FR2352834A1 - Initiateurs de polymerisation anionique a base d'amidures alcalins et procede de polymerisation anionique les utilisant - Google Patents
Initiateurs de polymerisation anionique a base d'amidures alcalins et procede de polymerisation anionique les utilisantInfo
- Publication number
- FR2352834A1 FR2352834A1 FR7715717A FR7715717A FR2352834A1 FR 2352834 A1 FR2352834 A1 FR 2352834A1 FR 7715717 A FR7715717 A FR 7715717A FR 7715717 A FR7715717 A FR 7715717A FR 2352834 A1 FR2352834 A1 FR 2352834A1
- Authority
- FR
- France
- Prior art keywords
- alkali
- heterocyclic
- vinyl
- diene monomers
- alkali metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 125000000623 heterocyclic group Chemical group 0.000 title abstract 3
- 239000003999 initiator Substances 0.000 title abstract 3
- 239000003513 alkali Substances 0.000 title abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 title abstract 2
- 125000000129 anionic group Chemical group 0.000 title abstract 2
- 150000001993 dienes Chemical class 0.000 title abstract 2
- 125000002887 hydroxy group Chemical class [H]O* 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 title abstract 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title abstract 2
- 229920002554 vinyl polymer Polymers 0.000 title abstract 2
- -1 alkali metal salts Chemical class 0.000 title 1
- 150000001412 amines Chemical class 0.000 title 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 239000000010 aprotic solvent Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/06—Preparatory processes
- C08G77/08—Preparatory processes characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/08—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkali metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/02—Aliphatic polycarbonates
- C08G64/0208—Aliphatic polycarbonates saturated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/30—General preparatory processes using carbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/08—Saturated oxiranes
- C08G65/10—Saturated oxiranes characterised by the catalysts used
- C08G65/12—Saturated oxiranes characterised by the catalysts used containing organo-metallic compounds or metal hydrides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2648—Alkali metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
- C08G75/06—Polythioethers from cyclic thioethers
- C08G75/08—Polythioethers from cyclic thioethers from thiiranes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7715717A FR2352834A1 (fr) | 1977-05-23 | 1977-05-23 | Initiateurs de polymerisation anionique a base d'amidures alcalins et procede de polymerisation anionique les utilisant |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7715717A FR2352834A1 (fr) | 1977-05-23 | 1977-05-23 | Initiateurs de polymerisation anionique a base d'amidures alcalins et procede de polymerisation anionique les utilisant |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2352834A1 true FR2352834A1 (fr) | 1977-12-23 |
FR2352834B1 FR2352834B1 (enrdf_load_stackoverflow) | 1980-11-28 |
Family
ID=9191176
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7715717A Granted FR2352834A1 (fr) | 1977-05-23 | 1977-05-23 | Initiateurs de polymerisation anionique a base d'amidures alcalins et procede de polymerisation anionique les utilisant |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2352834A1 (enrdf_load_stackoverflow) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0002159A1 (fr) * | 1977-11-23 | 1979-05-30 | Societe Nationale Des Poudres Et Explosifs | Procédé de polymérisation anionique en masse à l'aide d'amidure d'un métal alcalin et d'un hydroxylate du même métal alcalin |
EP0007817A1 (fr) * | 1978-07-06 | 1980-02-06 | Societe Nationale Des Poudres Et Explosifs | Amorceurs de polymérisation anionique à base d'amidures alcalins et procédé de polymérisation anionique les utilisant |
EP0039299A1 (fr) * | 1980-04-29 | 1981-11-04 | Rhone-Poulenc Specialites Chimiques | Procédé d'obtention de polysiloxanes de masses moléculaires élevées par polymérisation et réarrangement de polysiloxanes en présence de catalyseur alcalin et de tris (oxaalkyl)amine |
EP0236862A3 (en) * | 1986-03-07 | 1989-03-29 | Bayer Ag | Process for preparing linear aliphatic polycarbonates |
-
1977
- 1977-05-23 FR FR7715717A patent/FR2352834A1/fr active Granted
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0002159A1 (fr) * | 1977-11-23 | 1979-05-30 | Societe Nationale Des Poudres Et Explosifs | Procédé de polymérisation anionique en masse à l'aide d'amidure d'un métal alcalin et d'un hydroxylate du même métal alcalin |
EP0007817A1 (fr) * | 1978-07-06 | 1980-02-06 | Societe Nationale Des Poudres Et Explosifs | Amorceurs de polymérisation anionique à base d'amidures alcalins et procédé de polymérisation anionique les utilisant |
EP0039299A1 (fr) * | 1980-04-29 | 1981-11-04 | Rhone-Poulenc Specialites Chimiques | Procédé d'obtention de polysiloxanes de masses moléculaires élevées par polymérisation et réarrangement de polysiloxanes en présence de catalyseur alcalin et de tris (oxaalkyl)amine |
EP0236862A3 (en) * | 1986-03-07 | 1989-03-29 | Bayer Ag | Process for preparing linear aliphatic polycarbonates |
Also Published As
Publication number | Publication date |
---|---|
FR2352834B1 (enrdf_load_stackoverflow) | 1980-11-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
FR2665450B1 (fr) | Procede de preparation de dispersions aqueuses de copolymeres. | |
DE2861066D1 (en) | Water-soluble copolymers based on ethylenically unsaturated monomers; process for preparing these copolymers and their use | |
JPS5346389A (en) | Preparation of self-crosslinking polymer of acrylic alkali metal salt | |
FR2311046A1 (fr) | Electro-deposition de dispersions aqueuses de copolymeres de produits d'addition d'epoxy-amine polyethyleniquement insatures | |
NL7603184A (nl) | Werkwijze voor het polymeriseren van een mono- meer van het norborneentype. | |
IT1062554B (it) | Metodo per la polimerizzazione di monomeri etilenicamente insaturi | |
FR2352834A1 (fr) | Initiateurs de polymerisation anionique a base d'amidures alcalins et procede de polymerisation anionique les utilisant | |
IT7819557A0 (it) | Metodo per la polimerizzazione di un monomero di vinile ovvero di una miscela di monomeri di vinile. | |
GB1494673A (en) | Process for production of polymers | |
NL7711670A (nl) | Werkwijze voor de vrijeradicaalpolymerisatie van vinylmonomeren. | |
NL7710246A (nl) | Werkwijze voor de vrijeradicaalpolymerisatie van vinylmonomeren. | |
NL7713366A (nl) | Werkwijze voor de vrijeradicaalpolymerisatie van vinylmonomeren. | |
ES459105A1 (es) | Procedimiento de polimerizacion o copolimerizacion de mono- meros vinilicos heterociclicos o dienos susceptibles de po- limerizar anionicamente. | |
GB1265359A (enrdf_load_stackoverflow) | ||
JPS534967A (en) | Method for controlling operation of robot | |
SE7706131L (sv) | Sett att ympa vinylklorid pa eten-vinylacetat- eller alkylakrylatsampolymerisat | |
IL48145A0 (en) | Method for removing unreacted monomers from aqueous dispersions of polymerizate | |
AU515872B2 (en) | Initiator system for ethylenically unsaturated monomers | |
ZA78379B (en) | Method for the polymerization of vinyl monomers | |
GB1077956A (en) | Vinyl acetate copolymers | |
JPS57170693A (en) | Stereo speaker device for acoustic apparatus | |
JPS5432899B2 (enrdf_load_stackoverflow) | ||
JPS51125167A (en) | Preparation of improved aqueous polymer emulsion | |
JPS5432250A (en) | Pulse generator of wide range | |
JPS53128851A (en) | Positioning controller of robot for industry |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |