FR2364892A1 - Isomeres de bis-benzaldimines de di(p-aminocyclohexyl) methane - Google Patents

Isomeres de bis-benzaldimines de di(p-aminocyclohexyl) methane

Info

Publication number
FR2364892A1
FR2364892A1 FR7801198A FR7801198A FR2364892A1 FR 2364892 A1 FR2364892 A1 FR 2364892A1 FR 7801198 A FR7801198 A FR 7801198A FR 7801198 A FR7801198 A FR 7801198A FR 2364892 A1 FR2364892 A1 FR 2364892A1
Authority
FR
France
Prior art keywords
isomers
benzaldimine
aminocyclohexyl
methane bis
cis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7801198A
Other languages
English (en)
Other versions
FR2364892B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pharmacia and Upjohn Co
Original Assignee
Upjohn Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Upjohn Co filed Critical Upjohn Co
Publication of FR2364892A1 publication Critical patent/FR2364892A1/fr
Application granted granted Critical
Publication of FR2364892B1 publication Critical patent/FR2364892B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/33—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C07C211/34—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings of a saturated carbon skeleton
    • C07C211/36—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings of a saturated carbon skeleton containing at least two amino groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
    • C07C211/16—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of a saturated carbon skeleton containing rings other than six-membered aromatic rings
    • C07C211/18—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of a saturated carbon skeleton containing rings other than six-membered aromatic rings containing at least two amino groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/02—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups
    • C07C251/24—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to carbon atoms of six-membered aromatic rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La présente invention concerne les isomères Cis,cis, cis,trans, ou trans,trans de bis-benzaldimines du di-(p-amino-cyclohexyl) méthane de formule :
FR7801198A 1976-09-20 1978-01-17 Isomeres de bis-benzaldimines de di(p-aminocyclohexyl) methane Granted FR2364892A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/724,585 US4020104A (en) 1976-09-20 1976-09-20 Process for isomerizing cis,cis- and cis,trans-isomers of di-(p-aminocyclohexyl)methane to the corresponding trans,trans-isomer

Publications (2)

Publication Number Publication Date
FR2364892A1 true FR2364892A1 (fr) 1978-04-14
FR2364892B1 FR2364892B1 (fr) 1984-02-24

Family

ID=24911013

Family Applications (2)

Application Number Title Priority Date Filing Date
FR7728154A Granted FR2364891A1 (fr) 1976-09-20 1977-09-19 Procede d'isomerisation des stereoisomeres de diamines cycloaliphatiques
FR7801198A Granted FR2364892A1 (fr) 1976-09-20 1978-01-17 Isomeres de bis-benzaldimines de di(p-aminocyclohexyl) methane

Family Applications Before (1)

Application Number Title Priority Date Filing Date
FR7728154A Granted FR2364891A1 (fr) 1976-09-20 1977-09-19 Procede d'isomerisation des stereoisomeres de diamines cycloaliphatiques

Country Status (6)

Country Link
US (1) US4020104A (fr)
JP (2) JPS5814428B2 (fr)
DE (1) DE2741386C3 (fr)
FR (2) FR2364891A1 (fr)
GB (1) GB1555590A (fr)
NL (1) NL188470C (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63123888U (fr) * 1987-02-03 1988-08-11
US6140540A (en) * 1993-04-06 2000-10-31 Air Products And Chemicals, Inc. Hydrogenation of aromatic amines to produce their ring hydrogenated counterparts
US6121493A (en) * 1993-03-30 2000-09-19 Air Products And Chemicals, Inc. Isomerization of cyclohexylamines to produce their thermodynamic isomeric form
WO2015041262A1 (fr) * 2013-09-17 2015-03-26 三菱瓦斯化学株式会社 Procédé d'isomérisation de bis(aminométhyl)cyclohexane
ES2864167T3 (es) * 2015-03-09 2021-10-13 Mitsubishi Gas Chemical Co Método de isomerización de diaminodiciclohexilmetano
CN109535007A (zh) * 2018-11-07 2019-03-29 万华化学集团股份有限公司 一种二氨基二环己基甲烷同分异构体分离方法
WO2022009860A1 (fr) * 2020-07-08 2022-01-13 三菱瓦斯化学株式会社 Procédé d'isomérisation de diamine aliphatique, procédé de production de diisocyanate, procédé de production de polyuréthane et polyuréthane
AU2021365371A1 (en) 2020-10-19 2023-02-23 Sika Technology Ag Cycloaliphatic aldimine mixture

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2849487A (en) * 1957-05-06 1958-08-26 Dow Chemical Co Nu, nu'-alkanediylidenebis (bicyclohexyl)-4-amines
DE1593293A1 (de) * 1965-12-23 1970-07-16 Du Pont Verfahren zur Herstellung von 4,4'-Methylen-di-(cyclohexylamin)
DE2036502A1 (en) * 1970-07-23 1972-02-03 Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen Improving trans, trans isomer content - of a mixture contng isomers of bis(para-aminocyclohexyl)-propane
DE2038023A1 (en) * 1970-07-31 1972-02-03 Trans,trans - isomer sepn - from bis-(p-amino cycloheyl)-alkane mixtu
DE1768427B1 (de) * 1961-12-29 1972-03-23 Du Pont Verfahren zur Herstellung eines im Gleichgewicht oder nahezu im Gleichgewicht befindlichen Isomerengemisches von Bis-(p-aminocyclohexyl)-methan aus einem Stereoisomeren oder einem nicht im Gleichgewicht befindlichen Isomerengemisch
DE2301106A1 (de) * 1972-01-10 1973-07-19 Du Pont Verfahren, um ein gemisch, das eines oder mehrere der stereoisomeren von bis(4-aminocyclohexyl)-methan in der form der 1:1-salze einer dicarbonsaeure in von den gleichgewichtskonzentrationen abweichenden konzentrationen enthaelt, naeher an die gleichgewichtskonzentrationen zu bringen
DE2218647A1 (de) * 1972-04-18 1973-10-25 Thomae Gmbh Dr K Neues verfahren zur herstellung von n-(trans-4-hydroxy-cyclohexyl)-(2-amino3,5-dibrom-benzyl)-amin

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB725875A (en) * 1952-05-29 1955-03-09 Rudolf Grewe Process for the manufacture of n-methyl-ª‰-cyclohexen-(1)-yl-ethylamine and intermediates for the preparation thereof
US3856862A (en) * 1973-06-25 1974-12-24 Upjohn Co Process for hydrogenation of di(4-aminophenyl)methane with a rhodium catalyst

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2849487A (en) * 1957-05-06 1958-08-26 Dow Chemical Co Nu, nu'-alkanediylidenebis (bicyclohexyl)-4-amines
DE1768427B1 (de) * 1961-12-29 1972-03-23 Du Pont Verfahren zur Herstellung eines im Gleichgewicht oder nahezu im Gleichgewicht befindlichen Isomerengemisches von Bis-(p-aminocyclohexyl)-methan aus einem Stereoisomeren oder einem nicht im Gleichgewicht befindlichen Isomerengemisch
DE1593293A1 (de) * 1965-12-23 1970-07-16 Du Pont Verfahren zur Herstellung von 4,4'-Methylen-di-(cyclohexylamin)
DE2036502A1 (en) * 1970-07-23 1972-02-03 Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen Improving trans, trans isomer content - of a mixture contng isomers of bis(para-aminocyclohexyl)-propane
DE2038023A1 (en) * 1970-07-31 1972-02-03 Trans,trans - isomer sepn - from bis-(p-amino cycloheyl)-alkane mixtu
DE2301106A1 (de) * 1972-01-10 1973-07-19 Du Pont Verfahren, um ein gemisch, das eines oder mehrere der stereoisomeren von bis(4-aminocyclohexyl)-methan in der form der 1:1-salze einer dicarbonsaeure in von den gleichgewichtskonzentrationen abweichenden konzentrationen enthaelt, naeher an die gleichgewichtskonzentrationen zu bringen
DE2218647A1 (de) * 1972-04-18 1973-10-25 Thomae Gmbh Dr K Neues verfahren zur herstellung von n-(trans-4-hydroxy-cyclohexyl)-(2-amino3,5-dibrom-benzyl)-amin

Also Published As

Publication number Publication date
JPS5814428B2 (ja) 1983-03-18
FR2364891B1 (fr) 1981-06-12
JPS5699447A (en) 1981-08-10
NL188470B (nl) 1992-02-03
DE2741386B2 (de) 1981-06-04
US4020104A (en) 1977-04-26
DE2741386C3 (de) 1982-04-08
NL188470C (nl) 1992-07-01
DE2741386A1 (de) 1978-03-30
FR2364892B1 (fr) 1984-02-24
GB1555590A (en) 1979-11-14
JPS5337649A (en) 1978-04-06
JPS5925779B2 (ja) 1984-06-21
FR2364891A1 (fr) 1978-04-14
NL7709747A (nl) 1978-03-22

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