydroxyethylcarboxymethyl glycinate. Particularly preferred is the fatty acid amide derivative known as CTFA of Cocamidopropyl Betaine. Also suitable emulsifiers are ampholytic surfactants. The term "ampholytic surfactants" means surfactant compounds which, in addition to a C8 / 18 alkyl or acyl group, contain in the molecule at least one free amino group and at least one -COOH- or -SO3H- group, and are capable of forming internal salts. Examples of suitable ampholytic surfactants are N-alkylglycines, N-alkyl-propionic acids, N-alkylamino-butyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylamino-propionic acids and N-alkylamino-acetic acids respectively comprising about 8 to 18 C atoms in the alkyl group. Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C12 / 18 acyl sarcosine.

 Cationic surfactants are particularly suitable as emulsifiers, those of the esterquat type being particularly preferred, preferably di-fatty acid-triethanolamine-methylquaternized ester salts.

 Examples of substances that are used as superlipidant (superfatting) agents are lanolin and lecithin, as well as polyethoxylated or acylated derivatives of lanolin and lecithin,

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 fatty acid polyols, monoglycerides and fatty acid alkanolamides, the latter may simultaneously serve as foam stabilizers.

 Examples of polishing waxes are: alkylene glycol esters, particularly ethylene glycol distearate; fatty acid alkanolamides, and especially coconut fatty acid diethanolamide; partial glycerides, and particularly stearic acid monoglyceride; polyvalent carboxylic acid esters, optionally hydroxysubstituted, with fatty alcohols having 6 to 22 carbon atoms, in particular the long-chain esters of tartaric acid; fats, such as, for example, fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and carbonates, which have a sum of at least 24 carbon atoms, especially laurone and distearyl ether, fatty acids such as stearic acid, hydroxystearic acid or behenic acid, ring opening products of olefin epoxides having 12 to 22 carbon atoms with fatty alcohols having 12 to 22 carbon atoms and or polyols having 2 to 15 carbon atoms and 2 to 10 hydroxyl groups, and mixtures thereof.

 Fatty alcohols or fatty hydroxyalcohols having 12 to 22 carbon atoms, preferably 16 to 18 carbon atoms, and also partial glycerides, fatty acids or hydroxyacids, are firstly contemplated as consistency agents. fat. A combination of these substances is preferred with alkyl oligoglucosides and / or N-methylglucamides of the same length chain fatty acids and / or polyglycerin poly-12-hydroxystearates.

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exemple CarbopoleO de chez Goodrich ou Synthalene de chez Sigma), les polyacrylamides, l'alcool de polyvinyle et la polyvinylpyrrolidone, des tensioactifs comme par exemple les glycérides d'acides gras éthoxylés, des esters d'acides gras avec des polyols tels que par exemple le pentaérythritol ou le triméthylolpropane, des éthoxylats d'alcools gras avec une répartition serrée d'homologues ou des oligoglucosides d'alkyle, ainsi que les électrolytes comme le sel de cuisine et le chlorure d'ammonium
Les polymères cationiques appropriés sont par exemple des dérivés de cellulose cationiques, comme par exemple une hydroxyéthylcellulose quaternisée, disponible dans le commerce sous la désignation Polymer JR 400# de chez Amercol, de l'amidon cationique, des copolymères de sels de diallylammonium et d'acrylamides, des polymères quaternisés de vinylpyrrolidone / vinylimidazole, comme par exemple Luviquat# (BASF), des produits de condensation de polyglycols et d'amines, des polypeptides de collagène quaternisés, comme par exemple le collagène hydrolysé de lauryldimonium-hydroxypropyle (Lamequat@ UGrünau), les polypeptides de blé quaternisés, la polyéthylène-imine, des polymères cationiques de silicone, comme par exemple l'amodiméthicone, des copolymères de l'acide adipique et de la

diméthylaminohydroxypropyldiéthylènetriamine (Ca rtarétine@/Sandoz) , des copolymères de l'acide acrylique avec le chlorure de diméthyldiallylammonium (Merquat 550/Chemviron), le polyaminopolyamide, tel que par exemple décrit dans FR 2252840 A ainsi que leurs polymères hydrosolubles réticulés, des dérivés cationiques de Suitable thickening agents are, for example, aerosil types (hydrophilic silicas), polysaccharides, in particular xanthan gum, guar gum, agar-agar, alginates and tyloses, carboxymethylcellulose and hydroxyethylcellulose, in addition to polyethyleneglycol mono- and diesters of high molecular weight fatty acids, polyacrylates (eg

CarbopoleO from Goodrich or Synthalene from Sigma), polyacrylamides, polyvinyl alcohol and polyvinylpyrrolidone, surfactants, for example ethoxylated fatty acid glycerides, esters of fatty acids with polyols such as, for example pentaerythritol or trimethylolpropane, ethoxylates of fatty alcohols with a tight distribution of homologues or alkyl oligoglucosides, as well as electrolytes such as cooking salt and ammonium chloride
Suitable cationic polymers are, for example, cationic cellulose derivatives, such as, for example, a quaternized hydroxyethylcellulose commercially available under the name Polymer JR 400 # from Amercol, cationic starch, diallylammonium salt copolymers and acrylamides, quaternized vinylpyrrolidone / vinylimidazole polymers, for example Luviquat # (BASF), condensation products of polyglycols and amines, quaternized collagen polypeptides, for example hydrolyzed lauryldimonium-hydroxypropyl collagen (Lamequat @ UGrünau). ), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers, for example amodimethicone, copolymers of adipic acid and

dimethylaminohydroxypropyldiethylenetriamine (Ca rtetretin @ / Sandoz), copolymers of acrylic acid with dimethyldiallylammonium chloride (Merquat 550 / Chemviron), polyaminopolyamide, as for example described in FR 2252840 A and their crosslinked water-soluble polymers, cationic derivatives of

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quaternisé, comme par exemple Mirapol0 A-15, Mirapol AD-1, Mirapol
AZ-1 de la société Miranol. chitin, such as quaternized chitosan, optionally microcrystalline, condensation products, alkyl dihalides, such as dibromobutane with bisdialkylamines, such as for example bis-dimethylamino-1,3-propane, cationic guar gum, such as Jaguar CBS, Jaguar @ C-17, Jaguar
C-16 from Celanese, polymers of ammonium salt

quaternized, such as for example Mirapol® A-15, Mirapol AD-1, Mirapol
AZ-1 from Miranol.

The following are suitable as anionic, zwitterionic, amphoteric and nonionic polymers, for example vinyl acetate / crotonic acid copolymers, vinylpyrrolidone / vinyl acrylate copolymers, vinyl acetate / butyl maleate copolymers. isobornyl acrylate, methylvinylether / maleic acid anhydride copolymers and esters thereof, non-crosslinked polyacrylic acids crosslinked with polyols, copolymers of acrylamidopropyltrimethylammonium chloride / acrylate, octyl acrylamide copolymers / methyl methacrylate / methacrylate tert. butylaminoethyl / 2-hydroxypropyl methacrylate, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymers, terpolymers of vinylpyrrolidone / dimethylaminoethyl methacrylate / vinyl caprolactam, as well as optionally derived cellulose ethers and silicones
Typical examples of fats are glycerides, and waxes, for example, are natural waxes, for example candelilla wax, carnauba wax, japanese wax, aspen wax, cork wax, guaruma wax, rice germ oil wax, sugar cane wax, ouricury wax, lignite wax, beeswax, shellac wax, cetacean, lanolin (wax of

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 wool), badger blubber, ceresin, ozocerite (fossil wax), petroleum jelly, paraffin waxes, microcrystalline waxes; chemically modified waxes (hard waxes), such as, for example, lignite ester waxes, sasol waxes, hydrogenated jojoba waxes, as well as synthetic waxes, such as, for example, polyalkylene waxes and polyethylene glycol waxes. In addition to fats, greasy substances such as lecithins and phospholipids are also contemplated as additives. Those skilled in the art understand, under the name of lecithins, glycerophospholipids which are formed by esterification from fatty acids, glycerine, phosphoric acid and choline. Lecithins are therefore also often referred to in the world of the art as phosphatidylcholines (PC). Examples of natural lecithins are cephalins, which are also referred to as phosphatidic acids, and represent derivatives of 1,2-diacyl-s-glycerin-3-phosphoric acids. On the other hand, phospholipids are usually understood to mean mono- and preferably di-esters of phosphoric acid with glycerine (glycerine phosphate), which is generally counted as fats. Sphingosines or sphingolipids are also contemplated.

 Stabilizers may be metal salts of fatty acids, for example stearate or ricinoleate of magnesium, aluminum and / or zinc.

 By biogenic substances are meant, for example, tocopherol, tocopherol acetate, tocopherol palmitate, ascorbic acid, deoxyribonucleic acid, retinol, bisabolol, allantoin, phytantriol, panthenol, alpha- hydroxyacids, amino acids, ceramides, pseudoceramides, essential oils, plant extracts and vitamin complexes.

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 All substances effective against gram-positive bacteria, such as, for example, 4-hydroxybenzoic acid and its salts and esters, N- (4-chlorophenyl) -N '- are basically suitable as seed inhibitors. 3,4-dichlorophenyl) urea, 2,4,4'-trichloro-2'-hydroxydiphenyl ether (triclosan), 4-chloro-3,5-dimethylphenol, 2,2'-methylenebis (6-bromo-4) chlorophenol), 3-methyl-4- (1-methylethyl) phenol, 2-benzyl-4-chlorophenol, 3- (4chlorophenoxy) -1,2-propanediol, 3-iodo-2-propinylbutylcarbamate, chlorhexidine, 3,4,4'-trichlorocarbanilide (TTC), antibacterial odorous substances, thymol, thyme oil, eugenol, clove oil, menthol, mint oil, farnesol phenoxyethanol, glycerin monolaurate (GML), diglycerin monocaprinate (DMC), salicylic acid N-alkylamide, such as, for example, n-octylamide of salicylic acid or n-decylamide of salicylic acid.

 Suitable film-forming agents are, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinylpyrrolidone, a vinylpyrrolidone-vinyl acetate copolymer, polymers of the acrylic acid series, quaternary cellulose derivatives, collagen, hyaluronic acid or its salts, and similar compounds.

 As a blowing agent for the aqueous phases, montmorillonite, clay minerals, pemulene and alkyl-modified carbopol (Goodrich) types can be used. Other suitable polymers or blowing agents can be derived from R. Lochhead's summary in Cosm. Toil. 108, 95 (1993).

 The term "UV protection factors" is intended to mean, for example, organic substances which are present at ambient temperature in liquid or crystalline form (photoprotective filter) which are

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 able to absorb ultraviolet rays and to restore the absorbed energy in the form of radiation of longer wavelength, for example of heat. UV filters can be water soluble or oil soluble. For example, oil-soluble substances are: * 3-benzylidene camphor or 3-benzylidene norcamphor and its derivatives, for example 3- (4-methylbenzylidene) camphor, as described in EP 0693471 B1; 4-aminobenzoic acid derivatives, preferably 4- (dimethylamino) benzoic acid 2-ethylhexyl ester, 4- (dimethylamino) benzoic acid 2-octyl ester and amyl ester 4- (dimethylamino) benzoic acid; esters of cinnamic acid, preferably 2-ethylhexyl ester of 4-methoxy-cinnamic acid, propyl ester of 4-methoxycinnamic acid, isoamyl ester of 4-methoxy acid -cinnamic and 2-cyano-3,3-phenyl-cinnamic acid 2-ethylhexyl ester (Octocrylene); esters of salicylic acid, preferably 2-ethylhexyl ester of salicylic acid, 4-isopropylbenzyl ester of salicylic acid, homomenthylester of salicylic acid; benzophenone derivatives, preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone; esters of benzalmalonic acid, preferably di-2-ethylhexyl ester of 4-methoxybenzalmalonic acid; * triazine derivatives, such as 2,4,6-trianilino- (p-carbo-2'-ethyl-1'-hexyloxy) -1,3,5-triazine and octyl triazone, such as described in EP 0818450 A1, or dioctyl-butamido-triazone (Uvasorb @ HEB);

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 propane-1,3-diones, such as, for example, 1- (4-tert.-butylphenyl) -3- (4'-methoxyphenyl) propane-1,3-dione; * derivatives of cetotricyclo (5.2.1.0) decane, as described in EP 0694521 B1.

 Water-soluble substances are: 2-phenylbenzimidazol-5-sulfonic acids and their alkali, alkali metal, alkaline earth metal, ammonium, alkylammonium, alkanolammonium and glucammonium salts; benzophenone sulphonic acid derivatives, preferably 2-hydroxy-4-methoxybenzophenone-5-sulphonic acid and its salts; sulfonic acid derivatives of 3-benzylidenecamphor, such as, for example, 4- (2-oxo-3-bornylidenemethyl) benzolsulfonic acid and 2-methyl-5- (2-oxo-3-bornylidene) acid; sulfonic acid and its salts.

 UVA filters are particularly suitable benzoylmethane derivatives, such as for example 1- (4'-tert.butylphenyl) -3- (4'-methoxyphenyl) propane-1,3-dione, 4-tert.-butyl- 4'-methoxydibenzoylmethane (Parsol 1789), 1-phenyl-3- (4'isopropylphenyl) -propane-1,3-dione, as well as enamine compounds as described in DE 19712033 A1 (BASF). The filters U.V.A. and U.V.B. can obviously also be used in mixtures. In addition to the so-called soluble substances, insoluble photoresponsive pigments, namely finely dispersed metal oxides or salts are also suitable for this purpose. Examples of suitable metal oxides are, in particular, zinc oxide and titanium dioxide. and furthermore oxides of iron, zirconium, silicon, manganese, aluminum and cerium, and mixtures thereof. We can use as

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 salts of silicates (talc), barium sulphate or zinc stearate. Oxides and salts are used in the form of pigments for skin care and skin care emulsions, and in make-up cosmetics. In this respect, the particles should have an average diameter of less than 100 nm, preferably between 5 and 50 nm, and particularly between 15 and 30 nm. They may have a spherical shape, but particles may also be used which have an ellipsoid shape or a form deviating in a particular way from the spherical shape. The pigments may also have undergone a surface treatment, namely to be rendered hydrophilic or hydrophobic. Typical examples are coated titanium dioxide, such as, for example, titanium dioxide T 805 (Degussa) or Eusolex # T2000 (Merck). As a hydrophobic coating agent, silicones and especially trialkoxyoctylsilanes or simethicone. It is preferred to use in sunscreen agents so-called micro- and nanopigments. Micronized zinc oxide is preferably used. Other UV protection filters are mentioned in the summary by P. Finkel in SFFW-Journal 122, 543 (1996).

 In addition to the two previously named groups of primary photoprotective agents, it is also possible to use secondary photoprotective agents of the antioxidant type, which interrupt the chain of photochemical reactions which is triggered when the UV radiation enters the skin. Typical examples are amino acids (for example, glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (for example urocaninic acid) and their derivatives, peptides such as D, L-carnosine, D-carnosine, L-carnosine and their derivatives (for example, anserine), carotenoids, carotenes (for example, a-carotene, p-carotene,

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 lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (for example dihydrolipoic acid), aurothioglucose, propylthiouracil and other thiols (for example thioredoxin, glucathion, cysteine, cystine, cystamine and their esters of glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, γ-linolyl , cholesteryl and glyceryl), as well as their salts, dilaurylthiodipropionate, distearylthiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts), as well as sulfoximine compounds (by sulfoximine of buthionine, homocysteine sulfoximine, betaine sulfone, penta, hexa- and heptathionine sulfoximine) in very low compatible assays (eg pmol to mol / kg), and chelation (metallic) ( for example fatty α-hydroxy acids, palmitic acid, phytinic acid, lactoferrin), α-hydroxy acids (for example citric acid, lactic acid, malic acid), humic acid, bile acid, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (for example γ-linolenic acid, linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and ubiquinol and their derivatives, vitamin C and its derivatives (eg ascorbyl palmitate, Mg-ascorbyl phosphate, ascorbyl, tocopherols and their derivatives (eg vitamin E acetate), vitamin A and its derivatives (eg vitamin A palmitate), as well as benzoin resin coniferyl benzoate, rutinic acid and its derivatives. derivatives, α-glycosylrutin, ferric acid, furfurylideneglucitol, carnosine, butylhydroxytoluene, butylhydroxyaniso 1, guaiac resin nordihydro-acid, gaiaretic nordihydroacid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, zinc and its derivatives (for example ZnO, ZnSO4), selenium and its derivatives (by

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 for example selenium methionine), stilbene and its derivatives (for example stilbene oxide, trans-stilbene oxide), and derivatives suitable according to the present invention (salts, esters, ethers, sugars, nucleotides nucleosides, peptides and lipids) of these named substances.

 To improve viscoelasticity, it is also possible to use hydrotropes, such as, for example, ethanol, isopropyl alcohol or polyols. The polyols which are contemplated herein preferably have 2 to 15 carbon atoms and at least two hydroxyl groups. The polyols may still have other functional groups, particularly amino groups, or may be modified with nitrogen. Typical examples are glycerin; alkylene glycols, such as, for example, ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol, and polyethylene glycols having an average molecular weight of between 100 and 1000 Daltons; * technical mixtures of oligoglycerines having a degree of clean condensation of between 1.5 and 10, such as diglycerin mixtures comprising a diglycerin content of between 40 and 50% by weight; methylol compounds, especially trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol;

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 lower alkyl glucosides, in particular those containing 1 to 8 carbon atoms in the alkyl residue, for example methyl and butyl glucoside; sugar-alcohols having 5 to 12 carbon atoms, for example sorbitol and mannitol; sugars having 5 to 12 carbon atoms, for example glucose or sucrose; amino-sugars, such as for example glucamine; the dialcohol amines, such as diethanolamine or 2-amino-1,3-propanediol.

 Examples of suitable preservative agents are phenoxyethanol, a solution of formaldehyde, paraben, pentadiol or sorbic acid, as well as the other classes of substances listed in Annex 6, Parts A and B of the classification of cosmetics. Insect repellents are N, N-diethyl-m-toluamide, 1,2-pentanediol or ethylbutylacetyl aminopropionate, as self-tanners dihydroxyacetone. It is contemplated that tyrosine inhibitors, which inhibit the formation of melanin and find their use in depigmentation agents, for example arbutin, cogic acid, coumaric acid and ascorbic acid (vitamin C) .

 The named mixtures of natural and synthetic fragrances are suitable as perfume essences. Natural scents are flower extracts (lily, lavender, rose, jasmine,

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 neroli, ylang-ylang), stems and leaves (geranium, patchouli, petitgrain), fruits (anise, coriander, cumin, juniper), fruit peel (bergamot, lemon, orange), roots (mace, angelica, celery, cardamom, costus, iris, calmus), wood (pine wood, sandalwood, gaiac, cedar, rose), herbs and herbs (tarragon, lemongrass, sage, thyme), needles and branches (spruce, fir, pine, mountain pine), resins and balms (galbanum, elemi, benzoic, myrrh, olibanum, opoponax). Animal raw materials such as civet and castoreum are also considered. Compounds of typical synthetic odorants are products of the type of esters, ethers, aldehydes, ketones, alcohols and carboxylic acids. Odor compounds of the ester type are, for example, benzyl acetate, phenoxyethyl isobutyrate, p-acetate, and the like. tert-butylcyclohexyl, linalyl acetate, dimethylbenzylcarbinyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, ethylmethylphenyl glycinate, allylcyclohexyl propionate, styrallyl propionate, and benzyl salicylate. Examples of the ethers include benzylethyl ether, among the aldehydes, for example linear alkanals containing 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamenaldehyde, hydroxycitronellal, lilial and bud, among the ketones, for example ionone, α-isomethylionone and methylcedrylketone, among the alcohols anethole, citronellol, eugenol, isoeugenol, geraniol, linalool, phenylethyl alcohol and terpineol, among the hydrocarbon compounds essentially terpenes and balsams. However, it is preferred to use mixtures of different fragrance materials, which together generate a pleasant scent. Low volatility ethereal oils, which are most often used as flavor components, are also suitable as perfume essences, for example, sage essence, chamomile essence, clove oil, lemon balm essence, mint essence, leaf essence

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 cinnamon tree, linden blossom essence, juniper berries essence, vetiver essence, oliban essence, galbanum essence, labolanum essence and lavandin essence. Preferably, the essence of bergamot, dihydromyrcenol, lilial, lyral, citronellol, phenylethyl alcohol, cinnamal a-hexyl-aldehyde, geraniol, benzylacetone, cyclamenaldehyde, linalool is used. , Boisambrene Forte, ambroxane, indol, hedione, sandalwood essence, lemon essence, tangerine essence, orange essence, allylamyl glycolate, cyclovertal , lavandin essence, muscat sage essence, ss-damascone, Bourbon geranium essence, cyclohexyl salicylate, Vertofix C # ur, Iso-E-super, Fixolide NP, l egenyl, gamma-aldehyde, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romillate, irotyl and floramate, alone or in mixtures.

 Appropriate substances authorized for cosmetic purposes can be used here as dyes, as summarized in, for example, the publication "Kosmetische Färbemittel" der Farbstoffkommission des Deutschen Forschungsgemeinschaft, Verlag Chemie, Weinheim, 1984, p. These dyes are usually used in concentrations of between 0.001 and 0.1% by weight, based on the total mixture.

 The total proportion of auxiliaries and additives may be from 1 to 50, preferably from 5 to 40% by weight, based on the products or agents. The manufacture of the products or agents can be carried out by the usual hot or cold processes, preferably by the method of the phase inversion temperature.

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Examples
The following Table 1 mentions a series of formulation examples; these represent: (1) tinted day cream; (2) powder cream; (3) compact powder for the face; (4) free powder for the face; (5) red; (6) lip gloss; (7) caring lipstick; (8) makeup lipstick; (9) eyeliner; (10) mascara; (11) compact eyeshadow; (12) emulsion eyeshadow; (13) pearlescent varnish; (14) cream varnish.

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Table 1 Formulation Examples - Cosmetic Makeup (Part 1)

<Tb>
<tb> Composition <SEP> 1 <SEP> 2 <SEP> 3 <SEP> 4 <SEP> 5 <SEP> 6 <SEP> 7
<tb> Stearate <SEP> of <SEP> Glycerol <SEP> 4.0 <SEP> 1.8 <SEP> - <SEP> Laurate <SEP> of <SEP> sorbityl <SEP> PEG-20 <SEP> 1 , 0 <SEP> 0.7 <SEP> Alcohol <SEP> of <SEP> cetyl <SEP> 1.0 <SEP> - <SEP> - <SEP> $ - <SEP> - <SEP> Alcohol <SEP> lanolinylic acid <SEP> - <SEP> 4.0 <SEP> - <SEP> 3.0 <SEP> 45.0 <SEP> 3.0
<tb> Stearic acid <SEP><SEP> 2.0 <SEP> - <SEP> Isopropyl stearate <SEP><SEP> - <SEP> - <SEP> 2.0 <SEP> Octanoate <SEP> from <SEP> Cetylstearyl <SEP> 5.0- <SEP> - <SEP> - <SEP> - <SEP> Octyl Palmitate <SEP><SEP> 3.0 <SEP> - <SEP> - <SEP> - <SEP> - <SEP> - <SEP> Oleate <SEP> of oleyl <SEP> 3.2 <SEP> - <SEP> - <SEP> - <SEP> Dimethylpolysiloxane <SEP> - <SEP> 2, 5 <SEP> 10.0 <SEP> - <SEP>
<Tb>

Stéa roxyd im éth icone - - - - - - 1,0 Cire d'abeille - - -~~ 2fl -

Stéa roxyd im eth icone - - - - - - 1.0 Beeswax - - - ~~ 2fl -

<Tb>
<tb> Wax <SEP> of <SEP> carnauba <SEP> - <SEP> - <SEP> - <SEP> 1.0 <SEP> 3.0
<tb> Wax <SEP> of <SEP> Candellila <SEP> - <SEP> - <SEP> - <SEP> - <SEP> - <SEP> - <SEP> 7.0
<tb> Ozocerite <SEP> - <SEP> - <SEP> 2.0 <SEP> - <SEP> Oil <SEP> from <SEP> ricin- <SEP> - <SEP> 15.0 <SEP> 82, 5
<tb> Lanolin <SEP> - <SEP> - <SEP> - <SEP> 10.0
<tb> Ethnocolor <SEP> PM <SEP> 3.0 <SEP> 3.0 <SEP> 3.0 <SEP> - <SEP> - <SEP> Ethnocolor <SEP> VM <SEP> 3.0 <SEP > 3.0 <SEP> Ethnocolor <SEP> GG <SEP> 3.0 <SEP> 3.0
<tb> D-Panthanol <SEP> - <SEP> - <SEP> - <SEP> - <SEP> 0.5
<tb> Gum <SEP> of <SEP> xanthan <SEP> 0.4 <SEP> - <SEP> - <SEP> - <SEP> Stearate <SEP> of <SEP> magnesium <SEP> - <SEP> - <SEP> 3.0- <SEP> Stearate <SEP> of <SEP> zinc <SEP> - <SEP> - <SEP> - <SEP> - <SEP> 4.5 <SEP> - <SEP> Carboxymethylcellulose <SEP> - <SEP> 0.3 <SEP> - <SEP> - <SEP> Polybutylene <SEP> - <SEP> - <SEP> 17.0
<tb> Talc <SEP> 4.0 <SEP> 9.0 <SEP> 30.0 <SEP> 65.5 <SEP> 17.5
<tb> Kaolin <SEP> - <SEP> - <SEP> 5.0 <SEP> - <SEP> - <SEP> Silicate <SEP> of <SEP> Magnesium <SEP> 5.0 <SEP> 0.3 <SEP> 33.0 <SEP> 15.0 <SEP> 22.0 <SEP> Dioxide <SEP> of <SEP> titanium <SEP> 1.5 <SEP> 4.0 <SEP> 5.0 <SEP > - <SEP> 8.0 <SEP> Oxide <SEP> of <SEP> Iron <SEP> 0.8 <SEP> 1.1 <SEP> 2.0 <SEP> - <SEP> 4.0 <SEP > Pigments <SEP> of <SEP> mica <SEP> - <SEP> - <SEP> 7.0 <SEP> - <SEP> 35.0 <SEP> 3.0
<tb> Propylene Glycol <SEP> 5.0 <SEP> 10.0 <SEP> - <SEP> Triethanolamine <SEP> - <SEP> 1.0 <SEP> - <SEP> - <SEP> Essence <SEP> of <SEP> perfume <SEP> 0.5 <SEP> 0.4 <SEP> 0.5 <SEP> 1.0 <SEP> 0.5 <SEP> 0.4
<tb> qsp <SEP> to <SEP> 100 <SEP>
<Tb>

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Table 1 Formulation Examples - Cosmetic Makeup (Part 2)

<Tb>
<tb> Composition <SEP> 8 <SEP> 9 <SEP> 10 <SEP> 11 <SEP> 12 <SEP> 13 <SEP> 14
<Tb>

Stéarate de clvcérvle - - 6,O - 5,5 - -

Veterinary stearate - - 6, O - 5,5 - -

<Tb>
<tb> Alcohol <SEP> lanolinylic acid <SEP> - <SEP> - <SEP> - <SEP> 0,5 <SEP> 1,5 <SEP> Oleth-10 <SEP> 1,5
<tb> Stearic acid <SEP> ~~~~~~~~~~~~~ 1.0 <SEP> - <SEP> 1.0 <SEP> - <SEP> Oil <SEP> of <SEP> paraffin <SEP > - <SEP> - <SEP> 49.0 <SEP> - <SEP> - <SEP> - <SEP> - <SEP> Isopropyl stearate <SEP><SEP> - <SEP> - <SEP> - <SEP> - <SEP> 2.0 <SEP> 3.0 <SEP> - <SEP> Isostearate <SEP> Isostearyl <SEP> 12.0 <SEP> - <SEP> - <SEP> - <SEP > - <SEP> - <SEP> -
<Tb>

Lactate de m rist le 6,0 - - ~ - -

Lactate of m rist the 6.0 - - ~ - -

<Tb>
<tb> Dimethylpolysiloxane <SEP> - <SEP> - <SEP> - <SEP> 2.0 <SEP> - <SEP> - <SEP> Bees Wax <SEP><SEP> 3.0- <SEP> 16.0 <SEP> - <SEP> 2.5 <SEP> Wax <SEP> of <SEP> carnauba <SEP> 2.5 <SEP> - <SEP> 3.0 <SEP> - <SEP> - <SEP> - <SEP> Wax <SEP> of <SEP> Candellila <SEP> 2.0 <SEP> - <SEP> - <SEP> - <SEP> - <SEP> - <SEP> -
<Tb>

Ozocérite 2,0 Ozocérite 2,0 - ~

Ozocerite 2.0 Ozocerite 2.0 - ~

<Tb>
<tb> Oil <SEP> of <SEP> ricin <SEP> 44.5 <SEP> - <SEP> 1.5 <SEP> - <SEP> - <SEP>
<tb> Lanolin <SEP> 5.0 <SEP> - <SEP> - <SEP> Ethnocolor <SEP> PM <SEP> 3.0 <SEP> 3.0 <SEP> 3.0 <SEP> - <SEP > - <SEP> - <SEP> Ethnocolor <SEP> VM <SEP> - <SEP> - <SEP> - <SEP> 3.0 <SEP> 3.0 <SEP> -
<Tb>

Ethnocolor@ - 3,0 3,0 Ethnocolor GAG 3' 3.

Ethnocolor @ - 3.0 3.0 Ethnocolor GAG 3 '3.

<Tb>
& numsp <SEP> - <SEP> - <SEP> 0.5 <SEP> - <SEP> Stearate <SEP> from <SEP> zinc <SEP> - <SEP> - <SEP> - <SEP> 2.0 <SEP > - <SEP> - <SEP> - <SEP>
<tb> Carboxymethylcellulose <SEP> - <SEP> 1.5 <SEP> Plate <SEP> - <SEP> .. <SEP> 36.0 <SEP> - <SEP> - <SEP> Kaolin <SEP> - <SEP> - <SEP> 5.0 <SEP> - <SEP> - <SEP> Silicate <SEP> of <SEP> Magnesium <SEP> - <SEP> 1.5 <SEP> - <SEP> 2.0 <SEP> - <SEP> Hectorite <SEP> of <SEP> stearalconium <SEP> - <SEP> - <SEP> - <SEP> - <SEP> - <SEP> 1.0 <SEP> 1.0
<Tb>

Dioxyde de titane ?~~~"~~. 5,0 2.0 0,6 1,0

Titanium dioxide? ~~~ "~~. 5.0 2.0 0.6 1.0

<Tb>
<tb> Oxychloride <SEP> from <SEP> bismuth <SEP> - <SEP> - <SEP> - <SEP> 20.0 <SEP> - <SEP> 0.2 <SEP> Eraser <SEP> lacquer <SEP of <SEP> triethanolamine <SEP> - <SEP> 2.0 <SEP> - <SEP> - <SEP> - <SEP> Pigments <SEP> dyes <SEP> organic <SEP> 12.0 <SEP> - <SEP> - <SEP> 15.0 <SEP> 8.0 <SEP> 1.2 <SEP> 1.0
<tb> Acetate <SEP> of <SEP> methyl <SEP> - <SEP> - <SEP> - <SEP> - <SEP> 8.0 <SEP> 10.0
<tb> Acetate <SEP> ethyl <SEP> - <SEP> - <SEP> 8.0 <SEP> 18.0
<tb> Acetate <SEP> of <SEP> propyl <SEP> - <SEP> - <SEP> - <SEP> - <SEP> 12.0 <SEP> 16.0
<tb> Acetate <SEP> of <SEP> Butyl <SEP> - <SEP> - <SEP> - <SEP> - <SEP> - <SEP> 25.0 <SEP> 23.0
<tb> Resin <SEP> of <SEP> polyester <SEP> - <SEP> - <SEP> - <SEP> - <SEP> 7,5 <SEP> Nitrocellulose <SEP> / <SEP> alcohol <SEP> isopropyl <SEP> - <SEP> - <SEP> - <SEP> - <SEP> 21.0 <SEP> 19.0
<tb> Sulfonamide <SEP> of <SEP> toluene <SEP> resin <SEP> of <SEP> - <SEP> - <SEP> - <SEP> 9.0 <SEP> 11.0
<tb> formaldehyde
<tb> Polyacrylate <SEP> - <SEP> - <SEP> - <SEP> - <SEP> 1,5
<tb> Cam <SEP> hre <SEP> - <SEP> - <SEP> - <SEP> - <SEP> 1.5 <SEP> 1.5
<tb> Phthalate <SEP> of <SEP> dibutylate <SEP> - <SEP> - <SEP> - <SEP> 5.0 <SEP> 5.0
<tb> Propylene Glycol <SEP> - <SEP> 5.0 <SEP> 2-0 <SEP> 5.0
<tb> Essence <SEP> of <SEP> fragrance <SEP> 0.4 <SEP> - <SEP> - <SEP> - <SEP> 0.5 <SEP> - <SEP> Water <SEP> qsp <SEP > to <SEP> 100
<Tb>

<Desc / Clms Page number 30>

 Ethnocolor PM = Pterocarpus marsupium extract in dimethicone copolyol Ethnocolor # VM = Vaccinium myrtillus extract in dimethicone copolyol Ethnocolor # GG = Glycyrrhiza glabra extract in dimethicone copolyol Commercial products from Laboratoires Sérobiologiques, Nancy / FR,

Claims (10)

claims Cosmetic make-up preparations, characterized in that they comprise (a) at least one plant extract selected from the group consisting of the Pterocarpus, Vaccinium and Glycyrrhiza families, and (b) at least one fatty substance.  2. Preparations according to claim 1, characterized in that they comprise extracts of Pterocarpus marsupium.  3. Preparations according to claim 1, characterized in that they comprise extracts of Vaccinium myrtillus.  4. Preparations according to claim 1, characterized in that they comprise extracts of Glycyrrhiza glabra.  5. Preparations according to at least one of claims 1 to 4, characterized in that they comprise fatty substances which are selected from the group consisting of Guerbet alcohols based on fatty alcohol having 6 to 18 carbon atoms, C6-C22 linear fatty acid esters with C6-C22 linear fatty alcohols, C6-C13 branched carboxylic acid esters with linear C6-C22 fatty alcohols, linear fatty acid esters with C6-C22 linear fatty alcohols; C6 to C22 with branched alcohols, esters of hydroxycarboxylic acids with linear or branched C6 to C22 fatty alcohols, esters of linear and / or branched fatty acids with polyols, triglycerides based on fatty acids, C6 to C10, liquid mixtures of mono- / di- / tri-glycerides based on C6-C18 fatty acids, esters of C6-C22 fatty alcohol and / or Guerbet alcohols with carboxylic acids aromatic compounds, C2-C8 dicarboxylic acid esters, C12 with linear or branched alcohols having 1 to 22 carbon atoms or polyols comprising <Desc / Clms Page number 32>  2 to 10 carbon atoms and 2 to 6 hydroxyl groups, vegetable oils, branched primary alcohols, substituted cyclohexanes, linear or branched C 6 to C 22 fatty alcohol carbonates, Guerbet carbonates, esters of benzoic acid with linear and / or branched C 6 -C 22 alcohols, linear or branched, symmetrical or asymmetric dialkyl ethers having 6 to 22 carbon atoms per alkyl group, ring-opening products of the epoxidized fatty acid esters with polyols, silicone oils and / or aliphatic or naphthenic hydrocarbons.  6. Preparations according to at least one of claims 1 to 5, characterized in that they contain as fats silicones which are selected from the group which is formed dimethylpolysiloxanes, methylphenylpolysiloxanes, cyclic silicones, silicones and / or amino-modified simethicones, fatty acid, alcohol, polyether, epoxy, fluorine, glucoside and / or alkyl.  7. Preparations according to at least one of claims 1 to 5, characterized in that they contain (a) 0.01 to 7.5% by weight of plant extracts, and (b) 1 to 99.9% mass of fat.  8. Use of extracts of Pterocarpus, Vaccinium and Glycyrrhiza for the manufacture of cosmetic make-up preparations.  9. Use according to claim 8, characterized in that extracts of Pterocarpus marsupium, Vaccinium myrtillus and / or Glycyrrhiza glabra are used. <Desc / Clms Page number 33>  Use according to claims 8 and / or 9, characterized in that the extracts are used in amounts of 0.01 to 7.5% by weight, based on the final preparations.