FR2312479A1 - Procede d'alkylation ou de transalkylation en presence de catalyseur a base d'aluminosilicate cristallin - Google Patents

Procede d'alkylation ou de transalkylation en presence de catalyseur a base d'aluminosilicate cristallin

Info

Publication number
FR2312479A1
FR2312479A1 FR7615364A FR7615364A FR2312479A1 FR 2312479 A1 FR2312479 A1 FR 2312479A1 FR 7615364 A FR7615364 A FR 7615364A FR 7615364 A FR7615364 A FR 7615364A FR 2312479 A1 FR2312479 A1 FR 2312479A1
Authority
FR
France
Prior art keywords
alkylation
based catalyst
crystalline aluminosilicate
transalkylation process
transalkylation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7615364A
Other languages
English (en)
Other versions
FR2312479B1 (fr
Inventor
Werner Otto Haag
David Harold Olson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/580,864 external-priority patent/US4070407A/en
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of FR2312479A1 publication Critical patent/FR2312479A1/fr
Application granted granted Critical
Publication of FR2312479B1 publication Critical patent/FR2312479B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C01B39/445—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38 using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
FR7615364A 1975-05-27 1976-05-21 Procede d'alkylation ou de transalkylation en presence de catalyseur a base d'aluminosilicate cristallin Granted FR2312479A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/580,864 US4070407A (en) 1974-03-08 1975-05-27 Alkylation/transalkylation in presence of crystalline aluminosilicate catalyst
BE167334A BE842220A (fr) 1975-05-27 1976-05-25 Procede d'alkylation ou de transalkylation en presence de catalyseur a base d'aluminosilicate cristallin

Publications (2)

Publication Number Publication Date
FR2312479A1 true FR2312479A1 (fr) 1976-12-24
FR2312479B1 FR2312479B1 (fr) 1981-04-10

Family

ID=25649383

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7615364A Granted FR2312479A1 (fr) 1975-05-27 1976-05-21 Procede d'alkylation ou de transalkylation en presence de catalyseur a base d'aluminosilicate cristallin

Country Status (3)

Country Link
US (1) US4136128A (fr)
BE (1) BE842220A (fr)
FR (1) FR2312479A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0030084A1 (fr) * 1979-11-20 1981-06-10 Mobil Oil Corporation Procédé pour la préparation de phénylalcanes

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4899007A (en) * 1979-01-31 1990-02-06 Mobil Oil Corporation Aromatic conversion reactions with zeolitic catalyst composition of improved shape selectivity
US4302621A (en) * 1980-10-29 1981-11-24 Mobil Oil Corporation Shape selective reactions utilizing zeolites modified with Group V A metals
US4358397A (en) * 1980-10-29 1982-11-09 Mobil Oil Corporation Zeolite catalysts modified with group IV A metals
US4302620A (en) * 1980-10-29 1981-11-24 Mobil Oil Corporation Reactions involving zeolite catalysts modified with group IV A metals
US4302622A (en) * 1980-12-02 1981-11-24 Mobil Oil Corporation Shape selective reactions utilizing group III a metal-modified zeolite catalyst
US4520220A (en) * 1982-02-22 1985-05-28 Cosden Technology, Inc. Alkylation of aromatics employing silicalite catalysts
US4577050A (en) * 1983-05-02 1986-03-18 Mobil Oil Corporation ZSM-5/ZSM-12 Catalyst mixture for cracking alkylbenzenes
US4593136A (en) * 1984-06-14 1986-06-03 Mobil Oil Corporation ZSM-5/ZSM-12 catalyst mixture for cracking alkylbenzenes
US4975401A (en) * 1983-05-02 1990-12-04 Mobil Oil Corporation ZSM-5/ZSM-12 catalyst mixture for cracking alkylbenzenes
US5262576A (en) * 1989-03-23 1993-11-16 Chemical Research & Licensing Company Method for the alkylation of organic aromatic compounds
US5053573A (en) * 1990-09-14 1991-10-01 Mobil Oil Corporation Reduction of benzene content of reformate by reaction with cycle oils
US5082983A (en) * 1990-09-14 1992-01-21 Mobil Oil Corporation Reduction of benzene content of reformate in a catalytic cracking unit
USH1723H (en) * 1992-09-11 1998-04-07 Leuenberger; Ernest L. Process for producing gasoline blending components from jet range and heavier aromatics
EP0793634B1 (fr) * 1994-11-23 1999-08-18 Exxon Chemical Patents Inc. Procede de conversion d'hydrocarbures utilisant un catalyseur de zeolite a liant de zeolite
US5600048A (en) * 1994-12-27 1997-02-04 Mobil Oil Corporation Continuous process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation
US7601255B2 (en) * 2006-09-06 2009-10-13 Chemtura Corporation Process for removal of residual catalyst components
GB201615628D0 (en) * 2016-09-14 2016-10-26 Johnson Matthey Plc Production of alkylated compounds

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4070407A (en) * 1974-03-08 1978-01-24 Mobil Oil Corporation Alkylation/transalkylation in presence of crystalline aluminosilicate catalyst

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0030084A1 (fr) * 1979-11-20 1981-06-10 Mobil Oil Corporation Procédé pour la préparation de phénylalcanes

Also Published As

Publication number Publication date
US4136128A (en) 1979-01-23
BE842220A (fr) 1976-11-25
FR2312479B1 (fr) 1981-04-10

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