FR2391988A1 - High yield prepn. of 2,3-di:hydroxy propyl acrylate - by reacting glycidol with acrylic acid derivs. in presence of polymerisation inhibitor and organic base - Google Patents

High yield prepn. of 2,3-di:hydroxy propyl acrylate - by reacting glycidol with acrylic acid derivs. in presence of polymerisation inhibitor and organic base

Info

Publication number
FR2391988A1
FR2391988A1 FR7715716A FR7715716A FR2391988A1 FR 2391988 A1 FR2391988 A1 FR 2391988A1 FR 7715716 A FR7715716 A FR 7715716A FR 7715716 A FR7715716 A FR 7715716A FR 2391988 A1 FR2391988 A1 FR 2391988A1
Authority
FR
France
Prior art keywords
acrylic acid
organic base
propyl acrylate
prepn
high yield
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7715716A
Other languages
French (fr)
Other versions
FR2391988B1 (en
Inventor
Marc Piteau
Jean-Pierre Senet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe Nationale des Poudres et Explosifs
Original Assignee
Societe Nationale des Poudres et Explosifs
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Societe Nationale des Poudres et Explosifs filed Critical Societe Nationale des Poudres et Explosifs
Priority to FR7715716A priority Critical patent/FR2391988A1/en
Publication of FR2391988A1 publication Critical patent/FR2391988A1/en
Application granted granted Critical
Publication of FR2391988B1 publication Critical patent/FR2391988B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

propyl acrylate (I) is prepd. by adding glycidol slowly and with stirring to an acrylic acid of formula R1R2C=C(R3)COOH (II) at 80-120 degrees C, in the presence of a polymerisation inhibitor and an organic base. In the formula, R1 and R2 are each H, halo, lower alkyl or aryl; and R3 is H, hydrocarbyl or halo. (I) is obtd. in improved yields (e.g. 96.5%) and needs little or no purification. (I) is used for prepg. resins for dental prothesis, heamodialysis membranes, transparent prods. etc.
FR7715716A 1977-05-23 1977-05-23 High yield prepn. of 2,3-di:hydroxy propyl acrylate - by reacting glycidol with acrylic acid derivs. in presence of polymerisation inhibitor and organic base Granted FR2391988A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7715716A FR2391988A1 (en) 1977-05-23 1977-05-23 High yield prepn. of 2,3-di:hydroxy propyl acrylate - by reacting glycidol with acrylic acid derivs. in presence of polymerisation inhibitor and organic base

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7715716A FR2391988A1 (en) 1977-05-23 1977-05-23 High yield prepn. of 2,3-di:hydroxy propyl acrylate - by reacting glycidol with acrylic acid derivs. in presence of polymerisation inhibitor and organic base

Publications (2)

Publication Number Publication Date
FR2391988A1 true FR2391988A1 (en) 1978-12-22
FR2391988B1 FR2391988B1 (en) 1982-09-17

Family

ID=9191175

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7715716A Granted FR2391988A1 (en) 1977-05-23 1977-05-23 High yield prepn. of 2,3-di:hydroxy propyl acrylate - by reacting glycidol with acrylic acid derivs. in presence of polymerisation inhibitor and organic base

Country Status (1)

Country Link
FR (1) FR2391988A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6270341A (en) * 1985-09-24 1987-03-31 Daicel Chem Ind Ltd Production of glycidol ester unsaturated monomer

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6270341A (en) * 1985-09-24 1987-03-31 Daicel Chem Ind Ltd Production of glycidol ester unsaturated monomer

Also Published As

Publication number Publication date
FR2391988B1 (en) 1982-09-17

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