FR2362499A1 - Electrode negative pour accumulateur electrique et son procede de realisation - Google Patents

Electrode negative pour accumulateur electrique et son procede de realisation

Info

Publication number
FR2362499A1
FR2362499A1 FR7725156A FR7725156A FR2362499A1 FR 2362499 A1 FR2362499 A1 FR 2362499A1 FR 7725156 A FR7725156 A FR 7725156A FR 7725156 A FR7725156 A FR 7725156A FR 2362499 A1 FR2362499 A1 FR 2362499A1
Authority
FR
France
Prior art keywords
negative electrode
construction process
electric accumulator
lithium
alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7725156A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boeing North American Inc
Original Assignee
Rockwell International Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rockwell International Corp filed Critical Rockwell International Corp
Publication of FR2362499A1 publication Critical patent/FR2362499A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0438—Processes of manufacture in general by electrochemical processing
    • H01M4/0459—Electrochemical doping, intercalation, occlusion or alloying
    • H01M4/0461—Electrochemical alloying
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/40—Alloys based on alkali metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H01M4/72—Grids
    • H01M4/74—Meshes or woven material; Expanded metal
    • H01M4/745—Expanded metal
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H01M4/80—Porous plates, e.g. sintered carriers
    • H01M4/806—Nonwoven fibrous fabric containing only fibres
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0048—Molten electrolytes used at high temperature
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0483—Processes of manufacture in general by methods including the handling of a melt
    • H01M4/0485—Casting
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/40—Alloys based on alkali metals
    • H01M4/405—Alloys based on lithium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/661—Metal or alloys, e.g. alloy coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/669—Steels
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H01M4/72—Grids
    • H01M4/74—Meshes or woven material; Expanded metal
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H01M4/75—Wires, rods or strips
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H01M4/76—Containers for holding the active material, e.g. tubes, capsules
    • H01M4/762—Porous or perforated metallic containers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H01M4/80—Porous plates, e.g. sintered carriers
    • H01M4/808—Foamed, spongy materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

L'invention concerne une électrode négative composite contenant du lithium. Elle se rapporte à une électrode négative comprenant un support collecteur de courant portant un alliage de lithium, de silicium et de fer, à l'état chargé, cet alliage ayant la formule Lix SiFey , x étant compris entre 1 et 5 et y entre 0,125 et 1. Application à la réalisation d'accumulateurs électriques à électrodes de lithium.
FR7725156A 1976-08-18 1977-08-17 Electrode negative pour accumulateur electrique et son procede de realisation Withdrawn FR2362499A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/715,358 US4048395A (en) 1976-08-18 1976-08-18 Lithium electrode for electrical energy storage device

Publications (1)

Publication Number Publication Date
FR2362499A1 true FR2362499A1 (fr) 1978-03-17

Family

ID=24873707

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7725156A Withdrawn FR2362499A1 (fr) 1976-08-18 1977-08-17 Electrode negative pour accumulateur electrique et son procede de realisation

Country Status (8)

Country Link
US (2) US4048395A (fr)
JP (1) JPS5324535A (fr)
CA (1) CA1077560A (fr)
DE (1) DE2737341A1 (fr)
FR (1) FR2362499A1 (fr)
GB (1) GB1525214A (fr)
IT (1) IT1079834B (fr)
SE (1) SE7708679L (fr)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4158720A (en) * 1977-12-28 1979-06-19 The United States Of America As Represented By The United States Department Of Energy Lithium-aluminum-iron electrode composition
US4221849A (en) * 1979-04-27 1980-09-09 Catalyst Research Corporation Iron-lithium anode for thermal batteries and thermal batteries made therefrom
DE3222675A1 (de) * 1981-06-26 1983-01-13 Mine Safety Appliances Co., Ltd., Glasgow, Schottland Thermozelle und elektrische batterie aus thermozellen
FR2541825B1 (fr) * 1983-02-28 1986-02-28 Comp Generale Electricite Electrode pour generateur electrochimique secondaire, son procede de fabrication et generateur comportant une telle electrode
DE3483234D1 (de) * 1983-03-07 1990-10-25 Matsushita Electric Ind Co Ltd Wiederaufladbares elektrochemisches geraet und negativer pol hierfuer.
DE3483244D1 (de) * 1983-03-07 1990-10-25 Matsushita Electric Ind Co Ltd Aufladbare elektrochemische vorrichtung und negativer pol dazu.
US4632889A (en) * 1985-07-02 1986-12-30 The United States Of America As Represented By The Secretary Of The Navy Lithium composite anode
US4626335A (en) * 1985-08-26 1986-12-02 Eagle-Picher Industries, Inc. Lithium alloy anode for thermal cells
US4708917A (en) * 1985-12-23 1987-11-24 International Fuel Cells Corporation Molten carbonate cathodes and method of fabricating
US4950566A (en) * 1988-10-24 1990-08-21 Huggins Robert A Metal silicide electrode in lithium cells
US5278005A (en) * 1992-04-06 1994-01-11 Advanced Energy Technologies Inc. Electrochemical cell comprising dispersion alloy anode
EP0690517B1 (fr) * 1994-05-30 2003-10-01 Canon Kabushiki Kaisha Pile au lithium rechargeable
JP3713900B2 (ja) * 1996-07-19 2005-11-09 ソニー株式会社 負極材料及びこれを用いた非水電解液二次電池
US6203944B1 (en) 1998-03-26 2001-03-20 3M Innovative Properties Company Electrode for a lithium battery
US6255017B1 (en) 1998-07-10 2001-07-03 3M Innovative Properties Co. Electrode material and compositions including same
EP1028476A4 (fr) * 1998-09-08 2007-11-28 Sumitomo Metal Ind Matiere d'electrode negative pour accumulateur secondaire a electrode non aqueuse et procede de production de celle-ci
EP1043789B1 (fr) * 1998-10-22 2013-01-23 Panasonic Corporation Accumulateur a electrolyte non aqueux
AU2961600A (en) 1999-01-08 2000-07-24 Massachusetts Institute Of Technology Electroactive material for secondary batteries and methods of preparation
US6428933B1 (en) 1999-04-01 2002-08-06 3M Innovative Properties Company Lithium ion batteries with improved resistance to sustained self-heating
JP4666854B2 (ja) * 1999-07-01 2011-04-06 パナソニック株式会社 非水電解質二次電池
EP2278643B1 (fr) 2001-12-21 2018-03-28 Massachusetts Institute of Technology (MIT) Électrode conductrice de stockage de lithium
US7842420B2 (en) 2005-02-03 2010-11-30 A123 Systems, Inc. Electrode material with enhanced ionic transport properties
US20100288077A1 (en) * 2009-05-14 2010-11-18 3M Innovative Properties Company Method of making an alloy
US8287772B2 (en) 2009-05-14 2012-10-16 3M Innovative Properties Company Low energy milling method, low crystallinity alloy, and negative electrode composition
KR101209687B1 (ko) * 2010-12-03 2012-12-10 기아자동차주식회사 리튬이온-유황배터리
CN102881862B (zh) 2011-07-12 2015-03-25 中国科学院上海硅酸盐研究所 保护性金属阳极结构及其制备方法
EP2690685A1 (fr) * 2012-07-24 2014-01-29 General Electric Company Cathode pour batterie d'halogénure sodium-métal, batterie la comprenant, procédés de préparation et leur utilisation
JP6847667B2 (ja) * 2015-01-28 2021-03-24 三洋電機株式会社 非水電解質二次電池用負極活物質及び非水電解質二次電池
FR3087945B1 (fr) * 2018-10-29 2021-12-17 Commissariat Energie Atomique Accumulateur electrochimique au lithium du type lithium-soufre comprenant un materiau d'electrode negative specifique
CN114824512B (zh) * 2022-04-13 2024-02-02 华中科技大学 一种基于置换反应的钠基液态金属电池及其制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1901407A (en) * 1930-06-06 1933-03-14 Osborg Hans Electrolytic process for producing alloys of lithium
DE1151129B (de) * 1958-05-29 1963-07-04 Nobel Bozel S A Verfahren zur elektrothermischen Herstellung von Silicium-Calcium-Legierungen mit einem Eisengehalt unter 7%
US3503857A (en) * 1967-04-24 1970-03-31 Union Carbide Corp Method for producing magnesium ferrosilicon
FR2287781A1 (fr) * 1974-10-07 1976-05-07 Rockwell International Corp Electrode de lithium pour accumulateur electrique
US3969139A (en) * 1974-10-07 1976-07-13 Rockwell International Corporation Lithium electrode and an electrical energy storage device containing the same
US4003753A (en) * 1976-03-15 1977-01-18 Rockwell International Corporation Electrode structure for electrical energy storage device

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2786809A (en) * 1953-09-30 1957-03-26 Horizons Titanium Corp Electrolytic cladding
US3489659A (en) * 1967-07-03 1970-01-13 Gen Electric Process for lithiding
US3881951A (en) * 1974-07-05 1975-05-06 Rockwell International Corp Lithium electrode and method of producing the same
US3933520A (en) * 1975-04-03 1976-01-20 The United States Of America As Represented By The United States Energy Research And Development Administration Method of preparing electrodes with porous current collector structures and solid reactants for secondary electrochemical cells

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1901407A (en) * 1930-06-06 1933-03-14 Osborg Hans Electrolytic process for producing alloys of lithium
DE1151129B (de) * 1958-05-29 1963-07-04 Nobel Bozel S A Verfahren zur elektrothermischen Herstellung von Silicium-Calcium-Legierungen mit einem Eisengehalt unter 7%
US3503857A (en) * 1967-04-24 1970-03-31 Union Carbide Corp Method for producing magnesium ferrosilicon
FR2287781A1 (fr) * 1974-10-07 1976-05-07 Rockwell International Corp Electrode de lithium pour accumulateur electrique
US3969139A (en) * 1974-10-07 1976-07-13 Rockwell International Corporation Lithium electrode and an electrical energy storage device containing the same
US4003753A (en) * 1976-03-15 1977-01-18 Rockwell International Corporation Electrode structure for electrical energy storage device

Also Published As

Publication number Publication date
CA1077560A (fr) 1980-05-13
SE7708679L (sv) 1978-02-19
US4069111A (en) 1978-01-17
GB1525214A (en) 1978-09-20
JPS5324535A (en) 1978-03-07
US4048395A (en) 1977-09-13
IT1079834B (it) 1985-05-13
DE2737341A1 (de) 1978-02-23

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