FR2388781A1 - PROCESS FOR THE PREPARATION OF HYDROCARBONS FROM GAS MIXTURES OF LOW HYDROGEN CONTENT - Google Patents
PROCESS FOR THE PREPARATION OF HYDROCARBONS FROM GAS MIXTURES OF LOW HYDROGEN CONTENTInfo
- Publication number
- FR2388781A1 FR2388781A1 FR7812391A FR7812391A FR2388781A1 FR 2388781 A1 FR2388781 A1 FR 2388781A1 FR 7812391 A FR7812391 A FR 7812391A FR 7812391 A FR7812391 A FR 7812391A FR 2388781 A1 FR2388781 A1 FR 2388781A1
- Authority
- FR
- France
- Prior art keywords
- hydrocarbons
- preparation
- gas mixtures
- hydrogen content
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/043—Catalysts; their physical properties characterised by the composition
- C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
- C07C1/044—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8953—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/043—Catalysts; their physical properties characterised by the composition
- C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/045—Regeneration
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/46—Ruthenium, rhodium, osmium or iridium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/72—Copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with zinc, cadmium or mercury
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Procédé pour la préparation d'hydrocarbures. Un mélange d'oxyde de carbone et d'hydrogène, dont le rapport molaire H2 /CO est inférieur à 1,0 est mis en contact avec un catalyseur contenant de 5 à 50 % en poids d'un ou plusieurs métaux du groupe du fer et/ou de 0,1 à 5 % en poids de ruthénium et de 5 à 50 % en poids de cuivre et/ou de zinc Dans ce catalyseur, le rapport en poids entre la quantité totale de cuivre et de zinc et la quantité totale de métaux du groupe du fer, augmentée de dix fois la quantité de ruthénium, est compris entre 0,5 et 5. Application à la préparation d'hydrocarbures à partir de mélanges de gaz d'une faible teneur en hydrogène.Process for the preparation of hydrocarbons. A mixture of carbon monoxide and hydrogen with a H2 / CO molar ratio of less than 1.0 is contacted with a catalyst containing 5 to 50% by weight of one or more metals from the iron group and / or from 0.1 to 5% by weight of ruthenium and from 5 to 50% by weight of copper and / or zinc In this catalyst, the ratio by weight between the total quantity of copper and zinc and the total quantity of metals of the iron group, increased by ten times the amount of ruthenium, is between 0.5 and 5. Application to the preparation of hydrocarbons from gas mixtures with a low hydrogen content.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL7704658A NL7704658A (en) | 1977-04-28 | 1977-04-28 | PROCESS FOR THE PREPARATION OF HYDROCARBONS. |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2388781A1 true FR2388781A1 (en) | 1978-11-24 |
FR2388781B1 FR2388781B1 (en) | 1981-08-07 |
Family
ID=19828451
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7812391A Granted FR2388781A1 (en) | 1977-04-28 | 1978-04-26 | PROCESS FOR THE PREPARATION OF HYDROCARBONS FROM GAS MIXTURES OF LOW HYDROGEN CONTENT |
Country Status (11)
Country | Link |
---|---|
JP (1) | JPS53135906A (en) |
AU (1) | AU515324B2 (en) |
BE (1) | BE866072A (en) |
CA (1) | CA1095536A (en) |
DE (1) | DE2818308A1 (en) |
FR (1) | FR2388781A1 (en) |
GB (1) | GB1553959A (en) |
IN (1) | IN148281B (en) |
IT (1) | IT1094560B (en) |
NL (1) | NL7704658A (en) |
ZA (1) | ZA782399B (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2483400A1 (en) * | 1980-06-03 | 1981-12-04 | Shell Int Research | PROCESS FOR THE PREPARATION OF HYDROCARBONS |
EP0055512A1 (en) * | 1980-12-22 | 1982-07-07 | The Standard Oil Company | Process for the manufacture of 1-4-butanediol and tetrahydrofuran |
EP0082692A2 (en) * | 1981-12-21 | 1983-06-29 | The Standard Oil Company | Process for upgrading synthesis gas and catalysts therefor |
US4654321A (en) * | 1981-12-21 | 1987-03-31 | The Standard Oil Company | Upgrading synthesis gas catalyst |
FR2694013A1 (en) * | 1992-07-27 | 1994-01-28 | Inst Francais Du Petrole | Cobalt-based catalyst and process for converting synthesis gas to hydrocarbons. |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL7704656A (en) * | 1977-04-28 | 1978-10-31 | Shell Int Research | PROCESS FOR THE PREPARATION OF HYDROCARBONS. |
US4617283A (en) * | 1984-06-27 | 1986-10-14 | Union Carbide Corporation | Catalyst for converting synthesis gas to liquid motor fuels |
DE3578384D1 (en) * | 1984-11-02 | 1990-08-02 | Shell Int Research | CATALYST PRODUCTION. |
GB2169614A (en) * | 1984-12-31 | 1986-07-16 | Mobil Oil Corp | Producing alpha-olefins and their conversion into lubricants |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1011662A (en) * | 1949-02-26 | 1952-06-25 | Ruhrchemie Ag | Process for obtaining carbon monoxide hydrogenation products with a high content of oxygen compounds |
GB681648A (en) * | 1950-03-08 | 1952-10-29 | Du Pont | Process for preparing high molecular weight hydrocarbons |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL7704656A (en) * | 1977-04-28 | 1978-10-31 | Shell Int Research | PROCESS FOR THE PREPARATION OF HYDROCARBONS. |
-
1977
- 1977-04-28 NL NL7704658A patent/NL7704658A/en not_active Application Discontinuation
-
1978
- 1978-02-27 IN IN156/DEL/78A patent/IN148281B/en unknown
- 1978-03-01 CA CA297,989A patent/CA1095536A/en not_active Expired
- 1978-04-18 BE BE1008845A patent/BE866072A/en not_active IP Right Cessation
- 1978-04-24 AU AU35381/78A patent/AU515324B2/en not_active Expired
- 1978-04-26 DE DE19782818308 patent/DE2818308A1/en active Granted
- 1978-04-26 ZA ZA00782399A patent/ZA782399B/en unknown
- 1978-04-26 GB GB16499/78A patent/GB1553959A/en not_active Expired
- 1978-04-26 FR FR7812391A patent/FR2388781A1/en active Granted
- 1978-04-26 JP JP4881578A patent/JPS53135906A/en active Pending
- 1978-04-26 IT IT22723/78A patent/IT1094560B/en active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1011662A (en) * | 1949-02-26 | 1952-06-25 | Ruhrchemie Ag | Process for obtaining carbon monoxide hydrogenation products with a high content of oxygen compounds |
GB681648A (en) * | 1950-03-08 | 1952-10-29 | Du Pont | Process for preparing high molecular weight hydrocarbons |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2483400A1 (en) * | 1980-06-03 | 1981-12-04 | Shell Int Research | PROCESS FOR THE PREPARATION OF HYDROCARBONS |
EP0055512A1 (en) * | 1980-12-22 | 1982-07-07 | The Standard Oil Company | Process for the manufacture of 1-4-butanediol and tetrahydrofuran |
EP0082692A2 (en) * | 1981-12-21 | 1983-06-29 | The Standard Oil Company | Process for upgrading synthesis gas and catalysts therefor |
EP0082692A3 (en) * | 1981-12-21 | 1984-09-12 | The Standard Oil Company | Process for upgrading synthesis gas and catalysts therefor |
US4654321A (en) * | 1981-12-21 | 1987-03-31 | The Standard Oil Company | Upgrading synthesis gas catalyst |
FR2694013A1 (en) * | 1992-07-27 | 1994-01-28 | Inst Francais Du Petrole | Cobalt-based catalyst and process for converting synthesis gas to hydrocarbons. |
EP0581619A1 (en) * | 1992-07-27 | 1994-02-02 | Institut Francais Du Petrole | Cobalt based catalyst and process for the commution of synthesis gas into hydrocarbons |
US5302622A (en) * | 1992-07-27 | 1994-04-12 | Institut Francais Du Petrole | Cobalt-based catalyst and process for converting synthesis gas into hydrocarbons |
Also Published As
Publication number | Publication date |
---|---|
IT1094560B (en) | 1985-08-02 |
FR2388781B1 (en) | 1981-08-07 |
DE2818308C2 (en) | 1988-09-01 |
DE2818308A1 (en) | 1978-11-02 |
NL7704658A (en) | 1978-10-31 |
AU3538178A (en) | 1979-11-01 |
JPS53135906A (en) | 1978-11-28 |
IN148281B (en) | 1981-01-03 |
CA1095536A (en) | 1981-02-10 |
AU515324B2 (en) | 1981-03-26 |
ZA782399B (en) | 1979-04-25 |
GB1553959A (en) | 1979-10-17 |
BE866072A (en) | 1978-10-18 |
IT7822723A0 (en) | 1978-04-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |