FR2434863A1 - Sulphurised compsn. prepn. from olefin, sulphur and hydrogen sulphide - used as extreme pressure and antioxidant lubricant additive - Google Patents
Sulphurised compsn. prepn. from olefin, sulphur and hydrogen sulphide - used as extreme pressure and antioxidant lubricant additiveInfo
- Publication number
- FR2434863A1 FR2434863A1 FR7825391A FR7825391A FR2434863A1 FR 2434863 A1 FR2434863 A1 FR 2434863A1 FR 7825391 A FR7825391 A FR 7825391A FR 7825391 A FR7825391 A FR 7825391A FR 2434863 A1 FR2434863 A1 FR 2434863A1
- Authority
- FR
- France
- Prior art keywords
- compsn
- esp
- sulphurised
- olefin
- extreme pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/02—Sulfurised compounds
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- C10M2203/06—Well-defined aromatic compounds
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/046—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
- C10N2040/253—Small diesel engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
- C10N2070/02—Concentrating of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
A sulphurised compsn. is prepd. by reacting 0.7-1.2 g-atoms of S and 0.1-1.5 (0.4-1.25), esp. 0.4-0.8 moles H2S, with 1 mole of a 3-30C (3-16C), esp. 7C terminal aliphatic monoolefine, at 50-300 degrees C (100-200 degrees C) and under superatmos. pressure, in presence of a catalyst. Finally, all low boiling cpds., including unreacted olefine, mercaptan and monosulphide, are removed. The olefin may carry substits., but olefinic, aliphatic hydrocarbons are pref. esp. (di)isobutene. The catalyst is esp. a base, partic. NH3 or an amine. After removal of low-boiling cpds., the prod. may be treated with an alkali metal sulphide to reduce active S. The compsn. is a lubricant additive, improving extreme pressure properties, and reducing wear and oxidn.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7825391A FR2434863A1 (en) | 1978-09-04 | 1978-09-04 | Sulphurised compsn. prepn. from olefin, sulphur and hydrogen sulphide - used as extreme pressure and antioxidant lubricant additive |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7825391A FR2434863A1 (en) | 1978-09-04 | 1978-09-04 | Sulphurised compsn. prepn. from olefin, sulphur and hydrogen sulphide - used as extreme pressure and antioxidant lubricant additive |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2434863A1 true FR2434863A1 (en) | 1980-03-28 |
FR2434863B1 FR2434863B1 (en) | 1983-07-01 |
Family
ID=9212308
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7825391A Granted FR2434863A1 (en) | 1978-09-04 | 1978-09-04 | Sulphurised compsn. prepn. from olefin, sulphur and hydrogen sulphide - used as extreme pressure and antioxidant lubricant additive |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2434863A1 (en) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL42706C (en) * | ||||
US2061019A (en) * | 1934-04-18 | 1936-11-17 | Du Pont | Sulphurized unsaturated aliphatic hydrocarbons and process of preparing them |
US2289438A (en) * | 1940-09-28 | 1942-07-14 | Texas Co | Sulphurization of esters |
US2289437A (en) * | 1940-09-28 | 1942-07-14 | Texas Co | Sulphurization process |
FR2365629A1 (en) * | 1976-09-24 | 1978-04-21 | Cooper & Co Ltd Edwin | ASH-FREE ADDITIVE FOR LUBRICATING OIL AND ITS PREPARATION PROCESS |
-
1978
- 1978-09-04 FR FR7825391A patent/FR2434863A1/en active Granted
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL42706C (en) * | ||||
US2061019A (en) * | 1934-04-18 | 1936-11-17 | Du Pont | Sulphurized unsaturated aliphatic hydrocarbons and process of preparing them |
US2289438A (en) * | 1940-09-28 | 1942-07-14 | Texas Co | Sulphurization of esters |
US2289437A (en) * | 1940-09-28 | 1942-07-14 | Texas Co | Sulphurization process |
FR2365629A1 (en) * | 1976-09-24 | 1978-04-21 | Cooper & Co Ltd Edwin | ASH-FREE ADDITIVE FOR LUBRICATING OIL AND ITS PREPARATION PROCESS |
Also Published As
Publication number | Publication date |
---|---|
FR2434863B1 (en) | 1983-07-01 |
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