FR2447899A2 - Insecticidal (S) alpha-cyano-3-phenoxy-benzyl alcohol ester(s) - are prepd. by esterification of the alcohol with 2,2-di:methyl-3-di:halo:vinyl-cyclopropane-1-carboxylic acid - Google Patents

Insecticidal (S) alpha-cyano-3-phenoxy-benzyl alcohol ester(s) - are prepd. by esterification of the alcohol with 2,2-di:methyl-3-di:halo:vinyl-cyclopropane-1-carboxylic acid

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Publication number
FR2447899A2
FR2447899A2 FR7902861A FR7902861A FR2447899A2 FR 2447899 A2 FR2447899 A2 FR 2447899A2 FR 7902861 A FR7902861 A FR 7902861A FR 7902861 A FR7902861 A FR 7902861A FR 2447899 A2 FR2447899 A2 FR 2447899A2
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FR
France
Prior art keywords
prepd
cyclopropane
phenoxy
cyano
alpha
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7902861A
Other languages
French (fr)
Other versions
FR2447899B2 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanofi Aventis France
Original Assignee
Roussel Uclaf SA
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Filing date
Publication date
Application filed by Roussel Uclaf SA filed Critical Roussel Uclaf SA
Priority to FR7902861A priority Critical patent/FR2447899A2/en
Publication of FR2447899A2 publication Critical patent/FR2447899A2/en
Application granted granted Critical
Publication of FR2447899B2 publication Critical patent/FR2447899B2/fr
Granted legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles

Abstract

Uses of (S) alpha-cyano-3-phenoxy-benzyl alcohol (I) are defined in the parent patent FR appl. 78,02621. Functional derivs. of (I) i.e. esters are prepd. by reaction in an organic solvent with a 2,2-dimethyl-3-(2',2'-dihalovinyl)-cyclopropane-1-carboxylic acid, (II) (having cis or trans, racemic or optically active form) or its functional derivs. where X is F, Cl or Br.
FR7902861A 1979-02-05 1979-02-05 Insecticidal (S) alpha-cyano-3-phenoxy-benzyl alcohol ester(s) - are prepd. by esterification of the alcohol with 2,2-di:methyl-3-di:halo:vinyl-cyclopropane-1-carboxylic acid Granted FR2447899A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7902861A FR2447899A2 (en) 1979-02-05 1979-02-05 Insecticidal (S) alpha-cyano-3-phenoxy-benzyl alcohol ester(s) - are prepd. by esterification of the alcohol with 2,2-di:methyl-3-di:halo:vinyl-cyclopropane-1-carboxylic acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7902861A FR2447899A2 (en) 1979-02-05 1979-02-05 Insecticidal (S) alpha-cyano-3-phenoxy-benzyl alcohol ester(s) - are prepd. by esterification of the alcohol with 2,2-di:methyl-3-di:halo:vinyl-cyclopropane-1-carboxylic acid

Publications (2)

Publication Number Publication Date
FR2447899A2 true FR2447899A2 (en) 1980-08-29
FR2447899B2 FR2447899B2 (en) 1983-04-29

Family

ID=9221596

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7902861A Granted FR2447899A2 (en) 1979-02-05 1979-02-05 Insecticidal (S) alpha-cyano-3-phenoxy-benzyl alcohol ester(s) - are prepd. by esterification of the alcohol with 2,2-di:methyl-3-di:halo:vinyl-cyclopropane-1-carboxylic acid

Country Status (1)

Country Link
FR (1) FR2447899A2 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0080827A2 (en) * 1981-11-28 1983-06-08 Sumitomo Chemical Company, Limited Method for biotechnologically preparing (S)-(-)-alpha-cyano-3-phenoxybenzyl alcohol
EP0118163A1 (en) * 1983-01-10 1984-09-12 Sumitomo Chemical Company, Limited Method for biotechnologically preparing optically active alpha-cyano-3-phenoxybenzyl alcohol
EP0148272A1 (en) * 1983-05-09 1985-07-17 Sumitomo Chemical Company, Limited Process for producing optically active benzyl alcohol compounds
EP0312124A2 (en) * 1982-11-22 1989-04-19 E.I. Du Pont De Nemours And Company Process for the preparation of optically-active cyanomethyl esters
US4985365A (en) * 1981-11-28 1991-01-15 Sumitomo Chemical Company, Ltd. Process for producing optically active benzyl alcohol compound
TR25758A (en) * 1991-01-25 1993-09-01 Fmc Corp A FORMAL COMPOSITION FROM A NEW COMBINATION OF THE ISOMERS OF (SIYONO) (3-PHENOXIFENYL) METYL-3- (2,2-DICLOROETENIL) -2,2-DIMETYL CYLOPROPANKARBOXYLATE

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2375161A1 (en) * 1976-04-23 1978-07-21 Roussel Uclaf PROCESS FOR TRANSFORMATION OF AN OPTICALLY ACTIVE A-CYANE SECONDARY ALCOHOL CHIRAL ACID ESTER OF STRUCTURE (R) INTO A-CYANE SECONDARY ALCOHOL CHIRAL ACID ESTER OF STRUCTURE (S)
FR2382422A2 (en) * 1977-03-02 1978-09-29 Roussel Uclaf Transformation of alpha cyano secondary ester(s) of chiral acid - from the R form to the S form by treatment with base
FR2383147A2 (en) * 1977-03-09 1978-10-06 Roussel Uclaf Racemisation of cyclopropane carboxylic ester(s) - with alpha cyano 3-phenoxy benzyl alcohol(s), by treatment with an amine
EP0002091A2 (en) * 1977-11-22 1979-05-30 Shell Internationale Researchmaatschappij B.V. Method of controlling acarid pests by means of cyclopropane carboxylate esters, the use of such esters as an acaricide, and one of said esters as a novel compound

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2375161A1 (en) * 1976-04-23 1978-07-21 Roussel Uclaf PROCESS FOR TRANSFORMATION OF AN OPTICALLY ACTIVE A-CYANE SECONDARY ALCOHOL CHIRAL ACID ESTER OF STRUCTURE (R) INTO A-CYANE SECONDARY ALCOHOL CHIRAL ACID ESTER OF STRUCTURE (S)
FR2382422A2 (en) * 1977-03-02 1978-09-29 Roussel Uclaf Transformation of alpha cyano secondary ester(s) of chiral acid - from the R form to the S form by treatment with base
FR2383147A2 (en) * 1977-03-09 1978-10-06 Roussel Uclaf Racemisation of cyclopropane carboxylic ester(s) - with alpha cyano 3-phenoxy benzyl alcohol(s), by treatment with an amine
EP0002091A2 (en) * 1977-11-22 1979-05-30 Shell Internationale Researchmaatschappij B.V. Method of controlling acarid pests by means of cyclopropane carboxylate esters, the use of such esters as an acaricide, and one of said esters as a novel compound

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
EXBK/74 *

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0080827A2 (en) * 1981-11-28 1983-06-08 Sumitomo Chemical Company, Limited Method for biotechnologically preparing (S)-(-)-alpha-cyano-3-phenoxybenzyl alcohol
EP0080827A3 (en) * 1981-11-28 1984-05-23 Sumitomo Chemical Company, Limited Method for biotechnologically preparing (s)-(-)-alpha-cyano-3-phenoxybenzyl alcohol
US4985365A (en) * 1981-11-28 1991-01-15 Sumitomo Chemical Company, Ltd. Process for producing optically active benzyl alcohol compound
EP0312124A2 (en) * 1982-11-22 1989-04-19 E.I. Du Pont De Nemours And Company Process for the preparation of optically-active cyanomethyl esters
EP0312124A3 (en) * 1982-11-22 1989-09-13 E.I. Du Pont De Nemours And Company Process for the preparation of optically-active cyanomethyl esters
EP0118163A1 (en) * 1983-01-10 1984-09-12 Sumitomo Chemical Company, Limited Method for biotechnologically preparing optically active alpha-cyano-3-phenoxybenzyl alcohol
EP0148272A1 (en) * 1983-05-09 1985-07-17 Sumitomo Chemical Company, Limited Process for producing optically active benzyl alcohol compounds
EP0148272A4 (en) * 1983-05-09 1987-02-03 Sumitomo Chemical Co Process for producing optically active benzyl alcohol compounds.
TR25758A (en) * 1991-01-25 1993-09-01 Fmc Corp A FORMAL COMPOSITION FROM A NEW COMBINATION OF THE ISOMERS OF (SIYONO) (3-PHENOXIFENYL) METYL-3- (2,2-DICLOROETENIL) -2,2-DIMETYL CYLOPROPANKARBOXYLATE
EP0569461A4 (en) * 1991-01-25 1993-09-07 Fmc Corp Novel pyrethroid composition.
EP0569461A1 (en) * 1991-01-25 1993-11-18 Fmc Corp Novel pyrethroid composition.

Also Published As

Publication number Publication date
FR2447899B2 (en) 1983-04-29

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