FR2251615A1 - Y Zeolite cracking catalysts - contg cation-exchanged mordenite, CaA zeolite or H-erionite - Google Patents

Y Zeolite cracking catalysts - contg cation-exchanged mordenite, CaA zeolite or H-erionite

Info

Publication number
FR2251615A1
FR2251615A1 FR7437604A FR7437604A FR2251615A1 FR 2251615 A1 FR2251615 A1 FR 2251615A1 FR 7437604 A FR7437604 A FR 7437604A FR 7437604 A FR7437604 A FR 7437604A FR 2251615 A1 FR2251615 A1 FR 2251615A1
Authority
FR
France
Prior art keywords
zeolite
cation
erionite
contg
catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7437604A
Other languages
French (fr)
Other versions
FR2251615B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GCP Products UK Ltd
Original Assignee
WR Grace Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US416130A external-priority patent/US3925195A/en
Application filed by WR Grace Ltd filed Critical WR Grace Ltd
Publication of FR2251615A1 publication Critical patent/FR2251615A1/en
Application granted granted Critical
Publication of FR2251615B1 publication Critical patent/FR2251615B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/088—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7003—A-type

Landscapes

  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Catalysts based on Y zeolite contg. both rare-earth metal and H+ ions are prepd. by mixing the Y zeolite with a 2nd zeolite comprising (a) cation-exchanged mordenite, in which the exchange cation is H+, a rare-earth metal, Co, Ni and/or another di- or trivalent transition metal or Group II metal, (b) the Ca form of A zeolite, or (c) the H form of erionite. The catalysts are esp. useful for the prodn. of gasoline and C3-4 hydrocarbons by cracking heavier petroleum fractions, e.g. gas oil. The combined zeolite catalysts give reduced coke formation, have high stability w.r.t. high temps. and steam, and have high yields and selectivities.
FR7437604A 1973-11-15 1974-11-14 Y Zeolite cracking catalysts - contg cation-exchanged mordenite, CaA zeolite or H-erionite Granted FR2251615A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US416130A US3925195A (en) 1972-06-30 1973-11-15 Hydrocarbon cracking process using zeolite mixtures

Publications (2)

Publication Number Publication Date
FR2251615A1 true FR2251615A1 (en) 1975-06-13
FR2251615B1 FR2251615B1 (en) 1981-08-07

Family

ID=23648672

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7437604A Granted FR2251615A1 (en) 1973-11-15 1974-11-14 Y Zeolite cracking catalysts - contg cation-exchanged mordenite, CaA zeolite or H-erionite

Country Status (7)

Country Link
JP (1) JPS5080288A (en)
CA (1) CA1045069A (en)
DE (1) DE2453805C2 (en)
FR (1) FR2251615A1 (en)
IT (1) IT1025721B (en)
NL (1) NL7414863A (en)
ZA (1) ZA747306B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0278839A1 (en) * 1987-02-11 1988-08-17 Institut Français du Pétrole Hydrocarbon cracking catalyst containing an offretite, a zeolite and a matrix
EP0288363A1 (en) * 1987-04-24 1988-10-26 Institut Français du Pétrole Catalyst with a dealuminized mordenite, a Y zeolite and a matrix for cracking hydrocarbon feedstocks
EP0323784A1 (en) * 1988-01-08 1989-07-12 Institut Français du Pétrole Use of a catalyst containing a zeolite of the erionite family in a cracking process comprising a regeneration zone
EP0325502A1 (en) * 1988-01-21 1989-07-26 Institut Francais Du Petrole Catalytic cracking process
FR2626283A1 (en) * 1988-01-21 1989-07-28 Inst Francais Du Petrole Cracking catalyst and catalytic cracking process

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4810369A (en) * 1987-05-07 1989-03-07 Union Oil Company Of California Process for the catalytic cracking of feedstocks containing high levels of nitrogen
CN103449471B (en) * 2012-06-01 2017-07-14 中国石油天然气股份有限公司 A kind of phosphorous Ultra-stable rare earth Y-type molecular sieve and preparation method
CN103508467B (en) 2012-06-27 2015-09-23 中国石油化工股份有限公司 A kind of rare-earth Y molecular sieve and preparation method thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA940521A (en) * 1967-02-07 1974-01-22 Grace (W. R.) And Co. Catalyst and process for its preparation

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0278839A1 (en) * 1987-02-11 1988-08-17 Institut Français du Pétrole Hydrocarbon cracking catalyst containing an offretite, a zeolite and a matrix
EP0288363A1 (en) * 1987-04-24 1988-10-26 Institut Français du Pétrole Catalyst with a dealuminized mordenite, a Y zeolite and a matrix for cracking hydrocarbon feedstocks
FR2614220A1 (en) * 1987-04-24 1988-10-28 Inst Francais Du Petrole CATALYST FOR CRACKING HYDROCARBON LOADS COMPRISING A DESALUMINATED MORDENITY, A Y ZEOLITE AND A MATRIX
EP0323784A1 (en) * 1988-01-08 1989-07-12 Institut Français du Pétrole Use of a catalyst containing a zeolite of the erionite family in a cracking process comprising a regeneration zone
FR2625748A1 (en) * 1988-01-08 1989-07-13 Inst Francais Du Petrole USE OF A CATALYST CONTAINING A ZEOLITHE OF THE ERIONITE FAMILY IN A CRACKING METHOD COMPRISING AT LEAST ONE REGENERATION AREA
EP0325502A1 (en) * 1988-01-21 1989-07-26 Institut Francais Du Petrole Catalytic cracking process
FR2626283A1 (en) * 1988-01-21 1989-07-28 Inst Francais Du Petrole Cracking catalyst and catalytic cracking process

Also Published As

Publication number Publication date
FR2251615B1 (en) 1981-08-07
CA1045069A (en) 1978-12-26
DE2453805C2 (en) 1983-11-03
IT1025721B (en) 1978-08-30
NL7414863A (en) 1975-05-20
JPS5080288A (en) 1975-06-30
ZA747306B (en) 1975-11-26
DE2453805A1 (en) 1975-07-24

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Legal Events

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