FR2391220A2 - Tetra:organo-tin cpds. prepn. - by reacting organic halide with zinc in onium salt and then reacting with tin - Google Patents
Tetra:organo-tin cpds. prepn. - by reacting organic halide with zinc in onium salt and then reacting with tinInfo
- Publication number
- FR2391220A2 FR2391220A2 FR7814653A FR7814653A FR2391220A2 FR 2391220 A2 FR2391220 A2 FR 2391220A2 FR 7814653 A FR7814653 A FR 7814653A FR 7814653 A FR7814653 A FR 7814653A FR 2391220 A2 FR2391220 A2 FR 2391220A2
- Authority
- FR
- France
- Prior art keywords
- tin
- reacting
- onium salt
- prepn
- cpds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000003839 salts Chemical class 0.000 title abstract 5
- 150000004820 halides Chemical class 0.000 title abstract 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 title 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title 1
- 239000011701 zinc Substances 0.000 title 1
- 229910052725 zinc Inorganic materials 0.000 title 1
- 239000000543 intermediate Substances 0.000 abstract 2
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 abstract 1
- PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- 239000000417 fungicide Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000004714 phosphonium salts Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- DPKBAXPHAYBPRL-UHFFFAOYSA-M tetrabutylazanium;iodide Chemical compound [I-].CCCC[N+](CCCC)(CCCC)CCCC DPKBAXPHAYBPRL-UHFFFAOYSA-M 0.000 abstract 1
- AFCAKJKUYFLYFK-UHFFFAOYSA-N tetrabutyltin Chemical compound CCCC[Sn](CCCC)(CCCC)CCCC AFCAKJKUYFLYFK-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
Prepn. of tetraorganotin cpd. (I) is carried out by (a) reacting an organic halide of formula RX (where R is 1-20C alkyl or 2-20C alkenyl; X is Cl, Br or I) with a heated suspension of Zn in a molten onium salt (II); (b) adding Sn to the product in an amt. such that the Zn:Sn atomic ratio is >0.5:1 (pref. 1-4:1, esp. 1.5-2.5:1); and (c) heating the mixt. to produce (I). Cpd. (II) is a quat. ammonium or phosphonium salt or a tert. sulphonium salt. Cpds. (I) are useful as intermediates for organotin halides, which can be used as fungicides or intermediates for polymer stabilisers. The process gives high yields (e.g. 55-83% based on onium salt) of products with high purity (e.g. 92-99%). In an example, tetrabutyltin is prepd. using n-butyl chloride and tetra-n-butylammonium iodide.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2090277 | 1977-05-18 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2391220A2 true FR2391220A2 (en) | 1978-12-15 |
| FR2391220B2 FR2391220B2 (en) | 1980-07-04 |
Family
ID=10153716
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7814653A Granted FR2391220A2 (en) | 1977-05-18 | 1978-05-17 | Tetra:organo-tin cpds. prepn. - by reacting organic halide with zinc in onium salt and then reacting with tin |
Country Status (14)
| Country | Link |
|---|---|
| JP (1) | JPS53144533A (en) |
| AU (1) | AU3620878A (en) |
| BE (1) | BE867169R (en) |
| BR (1) | BR7803258A (en) |
| DE (1) | DE2821705A1 (en) |
| DK (1) | DK217678A (en) |
| ES (1) | ES469950A1 (en) |
| FR (1) | FR2391220A2 (en) |
| IT (1) | IT7868128A0 (en) |
| NL (1) | NL7805310A (en) |
| NO (1) | NO781716L (en) |
| NZ (1) | NZ187219A (en) |
| SE (1) | SE7805672L (en) |
| ZA (1) | ZA782657B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4006043C1 (en) * | 1990-02-26 | 1991-04-18 | Th. Goldschmidt Ag, 4300 Essen, De |
-
1978
- 1978-05-09 ZA ZA00782657A patent/ZA782657B/en unknown
- 1978-05-10 NZ NZ187219A patent/NZ187219A/en unknown
- 1978-05-16 NO NO78781716A patent/NO781716L/en unknown
- 1978-05-17 FR FR7814653A patent/FR2391220A2/en active Granted
- 1978-05-17 ES ES469950A patent/ES469950A1/en not_active Expired
- 1978-05-17 DK DK217678A patent/DK217678A/en unknown
- 1978-05-17 SE SE7805672A patent/SE7805672L/en unknown
- 1978-05-17 NL NL7805310A patent/NL7805310A/en not_active Application Discontinuation
- 1978-05-17 BE BE187774A patent/BE867169R/en active
- 1978-05-17 AU AU36208/78A patent/AU3620878A/en active Pending
- 1978-05-17 IT IT7868128A patent/IT7868128A0/en unknown
- 1978-05-18 BR BR7803258A patent/BR7803258A/en unknown
- 1978-05-18 DE DE19782821705 patent/DE2821705A1/en not_active Withdrawn
- 1978-05-18 JP JP5833678A patent/JPS53144533A/en active Pending
Non-Patent Citations (1)
| Title |
|---|
| NEANT * |
Also Published As
| Publication number | Publication date |
|---|---|
| BE867169R (en) | 1978-11-17 |
| BR7803258A (en) | 1979-01-02 |
| JPS53144533A (en) | 1978-12-15 |
| FR2391220B2 (en) | 1980-07-04 |
| NL7805310A (en) | 1978-11-21 |
| DE2821705A1 (en) | 1978-11-30 |
| AU3620878A (en) | 1979-11-22 |
| NZ187219A (en) | 1980-12-19 |
| ES469950A1 (en) | 1979-09-16 |
| IT7868128A0 (en) | 1978-05-17 |
| ZA782657B (en) | 1979-05-30 |
| SE7805672L (en) | 1978-11-19 |
| NO781716L (en) | 1978-11-21 |
| DK217678A (en) | 1978-11-19 |
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