FR2498372A1 - DIRECT HEATING CATHODE, METHOD FOR MANUFACTURING SAME, AND ELECTRONIC TUBE INCLUDING SUCH A CATHODE - Google Patents
DIRECT HEATING CATHODE, METHOD FOR MANUFACTURING SAME, AND ELECTRONIC TUBE INCLUDING SUCH A CATHODE Download PDFInfo
- Publication number
- FR2498372A1 FR2498372A1 FR8100782A FR8100782A FR2498372A1 FR 2498372 A1 FR2498372 A1 FR 2498372A1 FR 8100782 A FR8100782 A FR 8100782A FR 8100782 A FR8100782 A FR 8100782A FR 2498372 A1 FR2498372 A1 FR 2498372A1
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- FR
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- Prior art keywords
- cathode
- mixture
- layer
- tungsten
- cathode according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J1/00—Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
- H01J1/02—Main electrodes
- H01J1/13—Solid thermionic cathodes
- H01J1/14—Solid thermionic cathodes characterised by the material
Abstract
L'INVENTION A POUR OBJET UNE CATHODE A EMISSION THERMO-ELECTRONIQUE A CHAUFFAGE DIRECT. ELLE COMPORTE UN SUPPORT 1 EN GRAPHITE PYROLYTIQUE ET UN REVETEMENT EMISSIF 2 CONSTITUE D'UN MELANGE DE TUNGSTENE ET D'OXYDE DE LANTHANE, LE TUNGSTENE ETANT TRANSFORME DANS SA PARTIE SUPERFICIELLE 3 EN HEMICARBURE DE TUNGSTENE. L'INVENTION S'APPLIQUE NOTAMMENT AUX TUBES HAUTE FREQUENCE DU TYPE TRIODE, TETRODE OU PENTODE.THE OBJECT OF THE INVENTION A CATHODE WITH THERMO-ELECTRONIC EMISSION WITH DIRECT HEATING. IT INCLUDES A PYROLYTIC GRAPHITE SUPPORT 1 AND AN EMISSIVE COATING 2 CONSISTS OF A MIXTURE OF TUNGSTENE AND LANTHAN OXIDE, THE TUNGSTENE BEING TRANSFORMED IN ITS SURFACE PART 3 INTO TUNGSTEN HEMICARBIDE. THE INVENTION APPLIES IN PARTICULAR TO HIGH FREQUENCY TUBES OF THE TRIODE, TETRODE OR PENTODE TYPE.
Description
CATHODE A CHAUFFAGE DIRECT, SON PROCEDE DE FABRICATION,DIRECT HEATING CATHODE, METHOD FOR MANUFACTURING SAME,
ET TUBE ELECTRONIQUE INCORPORANT UNE TELLE CATHODE. AND ELECTRONIC TUBE INCORPORATING SUCH A CATHODE.
La présente invention a pour objet une cathode pour tube électronique haute fréquence, et plus particulièrement une cathode à émission thermoélectronique à chauffage direct. Elle a également The subject of the present invention is a cathode for a high frequency electron tube, and more particularly a cathode with thermoelectronic emission with direct heating. She also has
pour objet un tube électronique comportant une telle cathode. object is an electron tube comprising such a cathode.
Dans les tubes électroniques haute fréquence du type triode, tétrode ou pentode, qui comportent une cathode, une anode et une, deux ou trois grilles, il est avantageux de réaliser les grilles en graphite pyrolytique, matériau connu pour ses qualités mécaniques In the high frequency electronic tubes of the triode, tetrode or pentode type, which comprise a cathode, an anode and one, two or three grids, it is advantageous to produce the grids made of pyrolytic graphite, a material known for its mechanical qualities.
et thermiques.and thermal.
Toutefois, dans ces mêmes tubes les cathodes sont généra- However, in these same tubes the cathodes are generally
lement réalisées en fils de tungstène ou de tungstène thorié pour des made of tungsten or thorium tungsten wire for
raisons d'émissivité thermo-électronique, la température de fonc- reasons of thermo-electronic emissivity, the temperature of
tionnement est alors comprise entre 1900 et 2000@K. Il se pose alors, en fonctionnement, des problèmes mécaniques du fait de la différence de comportement thermique des matériaux, problèmees résolus imparfaitement par des montages mécaniques couteux. On a proposé d'éviter les problèmes thermo-mécaniques à l'intérieur du tube tout en assurant une bonne émissivité thermo-électronique en introduisant un chauffage direct à partir d'un support en graphite pyrolytique et en déposant à la surface du graphite un matériau émettant à plus basse température que le tungstène ou le tungstène thorié tel l'hexaborure de lanthane LaB6 par exemple. Une telle tion is then between 1900 and 2000 @ K. There then arise, in operation, mechanical problems due to the difference in thermal behavior of the materials, problems imperfectly solved by expensive mechanical assemblies. It has been proposed to avoid thermomechanical problems inside the tube while ensuring a good thermo-electronic emissivity by introducing direct heating from a pyrolytic graphite support and depositing on the surface of the graphite a material emitting at a lower temperature than tungsten or thoriated tungsten such as lanthanum hexaboride LaB6 for example. Such a
structure permet d'obtenir l'émission électronique à une tempé- This structure makes it possible to obtain electronic
rature comprise entre 1400 et 15000C. Toutefois, un inconvénient de matériaux émissifs tels l'hexaborure de Lanthane est leur grande activité chimique vis-à-vis du graphite à chaud, qui peut conduire à la destruction de la cathode. On est contraint de ce fait à introduire une couche intermédiaire entre le graphite et l'hexaborure de between 1400 and 15000C. However, a disadvantage of emissive materials such as Lanthanum hexaboride is their high chemical activity with respect to hot graphite, which can lead to the destruction of the cathode. It is therefore necessary to introduce an intermediate layer between the graphite and the hexaboride of
Lanthane formant barrière de diffusion entre ces deux matériaux. Lanthanum forming diffusion barrier between these two materials.
La présente invention a pour objet une cathode à chauffage The present invention relates to a heating cathode
direct travaillant à la même température que la cathode en hexa- direct working at the same temperature as the cathode in hexa-
borure de lanthane, mais ne nécessitant pas de couche intermédiaire lanthanum boride, but not requiring an intermediate layer
entre le graphite et la couche émissive. between the graphite and the emissive layer.
Par rapport à une cathode couramment utilisée dans l'art antérieur, les principaux avantages entraînés sont: With respect to a cathode commonly used in the prior art, the main advantages involved are:
- une température de fonctionnement plus faible. - a lower operating temperature.
- une meilleure tenue mécanique.- better mechanical strength.
Par rapport à une cathode en hexaborure de lanthane, l'avan- With respect to a lanthanum hexaboride cathode, the advantage
tage réside dans la suppression de la couche intermédiaire. is the removal of the intermediate layer.
La cathode selon l'invention comporte un support en graphite pyrolytique et un revêtement émissif composé d'un mélange de The cathode according to the invention comprises a pyrolytic graphite support and an emissive coating composed of a mixture of
tungstène et d'oxyde de terres rares (oxyde de lanthane par exem- tungsten and rare earth oxide (eg lanthanum oxide)
ple).ple).
La couche émissive peut être carburée en surface pour amé- The emitting layer can be carburized on the surface to improve
liorer lémission.improve the program.
D'autres objets, caractéristiques et résultats de l'invention Other objects, features and results of the invention
- ressortiront de la description suivante annexée par la figure unique - will appear from the following description appended by the single figure
qui représente une vue en coupe d'un mode de réalisation de la which represents a sectional view of an embodiment of the
cathode selon l'invention.cathode according to the invention.
Celle-ci comporte un support 1 en graphite pyrolytique d'une épaisseur d'environ 200p, sur lequel on dépose, par plasma ou par pulvérisation cathodique, ou par tout autre moyen connu de l'homme de l'art, une couche homogène (2) d'un mélange de tungstène et d'oxyde de lanthane ce dernier étant dans des proportions comprises entre 0,5% et 10%, l'épaisseur de la couche (2) peut être comprise This comprises a support 1 of pyrolytic graphite having a thickness of about 200p, on which is deposited, by plasma or sputtering, or by any other means known to those skilled in the art, a homogeneous layer ( 2) a mixture of tungsten and lanthanum oxide the latter being in proportions of between 0.5% and 10%, the thickness of the layer (2) can be understood
entre 50 et 100p.between 50 and 100p.
Le tungstène de la couche émissive peut être transformé dans sa partie superficielle (3), sur une épaisseur de 10 à 20 P, en hémicarbure de tungstène W2C. Cette transformation est réalisée d'une manière usuelle par chauffage de la cathode dans des vapeurs d'hydrocarbure à une température d'environ 1800 C. Dans une autre variante, le carbure de tungstène peut être codéposé avec le tungstène et Poxyde de lanthane, en proportion allant de 10% à 50% de carbure, de 0,5 à 10% d'oxyde de lanthane, The tungsten of the emitting layer can be converted in its surface portion (3), to a thickness of 10 to 20 P, into tungsten halide W2C. This conversion is carried out in a conventional manner by heating the cathode in hydrocarbon vapors at a temperature of about 1800 ° C. In another variant, the tungsten carbide can be coded with tungsten and lanthanum oxide, proportion ranging from 10% to 50% of carbide, from 0.5 to 10% of lanthanum oxide,
la balance étant faite par le tungstène. Cette variante permet d'éli- the balance being made by tungsten. This variant makes it possible
miner le proèssus de carburation du tungstène. undermine the carburization process of tungsten.
Claims (7)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8100782A FR2498372A1 (en) | 1981-01-16 | 1981-01-16 | DIRECT HEATING CATHODE, METHOD FOR MANUFACTURING SAME, AND ELECTRONIC TUBE INCLUDING SUCH A CATHODE |
EP82400030A EP0056749B1 (en) | 1981-01-16 | 1982-01-08 | Directly heated cathode and method of making it |
DE8282400030T DE3260969D1 (en) | 1981-01-16 | 1982-01-08 | Directly heated cathode and method of making it |
US06/338,872 US4577134A (en) | 1981-01-16 | 1982-01-12 | Direct heating cathode and a process for manufacturing same |
JP351982A JPS57138744A (en) | 1981-01-16 | 1982-01-14 | Direct heating cathode and method of producing same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8100782A FR2498372A1 (en) | 1981-01-16 | 1981-01-16 | DIRECT HEATING CATHODE, METHOD FOR MANUFACTURING SAME, AND ELECTRONIC TUBE INCLUDING SUCH A CATHODE |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2498372A1 true FR2498372A1 (en) | 1982-07-23 |
FR2498372B1 FR2498372B1 (en) | 1983-07-22 |
Family
ID=9254238
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR8100782A Granted FR2498372A1 (en) | 1981-01-16 | 1981-01-16 | DIRECT HEATING CATHODE, METHOD FOR MANUFACTURING SAME, AND ELECTRONIC TUBE INCLUDING SUCH A CATHODE |
Country Status (5)
Country | Link |
---|---|
US (1) | US4577134A (en) |
EP (1) | EP0056749B1 (en) |
JP (1) | JPS57138744A (en) |
DE (1) | DE3260969D1 (en) |
FR (1) | FR2498372A1 (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3148441A1 (en) * | 1981-12-08 | 1983-07-21 | Philips Patentverwaltung Gmbh, 2000 Hamburg | METHOD FOR PRODUCING A THERMIONIC CATHODE |
US4810926A (en) * | 1987-07-13 | 1989-03-07 | Syracuse University | Impregnated thermionic cathode |
DE4026300A1 (en) * | 1990-08-20 | 1992-02-27 | Siemens Ag | Electron emitter for X=ray tube - is of material contg. rare earth element covering support layer of large flat surface withstanding vibration |
EP0637046B1 (en) * | 1993-07-29 | 1998-04-01 | Nec Corporation | Thermoionic emissive cathode method of fabricating the same thermoionic emissive cathode and electron beam apparatus |
FR2733856B1 (en) * | 1995-05-05 | 1997-08-29 | Thomson Tubes Electroniques | CATHODE FOR GRID ELECTRON CANON, GRID TO BE ASSOCIATED WITH SUCH A CATHODE AND ELECTRON CANON INCLUDING SUCH CATHODE |
FR2775118B1 (en) | 1998-02-13 | 2000-05-05 | Thomson Tubes Electroniques | GRID FOR ELECTRONIC TUBE WITH AXIAL BEAM WITH IMPROVED PERFORMANCE |
FR2789800B1 (en) | 1999-02-16 | 2001-05-11 | Thomson Tubes Electroniques | VERY HIGH POWER RADIO FREQUENCY GENERATOR |
DE102008020187A1 (en) * | 2008-04-22 | 2009-10-29 | Siemens Aktiengesellschaft | Cathode, has flat emitter emitting electrons, and emission layer with circular cross section arranged on emitter, where material of emission layer has lower emission function than that of material of emitter |
EP3792369B1 (en) | 2011-12-20 | 2022-09-28 | Kabushiki Kaisha Toshiba | Method for producing a tungsten alloy |
US20170330725A1 (en) * | 2016-05-13 | 2017-11-16 | Axcelis Technologies, Inc. | Lanthanated tungsten ion source and beamline components |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2237303A1 (en) * | 1973-07-09 | 1975-02-07 | Bbc Brown Boveri & Cie | |
FR2290025A1 (en) * | 1974-10-25 | 1976-05-28 | Bbc Brown Boveri & Cie | REACTION CATHODE |
FR2398381A1 (en) * | 1977-07-21 | 1979-02-16 | Philips Nv | ELECTRONIC TUBE CONTAINING AN INCANDESCENT CATHODE |
US4143295A (en) * | 1976-08-09 | 1979-03-06 | Hitachi, Ltd. | Cathode structure for an electron tube |
EP0010128A1 (en) * | 1978-08-31 | 1980-04-30 | Siemens Aktiengesellschaft | Directly heated cathode for an electron tube with coaxial electrode structure and method of making such a cathode |
FR2445605A1 (en) * | 1978-12-27 | 1980-07-25 | Thomson Csf | DIRECT HEATING CATHODE AND HIGH FREQUENCY ELECTRONIC TUBE COMPRISING SUCH A CATHODE |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3389977A (en) * | 1964-08-05 | 1968-06-25 | Texas Instruments Inc | Tungsten carbide coated article of manufacture |
US3719856A (en) * | 1971-05-19 | 1973-03-06 | O Koppius | Impregnants for dispenser cathodes |
NL175480C (en) * | 1974-06-12 | 1984-11-01 | Philips Nv | ELECTRODE FOR A DISCHARGE LAMP, METHOD FOR MANUFACTURING SUCH ELECTRODE AND DISCHARGE LAMP PROVIDED WITH SUCH ELECTRODE. |
US4019081A (en) * | 1974-10-25 | 1977-04-19 | Bbc Brown Boveri & Company Limited | Reaction cathode |
-
1981
- 1981-01-16 FR FR8100782A patent/FR2498372A1/en active Granted
-
1982
- 1982-01-08 DE DE8282400030T patent/DE3260969D1/en not_active Expired
- 1982-01-08 EP EP82400030A patent/EP0056749B1/en not_active Expired
- 1982-01-12 US US06/338,872 patent/US4577134A/en not_active Expired - Fee Related
- 1982-01-14 JP JP351982A patent/JPS57138744A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2237303A1 (en) * | 1973-07-09 | 1975-02-07 | Bbc Brown Boveri & Cie | |
FR2290025A1 (en) * | 1974-10-25 | 1976-05-28 | Bbc Brown Boveri & Cie | REACTION CATHODE |
US4143295A (en) * | 1976-08-09 | 1979-03-06 | Hitachi, Ltd. | Cathode structure for an electron tube |
FR2398381A1 (en) * | 1977-07-21 | 1979-02-16 | Philips Nv | ELECTRONIC TUBE CONTAINING AN INCANDESCENT CATHODE |
EP0010128A1 (en) * | 1978-08-31 | 1980-04-30 | Siemens Aktiengesellschaft | Directly heated cathode for an electron tube with coaxial electrode structure and method of making such a cathode |
FR2445605A1 (en) * | 1978-12-27 | 1980-07-25 | Thomson Csf | DIRECT HEATING CATHODE AND HIGH FREQUENCY ELECTRONIC TUBE COMPRISING SUCH A CATHODE |
Also Published As
Publication number | Publication date |
---|---|
US4577134A (en) | 1986-03-18 |
EP0056749B1 (en) | 1984-10-17 |
JPS57138744A (en) | 1982-08-27 |
FR2498372B1 (en) | 1983-07-22 |
EP0056749A2 (en) | 1982-07-28 |
EP0056749A3 (en) | 1982-08-25 |
DE3260969D1 (en) | 1984-11-22 |
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CL | Concession to grant licences | ||
ST | Notification of lapse |