FR2239286A2 - Hydrogenation catalyst for unsatd. cpds. - by reducing cpds. of gps. IB-VIIB metals or iron and nickel or cobalt - Google Patents

Hydrogenation catalyst for unsatd. cpds. - by reducing cpds. of gps. IB-VIIB metals or iron and nickel or cobalt

Info

Publication number
FR2239286A2
FR2239286A2 FR7325933A FR7325933A FR2239286A2 FR 2239286 A2 FR2239286 A2 FR 2239286A2 FR 7325933 A FR7325933 A FR 7325933A FR 7325933 A FR7325933 A FR 7325933A FR 2239286 A2 FR2239286 A2 FR 2239286A2
Authority
FR
France
Prior art keywords
cpds
metal
iron
reducing
unsatd
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7325933A
Other languages
French (fr)
Other versions
FR2239286B2 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR7325933A priority Critical patent/FR2239286A2/en
Priority to JP49049620A priority patent/JPS5740811B2/ja
Priority to GB1983274A priority patent/GB1434000A/en
Priority to BR3700/74A priority patent/BR7403700D0/en
Priority to DE2421934A priority patent/DE2421934C2/en
Priority to IT22443/74A priority patent/IT1012603B/en
Priority to NLAANVRAGE7406210,A priority patent/NL178589C/en
Publication of FR2239286A2 publication Critical patent/FR2239286A2/en
Priority to US05/621,416 priority patent/US4271323A/en
Application granted granted Critical
Publication of FR2239286B2 publication Critical patent/FR2239286B2/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Unsatd cpds are hydrogenated in the liq. phase using a sol. catalyst prepd. by reducing a) a cpd. of a Group IB to VII B metal or iron and b) a nickel or cobalt cpd. using either a metal hydride or organometallic derivs. For a) zinc, zirconium, molybdenum or iron are specified. Cpds. preferred for a) and b) are carboxylates or acetylacetonates. The atomic ratio of metal a)/b) is from 10:1 to 0.01 to 1. The ratio of mols. reducing agent to a) plus b) metal atoms is from 0.5:1 to 10:1. The catalyst is pref. prepd. at 70-160 degrees C. In the hydrogenation the pref. conditions are 70-160 degrees C and 2-50 bars pressure. The catalyst quantity is 20-1000 ppm based on the total a) plus b) metal. A synergistic effect is obtd. with the two metal cpds. giving excellent activity and quantitative yields.
FR7325933A 1973-05-08 1973-07-13 Hydrogenation catalyst for unsatd. cpds. - by reducing cpds. of gps. IB-VIIB metals or iron and nickel or cobalt Granted FR2239286A2 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR7325933A FR2239286A2 (en) 1973-07-13 1973-07-13 Hydrogenation catalyst for unsatd. cpds. - by reducing cpds. of gps. IB-VIIB metals or iron and nickel or cobalt
JP49049620A JPS5740811B2 (en) 1973-05-08 1974-05-02
GB1983274A GB1434000A (en) 1973-05-08 1974-05-06 Process for hydrogenating unsaturated compounds
DE2421934A DE2421934C2 (en) 1973-05-08 1974-05-07 Process for the hydrogenation of unsaturated compounds
BR3700/74A BR7403700D0 (en) 1973-05-08 1974-05-07 HYDROGENATION PROCESS OF UNSATURATED COMPOUNDS
IT22443/74A IT1012603B (en) 1973-05-08 1974-05-08 PROCEDURE FOR HYDROGENATION OF UNSATURATED COMPOUNDS
NLAANVRAGE7406210,A NL178589C (en) 1973-05-08 1974-05-08 PROCESS FOR HYDROGENATION OF LIQUID PHASE UNSATURATED COMPOUNDS.
US05/621,416 US4271323A (en) 1973-05-08 1975-10-10 Process for hydrogenating unsaturated compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7325933A FR2239286A2 (en) 1973-07-13 1973-07-13 Hydrogenation catalyst for unsatd. cpds. - by reducing cpds. of gps. IB-VIIB metals or iron and nickel or cobalt

Publications (2)

Publication Number Publication Date
FR2239286A2 true FR2239286A2 (en) 1975-02-28
FR2239286B2 FR2239286B2 (en) 1977-05-13

Family

ID=9122616

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7325933A Granted FR2239286A2 (en) 1973-05-08 1973-07-13 Hydrogenation catalyst for unsatd. cpds. - by reducing cpds. of gps. IB-VIIB metals or iron and nickel or cobalt

Country Status (1)

Country Link
FR (1) FR2239286A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5662265A (en) * 1996-03-22 1997-09-02 International Paper Company Paperboard container with indicia tabs

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5662265A (en) * 1996-03-22 1997-09-02 International Paper Company Paperboard container with indicia tabs
US5690273A (en) * 1996-03-22 1997-11-25 International Paper Company Paperboard container with indicia tabs

Also Published As

Publication number Publication date
FR2239286B2 (en) 1977-05-13

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