FR2442866A1 - PROCESS FOR THE PREPARATION OF COPOLYMERS CONTAINING HYDROXY GROUPS AND SOLUBLE IN ORGANIC SOLVENTS - Google Patents

PROCESS FOR THE PREPARATION OF COPOLYMERS CONTAINING HYDROXY GROUPS AND SOLUBLE IN ORGANIC SOLVENTS

Info

Publication number
FR2442866A1
FR2442866A1 FR7929290A FR7929290A FR2442866A1 FR 2442866 A1 FR2442866 A1 FR 2442866A1 FR 7929290 A FR7929290 A FR 7929290A FR 7929290 A FR7929290 A FR 7929290A FR 2442866 A1 FR2442866 A1 FR 2442866A1
Authority
FR
France
Prior art keywords
soluble
preparation
organic solvents
hydroxy groups
copolymers containing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7929290A
Other languages
French (fr)
Other versions
FR2442866B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SYNTHOPOL CHEMIE RER POL KOCH CO
SYNTHOPOL CHEMIE DR KOCH
Original Assignee
SYNTHOPOL CHEMIE RER POL KOCH CO
SYNTHOPOL CHEMIE DR KOCH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SYNTHOPOL CHEMIE RER POL KOCH CO, SYNTHOPOL CHEMIE DR KOCH filed Critical SYNTHOPOL CHEMIE RER POL KOCH CO
Publication of FR2442866A1 publication Critical patent/FR2442866A1/en
Application granted granted Critical
Publication of FR2442866B1 publication Critical patent/FR2442866B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne un procédé de préparation de copolymères contenant des groupes hydroxy et solubles dans les solvants organiques. On prépare les copolymères de l'invention en estérifiant tout d'abord un acide monocarboxylique alpha , beta -insaturé avec un composé monoglycidylique en présence d'un composé vinylique et d'un catalyseur destérification à base d'un composé d'un métal alcalin, puis on effectue la copolymérisation en présence de solvants inertes. Lors de la copolymérisation, outre le produit monomère d'estérification, au moins deux autres composés vinyliques doivent être présents dans la charge réactionnelle. L'invention est utilisée pour l'application de pellicules non adhésives, élastiques et résistant à l'eau sur les substrats les plus divers, ou comme agents liants pour les pigments, les peintures de recouvrement et les voiles.The invention relates to a process for the preparation of copolymers containing hydroxy groups and soluble in organic solvents. The copolymers of the invention are prepared by first esterifying an alpha, beta -unsaturated monocarboxylic acid with a monoglycidyl compound in the presence of a vinyl compound and an esterification catalyst based on an alkali metal compound. , then the copolymerization is carried out in the presence of inert solvents. During the copolymerization, besides the esterification monomer product, at least two other vinyl compounds must be present in the reaction charge. The invention is used for the application of non-adhesive, elastic and water-resistant films on the most diverse substrates, or as binding agents for pigments, covering paints and veils.

FR7929290A 1978-11-29 1979-11-28 PROCESS FOR THE PREPARATION OF COPOLYMERS CONTAINING HYDROXY GROUPS AND SOLUBLE IN ORGANIC SOLVENTS Granted FR2442866A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2851614A DE2851614C2 (en) 1978-11-29 1978-11-29 Process for the preparation of copolymers containing hydroxyl groups which are soluble in organic solvents

Publications (2)

Publication Number Publication Date
FR2442866A1 true FR2442866A1 (en) 1980-06-27
FR2442866B1 FR2442866B1 (en) 1984-01-27

Family

ID=6055834

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7929290A Granted FR2442866A1 (en) 1978-11-29 1979-11-28 PROCESS FOR THE PREPARATION OF COPOLYMERS CONTAINING HYDROXY GROUPS AND SOLUBLE IN ORGANIC SOLVENTS

Country Status (3)

Country Link
DE (1) DE2851614C2 (en)
FR (1) FR2442866A1 (en)
GB (1) GB2037301B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002066527A2 (en) * 2001-02-20 2002-08-29 Eastman Chemical Company High solids acrylic resin

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4442769A1 (en) * 1994-12-01 1996-06-05 Hoechst Ag Low molecular weight functional copolymers, process for their preparation and their use

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1038754B (en) * 1956-06-25 1958-09-11 Devoe & Raynolds Co Process for the production of esterified polyhydroxy copolymers
GB1146474A (en) * 1966-06-10 1969-03-26 Bp Chem Int Ltd Addition copolymers for use in surface coating compositions and compositions containing these copolymers
DE2054231A1 (en) * 1969-12-18 1971-06-24 Reichhold Albert Chemie Ag Process for the production of soluble organic copolymers and their use as a binder component, especially in primers and top coats for galvanized iron sheets
FR2307012A1 (en) * 1975-04-10 1976-11-05 Hoechst Ag COPOLYMER SOLUTION BASED ON AN ACRYLIC RESIN AND PROCESS FOR THE PREPARATION OF THE SAME

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1109920A (en) * 1965-11-25 1968-04-18 Pfizer Ltd Esters of itaconic acid and polymeric derivatives thereof
US3549583A (en) * 1966-12-14 1970-12-22 Nippon Paint Co Ltd Polyurethane liquid containing compositions
GB1266159A (en) * 1968-10-15 1972-03-08 Shell hydroxyl-group containing copolymers
CS154962B1 (en) * 1971-08-19 1974-04-30
DE2603259C3 (en) * 1976-01-29 1982-10-21 Hoechst Ag, 6000 Frankfurt Process for the production of copolymers containing hydroxyl groups
DE2626900C2 (en) * 1976-06-16 1978-04-13 Hoechst Ag, 6000 Frankfurt Process for the production of copolymers containing hydroxyl groups
DE2709784C2 (en) * 1977-03-07 1983-06-01 Hoechst Ag, 6230 Frankfurt Process for the preparation of soluble copolymers containing hydroxyl groups and crosslinkable with organic polyisocyanates
DE2709782C2 (en) * 1977-03-07 1982-07-01 Hoechst Ag, 6000 Frankfurt Process for the production of soluble copolymers containing hydroxyl groups and crosslinkable with organic polyisocyanates

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1038754B (en) * 1956-06-25 1958-09-11 Devoe & Raynolds Co Process for the production of esterified polyhydroxy copolymers
GB1146474A (en) * 1966-06-10 1969-03-26 Bp Chem Int Ltd Addition copolymers for use in surface coating compositions and compositions containing these copolymers
DE2054231A1 (en) * 1969-12-18 1971-06-24 Reichhold Albert Chemie Ag Process for the production of soluble organic copolymers and their use as a binder component, especially in primers and top coats for galvanized iron sheets
FR2307012A1 (en) * 1975-04-10 1976-11-05 Hoechst Ag COPOLYMER SOLUTION BASED ON AN ACRYLIC RESIN AND PROCESS FOR THE PREPARATION OF THE SAME

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002066527A2 (en) * 2001-02-20 2002-08-29 Eastman Chemical Company High solids acrylic resin
WO2002066527A3 (en) * 2001-02-20 2003-05-01 Eastman Chem Co High solids acrylic resin

Also Published As

Publication number Publication date
GB2037301B (en) 1983-03-23
DE2851614A1 (en) 1980-06-04
GB2037301A (en) 1980-07-09
FR2442866B1 (en) 1984-01-27
DE2851614C2 (en) 1983-06-01

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