FR2450845A1 - PROCESS FOR THE REDUCTION OF METAL ALCOHOLATES AND USE OF THE PRODUCTS THUS OBTAINED IN THE POLYMERIZATION AND COPOLYMERIZATION OF UNSATURATED COMPOUNDS - Google Patents
PROCESS FOR THE REDUCTION OF METAL ALCOHOLATES AND USE OF THE PRODUCTS THUS OBTAINED IN THE POLYMERIZATION AND COPOLYMERIZATION OF UNSATURATED COMPOUNDSInfo
- Publication number
- FR2450845A1 FR2450845A1 FR8005071A FR8005071A FR2450845A1 FR 2450845 A1 FR2450845 A1 FR 2450845A1 FR 8005071 A FR8005071 A FR 8005071A FR 8005071 A FR8005071 A FR 8005071A FR 2450845 A1 FR2450845 A1 FR 2450845A1
- Authority
- FR
- France
- Prior art keywords
- polymerization
- alcoholates
- tetravalent
- copolymerization
- products
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 238000007334 copolymerization reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052768 actinide Inorganic materials 0.000 abstract 1
- 150000001255 actinides Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052747 lanthanoid Inorganic materials 0.000 abstract 1
- 150000002602 lanthanoids Chemical class 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/68—Preparation of metal alcoholates
- C07C29/685—Preparation of metal alcoholates by converting O-metal groups to other O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
PROCEDE POUR LA REDUCTION D'ALCOOLATES METALLIQUES ET UTILISATION DES PRODUITS AINSI OBTENUS DANS LA POLYMERISATION ET LA COPOLYMERISATION DE COMPOSES INSATURES. LES ALCOOLATES DES METAUX DE TRANSITION, CHOISIS PARMI LE TITANE TETRAVALENT, LE VANADIUM TETRAVALENT ET PENTAVALENT, LE CHROME TETRAVALENT ET LE ZIRCONIUM TETRAVALENT, LES ACTINIDES ET LANTHANIDES, SONT REDUITS EN ALCOOLATES CORRESPONDANTS DE VALENCE INFERIEURE EN FAISANT REAGIR CES ALCOOLATES DE METAUX DE VALENCE SUPERIEURE, DANS UNE PHASE LIQUIDE, AVEC LES VAPEURS DE METAUX DU GROUPE ALCALINOTERREUX, DU GROUPEIII ET DU GROUPEIV ET LE MANGANESE. UTILISATION DES COMPOSES OBTENUS COMME CATALYSEURS TRES EFFICACES POUR LA POLYMERISATION DE COMPOSES INSATURES.PROCESS FOR THE REDUCTION OF METAL ALCOHOLATES AND USE OF THE PRODUCTS THUS OBTAINED IN THE POLYMERIZATION AND COPOLYMERIZATION OF UNSATURE COMPOUNDS. THE ALCOHOLATES OF TRANSITION METALS, CHOSEN FROM TETRAVALENT TITANIUM, TETRAVALENT AND PENTAVALENT VANADIUM, TETRAVALENT CHROME AND TETRAVALENT ZIRCONIUM, ACTINIDES AND LANTHANIDES, ARE REDUCED IN CORRESPONDENT VALENCE ALCOHOLATES OF THESE INFANTALENCE ALCOHOLATES OF THESE INFURITY REALENCE , IN A LIQUID PHASE, WITH VAPORS OF METALS OF THE ALKALINOTERREUX GROUP, OF GROUP III AND OF GROUP IV AND MANGANESE. USE OF THE COMPOUNDS OBTAINED AS VERY EFFICIENT CATALYSTS FOR THE POLYMERIZATION OF UNSATURE COMPOUNDS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT20798/79A IT1113421B (en) | 1979-03-07 | 1979-03-07 | METHOD FOR THE REDUCTION OF METALLIC ALCOXIDS AND USE OF THE COMPOUNDS SO OBTAINED |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2450845A1 true FR2450845A1 (en) | 1980-10-03 |
| FR2450845B1 FR2450845B1 (en) | 1985-10-18 |
Family
ID=11172213
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8005071A Expired FR2450845B1 (en) | 1979-03-07 | 1980-03-06 | PROCESS FOR THE REDUCTION OF METAL ALCOHOLATES AND USE OF THE PRODUCTS THUS OBTAINED IN THE POLYMERIZATION AND COPOLYMERIZATION OF UNSATURATED COMPOUNDS |
Country Status (31)
| Country | Link |
|---|---|
| US (1) | US4333881A (en) |
| JP (1) | JPS55160784A (en) |
| AR (1) | AR226174A1 (en) |
| AT (1) | AT371796B (en) |
| AU (1) | AU528925B2 (en) |
| BE (1) | BE882137A (en) |
| BR (1) | BR8001392A (en) |
| CA (1) | CA1133018A (en) |
| CH (1) | CH646932A5 (en) |
| CS (1) | CS276219B6 (en) |
| DD (1) | DD149369A5 (en) |
| DE (1) | DE3008909C2 (en) |
| DK (1) | DK97380A (en) |
| ES (1) | ES8104328A1 (en) |
| FR (1) | FR2450845B1 (en) |
| GB (1) | GB2046740B (en) |
| HU (1) | HU182108B (en) |
| IE (1) | IE49524B1 (en) |
| IL (1) | IL59534A (en) |
| IN (2) | IN154572B (en) |
| IT (1) | IT1113421B (en) |
| LU (1) | LU82228A1 (en) |
| MX (1) | MX153451A (en) |
| NL (1) | NL8001390A (en) |
| NO (2) | NO157579C (en) |
| PT (1) | PT70912A (en) |
| RO (1) | RO81241A (en) |
| SE (2) | SE448460B (en) |
| SU (1) | SU1319782A3 (en) |
| YU (2) | YU41035B (en) |
| ZA (1) | ZA801254B (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4594439A (en) * | 1980-08-06 | 1986-06-10 | The Board Of Trustees Of The Leland Stanford Jr. University | Method for asymmetric epoxidation |
| IT1139827B (en) * | 1980-11-24 | 1986-09-24 | Nat Distillers Chem Corp | INTERMETALLIC COMPOUNDS OF OXIDES ALCOSS OF METALS OF TRANSITION POLYMERS |
| US4513095A (en) * | 1980-11-24 | 1985-04-23 | National Distillers And Chemical Corporation | Intermetallic compounds of polymeric transition metal oxide alkoxides and catalytic use thereof |
| JPS57193491A (en) * | 1981-05-25 | 1982-11-27 | Nippon Soda Co Ltd | Complex oxyalkoxide and its preparation |
| US4526724A (en) * | 1983-09-30 | 1985-07-02 | Standard Oil Company (Indiana) | Process for the preparation of zero valent bis-arene transition metal compounds |
| US4609755A (en) * | 1983-10-20 | 1986-09-02 | Allied Colloids Limited | Synthesis of vinyl esters |
| US4727165A (en) * | 1983-11-18 | 1988-02-23 | Phillips Petroleum Company | Catalytically hydrogenated decomposible molybdenum compounds as oil hydrofining agents |
| US4740570A (en) * | 1985-01-18 | 1988-04-26 | E. I. Du Pont De Nemours And Company | Metal halide vaporization into diluents |
| US4650778A (en) * | 1985-01-18 | 1987-03-17 | E. I. Du Pont De Nemours And Company | Metal halide vaporization into diluents |
| US5039636A (en) * | 1990-08-10 | 1991-08-13 | Hercules Incorporated | Preparation of aluminum titanate from an organometallic oligomer |
| US5536857A (en) * | 1994-07-05 | 1996-07-16 | Ford Motor Company | Single source volatile precursor for SiO2.TiO2 powders and films |
| DE19545444A1 (en) * | 1995-12-06 | 1997-06-12 | Du Pont | Alkoxides with alkaline earths and titanium, zirconium and / or hafnium, their production and use |
| RU2471763C1 (en) * | 2011-12-27 | 2013-01-10 | Федеральное государственное бюджетное учреждение науки Институт химии высокочистых веществ им. Г.Г. Девятых Российской академии наук (ИХВВ РАН) | Method of producing double isopropylate of magnesium and aluminium |
| RU2603771C1 (en) * | 2015-05-05 | 2016-11-27 | Федеральное государственное унитарное предприятие "Ордена Ленина и ордена Трудового Красного Знамени Научно-исследовательский институт синтетического каучука имени академика С.В. Лебедева" (ФГУП НИИСК) | Method of producing mixed barium-containing alcoholates |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE755750A (en) * | 1969-09-06 | 1971-02-15 | Dynamit Nobel Ag | PROCESS FOR SIMULTANEOUS PREPARATION OF ALCOHOLATES OF ALKALIS AND OF BETA-DICETONIC SOLUBLE COMPLEXES OF TRIVALENT TITANIUM |
| GB1415508A (en) * | 1972-07-24 | 1975-11-26 | Albright & Wilson | Diarene chromium compounds |
| IL51283A (en) * | 1976-01-30 | 1979-11-30 | Snam Progetti | Process for preparing a co-catalyst for use in the polymerization of a-olefins,a co-catalyst prepared by the process,a catalytic system comprising such a co-catalyst and a process for polymerizing an a-olefin using such catalytic system |
-
1979
- 1979-03-07 IT IT20798/79A patent/IT1113421B/en active
-
1980
- 1980-02-25 US US06/124,148 patent/US4333881A/en not_active Expired - Lifetime
- 1980-02-26 AU AU55897/80A patent/AU528925B2/en not_active Ceased
- 1980-02-26 IE IE386/80A patent/IE49524B1/en not_active IP Right Cessation
- 1980-03-03 GB GB8007160A patent/GB2046740B/en not_active Expired
- 1980-03-03 CA CA346,861A patent/CA1133018A/en not_active Expired
- 1980-03-03 IN IN245/CAL/80A patent/IN154572B/en unknown
- 1980-03-04 ZA ZA00801254A patent/ZA801254B/en unknown
- 1980-03-05 NO NO800628A patent/NO157579C/en unknown
- 1980-03-05 SE SE8001727A patent/SE448460B/en not_active IP Right Cessation
- 1980-03-06 AT AT0124680A patent/AT371796B/en not_active IP Right Cessation
- 1980-03-06 IL IL59534A patent/IL59534A/en unknown
- 1980-03-06 MX MX181452A patent/MX153451A/en unknown
- 1980-03-06 CH CH178380A patent/CH646932A5/en not_active IP Right Cessation
- 1980-03-06 PT PT70912A patent/PT70912A/en unknown
- 1980-03-06 LU LU82228A patent/LU82228A1/en unknown
- 1980-03-06 BR BR8001392A patent/BR8001392A/en not_active IP Right Cessation
- 1980-03-06 HU HU80523A patent/HU182108B/en not_active IP Right Cessation
- 1980-03-06 DK DK97380A patent/DK97380A/en not_active Application Discontinuation
- 1980-03-06 FR FR8005071A patent/FR2450845B1/en not_active Expired
- 1980-03-06 DD DD80219496A patent/DD149369A5/en not_active IP Right Cessation
- 1980-03-06 SU SU802891750A patent/SU1319782A3/en active
- 1980-03-06 ES ES489717A patent/ES8104328A1/en not_active Expired
- 1980-03-07 AR AR280234A patent/AR226174A1/en active
- 1980-03-07 RO RO80100413A patent/RO81241A/en unknown
- 1980-03-07 BE BE0/199722A patent/BE882137A/en not_active IP Right Cessation
- 1980-03-07 NL NL8001390A patent/NL8001390A/en not_active Application Discontinuation
- 1980-03-07 DE DE3008909A patent/DE3008909C2/en not_active Expired
- 1980-03-07 JP JP2819980A patent/JPS55160784A/en active Granted
- 1980-03-07 CS CS801595A patent/CS276219B6/en unknown
- 1980-03-07 YU YU638/80A patent/YU41035B/en unknown
-
1983
- 1983-01-06 YU YU16/83A patent/YU42065B/en unknown
- 1983-06-18 IN IN769/CAL/83A patent/IN156280B/en unknown
-
1985
- 1985-01-25 SE SE8500363A patent/SE460478B/en not_active IP Right Cessation
- 1985-03-06 NO NO850883A patent/NO850883L/en unknown
Also Published As
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |