FR2359192A1 - OLEOSOLUBLE COMPOUNDS OF CERIUM, THEIR PREPARATION PROCESS AND THEIR APPLICATION AS SICCATING AGENTS OR COMBUSTION ADDITIVES - Google Patents
OLEOSOLUBLE COMPOUNDS OF CERIUM, THEIR PREPARATION PROCESS AND THEIR APPLICATION AS SICCATING AGENTS OR COMBUSTION ADDITIVESInfo
- Publication number
- FR2359192A1 FR2359192A1 FR7622426A FR7622426A FR2359192A1 FR 2359192 A1 FR2359192 A1 FR 2359192A1 FR 7622426 A FR7622426 A FR 7622426A FR 7622426 A FR7622426 A FR 7622426A FR 2359192 A1 FR2359192 A1 FR 2359192A1
- Authority
- FR
- France
- Prior art keywords
- cerium
- compounds
- acid
- agents
- siccating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 title abstract 5
- 229910052684 Cerium Inorganic materials 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 title abstract 3
- 238000002485 combustion reaction Methods 0.000 title abstract 2
- 239000000654 additive Substances 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- 239000002253 acid Substances 0.000 abstract 4
- 150000003839 salts Chemical class 0.000 abstract 2
- 150000001785 cerium compounds Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000002274 desiccant Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 239000002966 varnish Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/12—Straight chain carboxylic acids containing eighteen carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/003—Compounds containing elements of Groups 3 or 13 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F9/00—Compounds to be used as driers, i.e. siccatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
- C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/26—Organic compounds containing phosphorus
- C10L1/2633—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond)
- C10L1/2641—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond) oxygen bonds only
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Combustion & Propulsion (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Paints Or Removers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Lubricants (AREA)
Abstract
La présente invention concerne de nouveaux composés oléosolubles du cérium. Selon l'invention, ces composés sont des sels d'acide organique ou organométalloïdique du cérium dans lesquels le rapport du nombre d'équivalents d'acide présents dans la molécule du sel au nombre d'atomes de cérium est inférieur à 3. On les prépare en faisant réagir à chaud, en milieu organique ou hydroorganique, l'acide et l'hydroxyde de cérium III fraîchement prepare, le rapport des nombres d'équivalents d'acide au nombre d'atomes de cérium étant inférieur à 3 dans le mélange réactionnel. Les composés selon l'invention sont utiles en tant qu'agents siccatifs pour peintures et vernis et en tant qu'adjuvants de combustion.The present invention relates to novel oil-soluble cerium compounds. According to the invention, these compounds are organic or organometalloidic acid salts of cerium in which the ratio of the number of acid equivalents present in the salt molecule to the number of cerium atoms is less than 3. They are prepares by reacting under hot conditions, in an organic or hydroorganic medium, the acid and the hydroxide of freshly prepared cerium III, the ratio of the number of equivalents of acid to the number of cerium atoms being less than 3 in the mixture reaction. The compounds according to the invention are useful as drying agents for paints and varnishes and as combustion aids.
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7622426A FR2359192A1 (en) | 1976-07-22 | 1976-07-22 | OLEOSOLUBLE COMPOUNDS OF CERIUM, THEIR PREPARATION PROCESS AND THEIR APPLICATION AS SICCATING AGENTS OR COMBUSTION ADDITIVES |
GB2643577A GB1571210A (en) | 1976-07-22 | 1977-06-23 | Cerium compounds method of obtaining said compounds and applications thereof |
DE19772729365 DE2729365A1 (en) | 1976-07-22 | 1977-06-29 | OIL-SOLUBLE CERIUM COMPOUNDS, PROCESS FOR PREPARATION OF THE SAME AND APPLICATION OF THESE COMPOUNDS AS DRYING MATERIALS OR COMBUSTION AID |
IT2522577A IT1202371B (en) | 1976-07-22 | 1977-06-30 | OIL SOLUBLE CERIO COMPOUNDS, THEIR PREPARATION PROCEDURE AND THEIR APPLICATION AS DRYING AGENTS OR COMBUSTION ADJUVANTS |
NL7707497A NL7707497A (en) | 1976-07-22 | 1977-07-06 | METHOD OF PREPARING OIL SOLUBLE CERIUM COMPOUNDS AND THEIR USE AS A SICCATIVE OR COMBUSTION ADDITION. |
AU26951/77A AU518590B2 (en) | 1976-07-22 | 1977-07-12 | Basic oil soluble cerium soaps |
JP8615377A JPS5312907A (en) | 1976-07-22 | 1977-07-20 | Basic* oillsoluble cerium soap and preparation |
BE179482A BE856974A (en) | 1976-07-22 | 1977-07-20 | OLEOSOLUBLE COMPOUNDS OF CERIUM, THEIR PROCESS OF PREPARATION AND THEIR APPLICATION AS SICCATING AGENTS OR COMBUSTION ADDITIVES. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7622426A FR2359192A1 (en) | 1976-07-22 | 1976-07-22 | OLEOSOLUBLE COMPOUNDS OF CERIUM, THEIR PREPARATION PROCESS AND THEIR APPLICATION AS SICCATING AGENTS OR COMBUSTION ADDITIVES |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2359192A1 true FR2359192A1 (en) | 1978-02-17 |
FR2359192B1 FR2359192B1 (en) | 1981-10-30 |
Family
ID=9176026
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7622426A Granted FR2359192A1 (en) | 1976-07-22 | 1976-07-22 | OLEOSOLUBLE COMPOUNDS OF CERIUM, THEIR PREPARATION PROCESS AND THEIR APPLICATION AS SICCATING AGENTS OR COMBUSTION ADDITIVES |
Country Status (8)
Country | Link |
---|---|
JP (1) | JPS5312907A (en) |
AU (1) | AU518590B2 (en) |
BE (1) | BE856974A (en) |
DE (1) | DE2729365A1 (en) |
FR (1) | FR2359192A1 (en) |
GB (1) | GB1571210A (en) |
IT (1) | IT1202371B (en) |
NL (1) | NL7707497A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0043326A2 (en) * | 1980-07-01 | 1982-01-06 | Gamlen Europe S.A. | Manganese salts soluble in organic solvents, process for their preparation, organic compositions, liquid fuels, paints, and varnishes containing the aforesaid salts |
EP0097563A1 (en) * | 1982-06-11 | 1984-01-04 | Rhone-Poulenc Specialites Chimiques | Process for the preparation of colloidal dispersions of cerium dioxide in organic liquids |
FR2537593A1 (en) * | 1982-12-10 | 1984-06-15 | Raffinage Cie Francaise | MIXED ORGANOMETALLIC COMPOSITIONS COMPRISING ELEMENTS OF IRON GROUPS AND LANTHANIDES, PROCESS FOR THE PREPARATION AND APPLICATION OF SAID COMPOSITIONS AS ADDITIVES FOR FUELS OR FUELS |
EP0134146A2 (en) * | 1983-08-17 | 1985-03-13 | Exxon Research And Engineering Company | Residual fuel oil composition |
EP0194369A1 (en) * | 1983-11-18 | 1986-09-17 | Texaco Development Corporation | Diesel fuel containing rare earth metal and oxygenated compounds |
FR2583761A1 (en) * | 1985-06-20 | 1986-12-26 | Rhone Poulenc Spec Chim | Process for the preparation of a colloidal dispersion of a metal cation compound in an organic medium and the sols obtained. |
EP0261002A1 (en) * | 1986-09-19 | 1988-03-23 | Rhone-Poulenc Chimie | Use of composition with rare earth metals to stabilize diesel engine fuel |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE14211T1 (en) * | 1982-04-12 | 1985-07-15 | Rhone Poulenc Spec Chim | PROCESS FOR THE PREPARATION OF CERIUMCARBOXYLATES. |
US4464227A (en) * | 1982-09-16 | 1984-08-07 | At&T Technologies, Inc. | Methods and apparatus for distilling a contaminated solvent |
DE3245882A1 (en) * | 1982-12-11 | 1984-06-14 | Ruhrchemie Ag, 4200 Oberhausen | Process for improving the combustion of liquid fuels |
GB2160527B (en) * | 1984-05-25 | 1988-02-17 | Kao Corp | Metal salts of phoshate monoesters |
US4670020A (en) * | 1984-12-24 | 1987-06-02 | Ford Motor Company | Carbon ignition temperature depressing agent and method of regenerating an automotive particulate trap utilizing said agent |
JPH02182783A (en) * | 1989-01-09 | 1990-07-17 | Nippon Mining Co Ltd | Combustion of fuel with high residual carbon content |
FR2911607B1 (en) * | 2007-01-23 | 2012-06-22 | Rhodia Recherches & Tech | PROCESS FOR PREPARING A SOLUTION OF A RARE EARTH ORGANOPHOSPHATE |
EP2809437B1 (en) * | 2012-01-30 | 2018-03-28 | Cerion LLC | Improved method for production of stable cerium oxide organic colloids |
US20130192122A1 (en) | 2012-01-30 | 2013-08-01 | Cerion Technology, Inc. | Rapid method for production of cerium-containing oxide organic colloids |
WO2024003254A1 (en) * | 2022-06-30 | 2024-01-04 | Umicore Specialty Materials Brugge | Fuel borne catalyst composition for oxidative soot removal |
-
1976
- 1976-07-22 FR FR7622426A patent/FR2359192A1/en active Granted
-
1977
- 1977-06-23 GB GB2643577A patent/GB1571210A/en not_active Expired
- 1977-06-29 DE DE19772729365 patent/DE2729365A1/en not_active Ceased
- 1977-06-30 IT IT2522577A patent/IT1202371B/en active
- 1977-07-06 NL NL7707497A patent/NL7707497A/en not_active Application Discontinuation
- 1977-07-12 AU AU26951/77A patent/AU518590B2/en not_active Expired
- 1977-07-20 BE BE179482A patent/BE856974A/en not_active IP Right Cessation
- 1977-07-20 JP JP8615377A patent/JPS5312907A/en active Pending
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0043326A2 (en) * | 1980-07-01 | 1982-01-06 | Gamlen Europe S.A. | Manganese salts soluble in organic solvents, process for their preparation, organic compositions, liquid fuels, paints, and varnishes containing the aforesaid salts |
EP0043326A3 (en) * | 1980-07-01 | 1982-01-13 | Gamlen Europe S.A. | Manganese salts soluble in organic solvents, process for their preparation, organic compositions, liquid fuels, paints, and varnishes containing the aforesaid salts |
EP0097563A1 (en) * | 1982-06-11 | 1984-01-04 | Rhone-Poulenc Specialites Chimiques | Process for the preparation of colloidal dispersions of cerium dioxide in organic liquids |
FR2537593A1 (en) * | 1982-12-10 | 1984-06-15 | Raffinage Cie Francaise | MIXED ORGANOMETALLIC COMPOSITIONS COMPRISING ELEMENTS OF IRON GROUPS AND LANTHANIDES, PROCESS FOR THE PREPARATION AND APPLICATION OF SAID COMPOSITIONS AS ADDITIVES FOR FUELS OR FUELS |
EP0112219A1 (en) * | 1982-12-10 | 1984-06-27 | COMPAGNIE FRANCAISE DE RAFFINAGE Société anonyme dite: | Compositions of organometal mixtures containing elements of the lanthanide group and the manganese or iron group, process for their preparation and their use as combustible and motor fuel additives |
US4568360A (en) * | 1982-12-10 | 1986-02-04 | Compagnie Francaise De Raffinage | Mixed organometallic compositions comprising elements from the lanthanide group and manganese or elements from the iron group, process for the preparation of said compositions, and their use as fuel additives |
EP0134146A2 (en) * | 1983-08-17 | 1985-03-13 | Exxon Research And Engineering Company | Residual fuel oil composition |
EP0134146A3 (en) * | 1983-08-17 | 1985-04-24 | Exxon Research And Engineering Company | Residual fuel oil composition |
EP0194369A1 (en) * | 1983-11-18 | 1986-09-17 | Texaco Development Corporation | Diesel fuel containing rare earth metal and oxygenated compounds |
FR2583761A1 (en) * | 1985-06-20 | 1986-12-26 | Rhone Poulenc Spec Chim | Process for the preparation of a colloidal dispersion of a metal cation compound in an organic medium and the sols obtained. |
EP0206907A1 (en) * | 1985-06-20 | 1986-12-30 | Rhone-Poulenc Chimie | Process for the preparation of a colloidal dispersion of a metallic cation compound in an organic solvent and the sols obtained |
EP0261002A1 (en) * | 1986-09-19 | 1988-03-23 | Rhone-Poulenc Chimie | Use of composition with rare earth metals to stabilize diesel engine fuel |
Also Published As
Publication number | Publication date |
---|---|
BE856974A (en) | 1977-11-14 |
GB1571210A (en) | 1980-07-09 |
DE2729365A1 (en) | 1978-03-09 |
AU2695177A (en) | 1979-01-18 |
IT1202371B (en) | 1989-02-09 |
FR2359192B1 (en) | 1981-10-30 |
NL7707497A (en) | 1978-01-24 |
AU518590B2 (en) | 1981-10-08 |
JPS5312907A (en) | 1978-02-06 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
CA | Change of address | ||
CD | Change of name or company name |