FR2382429A1 - Nouveau procede de preparation de polyarylamines de la serie des diphenylalcanes - Google Patents
Nouveau procede de preparation de polyarylamines de la serie des diphenylalcanesInfo
- Publication number
- FR2382429A1 FR2382429A1 FR7806216A FR7806216A FR2382429A1 FR 2382429 A1 FR2382429 A1 FR 2382429A1 FR 7806216 A FR7806216 A FR 7806216A FR 7806216 A FR7806216 A FR 7806216A FR 2382429 A1 FR2382429 A1 FR 2382429A1
- Authority
- FR
- France
- Prior art keywords
- arylamine
- prepn
- acid catalyst
- poly
- phenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 150000004982 aromatic amines Chemical class 0.000 title abstract 3
- 125000003118 aryl group Chemical group 0.000 title abstract 3
- 239000003377 acid catalyst Substances 0.000 title abstract 2
- 239000004814 polyurethane Substances 0.000 title abstract 2
- 229920002635 polyurethane Polymers 0.000 title abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 2
- 125000001188 haloalkyl group Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 229910000039 hydrogen halide Inorganic materials 0.000 abstract 1
- 239000012433 hydrogen halide Substances 0.000 abstract 1
- 238000006386 neutralization reaction Methods 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 229920000768 polyamine Polymers 0.000 abstract 1
- 229920001228 polyisocyanate Polymers 0.000 abstract 1
- 239000005056 polyisocyanate Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 230000017105 transposition Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/10—Preparation of derivatives of isocyanic acid by reaction of amines with carbonyl halides, e.g. with phosgene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
- C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
- C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
On fait réagir des composés aromatiques portant un substituant alpha -halogenoalkyle et au moins un groupe nitro en position ortho et/ou para de ce groupe avec des arylamines portant au moins un atome d'hydrogène sur le noyau aromatique en position ortho et/ou para dun groupe amino, on sépare l'halogénure d'hydrogène libéré par neutralisation à l'aide d'une base, on réduit les groupes nitro du produit de condensation en groupes amino et, finalement, on soumet à transposition en présence d'eau et d'un catalyseur acide en les polyarylamines recherchées. Le procédé selon l'invention permet de préparer des polyarylamines asymétriques qui présentent un intérêt croissant dans la chimie des polyuréthannes après transformation en les polyisocyanates correspondants.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2709489 | 1977-03-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2382429A1 true FR2382429A1 (fr) | 1978-09-29 |
Family
ID=6002794
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7806216A Withdrawn FR2382429A1 (fr) | 1977-03-04 | 1978-03-03 | Nouveau procede de preparation de polyarylamines de la serie des diphenylalcanes |
Country Status (6)
Country | Link |
---|---|
JP (1) | JPS53111046A (fr) |
BE (1) | BE864533A (fr) |
BR (1) | BR7801298A (fr) |
ES (1) | ES467535A1 (fr) |
FR (1) | FR2382429A1 (fr) |
IT (1) | IT7848258A0 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2382430A1 (fr) * | 1977-03-04 | 1978-09-29 | Bayer Ag | Procede de preparation de polyarylamines de la serie des diphenylalcanes |
FR2545083A1 (fr) * | 1983-04-29 | 1984-11-02 | Ugine Kuhlmann | Composition liquide, contenant des diisocyanates a structure diphenylmethane, et son procede de fabrication |
-
1978
- 1978-03-02 JP JP2288078A patent/JPS53111046A/ja active Pending
- 1978-03-02 IT IT7848258A patent/IT7848258A0/it unknown
- 1978-03-03 ES ES467535A patent/ES467535A1/es not_active Expired
- 1978-03-03 BR BR7801298A patent/BR7801298A/pt unknown
- 1978-03-03 BE BE185644A patent/BE864533A/fr unknown
- 1978-03-03 FR FR7806216A patent/FR2382429A1/fr not_active Withdrawn
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2382430A1 (fr) * | 1977-03-04 | 1978-09-29 | Bayer Ag | Procede de preparation de polyarylamines de la serie des diphenylalcanes |
FR2545083A1 (fr) * | 1983-04-29 | 1984-11-02 | Ugine Kuhlmann | Composition liquide, contenant des diisocyanates a structure diphenylmethane, et son procede de fabrication |
EP0125169A1 (fr) * | 1983-04-29 | 1984-11-14 | Elf Atochem S.A. | Composition liquide, contenant des diisocyanates à structure diphénylméthane, et son procédé de fabrication |
Also Published As
Publication number | Publication date |
---|---|
IT7848258A0 (it) | 1978-03-02 |
BR7801298A (pt) | 1979-01-02 |
JPS53111046A (en) | 1978-09-28 |
BE864533A (fr) | 1978-09-04 |
ES467535A1 (es) | 1978-10-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |