FR2380239A1 - METHOD FOR SYNTHESIS OF METHANE AND OF OTHER HYDROCARBONS AND ALCOHOLS, AND CATALYSTS USED FOR THE SUCH SYNTHESIS - Google Patents

METHOD FOR SYNTHESIS OF METHANE AND OF OTHER HYDROCARBONS AND ALCOHOLS, AND CATALYSTS USED FOR THE SUCH SYNTHESIS

Info

Publication number
FR2380239A1
FR2380239A1 FR7803797A FR7803797A FR2380239A1 FR 2380239 A1 FR2380239 A1 FR 2380239A1 FR 7803797 A FR7803797 A FR 7803797A FR 7803797 A FR7803797 A FR 7803797A FR 2380239 A1 FR2380239 A1 FR 2380239A1
Authority
FR
France
Prior art keywords
synthesis
methane
hydrocarbons
alcohols
catalysts used
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7803797A
Other languages
French (fr)
Other versions
FR2380239B1 (en
Inventor
Mehmet Nafiz Ozyagcilar
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rafel Industrial Group Ltd
Original Assignee
Rafel Industrial Group Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/797,294 external-priority patent/US4139551A/en
Application filed by Rafel Industrial Group Ltd filed Critical Rafel Industrial Group Ltd
Publication of FR2380239A1 publication Critical patent/FR2380239A1/en
Application granted granted Critical
Publication of FR2380239B1 publication Critical patent/FR2380239B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/08—Production of synthetic natural gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C07C1/044—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Abstract

Procédé de conversion d'hydrogène et d'oxydes de carbone, et en particulier d'anhydride carbonique, en présence d'un catalyseur bimétallique. Le catalyseur est constitué par un composé hydruré de fer-titane, préalablement activé par traitement par de l'hydrogène, à une température et sous une pression élevées. Application à la production de méthane, éthane et autres hydrocarbures et alcools.Process for the conversion of hydrogen and carbon oxides, and in particular carbon dioxide, in the presence of a bimetallic catalyst. The catalyst consists of a hydride compound of iron-titanium, activated beforehand by treatment with hydrogen, at an elevated temperature and under an elevated pressure. Application to the production of methane, ethane and other hydrocarbons and alcohols.

FR7803797A 1977-02-14 1978-02-10 METHOD FOR SYNTHESIS OF METHANE AND OF OTHER HYDROCARBONS AND ALCOHOLS, AND CATALYSTS USED FOR THE SUCH SYNTHESIS Granted FR2380239A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US77236077A 1977-02-14 1977-02-14
US05/797,294 US4139551A (en) 1977-02-14 1977-05-16 Catalyst for methane and ethane synthesis

Publications (2)

Publication Number Publication Date
FR2380239A1 true FR2380239A1 (en) 1978-09-08
FR2380239B1 FR2380239B1 (en) 1984-01-20

Family

ID=27118594

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7803797A Granted FR2380239A1 (en) 1977-02-14 1978-02-10 METHOD FOR SYNTHESIS OF METHANE AND OF OTHER HYDROCARBONS AND ALCOHOLS, AND CATALYSTS USED FOR THE SUCH SYNTHESIS

Country Status (14)

Country Link
JP (1) JPS53103403A (en)
AU (1) AU527568B2 (en)
BR (1) BR7800875A (en)
CA (1) CA1080754A (en)
DE (1) DE2806232A1 (en)
FR (1) FR2380239A1 (en)
GB (1) GB1582923A (en)
IL (1) IL54012A (en)
IT (1) IT1102391B (en)
MX (1) MX149541A (en)
NL (1) NL7801560A (en)
PL (1) PL114408B1 (en)
SE (1) SE438328B (en)
SU (1) SU1028244A3 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH660130A5 (en) * 1984-07-27 1987-03-31 Lonza Ag METHOD FOR THE PRODUCTION OF CATALYTICALLY EFFECTIVE, GLASS-FREEZING METALS.
GB2169614A (en) * 1984-12-31 1986-07-16 Mobil Oil Corp Producing alpha-olefins and their conversion into lubricants
JP2011062516A (en) * 2010-09-11 2011-03-31 Shoji Ako Device to prevent shoulder bag from slipping off

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR468427A (en) * 1913-03-07 1914-07-06 Basf Ag Process for the production of hydrocarbons and their derivatives
US2256969A (en) * 1940-06-12 1941-09-23 Standard Oil Dev Co Method for control of temperature in catalytic exothermic reactions
GB624869A (en) * 1945-08-23 1949-06-17 Kellogg M W Co Improvements in or relating to process for hydrogenating carbon oxides
FR970823A (en) * 1947-07-30 1951-01-09 Standard Oil Dev Co Advanced catalysts and their preparation process
FR1058797A (en) * 1951-01-08 1954-03-18 Ruhrchemie Ag Process for increasing the grain strength of precipitation catalysts, containing iron, for the hydrogenation of carbon monoxide

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR468427A (en) * 1913-03-07 1914-07-06 Basf Ag Process for the production of hydrocarbons and their derivatives
US2256969A (en) * 1940-06-12 1941-09-23 Standard Oil Dev Co Method for control of temperature in catalytic exothermic reactions
GB624869A (en) * 1945-08-23 1949-06-17 Kellogg M W Co Improvements in or relating to process for hydrogenating carbon oxides
FR970823A (en) * 1947-07-30 1951-01-09 Standard Oil Dev Co Advanced catalysts and their preparation process
FR1058797A (en) * 1951-01-08 1954-03-18 Ruhrchemie Ag Process for increasing the grain strength of precipitation catalysts, containing iron, for the hydrogenation of carbon monoxide

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
EXBK/74 *

Also Published As

Publication number Publication date
PL114408B1 (en) 1981-01-31
IT7848021A0 (en) 1978-02-13
NL7801560A (en) 1978-08-16
IL54012A0 (en) 1978-04-30
FR2380239B1 (en) 1984-01-20
IT1102391B (en) 1985-10-07
JPS53103403A (en) 1978-09-08
IL54012A (en) 1980-10-26
AU3326578A (en) 1979-08-23
SE438328B (en) 1985-04-15
SE7801577L (en) 1978-08-14
MX149541A (en) 1983-11-23
JPS6238331B2 (en) 1987-08-17
CA1080754A (en) 1980-07-01
PL204612A1 (en) 1979-03-26
BR7800875A (en) 1978-09-19
DE2806232A1 (en) 1978-08-17
GB1582923A (en) 1981-01-14
AU527568B2 (en) 1983-03-10
SU1028244A3 (en) 1983-07-07

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ST Notification of lapse