FR2476629A2 - Denitrification and nitrification reactors for water treatment - with at least one granular bacterial support bed - Google Patents

Denitrification and nitrification reactors for water treatment - with at least one granular bacterial support bed Download PDF

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Publication number
FR2476629A2
FR2476629A2 FR8003991A FR8003991A FR2476629A2 FR 2476629 A2 FR2476629 A2 FR 2476629A2 FR 8003991 A FR8003991 A FR 8003991A FR 8003991 A FR8003991 A FR 8003991A FR 2476629 A2 FR2476629 A2 FR 2476629A2
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France
Prior art keywords
denitrification
water
water treatment
reactors
nitrification
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR8003991A
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French (fr)
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FR2476629B2 (en
Inventor
Gerard Faup
Michel Picard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suez International SAS
Original Assignee
Degremont SA
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Filing date
Publication date
Application filed by Degremont SA filed Critical Degremont SA
Priority to FR8003991A priority Critical patent/FR2476629B2/en
Priority to IT67766/80A priority patent/IT1128446B/en
Publication of FR2476629A2 publication Critical patent/FR2476629A2/en
Application granted granted Critical
Publication of FR2476629B2 publication Critical patent/FR2476629B2/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/302Nitrification and denitrification treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/2806Anaerobic processes using solid supports for microorganisms

Abstract

An installation according to claim 2 of the principal patent comprising a denitrification reactor functioning anaerobically and a nitrification reactor functioning aerobically is characterised in that one and/or the other of the reactors consists of a granular filter bed on which microbial cultures are fixed through which the water to be treated is passed. The principal patent relates to the use of heterotrophic bacteria in the 1st and autotrophic bacteria in the 2nd system with recycling of water from the 2nd to the 1st system. The above replaces an active sludge basin and/or a bacterial bed. The installation avoids the need for clarifiers.

Description

Le brevet principal revendique un procédé pour l'elîmination de la pollution carbonée et azotée des eaux usées par nitrification - dénitrification au moyen de bactéries hétérotrophes et autotrophes, dans lequel l'eau à traiter est amenée à passer successivement dans deux systèmes séparés contenant des cultures bactériennes différentes, le premier à base de bactéries hétérotrophes maintenues en anoxie réalisant une élimination de la pollution carbonée et une dénitrification, le second, fonctionnant en aérobiose, à base de bactéries autotrophes, réalisant la nitrification de la pollution azotée, l'eau nitrifiée sortant du second système étant recyclée dans le premier système de dénitrification. The main patent claims a process for eliminating carbon and nitrogen pollution of wastewater by nitrification - denitrification by means of heterotrophic and autotrophic bacteria, in which the water to be treated is caused to pass successively in two separate systems containing cultures. different bacteria, the first based on heterotrophic bacteria maintained in anoxia achieving elimination of carbon pollution and denitrification, the second, operating aerobically, based on autotrophic bacteria, carrying out the nitrification of nitrogen pollution, the outgoing nitrified water from the second system being recycled to the first denitrification system.

Le procédé suivant le brevet principal est caractérisé en ce que les boues de chaque système sont séparées et parcourent des circuits indépendants pour être, éventuellement, ramenées, celles contenant des organismes hétérotrophes, au premier système, fonctionnant en anoxie, celles contenant des organismes autotrophes, au second système, fonctionnant en aérobiose. The process according to the main patent is characterized in that the sludges of each system are separated and run through independent circuits to be, optionally, brought back, those containing heterotrophic organisms, to the first system, operating in anoxia, those containing autotrophic organisms, to the second system, operating aerobically.

Le même brevet décrit également une installation pour la mise en oeuvre dudit procédé, comportant successivement un premier réacteur fonctionnant en anoxie et un second réacteur fonctionnant en aérobiose. The same patent also describes an installation for the implementation of said method, successively comprising a first reactor operating in anoxia and a second reactor operating in aerobic mode.

Suivant une forme de réalisation de l'invention, le second réacteur consiste en un bassin boues activées; suivant une autre forme de réalisation de l'invention, le second réacteur consiste en un lit bactérien. According to one embodiment of the invention, the second reactor consists of an activated sludge tank; according to another embodiment of the invention, the second reactor consists of a bacterial bed.

Dans l'une et l'autre de ces formes de réalisation, chaque réacteur est associé à un clarificateur (portant les références respectivement Z et 6 sur le dessin annexé au brevet) à partir desquels sont, éventuellement, recyclées les boues, dans les conditions prévues au brevet et d'où les boues en excès sont évacuées. In both of these embodiments, each reactor is associated with a clarifier (bearing the references Z and 6 respectively in the drawing appended to the patent) from which the sludge is optionally recycled, under the conditions provided for in the patent and from which the excess sludge is discharged.

Conformément à la présente addition, l'un et/ou l'autre des réacteurs, au lieu d'être constitués par un bassin à boues activées et/ou un lit bactérien, consistent en un filtre immergé, constitué d'un matériau granulaire support de bactéries que l'eau à traiter est amenée à traverser de haut en bas ou de bas en haut. According to the present addition, one and / or the other of the reactors, instead of being constituted by an activated sludge tank and / or a bacterial bed, consist of an immersed filter, made of a granular support material bacteria that the water to be treated is caused to pass from top to bottom or from bottom to top.

L'important avantage que détermine l'utilisation de tels réacteurs à lit de matériaux granulaires, lesquels jouent le rôle à la fois de support biologique et de filtre pour les matières en suspension contenues dans l'eau à traiter, consiste dans la suppression des clarificateurs qui, tant dans le cas d'un bassin de boues activées que dans celui d'un lit bactérien sont nécessairement associés à ces réacteurs pour séparer la boue de l'eau traitée. ll s'ensuit une économie importante dans la construction de l'installation et des facilités dans sa conduite et son entretien. The important advantage determined by the use of such reactors with a bed of granular materials, which act both as a biological support and as a filter for the suspended matter contained in the water to be treated, consists in the elimination of clarifiers which, both in the case of an activated sludge pool and in that of a bacterial bed, are necessarily associated with these reactors to separate the sludge from the treated water. This results in significant savings in the construction of the installation and facilities in its operation and maintenance.

Il suffit simplement de procéder, à des intervalles convenables, au lavage des matériaux granulaires que contiennent les réacteurs suivant des techniques bien connues et efficaces. It suffices simply to proceed, at suitable intervals, to washing the granular materials which the reactors contain according to well known and effective techniques.

Les matériaux utilisés pour la constitution de tels filtres peuvent être quelconques, tels que: diatomées, cellulose, charbon actif, sable ou consistent en des matériaux plus élaborés du type alvéolaires ou macroporeux tels que par exempleceux décrits et revendiqués dans le brevet français N0 71 41292 et ses additions N0 76 00219 et 77 14196 de la Demanderesse. The materials used for the constitution of such filters can be any, such as: diatoms, cellulose, activated carbon, sand or consist of more elaborate materials of the alveolar or macroporous type such as for example those described and claimed in French patent No. 71 41292 and its additions N0 76 00219 and 77 14196 from the Applicant.

ll en est de même en ce qui concerne la granulométrie qui doit être choisie en fonction des paramètres habituels de l'eau à traiter et du traitement à lui appliquer. It is the same with regard to the particle size which must be chosen according to the usual parameters of the water to be treated and the treatment to be applied to it.

Il convient de noter qu'aussi bien le réacteur fonctionnant en aérobiose que celui fonctionnant en anoxie peuvent consister en de tels filtres. It should be noted that both the reactor operating aerobically and that operating anoxically can consist of such filters.

ll est particulièrement intéressant que le réacteur fonctionnant en aérobiose dans lequel se développent les cellules bactériennes de nitrification soit un réacteur à lit de matériaux granulaires.  It is particularly interesting that the aerobically operating reactor in which the bacterial nitrification cells develop is a reactor with a bed of granular materials.

Claims (1)

REVENDICATION CLAIM Installation suivant la revendication 2 de la demande de brevet Installation according to claim 2 of the patent application principal, comportant un réacteur de dénitrification fonctionnant en main, comprising a denitrification reactor operating in anoxie et un réacteur de nitrification fonctionnant en aérobiose, caracté anoxia and an aerobic aerosol nitrification reactor, character risée en ce que l'un et/ou l'autre de ces réacteurs consistent en un (ou des) filtres immergés à lit granulaire, support de bactéries, sur lequel (ou les laughing at the fact that one and / or the other of these reactors consist of one (or more) submerged filters with a granular bed, support of bacteria, on which (or the quels) l'eau à traiter est amenée à passer, les cultures microbiennes res which) the water to be treated is caused to pass, the microbial cultures res tant fixées sur le support granulaire.  both fixed on the granular support.
FR8003991A 1979-05-16 1980-02-22 PROCESS AND PLANT FOR THE REMOVAL OF CARBONACEOUS AND NITROGEN POLLUTION FROM WASTEWATER Expired FR2476629B2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR8003991A FR2476629B2 (en) 1980-02-22 1980-02-22 PROCESS AND PLANT FOR THE REMOVAL OF CARBONACEOUS AND NITROGEN POLLUTION FROM WASTEWATER
IT67766/80A IT1128446B (en) 1979-05-16 1980-05-15 Denitrification and nitrification reactors for water treatment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8003991A FR2476629B2 (en) 1980-02-22 1980-02-22 PROCESS AND PLANT FOR THE REMOVAL OF CARBONACEOUS AND NITROGEN POLLUTION FROM WASTEWATER

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FR2476629A2 true FR2476629A2 (en) 1981-08-28
FR2476629B2 FR2476629B2 (en) 1985-11-15

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0102584A2 (en) * 1982-08-28 1984-03-14 Linde Aktiengesellschaft Process for water denitrification
EP0193979A2 (en) * 1985-02-25 1986-09-10 ACEC, Société Anonyme Process for the elimination of nitrates by a microbiological conversion in the presence of gaseous hydrogen
EP0247212A2 (en) * 1986-04-23 1987-12-02 GebràœDer Sulzer Aktiengesellschaft Process for the biological purification of water or waste water to remove organic nitrogen-contaning impurities
US4721585A (en) * 1985-01-25 1988-01-26 Consiglio Nazionale Delle Richerche Process for the biological treatment of sewage
EP0293521A2 (en) * 1987-06-04 1988-12-07 GebràœDer Sulzer Aktiengesellschaft Process for the biological purification of water or waste water from organic nitrogenous pollutants
EP0531586A1 (en) * 1990-06-13 1993-03-17 Zaidan Hojin Nanyo Kyokai Method and system for processing organic waste liquid

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2235089A1 (en) * 1973-06-26 1975-01-24 Anvar Elimination of chemically bound nitrogen from liquid effluent - by passing through beds contg. aerobic and then anaerobic bateria
FR2400489A1 (en) * 1977-08-17 1979-03-16 Carboxyque Francaise Biological purification of waste water - includes oxygenation, degradation, nitrification and denitrification steps

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2235089A1 (en) * 1973-06-26 1975-01-24 Anvar Elimination of chemically bound nitrogen from liquid effluent - by passing through beds contg. aerobic and then anaerobic bateria
FR2400489A1 (en) * 1977-08-17 1979-03-16 Carboxyque Francaise Biological purification of waste water - includes oxygenation, degradation, nitrification and denitrification steps

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0102584A2 (en) * 1982-08-28 1984-03-14 Linde Aktiengesellschaft Process for water denitrification
EP0102584A3 (en) * 1982-08-28 1985-05-08 Linde Aktiengesellschaft Process for water denitrification
US4715958A (en) * 1982-08-28 1987-12-29 Linde Aktiengesellschaft Process and means for conducting the denitrification of water
US4721585A (en) * 1985-01-25 1988-01-26 Consiglio Nazionale Delle Richerche Process for the biological treatment of sewage
EP0193979A2 (en) * 1985-02-25 1986-09-10 ACEC, Société Anonyme Process for the elimination of nitrates by a microbiological conversion in the presence of gaseous hydrogen
US4696747A (en) * 1985-02-25 1987-09-29 Ateliers De Constructions Electriques De Charleroi (Acec) Societe Anonyme Process for the elimination of nitrates by means of a microbiological conversion in the presence of hydrogen gas
EP0193979A3 (en) * 1985-02-25 1989-01-11 ACEC, Société Anonyme Process for the elimination of nitrates by a microbiological conversion in the presence of gaseous hydrogen
EP0247212A2 (en) * 1986-04-23 1987-12-02 GebràœDer Sulzer Aktiengesellschaft Process for the biological purification of water or waste water to remove organic nitrogen-contaning impurities
EP0247212A3 (en) * 1986-04-23 1988-10-05 GebràœDer Sulzer Aktiengesellschaft Process for the biological purification of water or waste water to remove organic nitrogen-contaning impurities
EP0293521A2 (en) * 1987-06-04 1988-12-07 GebràœDer Sulzer Aktiengesellschaft Process for the biological purification of water or waste water from organic nitrogenous pollutants
EP0293521A3 (en) * 1987-06-04 1989-01-04 GebràœDer Sulzer Aktiengesellschaft Process for the biological purification of water or waste water from organic nitrogenous pollutants
EP0531586A1 (en) * 1990-06-13 1993-03-17 Zaidan Hojin Nanyo Kyokai Method and system for processing organic waste liquid

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FR2476629B2 (en) 1985-11-15

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