FR2785279B1 - Zeolithe euo comprenant des cristaux et des agregats de cristaux de granulometries specifiques et son utilisation comme catalyseur d'isomerisation des c8 aromatiques - Google Patents

Zeolithe euo comprenant des cristaux et des agregats de cristaux de granulometries specifiques et son utilisation comme catalyseur d'isomerisation des c8 aromatiques

Info

Publication number
FR2785279B1
FR2785279B1 FR9816421A FR9816421A FR2785279B1 FR 2785279 B1 FR2785279 B1 FR 2785279B1 FR 9816421 A FR9816421 A FR 9816421A FR 9816421 A FR9816421 A FR 9816421A FR 2785279 B1 FR2785279 B1 FR 2785279B1
Authority
FR
France
Prior art keywords
zeolithe
granulometries
euo
isomerization
crystals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
FR9816421A
Other languages
English (en)
Other versions
FR2785279A1 (fr
Inventor
Elisabeth Merlen
Fabio Alario
Olivia Martin
Nathalie Ferrer
Sylvie Lacombe
Loic Rouleau
Drisch Julia Magne
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR9813839A external-priority patent/FR2785201B1/fr
Priority claimed from FR9813773A external-priority patent/FR2785278B1/fr
Priority to FR9816421A priority Critical patent/FR2785279B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to ZA9907664A priority patent/ZA997664B/xx
Priority to NL1013892A priority patent/NL1013892C2/nl
Priority to DE19961405A priority patent/DE19961405A1/de
Priority to JP36476199A priority patent/JP4880104B2/ja
Priority to US09/471,323 priority patent/US6514479B1/en
Priority to CN99126910A priority patent/CN1128672C/zh
Publication of FR2785279A1 publication Critical patent/FR2785279A1/fr
Publication of FR2785279B1 publication Critical patent/FR2785279B1/fr
Application granted granted Critical
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7023—EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7446—EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/7846—EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • B01J35/40—
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/60—Synthesis on support
    • B01J2229/62—Synthesis on support in or on other molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
FR9816421A 1998-11-02 1998-12-23 Zeolithe euo comprenant des cristaux et des agregats de cristaux de granulometries specifiques et son utilisation comme catalyseur d'isomerisation des c8 aromatiques Expired - Lifetime FR2785279B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR9816421A FR2785279B1 (fr) 1998-11-02 1998-12-23 Zeolithe euo comprenant des cristaux et des agregats de cristaux de granulometries specifiques et son utilisation comme catalyseur d'isomerisation des c8 aromatiques
ZA9907664A ZA997664B (en) 1998-12-23 1999-12-14 Euo zeolite comprising crystals and aggregates of crystals with specific granulometrys and its use as a catalyst in the isomerisation of C8 aromatic compounds.
NL1013892A NL1013892C2 (nl) 1998-12-23 1999-12-20 Zeoliet EUO, die kristallen en aggregaten van kristallen met bepaalde korrelgrootten bevat, en zijn toepassing als katalysator voor de isomerisatie van C8 aromatische verbindingen.
DE19961405A DE19961405A1 (de) 1998-12-23 1999-12-20 Kristalle und Kristallaggregate unterschiedlicher Korngrößen enthaltender EUO-Zeolith und seine Anwendung als Isomerisierungskatalysator
JP36476199A JP4880104B2 (ja) 1998-12-23 1999-12-22 特殊な粒度の結晶および結晶の集合体を含むゼオライトｅｕｏ、並びにｃ８芳香族化合物の異性化触媒としてのその使用
CN99126910A CN1128672C (zh) 1998-12-23 1999-12-23 含结晶和具特定颗粒分布的结晶聚集体的euo沸石及其作为异构化c8芳族化合物的催化剂用途
US09/471,323 US6514479B1 (en) 1998-12-23 1999-12-23 EUO zeolite comprising crystals and aggregates of crystals with specific granulometrys and its use as a catalyst in the isomerisation of C8 aromatic compounds

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9813839A FR2785201B1 (fr) 1998-11-02 1998-11-02 Procede de preparation d'une zeolithe de type structural euo utilisant des germes de materiaux zeolithiques
FR9813773A FR2785278B1 (fr) 1998-11-02 1998-11-02 Procede de preparation de zeolithes de type structural euo utilisant des precurseurs specifiques du structurant
FR9816421A FR2785279B1 (fr) 1998-11-02 1998-12-23 Zeolithe euo comprenant des cristaux et des agregats de cristaux de granulometries specifiques et son utilisation comme catalyseur d'isomerisation des c8 aromatiques

Publications (2)

Publication Number Publication Date
FR2785279A1 FR2785279A1 (fr) 2000-05-05
FR2785279B1 true FR2785279B1 (fr) 2000-12-15

Family

ID=27253476

Family Applications (1)

Application Number Title Priority Date Filing Date
FR9816421A Expired - Lifetime FR2785279B1 (fr) 1998-11-02 1998-12-23 Zeolithe euo comprenant des cristaux et des agregats de cristaux de granulometries specifiques et son utilisation comme catalyseur d'isomerisation des c8 aromatiques

Country Status (1)

Country Link
FR (1) FR2785279B1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2920423B1 (fr) * 2007-09-04 2009-11-13 Inst Francais Du Petrole Preparation d'un materiau composite poreux a base de zeolithe eu-1 et sa mise en oeuvre en isomerisation des aromatiques en c8.

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3165380D1 (en) * 1980-06-12 1984-09-13 Ici Plc Zeolite eu-1
US4640829A (en) * 1984-04-16 1987-02-03 Mobil Oil Corporation Synthesis of crystalline silicate ZSM-50 using dibenzyldimethylammonium ions and the product produced
EP0159845A3 (fr) * 1984-04-16 1987-09-23 Mobil Oil Corporation Synthèse d'une zéolite cristalline
ZA979264B (en) * 1996-10-17 1998-12-29 Exxon Chemical Patents Inc Synthesis of large crystal zeolites

Also Published As

Publication number Publication date
FR2785279A1 (fr) 2000-05-05

Similar Documents

Publication Publication Date Title
ZA997664B (en) Euo zeolite comprising crystals and aggregates of crystals with specific granulometrys and its use as a catalyst in the isomerisation of C8 aromatic compounds.
HK1011042A1 (en) Photo-curable liquid crystals
AU679873B2 (en) Catalyst composition useful for hydrogenation of alkynes
SG38876A1 (en) Photopolymerizable liquid crystals
KR960700457A (ko) 액티브매트릭스형 액정표시장치[active matrix type liquid crystal display system]
ITMI941252A0 (it) Composizione catalitica e processo per l'alchilazione di composti aromatici
ITMI962603A0 (it) Composizione catalitica e processo per l'alchilazione e/o la transalchilazione di composti aromatici
IT1277122B1 (it) Confezione con cerotto per l'applicazione alla pelle particolarmente cerotto transdermico
FR2739621B1 (fr) Peptides utilisables comme vecteurs pour l'adressage intracellulaire de molecules actives
AU3948495A (en) Specialized perfusion protocol for whole-body hyperthermia
DE69520631T2 (de) Folienförmiger Haken und Befestigungssystem zur Anwendung
DE69629413D1 (de) Flüssigkristallverbindung und diese enthaltende Flüssigkristall-Zusammensetzung
DE69506773T2 (de) Flüssigkristallzusammensetzung
FR2722172B1 (fr) Couvercle agitateur pour boites de teintes des machines d'agitation
DE69614756T2 (de) Smektische Flüssigkristallzusammensetzung für Aufzeichungs-/Anzeigemittel, Aufzeichnungs-/Anzeigemittel und seine Verwendung
FR2785279B1 (fr) Zeolithe euo comprenant des cristaux et des agregats de cristaux de granulometries specifiques et son utilisation comme catalyseur d'isomerisation des c8 aromatiques
DE69605751D1 (de) Nematische flüssigkristallzusammensetzung zur aktiv-matrix-anwendung
FR2808520B1 (fr) Procede de preparation d'une zeolithe de type structural euo , la zeolithe obtenue et son utilisation en tant que catalyseur d'isomerisation des c8 aromatiques
DE69738861D1 (de) Verteilung von Ressourcen für vorausgebuchte und momentan angeforderte Anrufe
FR2766810B1 (fr) Procede de preparation d'une zeolithe de type ferrierite et son utilisation comme catalyseur d'isomerisation d'une olefine lineaire en isoolefine
DE69505195D1 (de) Flüssigkristallzusammensetzung
DE69523916T2 (de) Flüssigkristallzusammensetzung
AU1653795A (en) Single line multiple purchase block & tackle system
DE69720999D1 (de) Flüssigkristallzusammensetzung
DE69208117T2 (de) Nematische Flüssigkristallzusammensetzung für Aktiv-Matrix-Anwendung

Legal Events

Date Code Title Description
CD Change of name or company name
PLFP Fee payment

Year of fee payment: 18

PLFP Fee payment

Year of fee payment: 19

PLFP Fee payment

Year of fee payment: 20