FR2237902A1 - Aromatic transition metal catalysts for unsatd. hydrocarbons - giving polymers, oligomers, isomers or hydrogenated cpds. - Google Patents
Aromatic transition metal catalysts for unsatd. hydrocarbons - giving polymers, oligomers, isomers or hydrogenated cpds.Info
- Publication number
- FR2237902A1 FR2237902A1 FR7326233A FR7326233A FR2237902A1 FR 2237902 A1 FR2237902 A1 FR 2237902A1 FR 7326233 A FR7326233 A FR 7326233A FR 7326233 A FR7326233 A FR 7326233A FR 2237902 A1 FR2237902 A1 FR 2237902A1
- Authority
- FR
- France
- Prior art keywords
- cpds
- unsatd
- oligomers
- isomers
- hydrogenated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/28—Titanium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
- C07C5/25—Migration of carbon-to-carbon double bonds
- C07C5/2506—Catalytic processes
- C07C5/2562—Catalytic processes with hydrides or organic compounds
- C07C5/2575—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
Abstract
The catalysts are of the type (I): where M is from Gp. IVA (Ti, Zr of Hf) and n is 2 or 4, R1-5 may be identical or different providing at least one is a substituent other than H, R1-5 may be independently H, halogen, aryl or (cyclo)aliphatic radicals contg. pref. 6-10C or 1-10 C respectively, which in turn may be substd. with OH or halogen. The (cyclo)aliphatic radicals may be unsaturated. Two or more gps. of R1-5 may be combined in a cyclic radical. These cpds. are prepd. by reaction of the tetrahalide of M with corresp. organomettalic cpd. contg. a metal from Gps. I-IIIA, pref. Li, Mg or Al.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7326233A FR2237902A1 (en) | 1973-07-17 | 1973-07-17 | Aromatic transition metal catalysts for unsatd. hydrocarbons - giving polymers, oligomers, isomers or hydrogenated cpds. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7326233A FR2237902A1 (en) | 1973-07-17 | 1973-07-17 | Aromatic transition metal catalysts for unsatd. hydrocarbons - giving polymers, oligomers, isomers or hydrogenated cpds. |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2237902A1 true FR2237902A1 (en) | 1975-02-14 |
FR2237902B1 FR2237902B1 (en) | 1976-09-17 |
Family
ID=9122740
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7326233A Granted FR2237902A1 (en) | 1973-07-17 | 1973-07-17 | Aromatic transition metal catalysts for unsatd. hydrocarbons - giving polymers, oligomers, isomers or hydrogenated cpds. |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2237902A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1551016A (en) | 1975-11-25 | 1979-08-22 | Ici Ltd | Supported transition metal-arene compounds |
-
1973
- 1973-07-17 FR FR7326233A patent/FR2237902A1/en active Granted
Also Published As
Publication number | Publication date |
---|---|
FR2237902B1 (en) | 1976-09-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
TP | Transmission of property | ||
ST | Notification of lapse |