FR2147067A2 - Water-soluble acrylic copolymers by irradiating concd aq - Google Patents

Water-soluble acrylic copolymers by irradiating concd aq

Info

Publication number
FR2147067A2
FR2147067A2 FR7225969A FR7225969A FR2147067A2 FR 2147067 A2 FR2147067 A2 FR 2147067A2 FR 7225969 A FR7225969 A FR 7225969A FR 7225969 A FR7225969 A FR 7225969A FR 2147067 A2 FR2147067 A2 FR 2147067A2
Authority
FR
France
Prior art keywords
irradiating
water
concd
acrylic copolymers
soluble acrylic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7225969A
Other languages
French (fr)
Other versions
FR2147067B2 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19702009748 external-priority patent/DE2009748A1/en
Priority claimed from DE19712136887 external-priority patent/DE2136887A1/en
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of FR2147067A2 publication Critical patent/FR2147067A2/en
Application granted granted Critical
Publication of FR2147067B2 publication Critical patent/FR2147067B2/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/46Polymerisation initiated by wave energy or particle radiation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • C08F20/34Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52Amides or imides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Water-soluble (co)polymers are produced by irradiating is not 50% aq. solns. of suitable monomer(s) with a CH2=C gp., opt. in the presence of photoinitiators, in the form of a thin film, is not >2 cm. thick, on a support, which pref. is moving under the source of radiation, as in parent patent. The aq. monomer soln. used contains 0 -80 wt.% (meth)acrylamide, 20 - 100% (meth) acrylic cpd. of formula CH2=CR-COY(CH2)n plus-or-minus NR'3X- (in which R is H or Me; R' is 1 - 3C alkyl or one R' is H; n is 1, 2, 3 or 4; Y is -O- or -NH-; X- is an acid gp.) and 0 -20% N-vinylimidazole (all w.r.t. the total amt. of monomers). The prods. are esp. efficient flocculants for sewage
FR7225969A 1970-03-03 1972-07-19 Water-soluble acrylic copolymers by irradiating concd aq Granted FR2147067A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19702009748 DE2009748A1 (en) 1970-03-03 1970-03-03 Process for the production of water-soluble polymers
DE19712136887 DE2136887A1 (en) 1971-07-23 1971-07-23 PROCESS FOR THE PRODUCTION OF WATER-SOLUBLE POLYMERIZES

Publications (2)

Publication Number Publication Date
FR2147067A2 true FR2147067A2 (en) 1973-03-09
FR2147067B2 FR2147067B2 (en) 1976-10-29

Family

ID=25758741

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7225969A Granted FR2147067A2 (en) 1970-03-03 1972-07-19 Water-soluble acrylic copolymers by irradiating concd aq

Country Status (1)

Country Link
FR (1) FR2147067A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0045720A2 (en) * 1980-08-01 1982-02-10 Ciba-Geigy Ag Quaternary polymers, high molecular weight ammonium salts based on acrylates, their preparation and their use in cosmetic preparations

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0045720A2 (en) * 1980-08-01 1982-02-10 Ciba-Geigy Ag Quaternary polymers, high molecular weight ammonium salts based on acrylates, their preparation and their use in cosmetic preparations
EP0045720A3 (en) * 1980-08-01 1982-09-08 Ciba-Geigy Ag Quaternary polymers, high molecular weight ammonium salts based on acrylates, their preparation and their use in cosmetic preparations

Also Published As

Publication number Publication date
FR2147067B2 (en) 1976-10-29

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