FR2096605A1 - Halo silane rearrangement - using tertiary amine hydrohalide catalysts - Google Patents
Halo silane rearrangement - using tertiary amine hydrohalide catalystsInfo
- Publication number
- FR2096605A1 FR2096605A1 FR7123682A FR7123682A FR2096605A1 FR 2096605 A1 FR2096605 A1 FR 2096605A1 FR 7123682 A FR7123682 A FR 7123682A FR 7123682 A FR7123682 A FR 7123682A FR 2096605 A1 FR2096605 A1 FR 2096605A1
- Authority
- FR
- France
- Prior art keywords
- rearrangement
- catalysts
- tertiary amine
- amine hydrohalide
- halo silane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title abstract 2
- 230000008707 rearrangement Effects 0.000 title abstract 2
- 229910000077 silane Inorganic materials 0.000 title abstract 2
- 125000001475 halogen functional group Chemical group 0.000 title 1
- 150000003512 tertiary amines Chemical class 0.000 title 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract 1
- 229910004721 HSiCl3 Inorganic materials 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/08—Compounds containing halogen
- C01B33/107—Halogenated silanes
- C01B33/10773—Halogenated silanes obtained by disproportionation and molecular rearrangement of halogenated silanes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
- C07F7/121—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
- C07F7/125—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20 by reactions involving both Si-C and Si-halogen linkages, the Si-C and Si-halogen linkages can be to the same or to different Si atoms, e.g. redistribution reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
Abstract
Process for rearrangement of a halogenosilane (I) pref. containing a Si-H bound, by contacting (I) above or in mixture with other cpds. (I) with a tert. amine hydrohalide (II) of formula: NRR1R2.HX (where R, R2 = is not 3C monovalent hydrocarbyl or together R, R1 = is not 4C divalent alkylene, diethylene oxide; R2 = is not 2C monovalent hydrocarbyl provided that R + R2 = is not 8C; and X = halogen). Pref. silane (I) is HSiCl3 rearranged to H2SiCl2 and catalyst (II) is Bu3NH+Cl-.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US5174370A | 1970-06-30 | 1970-06-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2096605A1 true FR2096605A1 (en) | 1972-02-18 |
Family
ID=21973122
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7123682A Withdrawn FR2096605A1 (en) | 1970-06-30 | 1971-06-29 | Halo silane rearrangement - using tertiary amine hydrohalide catalysts |
Country Status (5)
Country | Link |
---|---|
AU (1) | AU3059871A (en) |
BE (1) | BE769231A (en) |
DE (1) | DE2132335A1 (en) |
FR (1) | FR2096605A1 (en) |
NL (1) | NL7108970A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0107432A2 (en) * | 1982-10-08 | 1984-05-02 | Chisso Corporation | Process for producing dichlorosilane |
FR2541666A1 (en) * | 1983-02-25 | 1984-08-31 | Rhone Poulenc Spec Chim | METHOD FOR DISMUTING SILANES |
FR2552435A1 (en) * | 1983-09-28 | 1985-03-29 | Rhone Poulenc Spec Chim | PROCESS FOR PRODUCING HYDROGEN SILANES BY REDISTRIBUTION |
FR2563749A1 (en) * | 1984-04-06 | 1985-11-08 | Denki Kagaku Kogyo Kk | CHLOROSILANE DISMUTATION CATALYST AND PROCESS FOR PRODUCING SILANE COMPOUND USING SUCH A CATALYST |
EP0213215A1 (en) * | 1985-08-12 | 1987-03-11 | Denki Kagaku Kogyo Kabushiki Kaisha | Chlorosilane disproportionation catalyst and method for producing a silane compound by means of the catalyst |
US4746752A (en) * | 1983-09-28 | 1988-05-24 | Rhone-Poulenc Specialites Chimiques | Preparation of hydrogenosilanes by redistribution |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005019252A1 (en) | 2005-04-26 | 2006-11-09 | Wacker Chemie Ag | Process for the preparation of organyl hydrogen silanes |
DE102013021306A1 (en) * | 2013-12-19 | 2015-06-25 | Johann Wolfgang Goethe-Universität | Process for the preparation of linear, cyclic and / or cage-like perhalogenated oligo- and polysilyl anions |
-
1971
- 1971-06-29 DE DE19712132335 patent/DE2132335A1/en active Pending
- 1971-06-29 BE BE769231A patent/BE769231A/en unknown
- 1971-06-29 AU AU30598/71A patent/AU3059871A/en not_active Expired
- 1971-06-29 NL NL7108970A patent/NL7108970A/xx unknown
- 1971-06-29 FR FR7123682A patent/FR2096605A1/en not_active Withdrawn
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0107432A2 (en) * | 1982-10-08 | 1984-05-02 | Chisso Corporation | Process for producing dichlorosilane |
EP0107432A3 (en) * | 1982-10-08 | 1986-04-16 | Chisso Corporation | Process for producing dichlorosilane |
FR2541666A1 (en) * | 1983-02-25 | 1984-08-31 | Rhone Poulenc Spec Chim | METHOD FOR DISMUTING SILANES |
EP0117799A1 (en) * | 1983-02-25 | 1984-09-05 | Rhone-Poulenc Chimie | Process for the disproportionation of silanes |
FR2552435A1 (en) * | 1983-09-28 | 1985-03-29 | Rhone Poulenc Spec Chim | PROCESS FOR PRODUCING HYDROGEN SILANES BY REDISTRIBUTION |
EP0138670A2 (en) * | 1983-09-28 | 1985-04-24 | Rhone-Poulenc Chimie | Process for the preparation of silanes with a Si-H bond by redistribution |
EP0138670A3 (en) * | 1983-09-28 | 1985-05-22 | Rhone-Poulenc Specialites Chimiques | |
US4746752A (en) * | 1983-09-28 | 1988-05-24 | Rhone-Poulenc Specialites Chimiques | Preparation of hydrogenosilanes by redistribution |
FR2563749A1 (en) * | 1984-04-06 | 1985-11-08 | Denki Kagaku Kogyo Kk | CHLOROSILANE DISMUTATION CATALYST AND PROCESS FOR PRODUCING SILANE COMPOUND USING SUCH A CATALYST |
EP0213215A1 (en) * | 1985-08-12 | 1987-03-11 | Denki Kagaku Kogyo Kabushiki Kaisha | Chlorosilane disproportionation catalyst and method for producing a silane compound by means of the catalyst |
Also Published As
Publication number | Publication date |
---|---|
NL7108970A (en) | 1972-01-03 |
BE769231A (en) | 1971-12-29 |
DE2132335A1 (en) | 1972-01-05 |
AU3059871A (en) | 1973-01-04 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |