FR2380290A1 - Stabiliser preventing deterioration of organic material by light - comprises an organic phosphite cpd. - Google Patents

Stabiliser preventing deterioration of organic material by light - comprises an organic phosphite cpd.

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Publication number
FR2380290A1
FR2380290A1 FR7704184A FR7704184A FR2380290A1 FR 2380290 A1 FR2380290 A1 FR 2380290A1 FR 7704184 A FR7704184 A FR 7704184A FR 7704184 A FR7704184 A FR 7704184A FR 2380290 A1 FR2380290 A1 FR 2380290A1
Authority
FR
France
Prior art keywords
cpd
organic
light
preventing deterioration
phosphite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7704184A
Other languages
French (fr)
Inventor
Motonobu Minagawa
Naohiro Kubota
Toshihiro Shibata
Kazuo Sugibuchi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Argus Chemical NV
Original Assignee
Argus Chemical NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Argus Chemical NV filed Critical Argus Chemical NV
Priority to FR7704184A priority Critical patent/FR2380290A1/en
Priority to BE174928A priority patent/BE851424A/en
Publication of FR2380290A1 publication Critical patent/FR2380290A1/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/576Six-membered rings
    • C07F9/59Hydrogenated pyridine rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6561Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom containing systems of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring or ring system, with or without other non-condensed hetero rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574Esters of oxyacids of phosphorus
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/02Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
    • C08G79/04Phosphorus linked to oxygen or to oxygen and carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005Stabilisers against oxidation, heat, light, ozone
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/524Esters of phosphorous acids, e.g. of H3PO3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/529Esters containing heterocyclic rings not representing cyclic esters of phosphoric or phosphorous acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L85/00Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers
    • C08L85/02Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers containing phosphorus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)

Abstract

The phosphite cpds. is formula (I) or (II). In the formulae, R1 is of formula (II) X is = CH- or of formula (III),, (IV) or (V); R6 is lower alkyl or -CH2OH; R2+5 are alkyl(aryl), aryl(alkyl), cellusolve, carbitol, polyhydric alcohol or polyhydric phenol, all opt. substd., or H or as R1; R1 and R2 and R3 and R4 may be joined to form the gp. R1 where X is (II) and R6 is a divalent gp. -CH2-, R is H or -P(OR3)-OR4; A is polyhydric alcohol or polyhydric phenol; B is =C=, =C(R7)-CH2-O-CH2-C(R7)=, or of formula (VI) or (VII); R7 is (m)ethyl; Y is H or O; m = 0-4; n = 0-20; and when n = 0, >=1 of R2 and R3 is polyhydric alcohol or phenol.
FR7704184A 1977-02-15 1977-02-15 Stabiliser preventing deterioration of organic material by light - comprises an organic phosphite cpd. Withdrawn FR2380290A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR7704184A FR2380290A1 (en) 1977-02-15 1977-02-15 Stabiliser preventing deterioration of organic material by light - comprises an organic phosphite cpd.
BE174928A BE851424A (en) 1977-02-15 1977-02-15 ORGANIC STABILIZING COMPOUNDS

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR7704184A FR2380290A1 (en) 1977-02-15 1977-02-15 Stabiliser preventing deterioration of organic material by light - comprises an organic phosphite cpd.
BE174928A BE851424A (en) 1977-02-15 1977-02-15 ORGANIC STABILIZING COMPOUNDS
BE851424 1977-02-15

Publications (1)

Publication Number Publication Date
FR2380290A1 true FR2380290A1 (en) 1978-09-08

Family

ID=27158622

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7704184A Withdrawn FR2380290A1 (en) 1977-02-15 1977-02-15 Stabiliser preventing deterioration of organic material by light - comprises an organic phosphite cpd.

Country Status (2)

Country Link
BE (1) BE851424A (en)
FR (1) FR2380290A1 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0389430A1 (en) * 1989-03-21 1990-09-26 Ciba-Geigy Ag N-hydrocarbyloxy hindered amine light stabilizers substituted with phosphorus moieties
GB2288399A (en) * 1994-04-13 1995-10-18 Ciba Geigy Ag HALS phosphites and HALS phosphoramides as stabilizers
US5654430A (en) * 1994-04-13 1997-08-05 Ciba-Geigy Corporation Oligomeric aliphatic HALS phosphites and HALS phosphonites as stabilizers
US5665273A (en) * 1994-04-13 1997-09-09 Ciba-Geigy Corporation Hals phosphonites as stabilizers
US5777113A (en) * 1994-10-12 1998-07-07 Ciba Specialty Chemicals Corporation Hals phosphorinanes as stabilisers
US5777008A (en) * 1994-06-02 1998-07-07 Ciba Specialty Chemicals Corporation Oligomeric hals phosphites and hals phosphonites as stabilisers

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4256627A (en) * 1977-11-08 1981-03-17 Ciba-Geigy Corporation Novel light stabilizers for plastics
CA1116339A (en) * 1978-02-15 1982-01-12 Ingenuin Hechenbleikner Stabilization of propylene polymers

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2227689A1 (en) * 1971-06-05 1972-12-14 Sankyo CO1 Ltd , Tokio Piperidine derivatives and uses as stabilizers
FR2145193A5 (en) * 1971-07-02 1973-02-16 Sankyo Co

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2227689A1 (en) * 1971-06-05 1972-12-14 Sankyo CO1 Ltd , Tokio Piperidine derivatives and uses as stabilizers
FR2145193A5 (en) * 1971-07-02 1973-02-16 Sankyo Co

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0389430A1 (en) * 1989-03-21 1990-09-26 Ciba-Geigy Ag N-hydrocarbyloxy hindered amine light stabilizers substituted with phosphorus moieties
GB2288399A (en) * 1994-04-13 1995-10-18 Ciba Geigy Ag HALS phosphites and HALS phosphoramides as stabilizers
US5654430A (en) * 1994-04-13 1997-08-05 Ciba-Geigy Corporation Oligomeric aliphatic HALS phosphites and HALS phosphonites as stabilizers
US5665273A (en) * 1994-04-13 1997-09-09 Ciba-Geigy Corporation Hals phosphonites as stabilizers
GB2288399B (en) * 1994-04-13 1997-12-17 Ciba Geigy Ag HALS phosphites and HALS phosphoramides as stabilizers
US5925758A (en) * 1994-04-13 1999-07-20 Ciba Specialty Chemicals Corporation HALS phosphites and HALS phosphoramides as stabilizers
US5777008A (en) * 1994-06-02 1998-07-07 Ciba Specialty Chemicals Corporation Oligomeric hals phosphites and hals phosphonites as stabilisers
US5777113A (en) * 1994-10-12 1998-07-07 Ciba Specialty Chemicals Corporation Hals phosphorinanes as stabilisers

Also Published As

Publication number Publication date
BE851424A (en) 1977-08-16

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Legal Events

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