FR2753373A1 - PRESSURIZED DEVICE WITH A FOAMING COMPOSITION INCLUDING NON-IONIC AND ANIONIC SURFACTANTS - Google Patents

Abstract

The invention concerns novel transparent pressurised devices containing a transparent, stable, foaming, very soft cosmetic composition pressurised by a gas particularly hydrocarbonic, free from monohydric C1-C3 alcohol, and containing non-ionic and anionic surfactants. Such compositions are used for cleansing and removing make-up form the skin gently and efficiently.

Description

The subject of the invention is new aerosol devices comprising a cosmetic or dermatological cleaning and make-up removing composition.

The user expects a composition for cleaning and removing make-up from the skin that it makes it possible to remove all kinds of makeup products: lipstick, powder, eye shadow, foundation, etc., without damaging the skin and leaving it clean and soft. The usual makeup removers are usually in the form of a gel, lotion or cream. However, the market awaits new forms of products, both more aesthetic and possibly fun.

To meet this expectation, new make-up removers have appeared, in the form of transparent aerosol devices, containing a transparent make-up removing composition, monophasic and foaming.

Known, in particular from US Pat. No. 3,719,752, compositions for topical application, packaged in aerosols, foaming, transparent, monophasic and stable. These compositions comprise a surfactant and a propellant gas in an aqueous-alcoholic medium. The alcohol is preferably a C1-C3 monohydric alcohol. However, the use of alcohol, and in particular ethanol, in such compositions involves a risk linked to flammability. We have therefore sought to avoid the use of C1-C3 monohydric alcohol in cleansing compositions for the face.

Such devices free of C1-C3 monohydric alcohol are described in particular in document WO95 / 05796. The device described in this document comprises a monophasic, fluid composition, free of monohydric alcohol, consisting of a hydrocarbon-based propellant and an aqueous concentrate comprising a-olefin sulfonate salts, betaines and alkylpolyglucosides.

However, this device is not without drawbacks: the composition it contains is not stable over time, in particular we see appearing during storage a halo of aggregates in suspension in the composition. The aerosol can being transparent, such instability is not acceptable to the consumer.

Document EP-676188 discloses a similar device, comprising a monophasic, fluid composition, free of monohydric alcohols, consisting of a propellant gas and an aqueous concentrate. The propellant comprises a mixture of dimethyl ether and a hydrocarbon gas, the aqueous concentrate comprises surfactants and preferably a coupling agent. We also know that dimethyl ether is a flammable solvent with a very low flash point. Its use is therefore not without risks, both for the production site and for the user of the aerosol device. In addition, dimethyl ether has an unpleasant odor, capable of denaturing the fragrance of the composition.

Canadian patent CA1002256 discloses a transparent, uniform aerosol system usable for the distribution of transparent aqueous cosmetic products, including makeup-removing products. The use of a triethanolamine salt of an acyllactylic acid as surfactant makes it possible to obtain a system in which the propellant gas is completely dissolved in the aqueous phase.

US patent US 3,840,465 discloses a transparent aerosol system comprising a transparent foaming composition, free of alcohol conditioned in aerosol. This composition comprises an aqueous solution of a foaming surfactant, which is generally an anionic, in which a liquid propellant is dispersed by means of a second surfactant, soluble in the propellant and insoluble in water.

It is known, in particular from document US Pat. No. 3,719,752 and from the instability of certain compositions, that such compositions are extremely sensitive to small variations in the components of which they are made and in the proportions of these components.

Also, it is with astonishment that the applicant has discovered that it was possible to have transparent aerosol devices, comprising a transparent, stable, foaming cosmetic composition, pressurized by a gas, in particular a hydrocarbon gas, free of C1-C3 monohydric alcohol and comprising surfactants.

The invention therefore relates to a pressurized device comprising
(i) a pressurized bottle with a dispensing head,
(ii) a single-phase transparent composition comprising
A- 0.5 to 10% by weight of a propellant,
B- 90 to 99.5% by weight of an aqueous composition comprising
non-ionic surfactants and anionic surfactants, this device being capable of dispensing a foam when the dispensing head is actuated, characterized in that composition B comprises
(a) at least one nonionic emulsifying surfactant,
(b) at least one nonionic thickening surfactant, and
(c) at least one anionic surfactant.

Preferably, the single-phase transparent composition is free of dialkyl ether and of C1-C3 monohydric alcohol.

When the push button forming part of the dispensing head is actuated, the compositions of the invention are dispensed in the form of a creamy foam which cleanses the skin without attacking it. The compositions distributed by this device allow obtaining a soft foam for the skin and for the mucous membranes (lips, inside of the eyelids), having remarkable cleansing properties, which allows its use for cleansing and removing make-up from the face, including for removing make-up from products known to be difficult to remove, such as waterproof make-up.

Preferably, the pressurized bottles used in the invention are transparent. Such bottles are well known to those skilled in the art and in common use, one can for example refer to patent application WO95 / 05796 on the subject of these bottles. They particularly highlight the surprising nature of the invention: through the bottle, a transparent emulsion is observed, having a fluidity comparable to that of water, said emulsion being restored in the form of a smooth foam through the means of distribution, and not in the form of a spray as expected a priori. Any means of dispensing an aerosol can known to those skilled in the art can be used. A bottle and a dispensing means which can be used in the present invention are for example shown in patent application FR-95-12788.

Can be used in the devices according to the invention all propellants known for such applications. Mention may in particular be made of hydrocarbon gases, such as, for example, propane, n-butane, isobutane and their mixtures; fluorinated gases such as, for example, chlorodifluoromethane, dichlorodifluoromethane, difluoroethane, chlorodifluoroethane, dichlorotetrafluoroethane, etc. and their mixtures; Nitrogen, air and carbon dioxide and their mixtures can also be used as propellants in the present invention. Preferably, in the present invention, hydrocarbon gases having from 2 to 6 carbon atoms are used. Among the compositions of the invention, those having 1.5 to 6% by weight relative to the total weight of the composition of propellant gas are preferred.

The word transparent means that through the bottle containing the composition one can distinguish the characters printed on a newspaper page placed behind this bottle. This term also means that a 10 cm thick sample of the composition has a maximum light transmission of at least 4% in any wavelength between 200 nm and 800 nm.

The device according to the invention therefore comprises an aqueous composition B which comprises nonionic surfactants and anionic surfactants, in particular at least one nonionic emulsifying surfactant, at least one nonionic thickening surfactant, and at least one anionic surfactant.

Composition B therefore does not comprise a cationic or amphoteric surfactant.

Preferably, composition B is adjusted, and in particular the choice and the percentage of the thickener (s), so that this composition B has a Brookfield viscosity at 25 "C of between 5 and 200 mPa.s, and preferably between 10 and 150m Pa.s.

Preferably, the aqueous composition B comprises 1 to 25%, and even more preferably 3 to 12% by weight, of at least one nonionic emulsifying surfactant.

Advantageously, the aqueous composition B comprises 0.5 to 30%, and even more preferably 1 to 6% by weight, of at least one nonionic thickening surfactant.

See the document Encyclopedia of Chemical Technology, KIRK
OTHMER, volume 22, p.333-432, 3rd edition, 1979, WILEY, for the definition of the properties and functions (emulsifier, thickener) of surfactants, in particular p.360-377 of this reference, for non-surfactants ionic.

The nonionic emulsifying surfactants which can be used in the present invention are preferably chosen from those having an HLB balance of between 12 and 18. The HLB (hydrophilic-lipophilic balance) of an emulsifier is calculated according to the following formula:
100-L
HLB =
5 in which L represents the percentage by weight of the lipophilic group relative to the weight of the whole molecule.

Preferably, these surfactants are chosen from the products of addition of 1 to 200 moles of ethylene oxide or of propylene oxide on partial esters of polyols having 2 to 16 carbon atoms and of fatty acids having 12 to 22 carbon atoms. Advantageously, products such as those described above are chosen having an esterification rate less than or equal to 2.

The nonionic thickening surfactants which can be used in the present invention are preferably chosen from, alone or as a mixture,
a- C1-C6 alkanolamides of C8-C22 alkyl ether carboxylic acids;
b- adducts of 10 to 300 moles of ethylene oxide or propylene oxide on partial esters of polyols having 2 to 16 carbon atoms and of fatty acids having 12 to 22 carbon atoms. Among this family of products, preference is given to those having an esterification rate greater than or equal to 2;
g- polyoxyethylenated and / or polyoxypropylenated and / or polyglycerolated C12-C22 fatty alcohols comprising from 20 to 500 ethylene oxide and / or propylene oxide and / or glycerol residues,
d- the C12-C22 fatty esters of polyoxyethylene and / or polyoxypropylene and / or polyglycerol,
e- block polymers of polyethylene glycol and / or polypropylene glycol.

Advantageously, the compositions according to the invention comprise at least two thickening surfactants each belonging to two different families, among the families of thickeners a to e described above.

dans laquelle R représente une chaîne alkyle ayant 8 à 30 atomes de carbone, R' représente une chaîne alkyle ayant 1 à 6 atomes de carbone, Y représente un radical éthylène di-yle ou propylène 1,3-di-yle et n représente un nombre entier allant de O à 100.The expression C1-C6 alkanolamide of C8-C22 alkyl ether carboxylic acid denotes products corresponding to the formula:

in which R represents an alkyl chain having 8 to 30 carbon atoms, R 'represents an alkyl chain having 1 to 6 carbon atoms, Y represents an ethylene di-yl or propylene 1,3-di-yl radical and n represents a integer ranging from O to 100.

For example, R can be chosen from stearyl, oleyl, ricinoleyl, linoleyl, lauryl, myristyl, capryle, palmityl radicals or from mixtures of C8-C22 alkyl radicals.

R 'can for example be chosen from methyl, ethyl, n-propyl, isopropyl, terbutyl and n-hexyl radicals.

Among the partial polyol esters which can be used in the present invention, mention may be made in particular of those which are derived from glycol, glycerol and sugars, such as for example glucose, fructose, maltose, ribose, arabinose, xylose , lyxose, ribulose, xylulose, 'allocate, altrose, mannose, gulose, galactose, sucrose, sorbitol.

Among the thickening surfactants which can be used in the present invention, there may be mentioned, for example, the following products: castor oil, monoethanolamides of alkyl acid (C13, C15) carboxylic ether (2 EO), monoethanolamide of carboxylic ether acid ( Oxyethylenated tallow mono- and di-glycerides (200 OE), oxyethylenated tallow mono- and di-glycerides (82 OE), oxyethylenated coconut mono- and diglycerides (78 OE), triglycerides of stearic and hydroxystearic acid (40 EO), polyethylene glycol mono-stearate (100 EO),
Polyglycerolated dodecanediol alcohol (3.5 mol) and more generally the products described in patent FR-2091516, oxyethylenated (250 EO) 2-octyl dodecanol, oxyethylenated stearyl alcohol (100 EO), alcohol oxyethylenated oleic (50 EO), polyethylene glycol dioleate (50 EO), oxyethylenated glycerol palmitate (200 EO), oxyethylenated sorbitan triisostearate (160 EO), oxyethylenated sorbitan isostearate tri (200 EO) ), polyethylene glycol stearate (150 EO),), oxyethylenated methyl glucose di-oleate (120 EO), oxyethylenated penta-erythrityl tetra-stearate (150 EO), polyethylene glycol di-oleate (55 EO) ), Polyethylene glycol undecylenate (300 EO), polyethylene glycol di-stearate (150 EO).

Among the polyoxyalkylenated polyol esters which can be used as emulsifying surfactants, the following products may be mentioned, for example: oxyethylenated glycerol monoundecylenate (7 EO), oxyethylenated glycerol monostearate (15 EO), glycerol mono-laurate oxyethylenated (20 EO), oxyethylenated glycerol di-laurate (20 EO), oxyethylenated di-glycerol stearate (4 EO), oxyethylenated glycerol cocoate (7 EO), oxyethylenated glycerol monoisostearate pyrrolidone carboxylate (250E), oxyethylenated glycerol mono stearate (20 EO), oxyethylenated glycerol monostearate (30 EO), oxyethylenated diglycerol stearate (4 EO), oxyethylenated coconut mono- and di-glycerides (30 EO), oxyethylene sorbitan lanolate (40 EO), oxyethylenated sorbitan mono-oleate (20 EO), oxyethylenated sorbitan tri-oleate (20 EO), oxyethylenated sorbitan mono-palmitate (20 EO), sorbita mono-stearate oxyethylenated (20 EO), oxyethylenated sorbitan mono-laurate (20 EO),
Oxyethylenated sorbitan undecylenate (20 EO), oxyethylenated sorbitan undecylenate (18 EO), oxyethylenated sorbitan hexa-stearate (6 EO), oxyethylenated sorbitan monolaurate (44 EO), sorbitan tetra oleate oxyethylenated (30 EO), oxyethylenated sorbitan mono-stearate (4 EO), oxyethylenated sorbitan oleate (40 EO), oxyethylenated sorbitan mono-laurate (4 EO), oxyethylenated sorbitan mono-laurate (10 EO), oxyethylenated sorbitan tetra oleate (40 EO), oxyethylenated butyl glucoside cocoate (3 EO), oxypropylenated methyl glucoside di-stearate (20 OP), oxyethylenated methyl glucoside mono-laurate ( 20 EO), oxyethylenated methyl glucose benzoate (20 EO), oxyethylenated castor tri-glyceride esters (1.4 EO), ricin tri-glyceride esters of oxyethylenated sucrose (2 EO) , oxyethylenated methyl glucose sesquistearate (20 EO), di-stearate of oxyethylenated methyl glucose (20 EO), oxyethylenated butanediol mono-stearate (4 EO), oxyethylenated polyethylene glycol mono-stearate (50 EO), polyethylene glycol di-stearate, polyethylene glycol myristate (8 EO ), polyethylene glycol mono-stearate (8 EO), polyethylene glycol mono-stearate (20 EO), polyethylene glycol laurate (6 EO), polyethylene glycol di-stearate (8 EO), di -polyethylene glycol laurate (8 EO), polyethylene glycol mono-oleate (8 EO), tetra-ethylene glycol di-heptanoate, polyethylene glycol di-oleate (8 EO), polypropylene glycol oleate (26 EO), polyethylene glycol dipolyhydroxystearate (6 hydroxy) (30 EO), polyethylene glycol stearate (40 EO), polyethylene glycol di-laurate (8 EO).

Among the products which can be used in the present invention, which are commercially available, there may be mentioned:
- C1-C6 alkanolamides of C8-C22 alkyl ether carboxylic acids which are for example marketed by the company TENENKEL under the brand
COMPERLAN, or by the company CHEM Y under the brand name AMINOL;
- Adducts of ethylene oxide or propylene oxide on partial esters of polyols and fatty acids, which are for example marketed by the company BASF under the brand CREMOPHOR, or by the company
AMERCHOL under the brand GLUCAMATE;
polyoxyethylenated and / or polyoxypropylenated and / or polyglycerolated fatty alcohols, C12-C22, which are for example marketed by the company ICI under the brand BRIJ,
- C12-C22 fatty esters of polyoxyethylene and / or polyoxypropylene and / or polyglycerol, which are for example marketed by the company ICI under the brand MYRJ
- block polymers of polyethylene glycol and / or polypropylene glycol, which are for example marketed by the company ICI under the brand SYNPERONlC.

The compositions of the present invention preferably comprise at least one thickening surfactant as defined above. In practice, the amount of thickener used is adapted to satisfy the viscosity criterion given above. An excessive amount of this type of compound can lead to a significant thickening of the composition of the invention, which then becomes difficult to distribute as an aerosol. Too small a quantity has the disadvantage of jeopardizing the stability of the composition.

Preferably, the aqueous composition B comprises from 2 to 12%, and even more preferably from 4 to 10% by weight of anionic surfactant. This anionic surfactant can be chosen from those described in the document Encyclopedia of
Chemical Technology, KIRK-OTHMER, p.347-460, 3rd edition, WILEY.

According to a preferred embodiment of the invention, the aqueous composition B comprises at least two anionic surfactants. Advantageously, it comprises at least one foaming surfactant and at least one mild surfactant.

By foaming surfactant is preferably meant a surfactant chosen from sulfates, ether sulfates and their salts. Among the sulphate and ether sulphate salts, the sodium and triethanolamine salts are preferably chosen.

By mild surfactant is preferably meant a surfactant chosen from sulfosuccinates, isethionates, carboxylates and sarcosinates.

Advantageously, the compositions B also comprise at least one alkylpolyglucoside. Preferably, this alkylpolyglucoside represents from 0.01 to 10%, and even more preferably from 1 to 6% by weight of B.

Compositions B can comprise up to about 98% water. Usually, water is understood to mean pure demineralized water. However, all or part of the water used in compositions B can optionally be chosen from mineral and / or thermal waters. In general, mineral water is fit for consumption, which is not always the case with thermal water. Each of these waters contains, among other things, dissolved minerals and / or trace elements.

These waters are known to be used for specific treatment purposes according to the specific trace elements and minerals they contain, such as hydration and desensitization of the skin or the treatment of certain dermatoses. By mineral or thermal waters, we will not only denote natural mineral or thermal waters, but also natural mineral or thermal waters enriched with mineral constituents and / or additional trace elements, as well as aqueous mineral and / or trace element solutions prepared for from purified water (demineralized or distilled).

A natural thermal or mineral water used according to the invention can, for example, be chosen from Vittel water, the waters of the Vichy basin, Uriage water,
Roche Posay water, Bourboule water, Enghien-les-Bains water, Saint Gervais-les-Bains water, Néris-les-Bains water, water of Allevar-ies-Bains,
The water of Digne, the water of Maizières, the water of Neyrac-les-Bains, the water of Lons-le
Saunier, Eaux Bonnes, Rochefort water, Saint Christau water, smoking water and Tercis-les-Bains water, Avene water.

The cosmetic or dermatological compositions of the invention can, in addition, contain adjuvants customary in the fields concerned such as preservatives, antioxidants, perfumes, filters, coloring matters, hydrophilic or lipophilic active agents.

The active ingredients for the skin can be anti-aging active agents, anti-wrinkle active agents, moisturizers or humectants, depigmenting active agents, anti-free radical active agents (radical oxygen species), nutritive active agents, active protectors, restructuring active agents, firming active agents, anti-acne active agents, exfoliating active agents, emollient active agents or even active agents treating skin diseases such as mycoses, dermatitis, psoriasis, etc. These active agents are used, depending on their nature, in the usual proportions and for example from 0.01% to 10% by weight relative to the total weight of the composition.

As anti-acne, anti-aging, anti-wrinkle, hydrating, exfoliating active agents, there may be mentioned more particularly α-hydroxy acids (glycolic, lactic, malic, citric acids, etc.).

As antioxidants, there may be mentioned for example sulfites.

The following examples are given by way of illustration of the invention and are not intended to be limiting.

All the amounts are given as a percentage by weight of active material relative to the total weight of the composition. The raw materials are given in CTFA name. The viscosity is measured at 25 "C using a Brookfield viscometer, the speed of the rotating module (module I) is fixed at 5 revolutions / min.

Example 1:
G:
Isobutane 4
B:
Sodium laureth sulfate 8
Laureth-66 PPG-14dicarbamate 3
Decyl glucoside 2,4
Disodium laureth sulfosuccinate 1.9
Citric acid 1.9
Lactic acid 1.7
Polysorbate 20 1
Phenoxyethanol 0.5
Conservative qs
Demineralized water qs
Procedure: The aqueous composition B is prepared by mixing, with stirring, all the ingredients mentioned.

The viscosity of the aqueous composition B is measured: it is equal to 26 mPa.s.

These compositions are then introduced into a pressurized bottle provided with a dispensing head into which the pressurized gas G is introduced.

The whole is stirred so as to obtain a homogeneous mixture of the two initial phases.

Example 2:
G:
Isobutane 5
B:
Sodium laureth sulfate 5.3
Laureth-66 PPG-14 dicarbamate 0.3
Decyl glucoside 5
Disodium laureth sulfosuccinate 1.9
Cocamide MEA 1.5
Polysorbate 20 3.4
Phenoxyethanol 0.5
Alpha hydroxy acids qs
Conservative qs
Demineralized water qs
Procedure: see example 1.

Viscosity of the aqueous composition B: 50 mPa.s
The devices and compositions according to Examples 1 and 2 are perfectly transparent and halo-free, both at the time of their preparation and after several months of storage at room temperature in a room benefiting from natural lighting.

By actuating the dispensing head, a creamy foam is obtained, which is not very irritating and has good cleaning properties for human skin.

Example 3 (comparative)
G:
Isobutane 5
B:
Sodium laureth sulfate 8.4
Laureth-66 PPG-14dicarbamate 0.3
Polysorbate 20 3.4
Polysorbate 21 1
PEG-1 50 distearate 0.5
Laureth-4 0.5
Disodium laureth sulfosuccinate 1.5
Cocamido propyl betaine 1.5
Phenoxyethanol 0.5
Alpha hydroxy acids qs
Conservative qs
Demineralized water qs
Procedure: see example 1.

A device comprising a halo is obtained as soon as it is prepared.

Claims (25)

1- Pressurized device comprising  (i) a pressurized bottle with a dispensing head,  (ii) a single-phase transparent composition comprising  A- 0.5 to 10% by weight of a propellant,  B- 90 to 99.5% by weight of an aqueous composition comprising  non-ionic surfactants and anionic surfactants, this device being capable of dispensing a foam when the dispensing head is actuated, characterized in that composition B comprises  (a) at least one nonionic emulsifying surfactant,  (b) at least one nonionic thickening surfactant, and  (c) at least one anionic surfactant. 2- Device according to claim 1, characterized in that the pressurized bottle is transparent. 3- Device according to any one of the preceding claims, characterized in that it comprises from 1.5 to 6% by weight of propellant, relative to the total weight of the composition. 4- Device according to any one of the preceding claims, characterized in that the propellant gas is chosen from hydrocarbon gases having 2 to 6 carbon atoms. 5- Device according to any one of the preceding claims, characterized in that composition B has a Brookfield viscosity at 25 "C between 5 and 200 mPa.s. 6- Device according to any one of the preceding claims, characterized in that composition B has a Brookfield viscosity at 25 "C between 10 and 150 mPa.s. 7- Device according to any one of the preceding claims, characterized in that the aqueous composition B comprises 1 to 25%, and preferably 3 to 12% by weight, of at least one nonionic emulsifying surfactant. 8- Device according to any one of the preceding claims, characterized in that the aqueous composition B comprises 0.5 to 30%, and preferably 1 to 6% by weight, of at least one nonionic thickening surfactant. 9- Device according to any one of the preceding claims, characterized in that the nonionic emulsifying surfactant is chosen from those having an HLB balance of between 12 and 18.  10- Device according to Device according to any one of the preceding claims, characterized in that the emulsifying surfactant is chosen from products of addition of 1 to 200 moles of ethylene oxide or propylene oxide on partial esters polyols having 2 to 16 carbon atoms and fatty acids having 12 to 22 carbon atoms. 11- Device according to claim 10, characterized in that the emulsifying surfactant has an esterification rate less than or equal to 2. 12- Device according to any one of the preceding claims, characterized in that the nonionic thickening surfactant is chosen from, alone or as a mixture:  a- C1-C6 alkanolamides of C8-C22 alkyl ether carboxylic acids;  b- the adducts of 10 to 300 moles of ethylene oxide or propylene oxide on partial esters of polyols having 2 to 16 carbon atoms and of fatty acids having 12 to 22 carbon atoms;  g- fatty alcohols C12-C22 polyoxyethylenated and / or polyoxypropylenated eVou polyglycerolated, comprising from 20 to 500 residues of ethylene oxide and / or propylene oxide and / or glycerol;  d- C12-C22 fatty esters of polyoxyethylene and / or polyoxypropylene and / or polyglycerol;  e- block polymers of polyethylene glycol and / or polypropylene glycol. 13- Device according to claim 12, characterized in that the aqueous composition B comprises at least two thickening surfactants each belonging to two different families chosen from families 'a' to 'e'. 14- Device according to any one of claims 10 to 13, characterized in that the polyols are chosen from glycol, glycerol, glucose, fructose, maltose, ribose, arabinose, xylose, lyxose , ribulose, xylulose, Allose, altrose, mannose, gulose, galactose, ie sucrose, sorbitol. 15- Device according to any one of the preceding claims, characterized in that the thickening surfactant is chosen from castor oil, monoethanolamides of alkyl acid (C13, C15) carboxylic ether (2 EO), mo noethanolamide d carboxylic ether acid (50 EO), oxyethylenated tallow mono- and di-glycerides (200 EO), oxyethylenated tallow mono- and di-glycerides (82 EO), oxyethylenated coconut mono- and di-glycerides ( 78 EO), triglycerides of stearic and hydroxystearic acid (40 EO), polyethylene glycol mono-stearate (100 EO), polyglycerolated dodecanediol alcohol (3, Smoles), oxyethylenated 2-octyl dodecanol (250 EO) ), Oxyethylenated stearyl alcohol (100 EO), oxyethylenated oleic alcohol (50 EO), polyethylene glycol dioleate (50 EO), oxyethylenated glycerol palmitate (200 EO), sorbitan triisostearate oxyethylenated (160 EO), oxyethylenated sorbitan triisostearate (200 O E), polyethylene glycol stearate (150 EO),), oxyethylenated methyl glucose di-oleate (120 EO), oxyethylene pentaerythrityl tetra stearate (150 EO), polyethylene glycol di-oleate (55 EO), polyethylene glycol undecylenate (300 EO), polyethylene glycol di-stearate (150 EO). 16- Device according to any one of the preceding claims, characterized in that the emulsifying surfactant is chosen from oxyethylenated glycerol mono-undecylenate (7 EO), oxyethylenated glycerol monostearate (15 EO), glycerol mono-laurate oxyethylenated (20 EO), oxyethylenated glycerol di-laurate (20 EO), oxyethylenated di-glycerol stearate (4 EO), oxyethylenated glycerol cocoate (7 EO), oxyethylenated glycerol monoisostearate pyrrolidone carboxylate (250E ), oxyethylenated glycerol mono stearate (20 EO), oxyethylenated glycerol monostearate (30 EO), oxyethylenated di-glycerol stearate (4 EO), oxyethylenated coconut mono- and di-glycerides (30 EO), oxyethylenated sorbitan lanolate (40 EO), oxyethylenated sorbitan mono-oleate (20 EO), oxyethylenated sorbitan tri-oleate (20 EO), oxyethylenated sorbitan mono-palmitate (20 EO), mono-stearate sorbit oxyethylenated donkey (20 EO), oxyethylenated sorbitan mono-laurate (20 EO), oxyethylenated sorbitan undecylenate (20 EO), oxyethylenated sorbitan undecylenate (18 EO), oxyethylenated sorbitan hexastearate (6 EO) ), oxyethylenated sorbitan mono-laurate (44 EO), oxyethylenated sorbitan tetra-oleate (30 EO), oxyethylenated sorbitan mono-stearate (4 EO), oxyethylenated sorbitan oleate (40 EO), oxyethylenated sorbitan mono-laurate (4 EO), oxyethylenated sorbitan mono-laurate (10 EO), oxyethylenated sorbitan tetra-oleate (40 EO), butyl glucoside oxyethylenated (3 EO), di-stearate of oxypropylenated methyl glucoside (20 OP), oxyethylenated methyl glucoside mono-laurate (20 EO), oxyethylenated methyl glucose benzoate (20 EO), castor tri-glyceride esters of oxyethylenated sucrose (1.4 EO) ), oxyethylenated castor and sucrose tri-glyceride esters (2 EO) , oxyethylenated methyl glucose sesquistearate (20 EO), oxyethylenated methyl glucose di-stearate (20 EO), oxyethylene butanediol monostearate (4 EO), polyethylene glycol oxyethylenated mono-stearate, di -polyethylene glycol stearate, polyethylene glycol myristate (8 EO), polyethylene glycol mono-stearate (8 EO), polyethylene glycol mono-stearate (20 EO), polyethylene glycol laurate (6 EO), polyethylene glycol di-stearate (8 EO), polyethylene glycol di-laurate (8 EO), polyethylene glycol mono-oleate (8 EO), tetra-ethylene glycol di-heptanoate, di-oleate polyethylene glycol (8 EO), polypropylene glycol oleate (26 EO), di-polyhydroxystearate (6 hydroxy) polyethylene glycol (30 EO), polyethylene glycol stearate (40 EO), di-laurate polyethylene glycol (8 EO). 17- Device according to any one of the preceding claims, characterized in that the aqueous composition B comprises from 2 to 12%, and preferably from 4 to 10% by weight of anionic surfactant. 18- Device according to any one of the preceding claims, characterized in that the aqueous composition B comprises at least two anionic surfactants. 19- Device according to claim 18, characterized in that the aqueous composition B comprises at least one foaming anionic surfactant and at least one mild anionic surfactant. 20- Device according to any one of the preceding claims, characterized in that the aqueous composition B further comprises at least one alkylpolyglucoside. 21- Device according to any one of the preceding claims, characterized in that the aqueous composition B comprises 0.01 to 10%, and preferably 1 to 6% by weight, of at least one alkylpolyglucoside. 22- Device according to any one of the preceding claims, characterized in that the composition comprises mineral water and / or thermal water. 23- Device according to any one of the preceding claims, characterized in that the composition also comprises at least one adjuvant chosen from preservatives, antioxidants, perfumes, filters, coloring matters, hydrophilic or lipophilic active agents. 24- Device according to any one of the preceding claims, characterized in that the composition further comprises at least one α-hydroxy acid. 25- Device according to any one of the preceding claims, characterized in that the composition is suitable for cleaning and / or caring for human skin.