BE798878A - Alkylation en phase vapeur en presence d'un aluminosilicate cristallin catalytique - Google Patents

Alkylation en phase vapeur en presence d'un aluminosilicate cristallin catalytique

Info

Publication number
BE798878A
BE798878A BE130556A BE130556A BE798878A BE 798878 A BE798878 A BE 798878A BE 130556 A BE130556 A BE 130556A BE 130556 A BE130556 A BE 130556A BE 798878 A BE798878 A BE 798878A
Authority
BE
Belgium
Prior art keywords
aluminosilicate
alkylation
vapor
crystalline catalytic
catalytic
Prior art date
Application number
BE130556A
Other languages
English (en)
Inventor
G T Burress
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of BE798878A publication Critical patent/BE798878A/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7034—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3408—Regenerating or reactivating of aluminosilicate molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
BE130556A 1972-04-28 1973-04-27 Alkylation en phase vapeur en presence d'un aluminosilicate cristallin catalytique BE798878A (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US24836572A 1972-04-28 1972-04-28

Publications (1)

Publication Number Publication Date
BE798878A true BE798878A (fr) 1973-10-29

Family

ID=22938777

Family Applications (1)

Application Number Title Priority Date Filing Date
BE130556A BE798878A (fr) 1972-04-28 1973-04-27 Alkylation en phase vapeur en presence d'un aluminosilicate cristallin catalytique

Country Status (2)

Country Link
US (1) US3755483A (fr)
BE (1) BE798878A (fr)

Families Citing this family (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3894105A (en) * 1973-08-09 1975-07-08 Mobil Oil Corp Production of durene
US3894106A (en) * 1973-08-09 1975-07-08 Mobil Oil Corp Conversion of ethers
US3894107A (en) * 1973-08-09 1975-07-08 Mobil Oil Corp Conversion of alcohols, mercaptans, sulfides, halides and/or amines
US3907915A (en) * 1973-08-09 1975-09-23 Mobil Oil Corp Conversion of carbonyl compounds to aromatics
US3894104A (en) * 1973-08-09 1975-07-08 Mobil Oil Corp Aromatization of hetero-atom substituted hydrocarbons
US3894103A (en) * 1973-08-09 1975-07-08 Mobil Oil Corp Aromatization reactions
US3848012A (en) * 1973-09-26 1974-11-12 Monsanto Co Alkylation process
US3965208A (en) * 1975-01-06 1976-06-22 Mobil Oil Corporation Methylation of toluene
US4001346A (en) * 1975-01-06 1977-01-04 Mobil Oil Corporation Selective production of para-xylene
US3965209A (en) * 1975-01-06 1976-06-22 Mobil Oil Corporation Selective production of para-xylene
US4049737A (en) * 1975-09-18 1977-09-20 Mobil Oil Corporation Propylation of toluene
US4291185A (en) * 1978-12-14 1981-09-22 Mobil Oil Corporation Alkylation of benzene in petroleum
US4469908A (en) * 1978-12-14 1984-09-04 Mobil Oil Corporation Alkylation of aromatic hydrocarbons
US4393262A (en) * 1978-12-14 1983-07-12 Mobil Oil Corporation Production of isopropylbenzene
US4197413A (en) * 1978-12-14 1980-04-08 Mobil Oil Corporation Production of 3-methylphenol
CA1128549A (fr) * 1978-12-14 1982-07-27 Lewis B. Young Fabrication de 3-methylphenol
US4205189A (en) * 1978-12-14 1980-05-27 Mobil Oil Corporation Method for producing 3-alkylphenols and 1,3-dihydroxybenzene
CA1135286A (fr) * 1978-12-14 1982-11-09 Mobil Oil Corporation Alkylation des hydrocarbures aromatiques
US4301317A (en) * 1979-11-20 1981-11-17 Mobil Oil Corporation Preparation of 2-phenylalkanes
US4329509A (en) * 1979-11-30 1982-05-11 Mobil Oil Corporation Co-production of 2-alkanones and phenols
US4387259A (en) * 1981-07-16 1983-06-07 Mobil Oil Corporation Selective alkylation of aromatic hydrocarbons using a mixed ethylene/propylene alkylation agent
US4520220A (en) * 1982-02-22 1985-05-28 Cosden Technology, Inc. Alkylation of aromatics employing silicalite catalysts
JPS5939836A (ja) * 1982-08-27 1984-03-05 Toyo Soda Mfg Co Ltd １，２，４，５−テトラアルキルベンゼンの製造方法
US5019670A (en) * 1986-07-29 1991-05-28 Mobil Oil Corporation Process for producing alkylaromatic lubricant fluids
US4827069A (en) * 1988-02-19 1989-05-02 Mobil Oil Corporation Upgrading light olefin fuel gas and catalytic reformate in a turbulent fluidized bed catalyst reactor
AU3346689A (en) * 1988-02-19 1989-09-06 Mobil Oil Corporation Process for the production of gasoline from fuel gas and catalytic reformate
US5026943A (en) * 1988-05-09 1991-06-25 Mobil Oil Corp Catalytic conversion over catalyst comprising synthetic crystal MCM-35
US4992606A (en) * 1988-10-06 1991-02-12 Mobil Oil Corp. Process for preparing short chain alkyl aromatic compounds
US4992607A (en) * 1989-03-20 1991-02-12 Mobil Oil Corporation Petroleum refinery process and apparatus for the production of alkyl aromatic hydrocarbons from fuel gas and catalytic reformate
US5334795A (en) * 1990-06-28 1994-08-02 Mobil Oil Corp. Production of ethylbenzene
US5077445A (en) * 1991-02-06 1991-12-31 Mobil Oil Corp. Liquid-phase alkylbenzene synthesis using hydrated catalyst
IT1250435B (it) * 1991-07-01 1995-04-07 Mini Ricerca Scient Tecnolog Catalizzatore per l'alchilazione di composti aromatici e processo impiegante lo stesso
US5118894A (en) * 1991-07-18 1992-06-02 Mobil Oil Corporation Production of ethylbenzene
US5510561A (en) * 1992-12-21 1996-04-23 Kerr-Mcgee Chemical Corporation Homogenous catalyst and processes for fluid phase alkylation
US5434325A (en) * 1993-06-21 1995-07-18 Deltech Corporation Process for the production of tertiary butylethylbenzene
AU6675496A (en) * 1995-07-19 1997-02-18 Amoco Corporation Conversion of aromatics and olefins
WO2001021562A1 (fr) * 1999-09-20 2001-03-29 Consejo Superior De Investigaciones Científicas Alkylation de composes aromatiques
EP1358141B8 (fr) * 2001-02-07 2008-02-13 ExxonMobil Chemical Patents Inc. Obtention d'un compose alkylaromatique
EP1894909B1 (fr) 2001-02-07 2017-04-05 Badger Licensing LLC Production de composés alkyl-aromatiques
US6995295B2 (en) * 2002-09-23 2006-02-07 Exxonmobil Chemical Patents Inc. Alkylaromatics production
US7476774B2 (en) 2005-02-28 2009-01-13 Exxonmobil Research And Engineering Company Liquid phase aromatics alkylation process
EP1866267B1 (fr) * 2005-03-31 2014-11-05 Badger Licensing LLC Production d'alkylaromatiques utilisant un alcene dilue
KR101177220B1 (ko) * 2005-03-31 2012-08-24 바져 라이센싱 엘엘씨 다중상 알킬방향족의 제조방법
US7501547B2 (en) * 2006-05-10 2009-03-10 Exxonmobil Chemical Patents Inc. Alkylaromatics production
SG172597A1 (en) 2006-05-24 2011-07-28 Exxonmobil Chem Patents Inc Monoalkylated aromatic compound production
US7645913B2 (en) * 2007-01-19 2010-01-12 Exxonmobil Chemical Patents Inc. Liquid phase alkylation with multiple catalysts
KR101143238B1 (ko) * 2007-02-09 2012-05-18 엑손모빌 케미칼 패턴츠 인코포레이티드 개선된 알킬방향족 생산 방법
US7745676B2 (en) * 2007-07-30 2010-06-29 Exxonmobil Chemical Patents Inc. Alkylaromatics production
WO2009058522A2 (fr) * 2007-11-02 2009-05-07 Exxonmobil Chemical Patents Inc. Procédé de régénération d'une composition catalytique
KR101343332B1 (ko) * 2008-10-10 2013-12-20 바져 라이센싱 엘엘씨 알킬방향족 화합물의 제조 방법
CN106995713A (zh) 2011-02-07 2017-08-01 巴杰许可有限责任公司 用于降低汽油的苯含量的方法
JP2014513151A (ja) 2011-02-07 2014-05-29 バジャー・ライセンシング・エルエルシー ガソリンのベンゼン含有量を減少させる方法
AU2011358597B2 (en) 2011-02-07 2016-10-06 Badger Licensing Llc Process for reducing the benzene content of gasoline by alkylating benzene using a lower olefin in the presence of a paraffinic diluent
US20120296138A1 (en) * 2011-05-22 2012-11-22 Fina Technology, Inc. Method for alkylation of toluene to form styrene and ethylbenzene utilizing a moving bed reactor
US8946495B2 (en) * 2011-05-22 2015-02-03 Fina Technology, Inc. Process for alkylation of toluene to form styrene and ethylbenzene
EP2744875B1 (fr) 2011-08-19 2016-08-03 Badger Licensing LLC Procédé de réduction de la teneur de benzène de l'essence
US20130150640A1 (en) * 2011-12-08 2013-06-13 Gtc Technology Us, Llc Production of xylenes by methylation of aromatic compounds
US9586873B2 (en) * 2014-06-03 2017-03-07 King Fahd University Of Petroleum And Minerals Method for the selective production of para-dialkylbenzenes
CN109963828A (zh) 2016-10-06 2019-07-02 埃克森美孚化学专利公司 芳族烃的甲基化方法
JP6905055B2 (ja) * 2016-10-06 2021-07-21 エクソンモービル・ケミカル・パテンツ・インク ベンゼンおよび／またはトルエンのメチル化によるパラキシレン製造プロセス
KR102235874B1 (ko) 2016-10-06 2021-04-06 엑손모빌 케미칼 패턴츠 인코포레이티드 벤젠 및/또는 톨루엔의 메틸화에 의해 파라크실렌을 생성시키기 위한 촉매의 선택화 방법
US11673849B2 (en) 2016-12-21 2023-06-13 Exxonmobil Chemical Patents Inc. Process for selectivating catalyst for producing paraxylene by methylation of benzene and/or toluene

Also Published As

Publication number Publication date
US3755483A (en) 1973-08-28

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Legal Events

Date Code Title Description
RE20 Patent expired

Owner name: MOBIL OIL CORP.

Effective date: 19930427