JPS51146440A - Process for preparing vinyl-substituted cyclopropane-carboxylic acids - Google Patents
Process for preparing vinyl-substituted cyclopropane-carboxylic acidsInfo
- Publication number
- JPS51146440A JPS51146440A JP2860775A JP2860775A JPS51146440A JP S51146440 A JPS51146440 A JP S51146440A JP 2860775 A JP2860775 A JP 2860775A JP 2860775 A JP2860775 A JP 2860775A JP S51146440 A JPS51146440 A JP S51146440A
- Authority
- JP
- Japan
- Prior art keywords
- carboxylic acids
- preparing vinyl
- substituted cyclopropane
- substituted
- vinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To prepare industrially and advantageously vinyl-substituted cyclopropanecarboxylic acids, the acid component of synthetic pyrethroids, useful as insecticides, by treating cyclopropanecarboxylic acid esters with a base.
COPYRIGHT: (C)1976,JPO&Japio
Priority Applications (45)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP50028607A JPS5822463B2 (en) | 1975-03-11 | 1975-03-11 | Cyclopropane carbonate cyclopropane carbonate |
IN1621/CAL/75A IN142702B (en) | 1974-09-10 | 1975-08-20 | |
IL53593A IL53593A (en) | 1974-09-10 | 1975-08-20 | halo hexan-(hexen)ioc and 2-haloethyl cyclopropanecarboxylic acid derivatives as intermediates for the preparatiionof esters fo dihalovinylcyclopropane anecarboxylic acids |
US06/606,807 US4681953A (en) | 1974-09-10 | 1975-08-22 | Process for preparing dihalovinylcyclopropanecarboxylates |
AU84256/75A AU491852B2 (en) | 1975-08-26 | Preparation of certain cyclopropane-carboxylate esters | |
IE1891/75A IE43065B1 (en) | 1974-09-10 | 1975-08-28 | Process for the preparation of esters of dihalovinyl-cyclopropanecarboxylic acids |
CA000234464A CA1212685A (en) | 1974-09-10 | 1975-08-29 | Process for the preparation of esters of dihalovinylcyclopropanecarboxylic acids |
GB336177A GB1520446A (en) | 1974-09-10 | 1975-09-03 | Process for the preparation of esters of vinyl-cyclopropanecarboxylic acids |
GB52795/76A GB1520445A (en) | 1974-09-10 | 1975-09-03 | Cyclopropanecarboxylates |
GB50530/76A GB1520444A (en) | 1974-09-10 | 1975-09-03 | Preparation of unsaturated ethers and esters |
GB36340/75A GB1520443A (en) | 1974-09-10 | 1975-09-03 | Process for the preparation of esters of dihalovinycyclo-propanecarboxylic acids |
NLAANVRAGE7510479,A NL185513C (en) | 1974-09-10 | 1975-09-05 | PROCESS FOR THE PREPARATION OF A DIHALOGENIC VINYL CYCLOPROPANIC CARBOXYLATE. |
DE2539895A DE2539895C2 (en) | 1974-09-10 | 1975-09-08 | Process for the preparation of 2-dihalovinylcyclopropanecarboxylic acid esters |
DE2560240A DE2560240C2 (en) | 1974-09-10 | 1975-09-08 | Hexanoic acid, hexenoic acid and cyclopropanecarboxylic acid esters |
CH1161375A CH630891A5 (en) | 1974-09-10 | 1975-09-08 | METHOD FOR PRODUCING 2-DIHALOGENVINYLCYCLOPROPANCARBONIC ACID ESTERS. |
NZ18303575A NZ183035A (en) | 1974-09-10 | 1975-09-09 | Esters of hexanoic or hexenoic acid derivatives ethyl-2-( , , -trichloroethyl)-3,3-dimenthyl-cyclopropane-carboxylate and 1,1-diethoxy-1-(3-methyl-2-buten-1-yloxy)-ethane |
SE7510042A SE435618B (en) | 1974-09-10 | 1975-09-09 | PROCEDURE FOR PREPARING ESTHERS OF DIHALOGENVINYL CYCLEOPROPANCARBOXYL ACIDS |
DK402075A DK158614C (en) | 1974-09-10 | 1975-09-09 | PROCEDURE FOR PREPARING A DIHALOGENEVINYLYCYCLOPROPANCARBOXYLATE |
FR7527596A FR2318143A1 (en) | 1974-09-10 | 1975-09-09 | PROCESS FOR OBTAINING SUBSTITUTE CYCLOPROPANES, IN PARTICULAR USEFUL AS PYRETHROID INSECTICIDES |
NO75753085A NO147792C (en) | 1974-09-10 | 1975-09-09 | PROCEDURE FOR PREPARING ESTERS OF DIHALOGEN-VINYL CYCLOPROPANCARBOXYL ACIDS |
SU752170851A SU664558A3 (en) | 1974-09-10 | 1975-09-09 | Method of obtaining esters of dihaloidvinylcyclopropancarboxylic acids |
AT694975A AT347917B (en) | 1974-11-30 | 1975-09-09 | PROCESS FOR THE PRODUCTION OF 2-DIHALOGEN VINYLCYCLOPROPANCARBON ACID ESTERS |
NZ178641A NZ178641A (en) | 1974-09-10 | 1975-09-09 | Esters of vinylcycloprpane carboxylic acids and intermediates |
BE159921A BE833278A (en) | 1974-09-10 | 1975-09-10 | PROCESS FOR OBTAINING SUBSTITUTE CYCLOPROPANES, PARTICULARLY USEFUL AS PYRETHROID INSECTICIDES |
DD188270A DD122678A5 (en) | 1974-09-10 | 1975-09-10 | |
MX10052375U MX5451E (en) | 1974-09-10 | 1975-09-10 | PROCESS FOR PREPARING DIHALOVINYL CYCLOPROPAN CARBOXYLATE |
DD7500196142A DD128297A5 (en) | 1974-09-10 | 1975-09-10 | PROCESS FOR PREPARING CYCLOPROPANCARBOXIC ACID ESTERS |
DD7500196143A DD128298A5 (en) | 1974-09-10 | 1975-09-10 | PROCESS FOR THE PREPARATION OF TRIHALOGENCYCLOPROPANCARBOSE ACID ESTERS |
MX487775U MX5591E (en) | 1974-09-10 | 1975-09-10 | PROCESS FOR THE PREPARATION OF ESTERS OF DIHALOVINYL CYCLOPROPANOCARBOXYLIC ACIDS |
CS616475A CS212300B2 (en) | 1974-09-10 | 1975-09-10 | Method of preparation of esters of the dihalogenvinylcyclopropancarboxyl acid |
DD7500196141A DD128351A5 (en) | 1974-09-10 | 1975-09-10 | PROCESS FOR PREPARING UNCONDITIONED CARBONIC ACID ESTERS |
TR2087675A TR20876A (en) | 1974-09-10 | 1975-09-10 | MANUFACTURING PROCEDURE OF THE ESTERS OF DIHALO-VINYLICYCLOPROPANKARBOXYLED ACIDS |
DD7500196145A DD128352A5 (en) | 1974-09-10 | 1975-09-10 | PROCESS FOR PREPARING GAMMA-UNACCURATED CARBONIC ACID ESTERS |
FR7621447A FR2318144A1 (en) | 1974-09-10 | 1976-07-13 | PROCESS FOR OBTAINING VINYLCYCLOPROPANE CARBOXYLATES |
FR7621448A FR2333774A1 (en) | 1974-09-10 | 1976-07-13 | SUBSTITUTE HARLOCARBOXYLATES, USED AS INTERMEDIARIES FOR THE MANUFACTURE OF PYRETHROID INSECTICIDES |
IN1919/CAL/1976A IN143561B (en) | 1974-09-10 | 1976-10-20 | |
NO763934A NO763934L (en) | 1974-09-10 | 1976-11-18 | |
NO763933A NO148414C (en) | 1974-09-10 | 1976-11-18 | 4,6,6,6-TETRAHALOGENCARBOXYLIC ACID ESTERS FOR USE AS INTERMEDIATE IN THE PREPARATION OF ESTERS OF DIHALOGENVINYL-CYCLOPROPANCARBOXYL ACIDS |
FR7639510A FR2351946A1 (en) | 1974-11-30 | 1976-12-29 | 2-(Dihalovinyl) cyclopropane carboxylate insecticides prodn. - by reacting alkenol and orthoformate, addition of carbon tetrahalide, basic cyclisation and dehydrohalogenation |
IL53593A IL53593A0 (en) | 1974-09-10 | 1977-12-13 | Intermediates for the preparation of esters of dihalovinylcyclopropanecarboxylic acids |
DK263479A DK158461C (en) | 1974-09-10 | 1979-06-22 | 4,6,6,6-TETRAHALOGENCARBOXYLIC ACID ESTERS USED AS INTERMEDIATES IN THE PREPARATION OF DIHALOGEN-VINYLYCYCLOPROPANCARBOXYLATES |
CA000339362A CA1210776A (en) | 1974-09-10 | 1979-11-07 | Process for the preparation of esters of dihalovinylcyclopropanecarboxylic acids |
CH722281A CH641146A5 (en) | 1974-09-10 | 1981-11-10 | Process for the preparation of 2-dihalovinylcyclopropanecarboxylic acid esters |
US06/507,998 US4833266A (en) | 1974-09-10 | 1983-06-27 | Process for preparing dihalovinylcyclopropanecarboxylates |
US07/343,318 US4999451A (en) | 1974-09-10 | 1989-04-26 | Process for preparing dihalovinylcyclopropanecarboxylates |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP50028607A JPS5822463B2 (en) | 1975-03-11 | 1975-03-11 | Cyclopropane carbonate cyclopropane carbonate |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS51146440A true JPS51146440A (en) | 1976-12-16 |
JPS5822463B2 JPS5822463B2 (en) | 1983-05-09 |
Family
ID=12253250
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP50028607A Expired JPS5822463B2 (en) | 1974-09-10 | 1975-03-11 | Cyclopropane carbonate cyclopropane carbonate |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5822463B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5159839A (en) * | 1974-10-23 | 1976-05-25 | Sankyo Co | SHIKUROPUROPANKARUBONSANJUDOTAINO SEIZOHO |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5159839A (en) * | 1974-10-23 | 1976-05-25 | Sankyo Co | SHIKUROPUROPANKARUBONSANJUDOTAINO SEIZOHO |
-
1975
- 1975-03-11 JP JP50028607A patent/JPS5822463B2/en not_active Expired
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5159839A (en) * | 1974-10-23 | 1976-05-25 | Sankyo Co | SHIKUROPUROPANKARUBONSANJUDOTAINO SEIZOHO |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5159839A (en) * | 1974-10-23 | 1976-05-25 | Sankyo Co | SHIKUROPUROPANKARUBONSANJUDOTAINO SEIZOHO |
JPS5234619B2 (en) * | 1974-10-23 | 1977-09-05 |
Also Published As
Publication number | Publication date |
---|---|
JPS5822463B2 (en) | 1983-05-09 |
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