FR2536959A2 - Processes for reducing the accidents to wild fauna due to chemical treatments in agriculture - Google Patents

Processes for reducing the accidents to wild fauna due to chemical treatments in agriculture Download PDF

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Publication number
FR2536959A2
FR2536959A2 FR8220270A FR8220270A FR2536959A2 FR 2536959 A2 FR2536959 A2 FR 2536959A2 FR 8220270 A FR8220270 A FR 8220270A FR 8220270 A FR8220270 A FR 8220270A FR 2536959 A2 FR2536959 A2 FR 2536959A2
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Prior art keywords
agriculture
ammonia
chemical treatments
reducing
accidents
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FR8220270A
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French (fr)
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FR2536959B2 (en
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Priority claimed from FR7914564A external-priority patent/FR2458218A1/en
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Priority to FR8220270A priority Critical patent/FR2536959B2/en
Publication of FR2536959A2 publication Critical patent/FR2536959A2/en
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Publication of FR2536959B2 publication Critical patent/FR2536959B2/en
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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A01N47/14—Di-thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/26—Oxidation products of dithiocarbamic acid derivatives, e.g. thiuram sulfides

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Process for reducing the accidents to wild fauna due to chemical treatments in agriculture, by the inclusion in the repellents ziram and/or thiram of one or of a number of water-soluble ammonium salts which are stable in alkaline medium for application to the treatment of vine bark.

Description

Le brevet 79.14564 publié sous le n 2.458.218 et intitulé "Procédés pour réduire les accidents causés à la faune sauvage par les traitements chimiques en Agriculture" revendique l'inclusion de produits répulsifs aux formulations phytosanitaires, en particulier sous forme de produits azotés. Patent 79.14564 published under No. 2,458,218 and entitled "Methods for Reducing Accidents Caused to Wild Fauna by Chemical Treatments in Agriculture" claims the inclusion of repellents in phytosanitary formulations, in particular in the form of nitrogenous products.

Poursuivant notre recherche sur les molécules azotées et connaissant l'effet du dégagement du gaz ammoniac sur les muqueuses des mammifères, nous avons trouvé que le traitement d'hiver de la vigne contre l'esca et l'escoriose peut s'effectuer avec une dose homologuée d'arsenite de sodium formulée avec une quantité convenable de certains sels ammoniacaux, à condition qu'ils soient solubles dans l'eau et y donnent une réaction basique. Cette quantité varie de 2,5 à 50 kg/ha pour assurer une protection contre les mammifères rongeurs. L'efficacité sur l'esca et l'escoriose n'a pas été différente de ce qui est normalement obtenu avec l'arsenite de soude. Les sels ammoniacaux ci-dessous, éventuellement stabilisés, peuvent être utilisés, mais cette liste ne prétend pas être exhaustive. Continuing our research on nitrogen molecules and knowing the effect of the release of ammonia gas on the mucous membranes of mammals, we have found that the winter treatment of the vine against esca and escoriosis can be carried out with a dose approved sodium arsenite formulated with a suitable amount of certain ammoniacal salts, provided that they are soluble in water and give a basic reaction. This quantity varies from 2.5 to 50 kg / ha to provide protection against rodent mammals. The effectiveness on esca and escoriosis was not different from what is normally obtained with arsenite of soda. The ammonia salts below, possibly stabilized, can be used, but this list does not claim to be exhaustive.

. acetate C2 H7 N02
. benzoate C7 H9 N02
. bicarbonate CH5 N03
bîfluorure H5 F2 N
bimalate C4 H9 N05
. bisulfate H5 N04S
. bisulfure NH4 HS
. bisulfite H5 N03S
. bitartrate C4 H9 N06
. borate B4 H8 N2 07
. bromure NH4 Br
. carbamate CH6 N2 02
. carbonate mixte de bicarbonate et de carbamate
. chlorure C1 H4 N
. chromate Cr H8 N2 04
. sulfate chromique Cr H4 N08 S2
. dithiocarbamate CH6 N2 S2
. citrate ferrique à 9 % NH3
. sulfate ferrique Fe H4 N08 S2
. sulfate ferreux C6 H16 Fe N10
. formiate CH3 N02
. hexafluorophosphate F6 PH N4
. hypophosphite H6 N02 P
. iodure H4 IN
. lactate C3 H9 N03
. nitrate H4 N2 03
. phosphate dibasique H9 N2 04 P
. phosphate double de sodium H5 NNa 04 P
. sulfate 804 N2 H8
Curieusement, les mêmes propriétés sont observées avec une formulation aqueuse d'arsenite de sodium additionné de cyanamide calcique tout au moins sur mammifères.. acetate C2 H7 N02
. benzoate C7 H9 N02
. bicarbonate CH5 N03
fluoride H5 F2 N
bimalate C4 H9 N05
. bisulfate H5 N04S
. NH4 HS disulfide
. bisulfite H5 N03S
. bitartrate C4 H9 N06
. borate B4 H8 N2 07
. NH4 Br bromide
. carbamate CH6 N2 02
. mixed carbonate of bicarbonate and carbamate
. chloride C1 H4 N
. chromate Cr H8 N2 04
. chromic sulfate Cr H4 N08 S2
. dithiocarbamate CH6 N2 S2
. 9% NH3 ferric citrate
. ferric sulfate Fe H4 N08 S2
. ferrous sulfate C6 H16 Fe N10
. formate CH3 N02
. hexafluorophosphate F6 PH N4
. hypophosphite H6 N02 P
. iodide H4 IN
. lactate C3 H9 N03
. nitrate H4 N2 03
. dibasic phosphate H9 N2 04 P
. double sodium phosphate H5 NNa 04 P
. sulfate 804 N2 H8
Curiously, the same properties are observed with an aqueous formulation of sodium arsenite added with calcium cyanamide at least on mammals.

Exemplé 1 : Quand dans l'exemple 5 du brevet mentionné ci-dessus on a remplacé dans la formulation, dans les essais de février 80 et mars 81, le zirame et/ou le thirame par 15 et 30 kg/ha de sulfate ou de chlorure d'ammonium, on observe que les lièvres et les lapins ne consomment plus les bourgeons ou les écorces de la vigne pendant une période pouvant atteindre 5 jours suivant les conditions climatiques. Example 1: When, in example 5 of the patent mentioned above, the ziram and / or the thiram were replaced in the formulation, in the tests of February 80 and March 81, with 15 and 30 kg / ha of sulfate or ammonium chloride, it is observed that hares and rabbits no longer consume the buds or bark of the vine for a period of up to 5 days depending on weather conditions.

Exemple 2 : Quand en février 81 on a formulé une demi-dose homologuée de zirame avec 5 kg ou 10 kg de sulfate d'ammonium, on a observé une protection plus longue sur les mêmes ravageurs.  Example 2: When in February 1981 an approved half-dose of ziram was formulated with 5 kg or 10 kg of ammonium sulphate, longer protection was observed on the same pests.

Claims (4)

REVENDICATIONS 1- Procédé pour réduire les intoxications causées à la faune sauvage par les traitements chimiques en agriculture, selon revendications 2 et 3 du brevet nO 79.14564, caractérisé en ce que les produits répulsifs inclus dans les formulations phytosanitaires sont du zirame associé à un sel d'ammonium soluble dans l'eau et stable en milieu alcalin, ce qui permet leur formulation en liquide contenant des doses homologuées d'arsenite de sodium, en vue du traitement d'hiver des écorces de la vigne avant le débourrement contre les maladies esca et escoriose. 1- Method for reducing poisoning caused to wild fauna by chemical treatments in agriculture, according to claims 2 and 3 of patent No. 79.14564, characterized in that the repellents included in phytosanitary formulations are ziram associated with a salt of ammonium soluble in water and stable in alkaline medium, which allows their formulation in liquid containing approved doses of sodium arsenite, for the winter treatment of the bark of the vine before budding against esca and escoriose diseases . 2 - Procédé suivant revendication 1, caractérisé en ce que le sel ammoniacal choisi est le chlorure d!ammoniaque. 2 - Process according to claim 1, characterized in that the ammonia salt chosen is ammonia chloride! 3 - Procédé suivant revendication 1, caractérisé en ce que le sel ammoniacal choisi est le sulfate d'ammoniaque. 3 - Process according to claim 1, characterized in that the ammoniacal salt chosen is ammonia sulfate. 4 - Procédé suivant revendication 1, caractérisé en ce que le sel ammoniacal choisi est le bicarbonate d'ammoniaque.  4 - Process according to claim 1, characterized in that the ammoniacal salt chosen is ammonia bicarbonate.
FR8220270A 1979-06-07 1982-12-03 METHODS FOR REDUCING ACCIDENTS CAUSED TO WILDLIFE BY CHEMICAL TREATMENT IN AGRICULTURE Expired FR2536959B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR8220270A FR2536959B2 (en) 1979-06-07 1982-12-03 METHODS FOR REDUCING ACCIDENTS CAUSED TO WILDLIFE BY CHEMICAL TREATMENT IN AGRICULTURE

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR7914564A FR2458218A1 (en) 1979-06-07 1979-06-07 Repelling birds and animals from crops - by treating with nitro, amino or sulpho deriv. of thiocarbamate or thiuram
FR8220270A FR2536959B2 (en) 1979-06-07 1982-12-03 METHODS FOR REDUCING ACCIDENTS CAUSED TO WILDLIFE BY CHEMICAL TREATMENT IN AGRICULTURE

Publications (2)

Publication Number Publication Date
FR2536959A2 true FR2536959A2 (en) 1984-06-08
FR2536959B2 FR2536959B2 (en) 1986-05-09

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3069314A (en) * 1960-12-29 1962-12-18 James H Jenkins Snake repellent
CH468149A (en) * 1967-11-07 1969-02-15 Lesquereux Pierre Animal repellent composition

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3069314A (en) * 1960-12-29 1962-12-18 James H Jenkins Snake repellent
CH468149A (en) * 1967-11-07 1969-02-15 Lesquereux Pierre Animal repellent composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
WORTHING C.R., Pesticide Manual, édition 6, 1979, BCPC publications, CROYDON (GB) *

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FR2536959B2 (en) 1986-05-09

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