FR2794741B1 - LITHIA MANGANESE OXIDES, THEIR PREPARATION PROCESS AND THEIR USE AS POSITIVE ELECTRODE IN A LITHIUM BATTERY - Google Patents

LITHIA MANGANESE OXIDES, THEIR PREPARATION PROCESS AND THEIR USE AS POSITIVE ELECTRODE IN A LITHIUM BATTERY

Info

Publication number
FR2794741B1
FR2794741B1 FR9907491A FR9907491A FR2794741B1 FR 2794741 B1 FR2794741 B1 FR 2794741B1 FR 9907491 A FR9907491 A FR 9907491A FR 9907491 A FR9907491 A FR 9907491A FR 2794741 B1 FR2794741 B1 FR 2794741B1
Authority
FR
France
Prior art keywords
lithia
positive electrode
lithium battery
preparation process
manganese oxides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR9907491A
Other languages
French (fr)
Other versions
FR2794741A1 (en
Inventor
Didier Bloch
Stephane Bach
Ramos Jean Pierre Pereira
Noel Baffier
Sylvain Franger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to FR9907491A priority Critical patent/FR2794741B1/en
Priority to PCT/FR2000/001650 priority patent/WO2000076921A1/en
Priority to JP2001503392A priority patent/JP2003502256A/en
Priority to EP00949542A priority patent/EP1200354A1/en
Publication of FR2794741A1 publication Critical patent/FR2794741A1/en
Application granted granted Critical
Publication of FR2794741B1 publication Critical patent/FR2794741B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Manganates manganites or permanganates
    • C01G45/1221—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof
    • C01G45/1228—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof of the type [MnO2]n-, e.g. LiMnO2, Li[MxMn1-x]O2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/40—Cobaltates
    • C01G51/42—Cobaltates containing alkali metals, e.g. LiCoO2
    • C01G51/44—Cobaltates containing alkali metals, e.g. LiCoO2 containing manganese
    • C01G51/50—Cobaltates containing alkali metals, e.g. LiCoO2 containing manganese of the type [MnO2]n-, e.g. Li(CoxMn1-x)O2, Li(MyCoxMn1-x-y)O2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C01P2002/54—Solid solutions containing elements as dopants one element only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/77—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/78—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by stacking-plane distances or stacking sequences
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Secondary Cells (AREA)
FR9907491A 1999-06-14 1999-06-14 LITHIA MANGANESE OXIDES, THEIR PREPARATION PROCESS AND THEIR USE AS POSITIVE ELECTRODE IN A LITHIUM BATTERY Expired - Fee Related FR2794741B1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
FR9907491A FR2794741B1 (en) 1999-06-14 1999-06-14 LITHIA MANGANESE OXIDES, THEIR PREPARATION PROCESS AND THEIR USE AS POSITIVE ELECTRODE IN A LITHIUM BATTERY
PCT/FR2000/001650 WO2000076921A1 (en) 1999-06-14 2000-06-14 Lithium-containing manganese oxides, preparation method and use as positive electrode in a lithium cell battery
JP2001503392A JP2003502256A (en) 1999-06-14 2000-06-14 Lithium manganese oxide, its preparation method and its use as a positive electrode in lithium storage batteries
EP00949542A EP1200354A1 (en) 1999-06-14 2000-06-14 Lithium-containing manganese oxides, preparation method and use as positive electrode in a lithium cell battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9907491A FR2794741B1 (en) 1999-06-14 1999-06-14 LITHIA MANGANESE OXIDES, THEIR PREPARATION PROCESS AND THEIR USE AS POSITIVE ELECTRODE IN A LITHIUM BATTERY

Publications (2)

Publication Number Publication Date
FR2794741A1 FR2794741A1 (en) 2000-12-15
FR2794741B1 true FR2794741B1 (en) 2002-04-26

Family

ID=9546743

Family Applications (1)

Application Number Title Priority Date Filing Date
FR9907491A Expired - Fee Related FR2794741B1 (en) 1999-06-14 1999-06-14 LITHIA MANGANESE OXIDES, THEIR PREPARATION PROCESS AND THEIR USE AS POSITIVE ELECTRODE IN A LITHIUM BATTERY

Country Status (4)

Country Link
EP (1) EP1200354A1 (en)
JP (1) JP2003502256A (en)
FR (1) FR2794741B1 (en)
WO (1) WO2000076921A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102586288B1 (en) * 2021-01-08 2023-10-18 고려대학교 산학협력단 Cathode active material
KR102536228B1 (en) * 2021-01-08 2023-05-23 고려대학교 산학협력단 Cathode active material

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2087858B (en) * 1980-11-25 1984-08-22 Mizushima Koichi Reduction of so2 in polluted gases high surface area conductors
FR2704216A1 (en) * 1993-04-23 1994-10-28 Centre Nat Rech Scient Electrode materials for rechargeable lithium batteries and their method of synthesis
DE19519044A1 (en) * 1995-05-24 1996-11-28 Basf Magnetics Gmbh Spinels containing lithium and manganese (III / IV)
AU6864098A (en) * 1997-03-14 1998-10-12 Eveready Battery Company Inc. Lithiated metal oxides

Also Published As

Publication number Publication date
JP2003502256A (en) 2003-01-21
FR2794741A1 (en) 2000-12-15
WO2000076921A1 (en) 2000-12-21
EP1200354A1 (en) 2002-05-02

Similar Documents

Publication Publication Date Title
AU3644397A (en) A method for preparing mixed amorphous vanadium oxides and their use as electrodes in rechargeable lithium cells
EP1142834A4 (en) Lithium-manganese composite oxide, positive electrode material for lithium secondary cell, positive electrode and lithium secondary cell, and method for preparing lithium-manganese composite oxide
DE60029171D1 (en) Negative electrode for non-aqueous electrolyte rechargeable batteries
HK1035071A1 (en) Non-aqueous electrolyte and lithium secondary battery using the same.
IL128392A0 (en) Lithium manganese oxy-fluorides for li-ion rechargeable battery electrodes
EP1244163A4 (en) Electrode for lithium secondary cell and lithium secondary cell
EP1231654A4 (en) Electrode for lithium cell and lithium secondary cell
HK1023850A1 (en) Lithium-containing, lithium-intercalating phosphates and their use as the positive or negative electrode material in a lithium secondary battery
AU3370700A (en) Modified lithium vanadium oxide electrode materials, products, and methods
AU4885601A (en) Lithium secondary battery-use electrode and lithium secondary battery
MXPA01004029A (en) Positive electrode and non-aqueous electrolyte cell.
EP1011165A4 (en) Lithium secondary battery, polymer gel electrolyte, and binder for lithium secondary batteries
MXPA02007357A (en) Liquid electrolyte lithium sulfur batteries.
AU7951100A (en) Electrode for lithium secondary cell and lithium secondary cell
GB9919807D0 (en) Anode for rechargeable lithium cell
DE69900562D1 (en) Lithium-containing transition metal oxides, manufacturing processes therefor, electrodes and secondary lithium batteries
AU7951200A (en) Electrode for lithium cell and lithium secondary cell
FR2721308B1 (en) Manganese oxide insertion compounds, usable as a positive electrode in a lithium battery.
AU1823997A (en) Electrochemical cell or battery with a negative electrode comprising vanadium oxide, v6o13, or lithiated vanadium oxide, liyv6o13, as an active material
AU7557200A (en) Lithium-cobalt composite oxide, method for preparing the same, positive electrode for lithium secondary cell and lithium secondary cell using the same
DE60001377D1 (en) Positive electrode, process for its manufacture and lithium battery using the same
DE60013075D1 (en) Mixed lithium manganese oxides and secondary battery with non-aqueous electrolytes
AU3813799A (en) Rechargeable lithium electrochemical cell
AU3458599A (en) Composite manganese oxide cathodes for rechargeable lithium batteries
IT1296479B1 (en) RECHARGEABLE LITHIUM ANODE FOR A POLYMER ELECTROLYTE BATTERY

Legal Events

Date Code Title Description
ST Notification of lapse