FR2401891A1 - Olefin oxychlorination esp. vinyl chloride prodn. from ethylene - using supported catalyst contg. palladium, copper, iron, alkali metal and opt. rare earth (NL 8.3.79) - Google Patents

Olefin oxychlorination esp. vinyl chloride prodn. from ethylene - using supported catalyst contg. palladium, copper, iron, alkali metal and opt. rare earth (NL 8.3.79)

Info

Publication number
FR2401891A1
FR2401891A1 FR7825488A FR7825488A FR2401891A1 FR 2401891 A1 FR2401891 A1 FR 2401891A1 FR 7825488 A FR7825488 A FR 7825488A FR 7825488 A FR7825488 A FR 7825488A FR 2401891 A1 FR2401891 A1 FR 2401891A1
Authority
FR
France
Prior art keywords
cpd
esp
rare earth
alkali metal
vinyl chloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
FR7825488A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Publication of FR2401891A1 publication Critical patent/FR2401891A1/en
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Supported catalyst compsns. contg. a Pd cpd. a Cu cpd., an Fe cpd., an alkali metal cpd. esp. an Na cpd., and pref. also a rare earth metal cpd., are used in monohalogenated olefin prepn. by contacting an olefin with a halogen-source and O2, in gas-phase, with heating. Catalyst is used partic. for vinyl chloride prepn. from C2H4. Advantages comprises (i) high chlorinating agent conversion; (ii) high selectivity, (iii) low formation-rate of by-prods., e.g. C2H4Cl2 and CHCl2CH2Cl, and (iv) low C2H4 combustion.
FR7825488A 1977-09-06 1978-09-05 Olefin oxychlorination esp. vinyl chloride prodn. from ethylene - using supported catalyst contg. palladium, copper, iron, alkali metal and opt. rare earth (NL 8.3.79) Pending FR2401891A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3713277 1977-09-06

Publications (1)

Publication Number Publication Date
FR2401891A1 true FR2401891A1 (en) 1979-03-30

Family

ID=10393996

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7825488A Pending FR2401891A1 (en) 1977-09-06 1978-09-05 Olefin oxychlorination esp. vinyl chloride prodn. from ethylene - using supported catalyst contg. palladium, copper, iron, alkali metal and opt. rare earth (NL 8.3.79)

Country Status (7)

Country Link
JP (1) JPS5455505A (en)
AU (1) AU521294B2 (en)
CA (1) CA1116587A (en)
DE (1) DE2837514A1 (en)
FR (1) FR2401891A1 (en)
NL (1) NL7808938A (en)
ZA (1) ZA784827B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003066214A2 (en) * 2002-02-05 2003-08-14 Basf Aktiengesellschaft Catalyst composition for oxychlorination

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1244481A (en) * 1984-05-24 1988-11-08 Angelo J. Magistro Catalytic dehydrohalogenation process
JP5585987B2 (en) 2011-02-25 2014-09-10 三菱重工コンプレッサ株式会社 Compressor
TWI561299B (en) * 2015-04-02 2016-12-11 Formosa Plastics Corp A catalyst for preparing vinyl chloride and a method for preparing vinyl chloride
KR102243161B1 (en) * 2018-03-13 2021-04-22 주식회사 엘지화학 Method for partial oxidation of carbonate hydrogen

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5112204A (en) * 1974-07-17 1976-01-30 Shigetaro Yamaoka JUSHITOTSUPANNORENZOKUSEIZOHO

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003066214A2 (en) * 2002-02-05 2003-08-14 Basf Aktiengesellschaft Catalyst composition for oxychlorination
WO2003066214A3 (en) * 2002-02-05 2004-02-05 Basf Ag Catalyst composition for oxychlorination
US7126035B2 (en) 2002-02-05 2006-10-24 Basf Aktiengesellschaft Catalyst composition for oxychlorination
US7902411B2 (en) 2002-02-05 2011-03-08 Basf Catalysts Llc Catalyst composition for oxychlorination
EP2314374A1 (en) * 2002-02-05 2011-04-27 BASF Corporation Catalytic converter for oxychlorination

Also Published As

Publication number Publication date
CA1116587A (en) 1982-01-19
NL7808938A (en) 1979-03-08
AU521294B2 (en) 1982-03-25
JPS5455505A (en) 1979-05-02
DE2837514A1 (en) 1979-03-15
AU3936878A (en) 1980-03-06
ZA784827B (en) 1979-08-29

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