FR2375138A1 - Steam reforming with nickel catalyst - based on a magnesia-alumina support with special shape - Google Patents

Steam reforming with nickel catalyst - based on a magnesia-alumina support with special shape

Info

Publication number
FR2375138A1
FR2375138A1 FR7638819A FR7638819A FR2375138A1 FR 2375138 A1 FR2375138 A1 FR 2375138A1 FR 7638819 A FR7638819 A FR 7638819A FR 7638819 A FR7638819 A FR 7638819A FR 2375138 A1 FR2375138 A1 FR 2375138A1
Authority
FR
France
Prior art keywords
steam reforming
magnesia
nickel catalyst
special shape
alumina support
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7638819A
Other languages
French (fr)
Other versions
FR2375138B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Azote et Produits Chimiques SA
Original Assignee
Azote et Produits Chimiques SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Azote et Produits Chimiques SA filed Critical Azote et Produits Chimiques SA
Priority to FR7638819A priority Critical patent/FR2375138A1/en
Publication of FR2375138A1 publication Critical patent/FR2375138A1/en
Application granted granted Critical
Publication of FR2375138B1 publication Critical patent/FR2375138B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)

Abstract

Process for continuous steam reforming of hydrocarbons (gaseous or liq. with a final b.pt. of 250 degrees C) or for post-combustion (secondary reforming) of the steam-reformed gases is claimed. The catalyst used comprises 4-25 (pref. 10-20) wt.% of NiO on a support comprising 70-98% MgO (>= 70% of which is uncombined), 2-30% Al2O3 (part of which may be combined with MgO in the form of a spinel), and 0-5% SiO2 (in the form of aluminosilicate). The support particles are in the form of a hollow cylinder contg. 4-7 equally spaced radial partitions. The catalyst produces a smaller pressure drop and has a higher contact area than similar ring-shaped catalysts. It has high activity and good resistance to deactivation.
FR7638819A 1976-12-23 1976-12-23 Steam reforming with nickel catalyst - based on a magnesia-alumina support with special shape Granted FR2375138A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7638819A FR2375138A1 (en) 1976-12-23 1976-12-23 Steam reforming with nickel catalyst - based on a magnesia-alumina support with special shape

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7638819A FR2375138A1 (en) 1976-12-23 1976-12-23 Steam reforming with nickel catalyst - based on a magnesia-alumina support with special shape

Publications (2)

Publication Number Publication Date
FR2375138A1 true FR2375138A1 (en) 1978-07-21
FR2375138B1 FR2375138B1 (en) 1981-06-12

Family

ID=9181438

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7638819A Granted FR2375138A1 (en) 1976-12-23 1976-12-23 Steam reforming with nickel catalyst - based on a magnesia-alumina support with special shape

Country Status (1)

Country Link
FR (1) FR2375138A1 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0018511A1 (en) * 1979-04-07 1980-11-12 Forschungszentrum Jülich Gmbh Reactive filling substance having exchange properties
EP0041814A2 (en) * 1980-06-06 1981-12-16 United Kingdom Atomic Energy Authority Catalyst devices
EP0045126A1 (en) * 1980-06-25 1982-02-03 Imperial Chemical Industries Plc Catalytic process for producing hydrogen
US4460704A (en) * 1980-06-15 1984-07-17 Imperial Chemical Industries Plc Catalyst for the production of hydrogen
EP0389158A1 (en) * 1989-03-20 1990-09-26 Ube Industries, Ltd. High activity nickel catalyst and process for preparation thereof
DE102007046297A1 (en) 2007-09-27 2009-04-09 Süd-Chemie AG New catalyst design and manufacturing method for steam reforming catalysts

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0018511A1 (en) * 1979-04-07 1980-11-12 Forschungszentrum Jülich Gmbh Reactive filling substance having exchange properties
EP0041814A2 (en) * 1980-06-06 1981-12-16 United Kingdom Atomic Energy Authority Catalyst devices
EP0041814A3 (en) * 1980-06-06 1982-03-10 United Kingdom Atomic Energy Authority Catalyst devices
US4460704A (en) * 1980-06-15 1984-07-17 Imperial Chemical Industries Plc Catalyst for the production of hydrogen
EP0045126A1 (en) * 1980-06-25 1982-02-03 Imperial Chemical Industries Plc Catalytic process for producing hydrogen
DK157185B (en) * 1980-06-25 1989-11-20 Ici Ltd CATALYTIC PROCEDURE FOR PREPARING A HYDROGEN FLOW AND PROCEDURE FOR CLEANING THEM
EP0389158A1 (en) * 1989-03-20 1990-09-26 Ube Industries, Ltd. High activity nickel catalyst and process for preparation thereof
US5053379A (en) * 1989-03-20 1991-10-01 Ube Industries, Ltd. High-activity nickel catalyst and process for preparation thereof
DE102007046297A1 (en) 2007-09-27 2009-04-09 Süd-Chemie AG New catalyst design and manufacturing method for steam reforming catalysts

Also Published As

Publication number Publication date
FR2375138B1 (en) 1981-06-12

Similar Documents

Publication Publication Date Title
ES2149370T3 (en) PROCEDURE FOR PARTIAL CATALYTIC OXIDATION OF HYDROCARBONS.
IT7924290A0 (en) CATALYST FOR CAR EXHAUST GAS, AND PROCEDURE FOR ITS PRODUCTION.
CA2099083A1 (en) Process for the catalytic partial oxidation of hydrocarbons
MX9102781A (en) PROCEDURE FOR PREPARING AN ACTIVATED CARBON CATALYST.
JP2002519181A5 (en)
JPS5724639A (en) Catalyst for water vapor reforming and its manufacture
CA2306938A1 (en) A process for the preparation of hydrogen and carbon monoxide
MY110723A (en) Process for the catalytic partial oxidation of hydrocarbons
FR2375138A1 (en) Steam reforming with nickel catalyst - based on a magnesia-alumina support with special shape
CA1023391A (en) Catalyst and its use for the manufacture of methane from gases containing carbon monoxide and dioxide and hydrogen
BR8605505A (en) CATALYST, PROCESS FOR THE PREPARATION OF A CATALYST AND PROCESS FOR THE PREPARATION OF HYDROCARBONS BY CONTACTING A MIXTURE OF CARBON MONOXIDE AND HYDROGEN
IE37230B1 (en) Reforming petroleum hydrocarbons with catalysts promoted with gallium and rhenium
GB1491499A (en) Process and catalyst for conversion of carbon monoxide and steam to hydrogen and carbon dioxide
CA2017658A1 (en) Multizone catalytic reforming process with a plurality of catalysts
MX160131A (en) IMPROVED PROCEDURE FOR PREPARING RIMANTADINE
FR2352771A2 (en) Dehydrogenating hydrocarbons - using nonacidic multimetallic catalytic composite
EP0244338A3 (en) Steam reforming catalyst
ES8203791A1 (en) Catalytic process for producing hydrogen.
CA2129798A1 (en) Process for the catalytic partial oxidation of hydrocarbons
AU476124B2 (en) Process for the production of hydrogen-rich gas from carbon monoxide and hydrogen-containing gases
JPS5511555A (en) Isomerization of diacetoxybutene
FR2364877A1 (en) Ethane and propane prodn. - by hydrogenolysis of higher hydrocarbon cpds. on noble metal catalyst
JPS5691844A (en) Catalyst for steam-reforming reaction of hydrocarbon
NL7411008A (en) Regeneration of catalysts contg. iridium and halogen - by separately contacting with gases contg. oxygen, hydrogen and halogen
FR2234922A1 (en) Hydrocarbon-conversion (esp. reforming) catalysts - contg. platinum, ruthenium and manganese or rhenium

Legal Events

Date Code Title Description
CL Concession to grant licences
ST Notification of lapse