FR2465520A1 - Wear resistant components, esp. for milling or mixing plant - made from titanium contg. small amts. of dissolved oxygen and nitrogen - Google Patents

Wear resistant components, esp. for milling or mixing plant - made from titanium contg. small amts. of dissolved oxygen and nitrogen Download PDF

Info

Publication number
FR2465520A1
FR2465520A1 FR8018467A FR8018467A FR2465520A1 FR 2465520 A1 FR2465520 A1 FR 2465520A1 FR 8018467 A FR8018467 A FR 8018467A FR 8018467 A FR8018467 A FR 8018467A FR 2465520 A1 FR2465520 A1 FR 2465520A1
Authority
FR
France
Prior art keywords
nitrogen
titanium
contg
milling
esp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR8018467A
Other languages
French (fr)
Other versions
FR2465520B3 (en
Inventor
Dieter Buhling
Manfred Naumann
Karlheinz Rodegast
Wilm Heinrich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HERMSDORF KERAMIK VEB
Original Assignee
HERMSDORF KERAMIK VEB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HERMSDORF KERAMIK VEB filed Critical HERMSDORF KERAMIK VEB
Publication of FR2465520A1 publication Critical patent/FR2465520A1/en
Application granted granted Critical
Publication of FR2465520B3 publication Critical patent/FR2465520B3/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C14/00—Alloys based on titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C17/00—Disintegrating by tumbling mills, i.e. mills having a container charged with the material to be disintegrated with or without special disintegrating members such as pebbles or balls
    • B02C17/18—Details
    • B02C17/20—Disintegrating members

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Food Science & Technology (AREA)
  • Crushing And Grinding (AREA)
  • Powder Metallurgy (AREA)

Abstract

The components are made of Ti contg. (atomic %) 0.5-15(2-10)% dissolved oxygen, and 0.03-7.5 (1-6)% dissolved nitrogen. The ratio of oxygen:nitrogen in the components is pref. 2:1; and a Ti alloy may be used instead of Ti. The components are used esp. as milling- balls or -rollers in the ceramics- or metal-industries, or in machine construction; and also resist corrosive environments. The components are very easy to mfr. and possess a very high resistance to abrasion and wear.

Description

L'invention concerne des pièces ayant une résistance élevée à l'usure, pour machines et dispositifs, en particulier pour des mélangeurs et des broyeurs dans lesquels leur application est possible et utile. les domaines d'application de l'invention sont l'industrie de la céramique, la métallurgie et la construction mécanique. L'application de l'invention peut également avoir lieu en milieu corrosif. The invention relates to parts having a high wear resistance, for machines and devices, in particular for mixers and mills in which their application is possible and useful. the fields of application of the invention are the ceramic industry, metallurgy and mechanical construction. The application of the invention can also take place in a corrosive medium.

On connaît des éléments broyeurs et des tambours de broyage en métal dur, acier, porcelaine, silex, agate, matière plastique et titane. En raison de leur usure, ils n'assurent pas un traitement exempt de pollution des matières à broyer, ne présentent qu'une faible capacité de broyage, et/ou leur mode de préparation les rend coûteux. Grinding elements and grinding drums are known in hard metal, steel, porcelain, flint, agate, plastic and titanium. Due to their wear, they do not provide a pollution-free treatment of the materials to be ground, have only a low grinding capacity, and / or their method of preparation makes them expensive.

On connaît également des billes de broyeur en un matériau à base de titane et oxygène, soit jusqu'à 97 % en poids de TiO2 et une matière jouant le rôle de plastifiant et de liant, par exemple des bentonites ou de l'éther de cellulose (A. Palatzky, Techn. Eeramik, VEB Verlage Technique, Berlin, 1954). There are also known grinder balls made of a material based on titanium and oxygen, that is to say up to 97% by weight of TiO2 and a material playing the role of plasticizer and binder, for example bentonites or cellulose ether. (A. Palatzky, Techn. Eeramik, VEB Verlage Technique, Berlin, 1954).

le défaut de ce zen matériau, ctest qu'en raison de sa faible résis- tance à l'usure, les pièces que l'on en fabrique doivent être souvent échangées et le supplément de broyage abaisse considérablement l'aptitude à l'usinage du matériau broyé, et restreint le domaine d'application des objets qui en sont fabriqués. Les éléments broyeurs constitués par le matériau mentionné, imposent en raison de leur densité relativement faible de 4g/cm3, une durée de broyage relativement élevée. Par addition de composés du plomb en proportions allant de 2 à 10 ffi en poids, au TiO2 en poudre, on a réussi à doubler pratiquement la résistance à l'abrasion de billes de broyage de ce type (DE PS 1 072 179) mais l'usure reste encore relativement élevée, et le passage du plomb dans la matière broyée pose d'autres problèmes. the defect of this zen material is that due to its low resistance to wear, the parts which are manufactured from it must be often replaced and the grinding supplement considerably lowers the machinability of the crushed material, and restricts the field of application of the objects produced from it. Due to their relatively low density of 4g / cm3, the grinding elements made up of the mentioned material require a relatively high grinding time. By adding lead compounds in proportions ranging from 2 to 10 ffi by weight, to powdered TiO2, it has been possible to practically double the abrasion resistance of grinding balls of this type (DE PS 1 072 179) but l wear is still relatively high, and the passage of lead into the ground material poses other problems.

l'invention a pour objectif de prolonger la durée d'action de pièces soumises à l'usure, ainsi que 11 élimination dans une grande mesure des suppléments de broyage nuisibles? et l'abaissement de la durée de broyage dans l'industrie de la céramique et la métallurgie. the object of the invention is to extend the duration of action of parts subject to wear, as well as the elimination to a large extent of harmful grinding supplements? and lowering the grinding time in the ceramic industry and metallurgy.

L'invention s'est fixée pour but de proposer des éléments hautement résistants à l'usure, avec une meilleure tenue à l'abrasion, une densité relativement élevée, et un faible court de production. The invention has set itself the aim of providing elements which are highly resistant to wear, with better abrasion resistance, a relatively high density, and a short production run.

A cet effet, l'invention propose des éléments constitués de titane, avec 0,5 à 15 k atomique d'oxygène dissous et 0,03 à 7,5 % atomique d'azote dissous. Des teneurs en oxygène de 2 à 10 % atomique, et en azote de 1 à 6 fiv atomique, sont recommandées.Unrapport de l'oxygène à l'azote de 2 pour 1 est favorable. A la place de titane on peut également utiliser, pour des applications déterminées, des alliages de titane. To this end, the invention provides elements made of titanium, with 0.5 to 15 atomic k of dissolved oxygen and 0.03 to 7.5 atomic% of dissolved nitrogen. Oxygen levels of 2 to 10 atomic% and nitrogen of 1 to 6 atomic fiv are recommended. A ratio of oxygen to nitrogen of 2 to 1 is favorable. Instead of titanium, titanium alloys can also be used for specific applications.

Comme matériau hautement résistant à l'usure pour éléments broyeurs cylindriques, on prend du titane avec 6 % atomique d'oxygène dissous et 3 % atomique d'azote dissous. Comparée8 à des éléments broyeurs connus, à base de Ti02, la durée d'action des éléments proposés est 20 fois plus longue, et la période de broyage nécessaire est raccourcie de 20. Par rapport à des billes en agate, pour une même résistance à l'usure, on obtient une période de brcyage de 5 à 6 plus courte, et le cott en est nettement plus faible.  As highly wear-resistant material for cylindrical grinding elements, titanium is used with 6 atomic% of dissolved oxygen and 3 atomic% of dissolved nitrogen. Compared8 to known grinding elements, based on TiO 2, the duration of action of the proposed elements is 20 times longer, and the grinding period required is shortened by 20. Compared to agate balls, for the same resistance to wear, we obtain a shorter brciation period of 5 to 6, and the cost is much lower.

Claims (4)

REVENDICATIONS 10) Eléments à résistance élevée à l'usure, en particulier pour mélangeurs et broyeurs, caractérisés en ce qu'ils sont constitués par du titane, avec 0,5 à 15 % atomique d'oxygène dissous et 0,03 à 7,5 % atomique d'azote dissous. 10) Elements with high wear resistance, in particular for mixers and grinders, characterized in that they consist of titanium, with 0.5 to 15 atomic% of dissolved oxygen and 0.03 to 7.5 atomic% of dissolved nitrogen. 20) Eléments selon la revendication 1, caractérisés en ce qu'ils contiennent de 2 à 10 % atomique d'oxygène. 20) Elements according to claim 1, characterized in that they contain from 2 to 10 atomic% of oxygen. 30) Eléments selon les revendications 1 ou 2, caractérisés en ce qu'ils contiennent de 1 à 6 % atomique d'azote.  30) Elements according to claims 1 or 2, characterized in that they contain from 1 to 6 atomic% of nitrogen. 40) Eléments selon les revendications 1 à 3, caractérisés en ce qu'ils contiennent l'oxygène et l'azote dans un rapport de 2 à 1. 40) Elements according to claims 1 to 3, characterized in that they contain oxygen and nitrogen in a ratio of 2 to 1. 50) léments selon les revendications 1 à 4, caractérisés en ce que, à la place du titane, on emploie un alliage à base de titane. 50) elements according to claims 1 to 4, characterized in that, instead of titanium, a titanium-based alloy is used.
FR8018467A 1979-09-19 1980-08-25 Wear resistant components, esp. for milling or mixing plant - made from titanium contg. small amts. of dissolved oxygen and nitrogen Granted FR2465520A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DD21561979A DD149750A3 (en) 1979-09-19 1979-09-19 HIGH-WEAR-RESISTANT PARTS, ESPECIALLY FOR MIXING AND GRINDING AGGREGATES

Publications (2)

Publication Number Publication Date
FR2465520A1 true FR2465520A1 (en) 1981-03-27
FR2465520B3 FR2465520B3 (en) 1982-07-23

Family

ID=5520152

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8018467A Granted FR2465520A1 (en) 1979-09-19 1980-08-25 Wear resistant components, esp. for milling or mixing plant - made from titanium contg. small amts. of dissolved oxygen and nitrogen

Country Status (5)

Country Link
JP (1) JPS5655542A (en)
DD (1) DD149750A3 (en)
DE (1) DE3027974A1 (en)
FR (1) FR2465520A1 (en)
HU (1) HU190776B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0322087A2 (en) * 1987-12-23 1989-06-28 Nippon Steel Corporation High strength titanium material having improved ductility and method for producing same
EP0812924A1 (en) * 1996-06-11 1997-12-17 Institut Straumann Ag Titanium material, process for its production and use

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3501893A1 (en) * 1984-03-05 1985-09-05 Veb Werkzeugkombinat Schmalkalden, Ddr 6080 Schmalkalden Sintered materials based on titanium carbide, titanium nitride or titanium carbonitride
DE3546851C2 (en) * 1984-03-05 1995-05-18 Wilm Dr Heinrich Titanium carbide sinter material

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0322087A2 (en) * 1987-12-23 1989-06-28 Nippon Steel Corporation High strength titanium material having improved ductility and method for producing same
EP0322087A3 (en) * 1987-12-23 1990-01-24 Nippon Steel Corporation High strength titanium material having improved ductility and method for producing same
EP0812924A1 (en) * 1996-06-11 1997-12-17 Institut Straumann Ag Titanium material, process for its production and use

Also Published As

Publication number Publication date
JPS5655542A (en) 1981-05-16
HU190776B (en) 1986-11-28
DD149750A3 (en) 1981-07-29
FR2465520B3 (en) 1982-07-23
DE3027974A1 (en) 1981-04-09

Similar Documents

Publication Publication Date Title
US3967935A (en) Corrosion and wear resistant steel sinter alloy
US5679908A (en) Corrosion resistant, high vanadium, powder metallurgy tool steel articles with improved metal to metal wear resistance and a method for producing the same
CN101517111B (en) Metallurgical powder composition and method of production
JP6227871B2 (en) Master alloy for producing sintered hardened steel parts and process for producing sintered hardened parts
DE102013004817A1 (en) Sintered alloy and process for its production
JP2006233331A (en) Iron-based sintered alloy and manufacturing method therefor
FR2465520A1 (en) Wear resistant components, esp. for milling or mixing plant - made from titanium contg. small amts. of dissolved oxygen and nitrogen
US4787561A (en) Fine granular metallic powder particles and process for producing same
JP2885098B2 (en) Processing method of titanium sponge powder
JPH0826338B2 (en) Self-lubricating material and manufacturing method thereof
DD146556A1 (en) HIGH-WEAR-RESISTANT PARTS, ESPECIALLY FOR MIXING AND GRINDING AGGREGATES AND METHOD FOR THE PRODUCTION THEREOF
US3737290A (en) Sintered titanium alloy
EP0591305B1 (en) Cermets based on transition metal borides, their production and use
JP2016516135A (en) Powder metal composition for wear and temperature resistant applications and method for producing the same
DE2846574A1 (en) Hammer heads for coal crushing hammer mill - are made of low alloy spheroidal graphite cast iron contg. nickel, copper and pref. molybdenum and cobalt
DE19944592A1 (en) Process for the powder-metallurgical in-situ production of a wear-resistant composite material
RU2458172C2 (en) Metallurgical powdered composition and method for its obtaining
JPS616255A (en) High hardness and high toughness nitrided powder high speed steel
none Discussion of Session 1:‘Production Methods of Metal Powders’
US3933482A (en) Wear-resistant composite material
JPH0252681B2 (en)
SE521053C2 (en) Use of an alloy non-oxidizing metal powder
JPH02133545A (en) Highly alloyed high speed tool steel
KR100698367B1 (en) Boron added Fe-base hardfacing alloy with high-wear resistance caused by strain induced martensitic transformation
DE2721631A1 (en) METHOD FOR PRODUCING TITANIUM CARBIDE HARD MATERIAL