FR2344537A1 - N-substd. maleimide derivs. and prepn. - for prodn. of photocurable polymers - Google Patents

N-substd. maleimide derivs. and prepn. - for prodn. of photocurable polymers

Info

Publication number
FR2344537A1
FR2344537A1 FR7718933A FR7718933A FR2344537A1 FR 2344537 A1 FR2344537 A1 FR 2344537A1 FR 7718933 A FR7718933 A FR 7718933A FR 7718933 A FR7718933 A FR 7718933A FR 2344537 A1 FR2344537 A1 FR 2344537A1
Authority
FR
France
Prior art keywords
alkenyl
alkyl
oco
substd
opt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7718933A
Other languages
French (fr)
Other versions
FR2344537B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of FR2344537A1 publication Critical patent/FR2344537A1/en
Application granted granted Critical
Publication of FR2344537B1 publication Critical patent/FR2344537B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/44—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members
    • C07D207/444—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5
    • C07D207/448—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5 with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. maleimide
    • C07D207/452—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members having two doubly-bound oxygen atoms directly attached in positions 2 and 5 with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. maleimide with hydrocarbon radicals, substituted by hetero atoms, directly attached to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/44—Iso-indoles; Hydrogenated iso-indoles
    • C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C08G69/265—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from at least two different diamines or at least two different dicarboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

New imidyl cpds. have the formula (I): (in which n = 1 or 2. R1 and R1' independently are 1-4C alkyl or together an opt. Me-substd. tri- or tetra-methylene gp. Y is 1-20C alkylene, opt. contg. heteroatoms, 5 or 6C cycloalkylene, 6-10C arylene, -C6H4-Q-C6H4- (in which Q is a direct bond, NH-, -O-, -CH2-, -CMe2- or -OCO-) or 7 or 8C aralkylene or alkylarylene. If n = 1, X is -NH-CO-alkenyl, -C6H3R2R3, -C6H3(COR4)2, x = 0 or 1. A is alkenyl or (CH2)2COQ R9R8R-7Si If n = 2, X is halogen-COOH, -COOM, -COO-alkyl, -CN,-COO -alkenyl, -O-alkenyl, -OCO-alkenyl, -NH-alkyl, -NH-alkenyl, -NH-CO-alkenyl, -SH, -S-alkenyl If Y is cycloalkylene, arylene, aralkylene, alkylarylene or C6H4-Q-C6H4-, X can also be OH or NH2. R2 and R3 independently are OH or NH2. Both R4 are OH, 1-12C alkoxy, opt. substd. phenoxy, -OM or one R4 is OH and the other R4 is -O-(CH2)q-OCO-CQ1=CH2. R5 is OH, Cl, 1-12C alkoxy, opt. substd. phenoxy or -OM. Both R6 are the same as R4 or together are -O-. R7 and R8 independently are H, OH, Cl, -O-alkyl, -O-phenyl, -OCO-alkyl, -OCO-phenyl, -NH- alkyl or -N-(alkyl)2. R9 is -CH=CH2, Me, Ph or -O-SiMe3 or the same as R7 and R8; or R7 and R8 together are -(OSiMe2)m-O-. M is an alkali metal or 3-24C trialkylammonium cation. Z is linear or branched 1-12C alkylene. Q1 and Q2 are H or Me. m = 2,3 or 4 q = 2 or 3. The alkyl gps. have 1-8C and the alkylene gps 2-4C). (I) are used for the prodn. of photocurable polymers, e.g. polyesters, polyamides, polyamide-imides, polyimides, polyester-polyamides, polyesteramide-imides, polyethers, polyamines, gelatins, polysaccharides and polysiloxanes. (I) can be prepd. by reacting an amine with an anhyd; or if (Y)n-1 is 1-12C alkylene and X is an epoxy gp., by reacting an alkali metal imide with a halohydrin. E.g. 126g (1 mole) dimethylmaleic anhydride were reacted with 115g (1 mole) 4-aminocyclohexanol for 30 min. at 120-125 degrees C, giving 115g (70%) N(-4-hydroxycyclohexyl)-dimethylmaleimide.
FR7718933A 1975-06-18 1977-06-21 N-substd. maleimide derivs. and prepn. - for prodn. of photocurable polymers Granted FR2344537A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH795175A CH599153A5 (en) 1975-06-18 1975-06-18

Publications (2)

Publication Number Publication Date
FR2344537A1 true FR2344537A1 (en) 1977-10-14
FR2344537B1 FR2344537B1 (en) 1980-04-04

Family

ID=4332862

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7718933A Granted FR2344537A1 (en) 1975-06-18 1977-06-21 N-substd. maleimide derivs. and prepn. - for prodn. of photocurable polymers

Country Status (2)

Country Link
CH (1) CH599153A5 (en)
FR (1) FR2344537A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4935523A (en) * 1985-09-30 1990-06-19 The Boeing Company Crosslinking imidophenylamines
US4985568A (en) * 1985-09-30 1991-01-15 The Boeing Company Method of making crosslinking imidophenylamines
CA2212057C (en) * 1995-03-07 2007-02-13 Novartis Ag Photochemically cross-linked polysaccharide derivatives as supports for the chromatographic separation of enantiomers

Also Published As

Publication number Publication date
FR2344537B1 (en) 1980-04-04
CH599153A5 (en) 1978-05-12

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