FR2391859A1 - Marking devices for textiles - which are transferable by heat and pressure and are based on thermoplastic polyurethane(s) - Google Patents

Marking devices for textiles - which are transferable by heat and pressure and are based on thermoplastic polyurethane(s)

Info

Publication number
FR2391859A1
FR2391859A1 FR7816359A FR7816359A FR2391859A1 FR 2391859 A1 FR2391859 A1 FR 2391859A1 FR 7816359 A FR7816359 A FR 7816359A FR 7816359 A FR7816359 A FR 7816359A FR 2391859 A1 FR2391859 A1 FR 2391859A1
Authority
FR
France
Prior art keywords
mol
polyester
glycol
contg
gps
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7816359A
Other languages
French (fr)
Other versions
FR2391859B1 (en
Inventor
William Ashley Baldwin
Ian Harold Day
Harold Jacob Stern
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Polymark International Ltd
Original Assignee
Polymark International Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/801,275 external-priority patent/US4256795A/en
Priority claimed from GB24962/77A external-priority patent/GB1586511A/en
Application filed by Polymark International Ltd filed Critical Polymark International Ltd
Publication of FR2391859A1 publication Critical patent/FR2391859A1/en
Application granted granted Critical
Publication of FR2391859B1 publication Critical patent/FR2391859B1/fr
Granted legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/04—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps to be fastened or secured by the material of the label itself, e.g. by thermo-adhesion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/12—Transfer pictures or the like, e.g. decalcomanias
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
    • B44C1/1716—Decalcomanias provided with a particular decorative layer, e.g. specially adapted to allow the formation of a metallic or dyestuff layer on a substrate unsuitable for direct deposition
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/06—Polyurethanes from polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003—Transfer printing
    • D06P5/007—Transfer printing using non-subliming dyes
    • D06P5/009—Non-migrating dyes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
    • C08L2666/16—Addition or condensation polymers of aldehydes or ketones according to C08L59/00 - C08L61/00; Derivatives thereof

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Theoretical Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Decoration By Transfer Pictures (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)
  • Coloring (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

A device for heat-transfer making consists of a temporary support and a label carried on the support. The label includes a layer of a resin system prepd. from a soln. obtd. by dissolving a solvent a thermoplastic methane elastomer prod. (I). (I) is obtd. by reaction of (A) 1 mole of a linear polyester terminated by OH gps. and contg. recessing gps. of formula -C(O)R.C(O)O.O.R'-O- (where R=2-8C alkylidene; R'=4-10C alkylene) or of formula -C(O).R2-O- (where R2=4-8C alkylidene) or av.mol. wt. 1200-3000 and acid index 10; (B) 1.1-3.1 moles of diphenyl di-isocyanate contg. 1 NCO gp. per phenyl ring; (C) 0.1-2.1 moles of >=1 free glycol of 2-10C. The number av. mol. wt. of OH combined in polyester and in the free glycol is 450-1200 and the molar amt. of polyester plus glycol combined is equiv. to the molar amt. of the di-isocyanate. The resin system also incorporates an acid catalyst or acid generator, and, as cross-linking agent, a cpd. contg. is not N-alkoxymethyl gps. The device is used to transfer decorative and/or informative labels and stamps to extensible materials, esp. textiles. The marks transferred are inert, insol. and resistance to use. Cpd. with similar systems in which (A) has av. mol. wt. 600-1200 and the number of av. mol. wt. of OH in polyester and glycol is 450-600, the marks are transferable under milder conditions of temp. and pressure, are more resistant to washing and do not tend to split if transferred to loosely woven fabrics, e.g. wool.
FR7816359A 1977-05-27 1978-05-25 Marking devices for textiles - which are transferable by heat and pressure and are based on thermoplastic polyurethane(s) Granted FR2391859A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/801,275 US4256795A (en) 1974-11-05 1977-05-27 Heat transfers
GB24962/77A GB1586511A (en) 1977-06-15 1977-06-15 Heat transfers

Publications (2)

Publication Number Publication Date
FR2391859A1 true FR2391859A1 (en) 1978-12-22
FR2391859B1 FR2391859B1 (en) 1984-04-20

Family

ID=26257407

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7816359A Granted FR2391859A1 (en) 1977-05-27 1978-05-25 Marking devices for textiles - which are transferable by heat and pressure and are based on thermoplastic polyurethane(s)

Country Status (6)

Country Link
JP (1) JPS5942636B2 (en)
BR (1) BR7803387A (en)
DE (1) DE2822411A1 (en)
FR (1) FR2391859A1 (en)
IT (1) IT1202824B (en)
NL (1) NL7805677A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2466348A1 (en) * 1979-07-19 1981-04-10 Barta Franz Kg Transferring label or image to textile - with marking material contg. polypropylene-lined carrier and thermoplastic adhesive layer
EP0244181A2 (en) * 1986-04-29 1987-11-04 Sericol Group Limited Transfer compositions
FR2607435A1 (en) * 1986-11-27 1988-06-03 Vernhet Louis PROCESS FOR PRODUCING A PRODUCT WITH TRANSFERABLE PROTECTIVE FILM AND PRODUCT OBTAINED FOR THE PROTECTION OF DOCUMENTS OR THE LIKE

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116568523A (en) * 2020-10-16 2023-08-08 艾利丹尼森零售信息服务有限公司 Engravable heat transfer labels and decorations

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2084162A5 (en) * 1970-03-04 1971-12-17 Ciba Geigy Ag
FR2290312A1 (en) * 1974-11-05 1976-06-04 Polymark Int Ltd IMPROVEMENTS TO MARKING DEVICES TRANSFERABLE UNDER THE EFFECT OF HEAT OR TO DEVICES RELATED TO THESE

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3914484A (en) * 1971-02-24 1975-10-21 Dennison Mfg Co Pressure sensitive adhesive labels and method of making
GB1447049A (en) * 1972-12-18 1976-08-25 Payne P P Ltd Marking elements building including a ceiling light arrangement
SE414380B (en) * 1973-09-28 1980-07-28 Dennison Mfg Co LAMINATE PRODUCT IN THE FORM OF A HEAT TRANSFER LABEL COVERING A STICK LAYER, A PRINTING LAYER AND A PROTECTIVE LAYER OF TWO POLYMER COMPONENTS

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2084162A5 (en) * 1970-03-04 1971-12-17 Ciba Geigy Ag
FR2290312A1 (en) * 1974-11-05 1976-06-04 Polymark Int Ltd IMPROVEMENTS TO MARKING DEVICES TRANSFERABLE UNDER THE EFFECT OF HEAT OR TO DEVICES RELATED TO THESE

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2466348A1 (en) * 1979-07-19 1981-04-10 Barta Franz Kg Transferring label or image to textile - with marking material contg. polypropylene-lined carrier and thermoplastic adhesive layer
EP0244181A2 (en) * 1986-04-29 1987-11-04 Sericol Group Limited Transfer compositions
EP0244181A3 (en) * 1986-04-29 1990-05-02 Sericol Group Limited Transfer compositions
FR2607435A1 (en) * 1986-11-27 1988-06-03 Vernhet Louis PROCESS FOR PRODUCING A PRODUCT WITH TRANSFERABLE PROTECTIVE FILM AND PRODUCT OBTAINED FOR THE PROTECTION OF DOCUMENTS OR THE LIKE
EP0271941A1 (en) * 1986-11-27 1988-06-22 Louis Vernhet Method for manufacturing a transfer product with a protection layer, and product obtained for the protection of documents or other produce

Also Published As

Publication number Publication date
IT7849592A0 (en) 1978-05-29
FR2391859B1 (en) 1984-04-20
JPS5942636B2 (en) 1984-10-16
IT1202824B (en) 1989-02-09
JPS5431302A (en) 1979-03-08
BR7803387A (en) 1979-02-13
DE2822411A1 (en) 1978-12-14
NL7805677A (en) 1978-11-29

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