FR2603906A1 - Process for electrochemical reduction in primary aliphatic amines or liquid ammonia - Google Patents

Process for electrochemical reduction in primary aliphatic amines or liquid ammonia

Info

Publication number
FR2603906A1
FR2603906A1 FR8612746A FR8612746A FR2603906A1 FR 2603906 A1 FR2603906 A1 FR 2603906A1 FR 8612746 A FR8612746 A FR 8612746A FR 8612746 A FR8612746 A FR 8612746A FR 2603906 A1 FR2603906 A1 FR 2603906A1
Authority
FR
France
Prior art keywords
electrochemical reduction
liquid ammonia
primary aliphatic
aliphatic amines
reductions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR8612746A
Other languages
French (fr)
Other versions
FR2603906B1 (en
Inventor
Jacques Chaussard
Andre Thiebault
Catherine Combellas
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe Nationale des Poudres et Explosifs
Original Assignee
Societe Nationale des Poudres et Explosifs
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Societe Nationale des Poudres et Explosifs filed Critical Societe Nationale des Poudres et Explosifs
Priority to FR8612746A priority Critical patent/FR2603906B1/en
Publication of FR2603906A1 publication Critical patent/FR2603906A1/en
Application granted granted Critical
Publication of FR2603906B1 publication Critical patent/FR2603906B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The process according to the invention is a process for electrochemical reduction of organic compounds bearing at least one electroreducible group, used in a primary aliphatic amine or liquid ammonia medium in the presence of an inert electrolyte. The anode, made of zinc, aluminium or magnesium, is consumed during the electrochemical reduction. This process advantageously replaces reductions by alkali metals in an amine or ammonia medium ("Birch", "Bouveaux-blanc" or "Benkeser" reductions) by making it possible in particular to work in an uncompartmented cell; even in the case of compounds which are easily oxidisable or which carry an acidic proton, such as phenylglycine.
FR8612746A 1986-09-12 1986-09-12 PROCESS FOR ELECTROCHEMICAL REDUCTION IN PRIMARY ALIPHATIC AMINES OR LIQUID AMMONIA Expired - Lifetime FR2603906B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR8612746A FR2603906B1 (en) 1986-09-12 1986-09-12 PROCESS FOR ELECTROCHEMICAL REDUCTION IN PRIMARY ALIPHATIC AMINES OR LIQUID AMMONIA

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8612746A FR2603906B1 (en) 1986-09-12 1986-09-12 PROCESS FOR ELECTROCHEMICAL REDUCTION IN PRIMARY ALIPHATIC AMINES OR LIQUID AMMONIA

Publications (2)

Publication Number Publication Date
FR2603906A1 true FR2603906A1 (en) 1988-03-18
FR2603906B1 FR2603906B1 (en) 1990-11-16

Family

ID=9338872

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8612746A Expired - Lifetime FR2603906B1 (en) 1986-09-12 1986-09-12 PROCESS FOR ELECTROCHEMICAL REDUCTION IN PRIMARY ALIPHATIC AMINES OR LIQUID AMMONIA

Country Status (1)

Country Link
FR (1) FR2603906B1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005031040A2 (en) * 2003-09-25 2005-04-07 Basf Aktiengesellschaft Electrochemical method for producing diphenylphosphine oxide, diphenylphosphine or phosphine and their derivatives

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3444057A (en) * 1966-06-29 1969-05-13 Syntex Corp Electrolytic reduction of aromatic steroids
EP0189120A1 (en) * 1985-01-21 1986-07-30 Consiglio Nazionale Delle Ricerche Process for the electrocarboxylation of carbonyl compounds for producing alpha-hydroxycarboxylic acids

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3444057A (en) * 1966-06-29 1969-05-13 Syntex Corp Electrolytic reduction of aromatic steroids
EP0189120A1 (en) * 1985-01-21 1986-07-30 Consiglio Nazionale Delle Ricerche Process for the electrocarboxylation of carbonyl compounds for producing alpha-hydroxycarboxylic acids

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005031040A2 (en) * 2003-09-25 2005-04-07 Basf Aktiengesellschaft Electrochemical method for producing diphenylphosphine oxide, diphenylphosphine or phosphine and their derivatives
WO2005031040A3 (en) * 2003-09-25 2005-11-24 Basf Ag Electrochemical method for producing diphenylphosphine oxide, diphenylphosphine or phosphine and their derivatives

Also Published As

Publication number Publication date
FR2603906B1 (en) 1990-11-16

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