FR2394510A1 - PREPARATION OF 1,4-DIOLS FROM TETRAHYDROFURANS ALCOXYL - Google Patents

PREPARATION OF 1,4-DIOLS FROM TETRAHYDROFURANS ALCOXYL

Info

Publication number
FR2394510A1
FR2394510A1 FR7817608A FR7817608A FR2394510A1 FR 2394510 A1 FR2394510 A1 FR 2394510A1 FR 7817608 A FR7817608 A FR 7817608A FR 7817608 A FR7817608 A FR 7817608A FR 2394510 A1 FR2394510 A1 FR 2394510A1
Authority
FR
France
Prior art keywords
tetrahydrofurans
diols
preparation
alcoxyl
alkoxylated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7817608A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co
Original Assignee
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Co filed Critical General Electric Co
Publication of FR2394510A1 publication Critical patent/FR2394510A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
    • C07C29/103—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/18—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/20—Oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Préparation de diols-1,4 à partir de tétrahydrofurannes alcoxylés. On transforme des tétrahydrofurannes alcoxylés en 2 en diols-1,4 dans des conditions d'hydrolyse et d'hydrogénation. Le procédé peut être couplé à la synthèse de tétrahydrofurannes alcoxylés en 2 de manière à fournir une conversion en deux stades très efficaces d'alcool allylique en butanediol. Industries des matières plastiques.Preparation of 1,4-diols from alkoxylated tetrahydrofurans. 2-alkoxylated tetrahydrofurans are converted to 1,4-diols under hydrolysis and hydrogenation conditions. The process can be coupled with the synthesis of 2-alkoxylated tetrahydrofurans so as to provide a highly efficient two-step conversion of allyl alcohol to butanediol. Plastics industries.

FR7817608A 1977-06-13 1978-06-13 PREPARATION OF 1,4-DIOLS FROM TETRAHYDROFURANS ALCOXYL Withdrawn FR2394510A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/806,074 US4091041A (en) 1977-06-13 1977-06-13 Preparation of 1,4-diols by hydrolysis-hydrogenation of 2-alkoxytetrahydrofurans

Publications (1)

Publication Number Publication Date
FR2394510A1 true FR2394510A1 (en) 1979-01-12

Family

ID=25193252

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7817608A Withdrawn FR2394510A1 (en) 1977-06-13 1978-06-13 PREPARATION OF 1,4-DIOLS FROM TETRAHYDROFURANS ALCOXYL

Country Status (8)

Country Link
US (1) US4091041A (en)
JP (1) JPS5436207A (en)
AU (1) AU515466B2 (en)
CA (1) CA1099746A (en)
DE (1) DE2825586A1 (en)
FR (1) FR2394510A1 (en)
GB (1) GB2000126B (en)
NL (1) NL7806348A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2394540A1 (en) * 1977-06-13 1979-01-12 Gen Electric PROCESS FOR PREPARING ALCOHYL TETRAHYDROFURANS IN POSITION 2

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4091041A (en) * 1977-06-13 1978-05-23 General Electric Company Preparation of 1,4-diols by hydrolysis-hydrogenation of 2-alkoxytetrahydrofurans
US4224255A (en) * 1978-06-15 1980-09-23 General Electric Company Process for the production of aldehydes and alcohols from olefinically unsaturated compounds by hydroformylation with suppression of olefin hydrogenation
DE3018388A1 (en) * 1980-05-14 1981-11-19 Basf Ag, 6700 Ludwigshafen METHOD FOR PRODUCING OPTICALLY ACTIVE COMPOUNDS AND THE USE THEREOF FOR PRODUCING VITAMIN E
US4661643A (en) * 1981-09-30 1987-04-28 Union Carbide Corporation Hydrogenolysis process for the production of monoethylene glycol monomethyl ether, monoethylene glycol and ethanol
US4649225A (en) * 1981-09-30 1987-03-10 Union Carbide Corporation Hydrogenolysis of polyalkylene glycols to produce monoethylene glycol monoalkyl ethers, monoethylene glycol and ethanol
JPH0635404B2 (en) * 1985-02-27 1994-05-11 三菱化成株式会社 Purification method of crude 1,4-butanediol
US4879420A (en) * 1988-05-06 1989-11-07 E.I. Du Pont De Nemours And Company Preparation of mixtures of butanediols
DE4319456A1 (en) * 1993-06-11 1994-12-15 Huels Chemische Werke Ag Process for the catalytic dehydrogenation of diols
DE4325753A1 (en) * 1993-07-31 1995-02-02 Basf Ag Process for the preparation of 1,4-butanediol
US6555720B1 (en) 2000-04-28 2003-04-29 Mitsubishi Chemical Corporation Method and system for producing 1,4-butanediol
US7538060B2 (en) * 2007-02-14 2009-05-26 Eastman Chemical Company Palladium-copper chromite hydrogenation catalysts
US20080194398A1 (en) * 2007-02-14 2008-08-14 Eastman Chemical Company Ruthenium-copper chromite hydrogenation catalysts
CN105263892B (en) * 2013-06-04 2017-08-25 株式会社可乐丽 The manufacture method of polyalcohol

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB653765A (en) * 1947-09-06 1951-05-23 Bataafsche Petroleum A process for the preparation of dialdehydes and diols
DE1003704B (en) * 1947-10-25 1957-03-07 Bataafsche Petroleum Mattschap Process for the preparation of 1,5-diols
DE2404312A1 (en) * 1974-01-30 1975-08-14 Basf Ag PROCESS FOR PRODUCING 3-METHYLPENTANE-1,5-DIOL
DE2410156A1 (en) * 1974-03-02 1975-09-11 Basf Ag 2-Ethyl-3-propyl-butan-1,4- and 2,4-diethyl-pentan-1,5-diol mixt. - prepd. from 2-ethyl-hex-2-en-1-ol, for poly-urethane and poly-ester mfr.
DE2649900A1 (en) * 1975-11-05 1977-05-12 Firestone Tire & Rubber Co PROCESS FOR THE PRODUCTION OF GAMMA HYDROXYTETRAHYDROFURAN OR TETRAHYDROFURAN
US4091041A (en) * 1977-06-13 1978-05-23 General Electric Company Preparation of 1,4-diols by hydrolysis-hydrogenation of 2-alkoxytetrahydrofurans
FR2394540A1 (en) * 1977-06-13 1979-01-12 Gen Electric PROCESS FOR PREPARING ALCOHYL TETRAHYDROFURANS IN POSITION 2

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2546019A (en) * 1947-10-25 1951-03-20 Shell Dev Preparation of 1, 5-pentanediols
US2888492A (en) * 1955-08-08 1959-05-26 Shell Dev Production of polyols
FR1559112A (en) * 1968-01-25 1969-03-07
US3671550A (en) * 1970-06-10 1972-06-20 Eastman Kodak Co HEXAHYDRO-3,3,6,6-TETRA ALKYLFURO(3,2-b)FURAN-2,5-DIOL
US3929915A (en) * 1974-07-31 1975-12-30 Du Pont Process for the production of butanediol

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB653765A (en) * 1947-09-06 1951-05-23 Bataafsche Petroleum A process for the preparation of dialdehydes and diols
DE1003704B (en) * 1947-10-25 1957-03-07 Bataafsche Petroleum Mattschap Process for the preparation of 1,5-diols
DE2404312A1 (en) * 1974-01-30 1975-08-14 Basf Ag PROCESS FOR PRODUCING 3-METHYLPENTANE-1,5-DIOL
DE2410156A1 (en) * 1974-03-02 1975-09-11 Basf Ag 2-Ethyl-3-propyl-butan-1,4- and 2,4-diethyl-pentan-1,5-diol mixt. - prepd. from 2-ethyl-hex-2-en-1-ol, for poly-urethane and poly-ester mfr.
DE2649900A1 (en) * 1975-11-05 1977-05-12 Firestone Tire & Rubber Co PROCESS FOR THE PRODUCTION OF GAMMA HYDROXYTETRAHYDROFURAN OR TETRAHYDROFURAN
US4091041A (en) * 1977-06-13 1978-05-23 General Electric Company Preparation of 1,4-diols by hydrolysis-hydrogenation of 2-alkoxytetrahydrofurans
FR2394540A1 (en) * 1977-06-13 1979-01-12 Gen Electric PROCESS FOR PREPARING ALCOHYL TETRAHYDROFURANS IN POSITION 2

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2394540A1 (en) * 1977-06-13 1979-01-12 Gen Electric PROCESS FOR PREPARING ALCOHYL TETRAHYDROFURANS IN POSITION 2

Also Published As

Publication number Publication date
DE2825586A1 (en) 1978-12-21
NL7806348A (en) 1978-12-15
CA1099746A (en) 1981-04-21
AU3705278A (en) 1979-12-20
JPS5436207A (en) 1979-03-16
US4091041A (en) 1978-05-23
GB2000126B (en) 1982-02-10
AU515466B2 (en) 1981-04-02
GB2000126A (en) 1979-01-04

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Legal Events

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ST Notification of lapse