FR2380290A1 - Stabiliser preventing deterioration of organic material by light - comprises an organic phosphite cpd. - Google Patents
Stabiliser preventing deterioration of organic material by light - comprises an organic phosphite cpd.Info
- Publication number
- FR2380290A1 FR2380290A1 FR7704184A FR7704184A FR2380290A1 FR 2380290 A1 FR2380290 A1 FR 2380290A1 FR 7704184 A FR7704184 A FR 7704184A FR 7704184 A FR7704184 A FR 7704184A FR 2380290 A1 FR2380290 A1 FR 2380290A1
- Authority
- FR
- France
- Prior art keywords
- cpd
- organic
- light
- preventing deterioration
- phosphite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 title abstract 2
- 230000006866 deterioration Effects 0.000 title 1
- 239000011368 organic material Substances 0.000 title 1
- 239000003381 stabilizer Substances 0.000 title 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 150000005846 sugar alcohols Polymers 0.000 abstract 3
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/576—Six-membered rings
- C07F9/59—Hydrogenated pyridine rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6561—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom containing systems of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring or ring system, with or without other non-condensed hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
- C08G79/04—Phosphorus linked to oxygen or to oxygen and carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/529—Esters containing heterocyclic rings not representing cyclic esters of phosphoric or phosphorous acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L85/00—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers
- C08L85/02—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Abstract
The phosphite cpds. is formula (I) or (II). In the formulae, R1 is of formula (II) X is = CH- or of formula (III),, (IV) or (V); R6 is lower alkyl or -CH2OH; R2+5 are alkyl(aryl), aryl(alkyl), cellusolve, carbitol, polyhydric alcohol or polyhydric phenol, all opt. substd., or H or as R1; R1 and R2 and R3 and R4 may be joined to form the gp. R1 where X is (II) and R6 is a divalent gp. -CH2-, R is H or -P(OR3)-OR4; A is polyhydric alcohol or polyhydric phenol; B is =C=, =C(R7)-CH2-O-CH2-C(R7)=, or of formula (VI) or (VII); R7 is (m)ethyl; Y is H or O; m = 0-4; n = 0-20; and when n = 0, >=1 of R2 and R3 is polyhydric alcohol or phenol.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7704184A FR2380290A1 (en) | 1977-02-15 | 1977-02-15 | Stabiliser preventing deterioration of organic material by light - comprises an organic phosphite cpd. |
BE174928A BE851424A (en) | 1977-02-15 | 1977-02-15 | ORGANIC STABILIZING COMPOUNDS |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7704184A FR2380290A1 (en) | 1977-02-15 | 1977-02-15 | Stabiliser preventing deterioration of organic material by light - comprises an organic phosphite cpd. |
BE174928A BE851424A (en) | 1977-02-15 | 1977-02-15 | ORGANIC STABILIZING COMPOUNDS |
BE851424 | 1977-02-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2380290A1 true FR2380290A1 (en) | 1978-09-08 |
Family
ID=27158622
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7704184A Withdrawn FR2380290A1 (en) | 1977-02-15 | 1977-02-15 | Stabiliser preventing deterioration of organic material by light - comprises an organic phosphite cpd. |
Country Status (2)
Country | Link |
---|---|
BE (1) | BE851424A (en) |
FR (1) | FR2380290A1 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0389430A1 (en) * | 1989-03-21 | 1990-09-26 | Ciba-Geigy Ag | N-hydrocarbyloxy hindered amine light stabilizers substituted with phosphorus moieties |
GB2288399A (en) * | 1994-04-13 | 1995-10-18 | Ciba Geigy Ag | HALS phosphites and HALS phosphoramides as stabilizers |
US5654430A (en) * | 1994-04-13 | 1997-08-05 | Ciba-Geigy Corporation | Oligomeric aliphatic HALS phosphites and HALS phosphonites as stabilizers |
US5665273A (en) * | 1994-04-13 | 1997-09-09 | Ciba-Geigy Corporation | Hals phosphonites as stabilizers |
US5777113A (en) * | 1994-10-12 | 1998-07-07 | Ciba Specialty Chemicals Corporation | Hals phosphorinanes as stabilisers |
US5777008A (en) * | 1994-06-02 | 1998-07-07 | Ciba Specialty Chemicals Corporation | Oligomeric hals phosphites and hals phosphonites as stabilisers |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4256627A (en) * | 1977-11-08 | 1981-03-17 | Ciba-Geigy Corporation | Novel light stabilizers for plastics |
CA1116339A (en) * | 1978-02-15 | 1982-01-12 | Ingenuin Hechenbleikner | Stabilization of propylene polymers |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2227689A1 (en) * | 1971-06-05 | 1972-12-14 | Sankyo CO1 Ltd , Tokio | Piperidine derivatives and uses as stabilizers |
FR2145193A5 (en) * | 1971-07-02 | 1973-02-16 | Sankyo Co |
-
1977
- 1977-02-15 BE BE174928A patent/BE851424A/en unknown
- 1977-02-15 FR FR7704184A patent/FR2380290A1/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2227689A1 (en) * | 1971-06-05 | 1972-12-14 | Sankyo CO1 Ltd , Tokio | Piperidine derivatives and uses as stabilizers |
FR2145193A5 (en) * | 1971-07-02 | 1973-02-16 | Sankyo Co |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0389430A1 (en) * | 1989-03-21 | 1990-09-26 | Ciba-Geigy Ag | N-hydrocarbyloxy hindered amine light stabilizers substituted with phosphorus moieties |
GB2288399A (en) * | 1994-04-13 | 1995-10-18 | Ciba Geigy Ag | HALS phosphites and HALS phosphoramides as stabilizers |
US5654430A (en) * | 1994-04-13 | 1997-08-05 | Ciba-Geigy Corporation | Oligomeric aliphatic HALS phosphites and HALS phosphonites as stabilizers |
US5665273A (en) * | 1994-04-13 | 1997-09-09 | Ciba-Geigy Corporation | Hals phosphonites as stabilizers |
GB2288399B (en) * | 1994-04-13 | 1997-12-17 | Ciba Geigy Ag | HALS phosphites and HALS phosphoramides as stabilizers |
US5925758A (en) * | 1994-04-13 | 1999-07-20 | Ciba Specialty Chemicals Corporation | HALS phosphites and HALS phosphoramides as stabilizers |
US5777008A (en) * | 1994-06-02 | 1998-07-07 | Ciba Specialty Chemicals Corporation | Oligomeric hals phosphites and hals phosphonites as stabilisers |
US5777113A (en) * | 1994-10-12 | 1998-07-07 | Ciba Specialty Chemicals Corporation | Hals phosphorinanes as stabilisers |
Also Published As
Publication number | Publication date |
---|---|
BE851424A (en) | 1977-08-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
RE | Withdrawal of published application |