FR2456615A1 - TRANSPARENT POLYCARBONATE ARTICLE COATED WITH POLYORGANOSILOXANE - Google Patents

TRANSPARENT POLYCARBONATE ARTICLE COATED WITH POLYORGANOSILOXANE

Info

Publication number
FR2456615A1
FR2456615A1 FR7912771A FR7912771A FR2456615A1 FR 2456615 A1 FR2456615 A1 FR 2456615A1 FR 7912771 A FR7912771 A FR 7912771A FR 7912771 A FR7912771 A FR 7912771A FR 2456615 A1 FR2456615 A1 FR 2456615A1
Authority
FR
France
Prior art keywords
polyorganosiloxane
scratches
transparent polycarbonate
article coated
polycarbonate article
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7912771A
Other languages
French (fr)
Other versions
FR2456615B1 (en
Inventor
James Stevenson Humphrey Jr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co
Original Assignee
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Co filed Critical General Electric Co
Publication of FR2456615A1 publication Critical patent/FR2456615A1/en
Application granted granted Critical
Publication of FR2456615B1 publication Critical patent/FR2456615B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12—Chemical modification
    • C08J7/16—Chemical modification with polymerisable compounds
    • C08J7/18—Chemical modification with polymerisable compounds using wave energy or particle radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • B05D7/04—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber to surfaces of films or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/53—Base coat plus clear coat type
    • B05D7/536—Base coat plus clear coat type each layer being cured, at least partially, separately
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065—After-treatment
    • B05D3/067—Curing or cross-linking the coating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2369/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2483/04—Polysiloxanes

Abstract

ARTICLE PRESENTANT UNE EXCELLENTE RESISTANCE AUX RAYURES, AUX STRIURES, A L'ABRASION ET AUX SOLVANTS. IL COMPREND UN SUBSTRAT DE POLYCARBONATE SUR LEQUEL ON A DEPOSE I UNE COUCHE D'ACCROCHAGE DURCIE PAR LES RAYONS ULTRAVIOLETS QUI RENFERME LE PRODUIT DE REACTION DE A AU MOINS UN MONOMETRE D'ESTER D'ACIDE ACRYLIQUE POLYFONCTIONNEL, ET BUN COMPOSE D'ORGANOSILICIUM RENFERMANT AU MOINS UN GROUPE ORGANIQUE PRESENTANT UNE INSATURATION OLEFINIQUE ET II SUR CETTE COUCHE D'ACCROCHAGE, UN REVETEMENT SUPERFICIEL DURCI RENFERMANT UN POLYORGANOSILOXANE THERMODURCI RENFERMANT UNE CHARGE DE SILICE COLLOIDALE. APPLICATION A LA FABRICATION DE VITRES, PARE-BRISE, ETC.ARTICLE WITH EXCELLENT RESISTANCE TO SCRATCHES, SCRATCHES, ABRASION AND SOLVENTS. IT INCLUDES A POLYCARBONATE SUBSTRATE ON WHICH A TICKET LAYER CURED BY ULTRAVIOLET RAYS HAS BEEN DEPOSITED WHICH CONTAINS THE REACTION PRODUCT OF AT LEAST ONE MONOMETER OF ESTER OF POLYFUNCTIONAL ACRYLIC ACID, AND RENFERMICIUM COMPOUND WITH BOSILICIUM. AT LEAST ONE ORGANIC GROUP PRESENTING AN OLEFINIC INSATURATION AND II ON THIS BONDING LAYER, A CURED SURFACE COATING CONTAINING A THERMODURCED POLYORGANOSILOXANE CONTAINING A LOAD OF COLLOIDAL SILICA. APPLICATION TO THE MANUFACTURE OF WINDOWS, WINDSHIELDS, ETC.

FR7912771A 1978-04-12 1979-05-18 TRANSPARENT POLYCARBONATE ARTICLE COATED WITH POLYORGANOSILOXANE Granted FR2456615A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US89579078A 1978-04-04 1978-04-04

Publications (2)

Publication Number Publication Date
FR2456615A1 true FR2456615A1 (en) 1980-12-12
FR2456615B1 FR2456615B1 (en) 1985-02-15

Family

ID=25405107

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7912771A Granted FR2456615A1 (en) 1978-04-12 1979-05-18 TRANSPARENT POLYCARBONATE ARTICLE COATED WITH POLYORGANOSILOXANE

Country Status (5)

Country Link
AU (1) AU532624B2 (en)
DE (1) DE2917833A1 (en)
FR (1) FR2456615A1 (en)
GB (1) GB2018621B (en)
NL (1) NL185289C (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4210699A (en) * 1978-11-01 1980-07-01 General Electric Company Abrasion resistant silicone coated polycarbonate article
US4239798A (en) * 1978-11-01 1980-12-16 General Electric Company Abrasion resistant silicone coated polycarbonate article
US4198465A (en) * 1978-11-01 1980-04-15 General Electric Company Photocurable acrylic coated polycarbonate articles
US4353959A (en) * 1979-12-21 1982-10-12 General Electric Company Abrasion resistant silicone coated polycarbonate article having an acrylic primer layer containing a U.V. absorbing compound
US5232781A (en) * 1989-04-01 1993-08-03 Nippon Sheet Glass Co., Ltd. Method for manufacturing layer-built material with silicon dioxide film containing organic colorant and the layer-built material manufactured thereby
DE69010537T2 (en) * 1989-04-01 1994-12-01 Nippon Sheet Glass Co Ltd Process for producing a layered material with an organic dye-containing silicon dioxide film and the product thus produced.
CA2029665C (en) * 1989-11-17 1996-12-03 Shoichi Nagai Shaped articles and method of making same
CA2086276C (en) * 1992-12-24 2001-12-11 Masamoto Uenishi Coated shaped articles and method of making same
US5912061A (en) * 1995-08-03 1999-06-15 Matsushita Electric Industrial Co., Ltd. UV-ray setting resin and a method for manufacturing a magneto-optical disk by the use of the UV-ray setting resin
DE69841905D1 (en) * 1998-03-04 2010-11-04 Mitsubishi Rayon Co PHOTOVERNET-FILM, MOLDED MADE AND METHOD FOR THE PRODUCTION THEREOF
US6458462B1 (en) 2000-12-13 2002-10-01 3M Innovative Properties Company Sporting goods having a ceramer coating
US20150030832A1 (en) 2012-08-03 2015-01-29 Mazda Motor Corporation Transparent layered structure and method for producing the same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3616367A (en) * 1968-11-25 1971-10-26 Du Pont Photopolymerizable acrylic compositions containing rearrangeable ultraviolet stabilizer precursors
US3707397A (en) * 1971-02-26 1972-12-26 Owens Illinois Inc Process for providing uniform organopolysiloxane coatings on polycarbonate and acrylic surfaces
FR2260608A1 (en) * 1974-02-12 1975-09-05 Union Carbide Corp
FR2276360A1 (en) * 1974-06-25 1976-01-23 Dow Corning NON-PIGMENTED COATING COMPOSITIONS BASED ON COLLOIDAL SILICA AND THE PRODUCT OF PARTIAL CONDENSATION OF A SILANOL
FR2378836A1 (en) * 1977-01-28 1978-08-25 Gen Electric COMPOSITION FOR PRIMARY BONDING LAYER

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3650808A (en) * 1970-04-08 1972-03-21 Donald W Gagnon Polycarbonate surfaces having tenaciously adhered organopolysiloxane coatings thereon and process for making
US3708225A (en) * 1971-06-09 1973-01-02 Mbt Corp Coated synthetic plastic lens
DE2523224C3 (en) * 1975-05-26 1979-09-27 Wacker-Chemie Gmbh, 8000 Muenchen Process for enhancing the adhesion of organopolysiloxane elastomers
US4159206A (en) * 1977-03-18 1979-06-26 Rohm And Haas Company Weatherable, abrasion resistant coating composition, method, and coated articles

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3616367A (en) * 1968-11-25 1971-10-26 Du Pont Photopolymerizable acrylic compositions containing rearrangeable ultraviolet stabilizer precursors
US3707397A (en) * 1971-02-26 1972-12-26 Owens Illinois Inc Process for providing uniform organopolysiloxane coatings on polycarbonate and acrylic surfaces
FR2260608A1 (en) * 1974-02-12 1975-09-05 Union Carbide Corp
FR2276360A1 (en) * 1974-06-25 1976-01-23 Dow Corning NON-PIGMENTED COATING COMPOSITIONS BASED ON COLLOIDAL SILICA AND THE PRODUCT OF PARTIAL CONDENSATION OF A SILANOL
FR2378836A1 (en) * 1977-01-28 1978-08-25 Gen Electric COMPOSITION FOR PRIMARY BONDING LAYER

Also Published As

Publication number Publication date
GB2018621A (en) 1979-10-24
NL7903333A (en) 1980-10-28
DE2917833A1 (en) 1980-11-13
FR2456615B1 (en) 1985-02-15
NL185289C (en) 1990-03-01
AU4620279A (en) 1979-10-18
GB2018621B (en) 1982-03-24
AU532624B2 (en) 1983-10-06

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