FR2731435A1 - Liq. surfactant compsn. esp. for skin and hair care - Google Patents
Liq. surfactant compsn. esp. for skin and hair care Download PDFInfo
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- FR2731435A1 FR2731435A1 FR9502849A FR9502849A FR2731435A1 FR 2731435 A1 FR2731435 A1 FR 2731435A1 FR 9502849 A FR9502849 A FR 9502849A FR 9502849 A FR9502849 A FR 9502849A FR 2731435 A1 FR2731435 A1 FR 2731435A1
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- seawater
- detergent
- skin
- liq
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/965—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of inanimate origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
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- General Health & Medical Sciences (AREA)
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- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Dermatology (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
L'invention concerne des compositions contenant l'eau de mer débactérisée à usage de savons liquides pour la peau, de shampooings pour cheveux et autres matières fibreuses et de bains moussants. The invention relates to compositions containing debacterized seawater for the use of liquid skin soaps, hair shampoos and other fibrous materials and bubble baths.
Le fait banal qui, aux yeux de tous, caractérise l'eau de mer est certainement la salinité. La salinité (S Qo) qu'on détermine expérimentalement selon la méthode de KNUDSEN, représente la concentration en sels minéraux, qui ne sont pas uniquement du chlorure de sodium. La salinité moyenne de l'eau de mer est de 35 %o(1000 g d'eau de mer contient 35 g de sels: chlorure de sodium, de magnésium, de potassium, sulfates de calcium, carbonates, bromures etc). The commonplace fact which, in everyone's eyes, characterizes seawater is certainly salinity. The salinity (S Qo) which is determined experimentally according to the KNUDSEN method, represents the concentration of mineral salts, which are not only sodium chloride. The average salinity of sea water is 35% o (1000 g of sea water contains 35 g of salts: sodium chloride, magnesium, potassium, calcium sulfates, carbonates, bromides etc).
Un kilogramme d'eau marine de 35 %, de salinité et 19 % de chlorinité (cl % ) contient:
18900 mg de Chlore
10561 mg de Sodium
1272 mg de Magnésium
884 mg de Soufre
400 mg de Calcium
380 mg de Potassium
65 mg de Brome
28 mg de Carbone
Il contient d'autres éléments à l'état de trace (oligo éléments), soient:
0,005 mg de Zinc
0,0015 mg de Uranium
0,0003 mg d'Argent
0,0001 mg de Nickel
0,000006 mg d'Or
0,0000000003 mg de Radium
M.KNUDSEN, Océanographe Danois, en considérant l'eau de mer comme étant une solution plus ou moins diluée, où tous les sels restent dans un rapport constant, a établi des tables qui permettent, en dosant un seul élément (le chlore) de déduire immédiatement la salinité de l'eau étudiée (S %. = 0,030+1,805 cl %o). One kilogram of 35% marine water, salinity and 19% chlorinity (cl%) contains:
18900 mg of Chlorine
10561 mg of Sodium
1272 mg of Magnesium
884 mg of Sulfur
400 mg of Calcium
380 mg of Potassium
65 mg of Bromine
28 mg of Carbon
It contains other trace elements (trace elements), namely:
0.005 mg of Zinc
0.0015 mg of Uranium
0.0003 mg Silver
0.0001 mg of Nickel
0.000006 mg of Gold
0.000000003 mg of Radium
M.KNUDSEN, Danish Oceanographer, considering seawater as being a more or less diluted solution, where all the salts remain in a constant ratio, has established tables which allow, by dosing a single element (chlorine) to immediately deduct the salinity of the water studied (S%. = 0.030 + 1.805 cl% o).
D'autres éléments, dépendant du plancton ont par contre des teneurs variables : (phosphates, nitrates, nitrites, silicates, fer, manganèse, cuivre, Arsenic).Other elements, dependent on plankton, on the other hand, have varying contents: (phosphates, nitrates, nitrites, silicates, iron, manganese, copper, Arsenic).
Pour une Chlorinité de 19 % les éléments à teneur variable oscillent entre les chiffres suivants:
Silicium 0,02 à 4,0 mg/kg
Azote ( à l'état liée) 0,01 à 0,7 mg/kg
Phosphore 0,001 à 0,10 mg/kg
Arsenic 0,01 à 0,02 mg/kg
Fer 0,002 à 0,02 mg/kg
Manganèse 0,001 à 0,01 mg/kg
Cuivre 0,001 à 0,01 mg/kg
L'eau de mer a un pH alcalin qui est voisin de 8. Sa teneur en Oxygène dissous est d'environ 8 mg/l (en surface), cette teneur frôle la saturation.For a Chlorinity of 19% the elements with variable content oscillate between the following figures:
Silicon 0.02 to 4.0 mg / kg
Nitrogen (in bound state) 0.01 to 0.7 mg / kg
Phosphorus 0.001 to 0.10 mg / kg
Arsenic 0.01 to 0.02 mg / kg
Iron 0.002 to 0.02 mg / kg
Manganese 0.001 to 0.01 mg / kg
Copper 0.001 to 0.01 mg / kg
Seawater has an alkaline pH which is close to 8. Its dissolved oxygen content is approximately 8 mg / l (at the surface), this content is close to saturation.
Alors que la plupart des compositions détergentes liquides dont l'eau est l'excipient subissent avant finition, des additions telles que:
- le Chlorure de sodium pour l'augmentation de la viscosité ou du blanchiment.While most liquid detergent compositions whose water is the excipient undergo before finishing, additions such as:
- Sodium chloride for increasing viscosity or bleaching.
- Un composé libérant l'oxygène ou l'eau oxygénée pour l'hygiène de la peau. - A compound releasing oxygen or oxygenated water for skin hygiene.
- Des oligo-éléments pour le traitementet la reminéralisationde la peau. - Trace elements for the treatment and remineralization of the skin.
- Une base chimique pour augmenter le pH (la plupart des savons sont plus stables dans des milieux alcalins). - A chemical base to increase the pH (most soaps are more stable in alkaline environments).
L'eau de mer avec ses caractéristiques intrinsèques (sels minéraux, oligo éléments, pH alcalin,teneur importante en oxygène dissous) conviendrait parfaitement à des compositions dont le besoin en ces propriétés existe. Sans oublier l'eau comme excipient. D'où l'intérêt des compositions détergentes contenant l'eau de mer débactérisée pour le traitement et le nettoyage de la peau ou / et des cheveux. Seawater with its intrinsic characteristics (mineral salts, trace elements, alkaline pH, high content of dissolved oxygen) would be perfectly suitable for compositions whose need for these properties exists. Without forgetting water as an excipient. Hence the interest of detergent compositions containing debacterized seawater for the treatment and cleansing of the skin and / or hair.
La substance détergente utilisée dans les compositions de l'invention peut-être n'importe laquelle de celles qui trouvent une application dans le lavage de la peau, des cheveux et d'autres matières fibreuses. Ces substances détergentes comprennent des tensio-actifs non ioniques éthoxylès, des savons d'acides gras, des aikyl benzène sulfonates, des alkyl sulfates, des sulfates d'éther alkyliques, des sulfates de monoglycérides, des alkylphosphates, des méthyltaurides et alconolamides d'acides gras. Quand la compositions détergente est destinée à servir de savon liquide pour la peau, les substances détergentes préférées sont celles à base de sels d'acides gras, particulièrement l'oléate de sodium, I'oléate de potassium, I'oléate d'ammonium, I'oléate de triéthanolamine ou/et un non ionique poîyéthoxylé comme le mony 1 phémol (NP9).Quand la composition détergente est destinée à servir de bain moussant ou de shampooing pour les cheveux humains ou les poils des animaux, les substances préférées sont celles à base d'alcools gras ou de produits d'éthoxylation d'alcools gras, particulièrement ceux qui sont dérivés des alcools laurylique et myristylique et leurs sels, par exemple le lauryl sulfate de sodium, le sel de sodium du sulfate d'éther laurylique, le lauryl sulfate de monoéthanolamine, le lauryl sulfate d'ammonium, le lauryl sulfate de triéhanolamine, le sel dissodique de I'étoxy-sulfosuccinate.de cocomonoéthanolamide.La composition détergente liquide comprend au moins une substance détergente dans les proportions pondérales comprises entre 7 et 30 Gá selon la nature de la ou des substances détergentes utilisées et un complément de 60 à 90 to d'eau de mer débactériarisée. Dans la composition, la concentration en matière active du savon peut varier, en poids, de 12,5 à 25 %;
Celle du bain moussant peut varier de 10 à 25 eá et celle du shampooing peut varier de 7 à 30 %.The detergent substance used in the compositions of the invention may be any of those which find application in washing the skin, hair and other fibrous materials. These detergents include ethoxylated nonionic surfactants, fatty acid soaps, aikyl benzene sulfonates, alkyl sulfates, alkyl ether sulfates, monoglyceride sulfates, alkylphosphates, methyltaurides and acid alconolamides bold. When the detergent composition is intended to serve as a liquid soap for the skin, the preferred detergent substances are those based on salts of fatty acids, particularly sodium oleate, potassium oleate, ammonium oleate, Triethanolamine oleate or / and a nonionic polyethoxylate such as mony 1 phémol (NP9) .When the detergent composition is intended to be used as a foaming bath or shampoo for human hair or animal hair, the preferred substances are those based on fatty alcohols or on ethoxylation products of fatty alcohols, particularly those which are derived from lauryl and myristylic alcohols and their salts, for example sodium lauryl sulfate, the sodium salt of lauryl ether sulfate, monoethanolamine lauryl sulphate, ammonium lauryl sulphate, triehanolamine lauryl sulphate, dissodic salt of cocomonoethanolamide etoxy-sulfosuccinate. which comprises at least one detergent substance in the weight proportions of between 7 and 30 Gá depending on the nature of the detergent substance (s) used and an additional 60 to 90 tonnes of debacterialized sea water. In the composition, the concentration of active ingredient of the soap can vary, by weight, from 12.5 to 25%;
That of the bubble bath can vary from 10 to 25 eá and that of the shampoo can vary from 7 to 30%.
Le reste de la composition étant de l'eau de mer débactérisée et d'autres additifs tels que des stabilisateurs de mousse, et de conservateurs et des parfums.The rest of the composition being debacterized seawater and other additives such as foam stabilizers, and preservatives and perfumes.
Outre les ingrédients essentiels, les compositions de l'invention peuvent contenir d'autres substances généralement présentes dans les compositions détergentes. Par exemple, on peut épaissir la composition si on le désire en ajoutant des agents connus d'accroissement de la viscosité comme la gomme de xanthane, I'alcool cétylique, le diéthanolamide linoléique et des épaississants cellulosiques tels que l'hydroxyéthyl cellulose. On peut aussi incorporer des stabilisateurs de mousse dont des exemples sont le coco-diéthamolamide, l'isopropanolamide launque, les alky diméthyl bétoines, les oxydes d'alkyl diméthylamine et les copolymères silicone, glycol.Des ingrédients supplémentaires qui peuvent normalement être présents sont notamment des conservateurs comme le formol, des agents de "nacrage", des siloxanes pour ses propriétés de souplesse et toucher agréable et de réduction de la tension de surface (diminue la tendance des cheveux à s'emmêler), des colorants et des parfums. In addition to the essential ingredients, the compositions of the invention may contain other substances generally present in detergent compositions. For example, the composition can be thickened if desired by adding known viscosity increasing agents such as xanthan gum, cetyl alcohol, linoleic diethanolamide and cellulosic thickeners such as hydroxyethyl cellulose. Foam stabilizers can also be incorporated, examples of which are coco-diethamolamide, isopropanolamide launque, alky dimethyl betoines, alkyl dimethylamine oxides and copolymers of silicone, glycol. Additional ingredients which may normally be present are in particular preservatives like formaldehyde, "pearlescent" agents, siloxanes for its properties of flexibility and pleasant touch and reduction of surface tension (decreases the tendency of hair to become tangled), dyes and perfumes.
Les exemples suivants, dans lesquelles les 90 sont en poids, illustrent l'invention:
Exemple 1 savon
Préparation A): On fait gonfler 0,5 % de gomme de xanthane dans 36 % d'eau de mer débactérisée.The following examples, in which the 90 are by weight, illustrate the invention:
Example 1 soap
Preparation A): 0.5% of xanthan gum is swollen in 36% of demineralized sea water.
Préparation B): Dans 36 % d'eau de mer débactérisée on émulsione 12 90 d'acide oléique avec 1,0 90 d'un émulsifiant non ionique. 5,0 % de coco diéthonol amide est alors ajouté sous agitation, suivi de la neutralisation par 7,2 % de tnéthanonolamine.Sous agitation la préparation a) est ajoutée à la préparation b). Preparation B): In 36% of demineralized sea water, 12 90 oleic acid is emulsified with 1.0 90 of a nonionic emulsifier. 5.0% of coco diethonol amide is then added with stirring, followed by neutralization with 7.2% of tethanonolamine. Under stirring, preparation a) is added to preparation b).
Et toujours sous bonne agitation on ajoute à l'ensemble
- 1,0 qc de diméthicone ( poly diméthylsiloxane, DOW CONIMG 200). And always with good agitation we add to the whole
- 1.0 qc of dimethicone (poly dimethylsiloxane, DOW CONIMG 200).
- 1,0 % du produit nacrant (Génapol)
- 0,2 % de formol (conservateur).- 1.0% of pearlescent product (Génapol)
- 0.2% formalin (preservative).
Exemple 2 de savon
Préparation A) : Dissoudre 7,2 % de triéthanolamine dans 70 90 d'eau de mer débactérisée.Example 2 of soap
Preparation A): Dissolve 7.2% of triethanolamine in 70 90 of demineralised sea water.
Préparation B) : Dissoudre 12 % d'acide oléique dans 3,0 % de DMP (Dipropylène Glycol mono métal éther) et 2,0 90 de PM (Propylène Glycol mono méthyl éther). Preparation B): Dissolve 12% of oleic acid in 3.0% of DMP (Dipropylene Glycol mono metal ether) and 2.0 90 of PM (Propylene Glycol mono methyl ether).
La préparation B) est ajoutée à la préparation A), sous agitation, 5,0 % de coco diéthonolarnide sont ajoutés à l'ensemble suivi de 0,7 cro de parfum et 0,1 % de formol.Preparation B) is added to preparation A), with stirring, 5.0% of coco diethonolarnide are added to the whole followed by 0.7 cro of perfume and 0.1% of formalin.
Exemple 3 : Bain moussant
On emulsionne 30 % de laurwléther sulfate de sodium dans 52 90 d'eau de mer débactérisée additionné de 0,5 9c du sel disodique d'acide éthylène diaminotétracétique (EDTA) avec l'aide de 15 % d'un dérivé de glycine amphoétère modifié. 3 % de cocodiéthanolamide sont alors ajoutés suivi d'un conservateur (0,2 % de Bronidox L, Bromo 5, Nitro 5, Dioxane 1,3).Example 3: Bubble Bath
30% of sodium laurwlether sulphate is emulsified in 52 90 of demineralised seawater supplemented with 0.5% of the disodium salt of ethylene diaminotetracetic acid (EDTA) with the aid of 15% of a modified amphoether glycine derivative . 3% of cocodiethanolamide are then added followed by a preservative (0.2% of Bronidox L, Bromo 5, Nitro 5, Dioxane 1.3).
Exemple 4: Shampooing
On mélange 40 % de lauryléthersuliate de sodium (à 27 %). Example 4: Shampoo
40% of sodium laurylethersuliate (27%) is mixed.
3 % de cocodiéthanolamide, de 56,8 Go d'eau de mer débacténsée, 0,5 % d'EDTA et 0,2 % d'agent conservateur (Bronidox L). 3% cocodiethanolamide, 56.8 GB of debittened seawater, 0.5% EDTA and 0.2% preservative (Bronidox L).
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9502849A FR2731435B1 (en) | 1995-03-07 | 1995-03-07 | LIQUID DETERGENT COMPOSITIONS CONTAINING DEBACTERIZED SEA WATER FOR THE TREATMENT OF SKIN, HAIR AND OTHER FIBROUS MATERIALS |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9502849A FR2731435B1 (en) | 1995-03-07 | 1995-03-07 | LIQUID DETERGENT COMPOSITIONS CONTAINING DEBACTERIZED SEA WATER FOR THE TREATMENT OF SKIN, HAIR AND OTHER FIBROUS MATERIALS |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2731435A1 true FR2731435A1 (en) | 1996-09-13 |
| FR2731435B1 FR2731435B1 (en) | 1998-04-17 |
Family
ID=9476949
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR9502849A Expired - Fee Related FR2731435B1 (en) | 1995-03-07 | 1995-03-07 | LIQUID DETERGENT COMPOSITIONS CONTAINING DEBACTERIZED SEA WATER FOR THE TREATMENT OF SKIN, HAIR AND OTHER FIBROUS MATERIALS |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2731435B1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2777778A1 (en) * | 1998-04-24 | 1999-10-29 | Codif International Sa | Cosmetic products containing mineralized water |
| ITRC20120004A1 (en) * | 2012-01-30 | 2012-04-30 | Astril S R L | DETERGENT FOR THE HAND WASHING OF DISHES AND DISHES MADE ENTIRELY WITH SEA WATER AND BIODEGRADABII SURFACTANTS, COMPLETE WITH PRODUCTION PROCESS. |
| ITCS20130002A1 (en) * | 2013-01-29 | 2014-07-30 | Astril Srl | CLEANING COMPOSITION FOR HAND DISHWASHING OF DISHES AND DISHES MADE WITH SEA WATER AND BIODEGRADABLE SURFACTANTS AND PRODUCTION PROCEDURE |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2094708A5 (en) * | 1970-06-30 | 1972-02-04 | Moreau Francis | Foamed javel water-contg a detergent |
| DE3232136A1 (en) * | 1982-08-28 | 1984-03-01 | Ruth Cegla GmbH, 7542 Schömberg | Mixture containing sea salt and/or saline salt |
| JPH05117158A (en) * | 1991-10-22 | 1993-05-14 | Sasaki Kagaku Yakuhin Kk | External preparation composition for skin |
-
1995
- 1995-03-07 FR FR9502849A patent/FR2731435B1/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2094708A5 (en) * | 1970-06-30 | 1972-02-04 | Moreau Francis | Foamed javel water-contg a detergent |
| DE3232136A1 (en) * | 1982-08-28 | 1984-03-01 | Ruth Cegla GmbH, 7542 Schömberg | Mixture containing sea salt and/or saline salt |
| JPH05117158A (en) * | 1991-10-22 | 1993-05-14 | Sasaki Kagaku Yakuhin Kk | External preparation composition for skin |
Non-Patent Citations (1)
| Title |
|---|
| DATABASE WPI Section Ch Week 9324, Derwent World Patents Index; Class D21, AN 93-191439, XP002027692 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2777778A1 (en) * | 1998-04-24 | 1999-10-29 | Codif International Sa | Cosmetic products containing mineralized water |
| ITRC20120004A1 (en) * | 2012-01-30 | 2012-04-30 | Astril S R L | DETERGENT FOR THE HAND WASHING OF DISHES AND DISHES MADE ENTIRELY WITH SEA WATER AND BIODEGRADABII SURFACTANTS, COMPLETE WITH PRODUCTION PROCESS. |
| EP2620487A1 (en) | 2012-01-30 | 2013-07-31 | Astril srl | Manual dishwashing detergent formulation made with sea water and biodegradable surfactants and method of production |
| ITCS20130002A1 (en) * | 2013-01-29 | 2014-07-30 | Astril Srl | CLEANING COMPOSITION FOR HAND DISHWASHING OF DISHES AND DISHES MADE WITH SEA WATER AND BIODEGRADABLE SURFACTANTS AND PRODUCTION PROCEDURE |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2731435B1 (en) | 1998-04-17 |
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