FR2505080A1 - Partition protective against pollutants and radiation - with layers of compsn. contg. boracic prods. and highly hydrogenated plastics - Google Patents

Partition protective against pollutants and radiation - with layers of compsn. contg. boracic prods. and highly hydrogenated plastics Download PDF

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Publication number
FR2505080A1
FR2505080A1 FR8108518A FR8108518A FR2505080A1 FR 2505080 A1 FR2505080 A1 FR 2505080A1 FR 8108518 A FR8108518 A FR 8108518A FR 8108518 A FR8108518 A FR 8108518A FR 2505080 A1 FR2505080 A1 FR 2505080A1
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Prior art keywords
partition
semi
boracic
layer
radiation
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FR8108518A
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FR2505080B1 (en
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    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21FPROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F1/00Shielding characterised by the composition of the materials

Abstract

A compsn. which forms a protective and anti-fission partition comprises several layers of material contg. boracic prods. and strongly hydrogenated plastics. The partition gives protection to man against the widest range of physical, chemical and biological pollutants, including radioactive dust. The partition gives anti-neutron protection to men in ground, sea or air vehicles. Reinforced concrete contg. boracic materials, partic. at least 3 wt.% of colemanite, is the pref. layer impermeable to mechanical penetration, and to alpha-, beta-, gamma-, and X-rays, and gives some protection against penetration by neutrons. A semi-rigid layer may be applied on 1 or both faces of a concrete or metal partition, or may be interposed within the partition; this layer consists of several sub-layers of differing mechanical strength, some being of highly hydrogenated polystyrene and others of highly hydrogenated polyethylene, with a high content of elements of low atomic number giving protection against radiation. Pref., the semi-rigid layer contains at least 40 wt.% of polyethylene and 5% of polystyrene.

Description

LA PRESENTE INVENTION A POUR OBIET :
Une nouvelle association de matériaux dont la particularité est de pouvoir constituer une protection pour l'homme contre tous les polluants ou agressifs physiques, chimiques et biologiques, au sens le plus large.
THIS INVENTION HAS THE OBJECT:
A new association of materials whose particularity is to be able to constitute a protection for the man against all pollutants or aggressive physical, chemical and biological, in the broadest sense.

Cette association de matériaux répond à des caractéristiques qui en font, notamment, une paroi dont l'étanchéité est à l'abri des fissures dues, par exemples, à des secousses telluriques. Il existe deux types très différents de dangers physiques, chimiquès et biologiques, à l'abri desquels l'homme se doit de rester isolé : - les polluants ne traversant pas une barrière physique continue à l'échelle moléculaire - polluants chimiques, bactériologiques, poussières ... et les agressifs, ayant la capacité de traverser, sans les détruire, des barrières continues : les rayonnements, qu'ils soient particulaires ou non. Dans la protection classique, ces deux types de protection sont dissociés.This association of materials meets characteristics which make it, in particular, a wall whose sealing is protected from cracks due, for example, to earthquakes. There are two very different types of physical, chemical and biological dangers, from which humans must remain isolated: - pollutants which do not cross a continuous physical barrier on a molecular scale - chemical, bacteriological and dust pollutants ... and the aggressive, having the capacity to cross, without destroying them, continuous barriers: radiation, whether particulate or not. In conventional protection, these two types of protection are dissociated.

La présente invention a pour objet une nouvelle association protectrice, en vue de créer des parois multi-protection. La protection contre les polluants ou agressifs chimiques ou bactériologiques, est obtenue par l'établissement d'une paroi dont l'étanchéité est totale vis-à-vis de toutes les particules, aussi petites soient-elles. Cette protection est aussi efficace contre toute contamination par des poussières radioactives, dont, à part les problèmes de rayonnement abordés plus loin, l'essentiel est la résistance mécanique de la paroi.The present invention relates to a new protective association, with a view to creating multi-protection walls. Protection against pollutants or aggressive chemical or bacteriological, is obtained by the establishment of a wall whose tightness is total vis-à-vis all the particles, as small as they are. This protection is also effective against any contamination by radioactive dust, of which, apart from the radiation problems discussed below, the main thing is the mechanical resistance of the wall.

Le béton armé constitue la sulution la plus appr@priée pour cette couche, préparée selon l'art antérieur, enrichie en matériaux boraciques et dont les armatures ont une orientation telles qu'elles ne peuvent servir de ligne de passage privilégié aux neutrons, et ce, par un positionnement tel que ces armatures métalliques soient le plus perpendiculaire possible à la trajectoire présumée d'un flux de neutrons incident.Reinforced concrete constitutes the most suitable solution for this layer, prepared according to the prior art, enriched with boracic materials and the reinforcements of which have an orientation such that they cannot serve as a preferred line of passage for neutrons, and this , by a positioning such that these metallic reinforcements are as perpendicular as possible to the presumed trajectory of an incident neutron flux.

L'épaisseur du béton sera calculée en fonction du degré de protection recherché et du site choisi.The thickness of the concrete will be calculated according to the degree of protection sought and the site chosen.

La protection contre les agressifs de type ondulatoire est résolue de façon globale par la structure multicouche de la paroi.Protection against aggressive wave-like properties is generally resolved by the multilayer structure of the wall.

Les caractéristiques physiques et mécaniques des couches bétonnées, boracique, d'une part, polyethylène-polystyrène d'autre part, font de cette paroi un écran efficace au rayonnement, quelle que soit la fréquence de celui-ci ou de ceux-ci, et donc, quelle @@@ seit @ear nature, à @a cond@tion que @@ux-ci s@@@nt de c@@r@@@ @@@ée (de l'ordre de quelques sec@ndes). The physical and mechanical characteristics of the concrete, boracic, on the one hand, and polyethylene-polystyrene layers, on the other hand, make this wall an effective radiation shield, whatever the frequency of this or these, and so, @@@ seit @ear nature, provided that @@ ux-ci s @@@ nt de c @@ r @@@ @@@ ée (of the order of a few seconds ).

@uelques exemples sont donnés pour préciser ce qui précède : - lors du rayonnement calorifique : arrêt par la couche de bét@n,
résistance à plusieurs milliers de degrés, - lors d'une onde de choc : épaisseur du béton armé résistant à
plusieurs tonnes par m2 de surface, - sécurité très largement augmentée par la couche semi-rigide
jouant un rôle anti-fissure.
@some examples are given to clarify the above: - during heat radiation: stop by the layer of bet @ n,
resistance to several thousand degrees, - during a shock wave: thickness of reinforced concrete resistant to
several tonnes per m2 of surface, - safety greatly increased by the semi-rigid layer
playing an anti-cracking role.

CAS DU RAYONNEMENT "ALPHA" :
C'est un rayonnement peu pénétrant, donc arrété par les premiers millimètres de la paroi. La protection est surtout utile contre une contamination, - étanchéité -.
"ALPHA" RADIATION:
It is a little penetrating radiation, therefore stopped by the first millimeters of the wall. Protection is especially useful against contamination, - sealing -.

CAS DU RAYONNEMENT "BETA" : @rotection également largement établie par la couche bétonnée. Le rayonnement gamma émis par freinage est aussi arrété par la couche bétonnée, même pour des particules BETA de haute énergie."BETA" RADIATION: @rotection also widely established by the concrete layer. The gamma radiation emitted by braking is also stopped by the concrete layer, even for high energy BETA particles.

CAS DU RAYONNEMENT "GAMMA" :
Les corps de densité élevée présentent le meilleur facteur d'atténuation. La couche bétonnée, suffisamment dense, est un écran anti-gamma efficace.
"GAMMA" RADIATION:
High density bodies have the best attenuation factor. The sufficiently dense concrete layer is an effective anti-gamma screen.

CAS DU RAYONNEMENT "X" :
L'atténuation des rayons "X" traversant la matière est d'autant plus importante que le numéro atomique moyen de celle-ci est élevé.
"X" RADIATION:
The attenuation of the "X" rays passing through the material is all the more important as the average atomic number of this one is high.

Le bêton, encore ici, est considéré, dans l'art ancien, comme une protection efficace et économique.The concrete, still here, is considered, in ancient art, as an effective and economical protection.

CAS DES NEUTRONS :
Contre les neutrons, les corps les plus efficaces sont ceux de numé r@ atomique faible. La sous-couche anti-fissure, constituée de polyethylène et de polystyrène, fortement hydrogénée, atténue de façon très puissante, tout flux de neutrons. Par ailleurs, l'enrichissement du béton en matériaux boraciques accentue cette protection, tant en ce qui concerne les flux de neutrons thermiques, qu'en ce qui concerne les neutrons rapides. Les contraintes, dues à l'écha@f- @ement par absorption du rayonnement, sont maitrisées par les armatures disposées dans le béton et la sous-couche. Dans le but de montrer les propriétés intéressantes de la nouvelle association de matériaux selon l'invention, des essais ent été demandés, destinés à tester la protection contre des rayonnements des moins connus dans l'art et les plus dangereux dont le rayonnement neutronique (@ssai du LABORATOIRE NATIONAL D'ESSAIS@RARIS).
CASE OF NEUTRONS:
Against neutrons, the most efficient bodies are those with a low atomic number. The anti-crack underlay, made of polyethylene and polystyrene, highly hydrogenated, very powerfully attenuates any neutron flux. In addition, the enrichment of concrete with boracic materials increases this protection, both with regard to thermal neutron fluxes and with regard to fast neutrons. The stresses, due to the scha @ f- @ement by absorption of the radiation, are controlled by the reinforcements placed in the concrete and the under-layer. In order to show the interesting properties of the new combination of materials according to the invention, tests have been requested, intended to test the protection against radiation of the least known in the art and the most dangerous including neutron radiation (@ ssai of the NATIONAL ESSAY LABORATORY @ RARIS).

Claims (6)

REVENDICATIONS 1) composition constituant une paroi protectrice et anti1) composition constituting a protective and anti wall fissures comprenant plusieurs couches de matériaux, cracks comprising several layers of material, additionnés de produits boraciques et de matières with added boracics and materials plastiques fortement hydrogénées. highly hydrogenated plastics. 2) Composition selon la revendication 1, caractérisée par2) Composition according to claim 1, characterized by le fait que l'un au moins des produits est la colemanite, the fact that at least one of the products is colemanite, associéé par mélange ou application à la paroi protectrice. associated by mixing or applying to the protective wall. 3) Composition selon les revendications 1 et 2 et caractéri3) Composition according to claims 1 and 2 and character sée en outre par la présence sur l'une, les deux faces additionally created by the presence on one, both sides ou intercalée dans la paroi, de béton ou métallique, or inserted in the wall, concrete or metallic, d'une couche semi-rigide elle-même constituée de plusieurs a semi-rigid layer itself made up of several sous-couches de résistances mécaniques différentes, et dont underlays of different mechanical strengths, of which la densité en éléments de numéro atomique faible est impor the density of elements with a low atomic number is important tante. aunt. 4) Composition selon les revendications 1, 2 et 3 et carac4) Composition according to Claims 1, 2 and 3 and charac térisée par le fait que la couche semi-rigide est consti terrified by the fact that the semi-rigid layer is made up tuée de sous-couches dont l'une au moins comprend du killed by underlayers, at least one of which contains polyéthylène et d'autres de polystyrène fortement hydro polyethylene and other highly hydro polystyrene génés. Genoa. 5) Composition selon les revendications 1, 2, 3 et 4 et carac5) Composition according to Claims 1, 2, 3 and 4 and charac térisée par le fait que la couche bétonnée contient au moin terrified by the fact that the concrete layer contains at least 3% en poids de colemanite et la couche semi-rigide au moins 3% by weight of colemanite and the semi-rigid layer at least 40% de son poids en polyéthylène et 5% en polystyrène. 40% of its weight in polyethylene and 5% in polystyrene. 6) Composition dérivée du principe des revendications 1, 2,6) Composition derived from the principle of claims 1, 2, 3, 4 et 5 permettant par application d'une couche plastique 3, 4 and 5 allowing by application of a plastic layer semi-rigide traitée, externe, interne ou intercalée, la semi-rigid treated, external, internal or intercalated, the protection anti-neutronique des personnes à l'intérieur anti-neutron protection for people inside de véhicules sur terre, en mer et dans les airs.  vehicles on land, at sea and in the air.
FR8108518A 1981-04-29 1981-04-29 ANTI-ATOMIC, NEUTRONIC AND CHEMICAL POLLUTANT WALLS Expired FR2505080B1 (en)

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FR8108518A FR2505080B1 (en) 1981-04-29 1981-04-29 ANTI-ATOMIC, NEUTRONIC AND CHEMICAL POLLUTANT WALLS

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FR8108518A FR2505080B1 (en) 1981-04-29 1981-04-29 ANTI-ATOMIC, NEUTRONIC AND CHEMICAL POLLUTANT WALLS

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FR2505080B1 FR2505080B1 (en) 1987-12-18

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2830367A1 (en) * 2001-10-01 2003-04-04 Transnucleaire NEUTRONIC SHIELDING AND SUB-CRITICALITY MAINTENANCE MATERIAL BASED ON INSATURE POLYESTER
US7399431B2 (en) 2002-10-25 2008-07-15 Cogema Logistics Material for neutron shielding and for maintaining sub-critically, process for its preparation and its applications

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2796529A (en) * 1948-08-23 1957-06-18 Morrison Philip Radiation shield
FR1398490A (en) * 1963-06-13 1965-05-07 Radiation shielding composition
FR1458833A (en) * 1964-11-27 1966-11-10 English Electric Co Ltd Radiation blocking material
US3705101A (en) * 1967-06-14 1972-12-05 Commissariat Energie Atomique Neutron-absorbing material and method of manufacture
US4123392A (en) * 1972-04-13 1978-10-31 Chemtree Corporation Non-combustible nuclear radiation shields with high hydrogen content

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2796529A (en) * 1948-08-23 1957-06-18 Morrison Philip Radiation shield
FR1398490A (en) * 1963-06-13 1965-05-07 Radiation shielding composition
FR1458833A (en) * 1964-11-27 1966-11-10 English Electric Co Ltd Radiation blocking material
US3705101A (en) * 1967-06-14 1972-12-05 Commissariat Energie Atomique Neutron-absorbing material and method of manufacture
US4123392A (en) * 1972-04-13 1978-10-31 Chemtree Corporation Non-combustible nuclear radiation shields with high hydrogen content

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
REACTOR SHIELDING DESIGN MANUAL, T. ROCKWELL, 1ère édition 1956, VAN NOSTRAND, PRINCETON N.J. (US), chapitre 6, paragraphes 3.1, 3.2; figures 6.7-6.10 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2830367A1 (en) * 2001-10-01 2003-04-04 Transnucleaire NEUTRONIC SHIELDING AND SUB-CRITICALITY MAINTENANCE MATERIAL BASED ON INSATURE POLYESTER
WO2003030183A2 (en) * 2001-10-01 2003-04-10 Cogema Logistics Neutron shielding material for maintaining sub-criticality based on unsaturated polymer
WO2003030183A3 (en) * 2001-10-01 2003-12-04 Cogema Logistics Neutron shielding material for maintaining sub-criticality based on unsaturated polymer
US7524438B2 (en) 2001-10-01 2009-04-28 Cogema Logistics Unsaturated polyester-based material for neutron-shielding and for maintaining sub-criticality
KR100901151B1 (en) 2001-10-01 2009-06-04 꼬제마 로지스틱스 에스.아. Neutron shielding material for maintaining sub-criticality based on unsaturated polymer
US7399431B2 (en) 2002-10-25 2008-07-15 Cogema Logistics Material for neutron shielding and for maintaining sub-critically, process for its preparation and its applications

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