FR2348153A1 - Synthetic alumino-silicate zeolites - contg. organic nitrogen cations derived from choline or pyrrolidine, and used for catalytic cracking - Google Patents

Synthetic alumino-silicate zeolites - contg. organic nitrogen cations derived from choline or pyrrolidine, and used for catalytic cracking

Info

Publication number
FR2348153A1
FR2348153A1 FR7610786A FR7610786A FR2348153A1 FR 2348153 A1 FR2348153 A1 FR 2348153A1 FR 7610786 A FR7610786 A FR 7610786A FR 7610786 A FR7610786 A FR 7610786A FR 2348153 A1 FR2348153 A1 FR 2348153A1
Authority
FR
France
Prior art keywords
choline
pyrrolidine
contg
angstrom
catalytic cracking
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7610786A
Other languages
French (fr)
Other versions
FR2348153B1 (en
Inventor
Mae Koenig Rubin
Charles Joseph Plank
Edward Joseph Rosinski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Priority to FR7610786A priority Critical patent/FR2348153A1/en
Publication of FR2348153A1 publication Critical patent/FR2348153A1/en
Application granted granted Critical
Publication of FR2348153B1 publication Critical patent/FR2348153B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7011—MAZ-type, e.g. Mazzite, Omega, ZSM-4 or LZ-202
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/34—Type ZSM-4
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/38—Base treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)

Abstract

New industrial product, consisting of a synthetic crystalline alumino-silicate zeolite with molar compsn., expressed as an anhydride: 1.0 plus-or-minus 0.3 R2O/Al2O3/3-20 SiO2; where R is a mixt. of the cations of an alkali metal and cations contg. nitrogen derived from choline, a salt of choline, or pyrrolidine; and with an X-ray diffraction pattern including: inter planar space 9.1 d (angstrom) = VS; 7.94 d (angstrom) = MW; 5.97 d (angstrom) = S, where the relative intensity of the X-ray pattern is expressed as VS = very strong; MW = fairly weak; and S = strong; and further, extensive X-ray data are included in claim 1. A pref. formula is 1.0 plus-or-minus 0.3 (xM2O + 1-xR2O)/Al2O3/SiO2; where R is a radical derived from choline, one of its salts, or pyrrolidine; M is an alkali metal; and X = 0.1-0.,. A ZSM-4 zeolite pref. used for converting hydrocarbons, esp. cracking olefins and paraffins.
FR7610786A 1976-04-13 1976-04-13 Synthetic alumino-silicate zeolites - contg. organic nitrogen cations derived from choline or pyrrolidine, and used for catalytic cracking Granted FR2348153A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7610786A FR2348153A1 (en) 1976-04-13 1976-04-13 Synthetic alumino-silicate zeolites - contg. organic nitrogen cations derived from choline or pyrrolidine, and used for catalytic cracking

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7610786A FR2348153A1 (en) 1976-04-13 1976-04-13 Synthetic alumino-silicate zeolites - contg. organic nitrogen cations derived from choline or pyrrolidine, and used for catalytic cracking

Publications (2)

Publication Number Publication Date
FR2348153A1 true FR2348153A1 (en) 1977-11-10
FR2348153B1 FR2348153B1 (en) 1979-08-31

Family

ID=9171751

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7610786A Granted FR2348153A1 (en) 1976-04-13 1976-04-13 Synthetic alumino-silicate zeolites - contg. organic nitrogen cations derived from choline or pyrrolidine, and used for catalytic cracking

Country Status (1)

Country Link
FR (1) FR2348153A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0034444A2 (en) * 1980-02-14 1981-08-26 Mobil Oil Corporation Enhancement of zeolite catalytic activity
US4374296A (en) * 1980-02-14 1983-02-15 Mobil Oil Corporation Isomerization of paraffin hydrocarbons using zeolites with high steam-enhanced acidity

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0034444A2 (en) * 1980-02-14 1981-08-26 Mobil Oil Corporation Enhancement of zeolite catalytic activity
EP0034444A3 (en) * 1980-02-14 1981-11-25 Mobil Oil Corporation Enhancement of zeolite catalytic activity
US4374296A (en) * 1980-02-14 1983-02-15 Mobil Oil Corporation Isomerization of paraffin hydrocarbons using zeolites with high steam-enhanced acidity

Also Published As

Publication number Publication date
FR2348153B1 (en) 1979-08-31

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ST Notification of lapse