FR2435456A1 - CATALYST FOR VAPOR OXIDATION OF ISOBUTYLENE OR TERTIARY BUTYL ALCOHOL, PREPARATION METHOD THEREOF AND APPLICATION TO THE PRODUCTION OF METHACROLEIN - Google Patents

CATALYST FOR VAPOR OXIDATION OF ISOBUTYLENE OR TERTIARY BUTYL ALCOHOL, PREPARATION METHOD THEREOF AND APPLICATION TO THE PRODUCTION OF METHACROLEIN

Info

Publication number
FR2435456A1
FR2435456A1 FR7922126A FR7922126A FR2435456A1 FR 2435456 A1 FR2435456 A1 FR 2435456A1 FR 7922126 A FR7922126 A FR 7922126A FR 7922126 A FR7922126 A FR 7922126A FR 2435456 A1 FR2435456 A1 FR 2435456A1
Authority
FR
France
Prior art keywords
catalyst
methacrolein
application
isobutylene
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7922126A
Other languages
French (fr)
Other versions
FR2435456B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Halcon Research and Development Corp
Original Assignee
Halcon Research and Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Halcon Research and Development Corp filed Critical Halcon Research and Development Corp
Publication of FR2435456A1 publication Critical patent/FR2435456A1/en
Application granted granted Critical
Publication of FR2435456B1 publication Critical patent/FR2435456B1/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8874—Gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Abstract

L'invention concerne l'obtention d'un catalyseur et son application à l'oxydation d'oléfines. Le catalyseur contient des oxydes de Mo, Co, Fe, Bi, Tl, Sb, Si et Ni et d'un ou plusicurs métaux alcalins, alcalino-terreux ou des terres rares et W. Il a une surface de contact BET d'environ 0,5 à 10 m**2/g. La méthacroléine est un intermédiaire de synthèse (acide méthacrylique, méthacrylate de méthyle, verre organique).The invention relates to obtaining a catalyst and its application to the oxidation of olefins. The catalyst contains oxides of Mo, Co, Fe, Bi, Tl, Sb, Si and Ni and one or more alkali, alkaline earth or rare earth metals and W. It has a BET contact area of approximately 0.5 to 10 m ** 2 / g. Methacrolein is a synthetic intermediate (methacrylic acid, methyl methacrylate, organic glass).

FR7922126A 1978-09-05 1979-09-04 CATALYST FOR VAPOR OXIDATION OF ISOBUTYLENE OR TERTIARY BUTYL ALCOHOL, PROCESS FOR THEIR PREPARATION AND ITS APPLICATION TO THE PRODUCTION OF METHACROLEIN Expired FR2435456B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US93964578A 1978-09-05 1978-09-05

Publications (2)

Publication Number Publication Date
FR2435456A1 true FR2435456A1 (en) 1980-04-04
FR2435456B1 FR2435456B1 (en) 1986-02-21

Family

ID=25473515

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7922126A Expired FR2435456B1 (en) 1978-09-05 1979-09-04 CATALYST FOR VAPOR OXIDATION OF ISOBUTYLENE OR TERTIARY BUTYL ALCOHOL, PROCESS FOR THEIR PREPARATION AND ITS APPLICATION TO THE PRODUCTION OF METHACROLEIN

Country Status (9)

Country Link
JP (2) JPS5829139B2 (en)
AR (1) AR221897A1 (en)
BE (1) BE878585A (en)
BR (1) BR7905703A (en)
DE (1) DE2935903C2 (en)
FR (1) FR2435456B1 (en)
GB (1) GB2030885B (en)
IT (1) IT1120007B (en)
NL (1) NL183170C (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2481146A1 (en) * 1980-04-25 1981-10-30 Rhone Poulenc Ind PROCESS FOR THE PREPARATION OF CATALYSTS BASED ON OXIDES OF MOLYBDENUM AND / OR TUNGSTEN AND OXIDES OF OTHER METALS
EP0267556A2 (en) * 1986-11-11 1988-05-18 Mitsubishi Rayon Co., Ltd. Process for production of methacrolein and methacrylic acid
EP0417723A2 (en) * 1989-09-13 1991-03-20 Degussa Aktiengesellschaft Process for the preparation of acrolein by the catalytic gasphase oxydation of propylene
US5208371A (en) * 1986-11-11 1993-05-04 Mitsubishi Rayon Co., Ltd. Process for production of methacrolein and methacrylic acid

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5849338A (en) * 1981-09-17 1983-03-23 Mitsui Toatsu Chem Inc Preparation of alpha, beta-unsaturated carboxylate
US4535188A (en) * 1982-04-14 1985-08-13 The Halcon Sd Group, Inc. Conversion of isobutane to methacrolein
US4532365A (en) * 1982-09-20 1985-07-30 The Halcon Sd Group, Inc. Conversion of alkanes to unsaturated aldehydes
US4413147A (en) * 1982-04-14 1983-11-01 The Halcon Sd Group, Inc. Conversion of isobutane to methacrolein
USRE32082E (en) * 1982-04-14 1986-02-11 The Halcon Sd Group, Inc. Conversion of isobutane to methacrolein
JPS5946132A (en) * 1982-09-06 1984-03-15 Nippon Shokubai Kagaku Kogyo Co Ltd Catalyst for synthesis of methacrolein
JPS6028824A (en) * 1983-07-27 1985-02-14 Nippon Shokubai Kagaku Kogyo Co Ltd Catalyst for manufacturing methacrolein
US4537874A (en) * 1982-10-22 1985-08-27 Nippon Shokubai Kagaku Kogyo Co Ltd Catalyst for production of unsaturated aldehydes
JP2547901B2 (en) * 1991-02-27 1996-10-30 北海道電力株式会社 Mud treatment agent and treatment method
KR100277241B1 (en) † 1993-06-25 2001-02-01 고오사이 아끼오 Process for preparing unsaturated aldehyde and unsaturated carboxylic acid
EP2343123B1 (en) 2001-11-08 2021-01-06 Mitsubishi Chemical Corporation METHOD FOR PREPARATION of a COMPOSITE OXIDE CATALYST
JP4242597B2 (en) 2002-02-28 2009-03-25 株式会社日本触媒 Unsaturated aldehyde synthesis catalyst, production method thereof, and production method of unsaturated aldehyde using the catalyst
EP1602405B1 (en) * 2003-03-05 2014-09-10 Asahi Kasei Chemicals Corporation Particulate porous ammoxidation catalyst

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4087382A (en) * 1976-11-24 1978-05-02 Halcon International, Inc. Catalyst

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2481146A1 (en) * 1980-04-25 1981-10-30 Rhone Poulenc Ind PROCESS FOR THE PREPARATION OF CATALYSTS BASED ON OXIDES OF MOLYBDENUM AND / OR TUNGSTEN AND OXIDES OF OTHER METALS
EP0039267A1 (en) * 1980-04-25 1981-11-04 Rhone-Poulenc Chimie De Base Catalysts preparation process based on molybden and/or tungsten oxides and oxides of other metals
EP0267556A2 (en) * 1986-11-11 1988-05-18 Mitsubishi Rayon Co., Ltd. Process for production of methacrolein and methacrylic acid
EP0267556A3 (en) * 1986-11-11 1989-08-02 Mitsubishi Rayon Co. Ltd. Process for production of methacrolein and methacrylic acid
US5208371A (en) * 1986-11-11 1993-05-04 Mitsubishi Rayon Co., Ltd. Process for production of methacrolein and methacrylic acid
EP0417723A2 (en) * 1989-09-13 1991-03-20 Degussa Aktiengesellschaft Process for the preparation of acrolein by the catalytic gasphase oxydation of propylene
EP0417723A3 (en) * 1989-09-13 1992-01-02 Degussa Aktiengesellschaft Process for the preparation of acrolein by the catalytic gasphase oxydation of propylene

Also Published As

Publication number Publication date
NL7906480A (en) 1980-03-07
GB2030885B (en) 1983-04-07
JPS5536000A (en) 1980-03-13
AR221897A1 (en) 1981-03-31
IT7950160A0 (en) 1979-09-04
FR2435456B1 (en) 1986-02-21
JPS58113141A (en) 1983-07-05
GB2030885A (en) 1980-04-16
DE2935903A1 (en) 1980-03-13
BR7905703A (en) 1980-07-15
IT1120007B (en) 1986-03-19
DE2935903C2 (en) 1982-08-05
NL183170C (en) 1988-08-16
BE878585A (en) 1980-03-04
NL183170B (en) 1988-03-16
JPS5829139B2 (en) 1983-06-21

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