FR2261297A1 - Liquid or powder lutidine-prepolymers - prepd by reacting 2,4- or 2,6- lutidine with aromomatic dialdehyde and acid catalyst - Google Patents
Liquid or powder lutidine-prepolymers - prepd by reacting 2,4- or 2,6- lutidine with aromomatic dialdehyde and acid catalystInfo
- Publication number
- FR2261297A1 FR2261297A1 FR7405066A FR7405066A FR2261297A1 FR 2261297 A1 FR2261297 A1 FR 2261297A1 FR 7405066 A FR7405066 A FR 7405066A FR 7405066 A FR7405066 A FR 7405066A FR 2261297 A1 FR2261297 A1 FR 2261297A1
- Authority
- FR
- France
- Prior art keywords
- lutidine
- prepd
- prepolymers
- reacting
- dialdehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G16/00—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00
- C08G16/02—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes
- C08G16/025—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with heterocyclic organic compounds
- C08G16/0268—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with heterocyclic organic compounds containing nitrogen in the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
Lutidine prepolymers are prepd. by reacting 2, 4- or 2, 6-lutidine with an aromatic dialdehyde, at 150-220 degrees C, (pref. b. pt), and in the presence of a suitable catalyst (for the condensation between the >CO gp. of the aldehyde and the CH3 gps. of the lutidine), until a viscous liquid is obtd. The prepolymer may be formed as a pptd by adding an ether, MeOH or EtOH to the viscous liquid. The process obviates prior art, rapid setting; the reaction being controlled to give a viscous prepolymer which can be processed and hardener at 200-250 degrees C to prods. with good mechanical strength and heat resistance. It is esp. useful in prodn. of composite structures, e.g. laminates, in combination with fibrous materials, esp. carbon fibres.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7405066A FR2261297A1 (en) | 1974-02-14 | 1974-02-14 | Liquid or powder lutidine-prepolymers - prepd by reacting 2,4- or 2,6- lutidine with aromomatic dialdehyde and acid catalyst |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7405066A FR2261297A1 (en) | 1974-02-14 | 1974-02-14 | Liquid or powder lutidine-prepolymers - prepd by reacting 2,4- or 2,6- lutidine with aromomatic dialdehyde and acid catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2261297A1 true FR2261297A1 (en) | 1975-09-12 |
FR2261297B1 FR2261297B1 (en) | 1978-09-29 |
Family
ID=9134919
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7405066A Granted FR2261297A1 (en) | 1974-02-14 | 1974-02-14 | Liquid or powder lutidine-prepolymers - prepd by reacting 2,4- or 2,6- lutidine with aromomatic dialdehyde and acid catalyst |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2261297A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2415117A2 (en) * | 1978-01-20 | 1979-08-17 | Poudres & Explosifs Ste Nale | Polystyrene pyridine resin prepn. - from aromatic di:aldehyde and methyl substd. pyridine, giving solns. directly utilisable as impregnants |
FR2551763A1 (en) * | 1983-09-13 | 1985-03-15 | Onera (Off Nat Aerospatiale) | NOVEL THERMOSETTING POLYMERS AND ACCELERATED CURING THERMOSETTING PREPOLYMERS RESULTING FROM THE POLYCONDENSATION OF PYRIDINE DERIVATIVES AND AROMATIC DIALDEHYDES AND THE ADDITION OF A PHENOLIC COMPOUND |
EP0149726A2 (en) * | 1984-01-23 | 1985-07-31 | Rockwell International Corporation | Friction material for brake linings and the like |
-
1974
- 1974-02-14 FR FR7405066A patent/FR2261297A1/en active Granted
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2415117A2 (en) * | 1978-01-20 | 1979-08-17 | Poudres & Explosifs Ste Nale | Polystyrene pyridine resin prepn. - from aromatic di:aldehyde and methyl substd. pyridine, giving solns. directly utilisable as impregnants |
FR2551763A1 (en) * | 1983-09-13 | 1985-03-15 | Onera (Off Nat Aerospatiale) | NOVEL THERMOSETTING POLYMERS AND ACCELERATED CURING THERMOSETTING PREPOLYMERS RESULTING FROM THE POLYCONDENSATION OF PYRIDINE DERIVATIVES AND AROMATIC DIALDEHYDES AND THE ADDITION OF A PHENOLIC COMPOUND |
EP0136227A1 (en) * | 1983-09-13 | 1985-04-03 | Societe Nationale Des Poudres Et Explosifs | Thermosetting polymers and prepolymers exhibiting an accelerated cure, obtained by condensing pyridine with aromatic dialdehydes and adding a phenolic compound |
EP0149726A2 (en) * | 1984-01-23 | 1985-07-31 | Rockwell International Corporation | Friction material for brake linings and the like |
EP0149726A3 (en) * | 1984-01-23 | 1985-08-14 | Rockwell International Corporation | Friction material for brake linings and the like |
Also Published As
Publication number | Publication date |
---|---|
FR2261297B1 (en) | 1978-09-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
CL | Concession to grant licenses | ||
ST | Notification of lapse |