FR2360543A1 - PROCESS FOR THE PREPARATION OF ALLYL ALCOHOLS AND CATALYST FOR ITS IMPLEMENTATION - Google Patents

PROCESS FOR THE PREPARATION OF ALLYL ALCOHOLS AND CATALYST FOR ITS IMPLEMENTATION

Info

Publication number
FR2360543A1
FR2360543A1 FR7723281A FR7723281A FR2360543A1 FR 2360543 A1 FR2360543 A1 FR 2360543A1 FR 7723281 A FR7723281 A FR 7723281A FR 7723281 A FR7723281 A FR 7723281A FR 2360543 A1 FR2360543 A1 FR 2360543A1
Authority
FR
France
Prior art keywords
catalyst
implementation
preparation
allyl alcohols
silver
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7723281A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Corp
Original Assignee
Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/710,947 external-priority patent/US4096193A/en
Priority claimed from US05/714,057 external-priority patent/US4072727A/en
Application filed by Celanese Corp filed Critical Celanese Corp
Publication of FR2360543A1 publication Critical patent/FR2360543A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention a pour objet un procédé d'hydrogénation pour convertir des composés carbonyliques à insaturation alpha , beta -oléfinique en les alcools allyliques correspondants en présence de nouveaux catalyseurs à base d'alliage argent-cadmium et d'alliage argent-cadmium-zinc. L'acroléine est hydrogénée en alcool allylique avec une conversion de 100 % et un rendement de 70 %.The invention relates to a hydrogenation process for converting carbonyl compounds with alpha, beta-olefinic unsaturation into the corresponding allyl alcohols in the presence of new catalysts based on silver-cadmium alloy and silver-cadmium-zinc alloy. . Acrolein is hydrogenated to allyl alcohol with a conversion of 100% and a yield of 70%.

FR7723281A 1976-08-02 1977-07-28 PROCESS FOR THE PREPARATION OF ALLYL ALCOHOLS AND CATALYST FOR ITS IMPLEMENTATION Withdrawn FR2360543A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US05/710,947 US4096193A (en) 1976-08-02 1976-08-02 Production of alpha beta olefinically unsaturated alcohols
US71420176A 1976-08-13 1976-08-13
US05/714,057 US4072727A (en) 1976-08-13 1976-08-13 Silver-cadmium-zinc alloy catalyst for hydrogenation of acrolein to allyl alcohol

Publications (1)

Publication Number Publication Date
FR2360543A1 true FR2360543A1 (en) 1978-03-03

Family

ID=27418881

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7723281A Withdrawn FR2360543A1 (en) 1976-08-02 1977-07-28 PROCESS FOR THE PREPARATION OF ALLYL ALCOHOLS AND CATALYST FOR ITS IMPLEMENTATION

Country Status (8)

Country Link
JP (1) JPS5318506A (en)
CA (1) CA1087597A (en)
DE (1) DE2734811A1 (en)
FR (1) FR2360543A1 (en)
GB (2) GB1549084A (en)
IT (1) IT1086349B (en)
MX (1) MX144402A (en)
NL (1) NL7708266A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19819396C2 (en) * 1998-04-30 2002-02-14 Kataleuna Gmbh Catalysts Catalyst for the selective hydrogenation of unsaturated alcohols, its production and use

Also Published As

Publication number Publication date
MX144402A (en) 1981-10-08
CA1087597A (en) 1980-10-14
DE2734811A1 (en) 1978-02-09
GB1549085A (en) 1979-08-01
GB1549084A (en) 1979-08-01
IT1086349B (en) 1985-05-28
JPS5318506A (en) 1978-02-20
NL7708266A (en) 1978-02-06

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Legal Events

Date Code Title Description
ST Notification of lapse