FI923477A0 - Katalytisk reduktion av nox under anvaendning av metan i naervaro av syre. - Google Patents

Katalytisk reduktion av nox under anvaendning av metan i naervaro av syre.

Info

Publication number
FI923477A0
FI923477A0 FI923477A FI923477A FI923477A0 FI 923477 A0 FI923477 A0 FI 923477A0 FI 923477 A FI923477 A FI 923477A FI 923477 A FI923477 A FI 923477A FI 923477 A0 FI923477 A0 FI 923477A0
Authority
FI
Finland
Prior art keywords
naervaro
syre
metan
catalytic reduction
nox under
Prior art date
Application number
FI923477A
Other languages
English (en)
Other versions
FI923477A (fi
Inventor
Yuejin Li
John Nelson Armor
Original Assignee
Air Prod & Chem
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Prod & Chem filed Critical Air Prod & Chem
Publication of FI923477A0 publication Critical patent/FI923477A0/fi
Publication of FI923477A publication Critical patent/FI923477A/fi

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2066—Selective catalytic reduction [SCR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/38—Removing components of undefined structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/208—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1025—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/2073—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20746—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20753—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20784—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00—Adding substances to exhaust gases
    • F01N2610/03—Adding substances to exhaust gases the substance being hydrocarbons, e.g. engine fuel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Toxicology (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
FI923477A 1991-08-01 1992-07-31 Katalytisk reduktion av nox under anvaendning av metan i naervaro av syre FI923477A (fi)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/739,273 US5149512A (en) 1991-08-01 1991-08-01 Catalytic reduction of NOx using methane in the presence of oxygen

Publications (2)

Publication Number Publication Date
FI923477A0 true FI923477A0 (fi) 1992-07-31
FI923477A FI923477A (fi) 1993-02-02

Family

ID=24971567

Family Applications (1)

Application Number Title Priority Date Filing Date
FI923477A FI923477A (fi) 1991-08-01 1992-07-31 Katalytisk reduktion av nox under anvaendning av metan i naervaro av syre

Country Status (15)

Country Link
US (1) US5149512A (fi)
EP (1) EP0525701A1 (fi)
JP (1) JPH0798133B2 (fi)
KR (1) KR950008627B1 (fi)
CN (1) CN1070352A (fi)
AR (1) AR247492A1 (fi)
AU (1) AU645432B2 (fi)
BR (1) BR9202908A (fi)
CA (1) CA2074687A1 (fi)
FI (1) FI923477A (fi)
MX (1) MX9204495A (fi)
NZ (1) NZ243726A (fi)
PT (1) PT100750A (fi)
TW (1) TW225481B (fi)
ZA (1) ZA925779B (fi)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
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AU634005B2 (en) * 1989-12-21 1993-02-11 Tosoh Corporation Catalyst for and method of purifying oxygen-excess exhaust gas
US5271913A (en) * 1989-12-28 1993-12-21 Mitsubishi Jukogyo Kabushiki Kaisha Denitration catalyst for high-temperature exhaust gas
CA2046951A1 (en) * 1990-07-19 1992-01-20 Akinori Eshita Catalyst for purifying exhaust gas and method of using same
US5407651A (en) * 1991-02-15 1995-04-18 Tosoh Corporation Catalyst for and method of purifying exhaust gas
US5260043A (en) * 1991-08-01 1993-11-09 Air Products And Chemicals, Inc. Catalytic reduction of NOx and carbon monoxide using methane in the presence of oxygen
US5451385A (en) * 1991-08-01 1995-09-19 Air Products And Chemicals, Inc. Control of exhaust emissions from methane-fueled internal combustion engines
GB9223170D0 (en) * 1992-11-05 1992-12-16 British Petroleum Co Plc Process for preparing carboxylic acids
US5364606A (en) * 1993-03-01 1994-11-15 General Electric Company NOx reduction through the use of methane
US5401372A (en) * 1993-04-26 1995-03-28 Ceramatec, Inc. Electrochemical catalytic reduction cell for the reduction of NOx in an O2 -containing exhaust emission
US5869013A (en) * 1993-11-04 1999-02-09 Osaka Gas Company Limited Process and catalyst for reducing Nox in exhaust combustion gases
DK0652040T3 (da) * 1993-11-04 2000-07-03 Enitecnologie Spa Fremgangsmåde og katalysator til reduktion af NOx i forbrændingsudstødningsgasser
US5354544A (en) * 1993-12-27 1994-10-11 Ford Motor Company Selective reduction of nitric oxide
DE69519243T2 (de) * 1994-02-15 2001-03-08 Tokyo Gas Co Ltd Verfahren und Katalysator zur Reinigung von NOx-enthaltenden Abgasen
JPH11221469A (ja) * 1995-03-17 1999-08-17 Osaka Gas Co Ltd 窒素酸化物還元用触媒及び排ガス中の窒素酸化物の還元方法
CA2141734C (en) * 1995-01-25 2000-06-06 Raj Narain Pandey Selective catalytic reduction of nitrogen oxides
DK0739651T3 (da) * 1995-04-17 2001-12-10 Enitecnologie Spa Nitrogenoxid-reduktionskatalysator og fremgangsmåde til reduktion af nitrogenoxider i udstødningsgas
US5743929A (en) * 1995-08-23 1998-04-28 The Boc Group, Inc. Process for the production of high purity carbon dioxide
EP0766992B1 (en) * 1995-10-06 2003-07-30 ENITECNOLOGIE S.p.a. Nitrogen oxides reduction catalyst and process for reducing nitrogen oxides in exhaust gas
FR2754468B1 (fr) * 1996-10-10 2001-12-14 Gaz De France Catalyseur, en particulier de reduction des nox, et procede de reduction des nox
KR100239462B1 (ko) * 1996-12-28 2000-01-15 구자홍 브이에스비(vsb) 디지탈 티브이
FR2773087B1 (fr) * 1997-12-26 2000-02-11 Inst Francais Du Petrole Catalyseurs de reduction des oxydes d'azote dans un milieu oxydant, preparation et utilisation
NL1008746C2 (nl) * 1998-03-30 1999-10-01 Stichting Energie Werkwijze voor het omzetten van distikstofoxide.
CN1123375C (zh) * 1998-10-21 2003-10-08 中国科学院大连化学物理研究所 一种富氧条件下氢部分选择还原一氧化氮的方法
NL1013862C2 (nl) * 1999-09-06 2001-03-08 Stichting Energie Reductie van N#2O emissies.
JP4573320B2 (ja) * 2000-09-08 2010-11-04 昭和電工株式会社 亜酸化窒素分解触媒、その製造方法及び亜酸化窒素の分解方法
NL1017245C2 (nl) * 2001-01-31 2002-08-01 Stichting Energie Werkwijze voor het gelijktijdig verwijderen van stikstofoxiden en lachgas uit een stikstofoxiden en lachgas bevattende gasstroom.
US7137382B2 (en) * 2002-11-01 2006-11-21 Visteon Global Technologies, Inc. Optimal wide open throttle air/fuel ratio control
DE60307291T2 (de) * 2003-11-26 2007-10-18 Ford Global Technologies, LLC, Dearborn Vorrichtung und Verfahren zur Beseitigung von Nebenprodukten aus dem Abgas einer Brennkraftmaschine
NL1026207C2 (nl) * 2004-05-17 2005-11-21 Stichting Energie Werkwijze voor de decompositie van N2O, katalysator daarvoor en bereiding van deze katalysator.
US7488462B2 (en) * 2005-04-26 2009-02-10 The Ohio State University Multi-stage catalyst systems and uses thereof
US7939039B2 (en) * 2007-09-11 2011-05-10 GM Global Technology Operations LLC Bimetallic catalyst for NOx reduction in engine exhaust
DE102011013271A1 (de) * 2011-03-07 2012-09-13 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Verfahren und Anlage zur Reduktion von Stickoxidemissionen bei der Dampfreformierung
JP6134552B2 (ja) * 2012-03-30 2017-05-24 日立造船株式会社 燃焼排ガスの浄化方法、および脱硝触媒
CN103752352A (zh) * 2014-01-02 2014-04-30 上海大学 钴锰双交换分子筛脱硝催化剂的制备方法
CN104841474A (zh) * 2015-03-19 2015-08-19 碗海鹰 Scr催化剂及其制备方法
US10188986B2 (en) 2015-11-06 2019-01-29 Paccar Inc Electrochemical reductant generation while dosing DEF
US9757691B2 (en) * 2015-11-06 2017-09-12 Paccar Inc High efficiency and durability selective catalytic reduction catalyst
US10058819B2 (en) 2015-11-06 2018-08-28 Paccar Inc Thermally integrated compact aftertreatment system
US9764287B2 (en) 2015-11-06 2017-09-19 Paccar Inc Binary catalyst based selective catalytic reduction filter
GB201608643D0 (en) * 2016-05-17 2016-06-29 Thermo Fisher Scient Bremen Elemental analysis system and method
US10675586B2 (en) 2017-06-02 2020-06-09 Paccar Inc Hybrid binary catalysts, methods and uses thereof
US10835866B2 (en) 2017-06-02 2020-11-17 Paccar Inc 4-way hybrid binary catalysts, methods and uses thereof
CN108187732B (zh) * 2017-12-12 2021-04-02 哈尔滨工业大学深圳研究生院 一种抗硫抗水的ch4-scr脱硝催化剂及其制备方法
DE112019001699T5 (de) * 2018-03-30 2020-12-24 Iee International Electronics & Engineering S.A. Flexible und dehnbare Heizungen von hoher Robustheit für Kraftfahrzeuganwendungen
US11007514B2 (en) 2019-04-05 2021-05-18 Paccar Inc Ammonia facilitated cation loading of zeolite catalysts
US10906031B2 (en) 2019-04-05 2021-02-02 Paccar Inc Intra-crystalline binary catalysts and uses thereof
US10934918B1 (en) 2019-10-14 2021-03-02 Paccar Inc Combined urea hydrolysis and selective catalytic reduction for emissions control

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JPS62291258A (ja) * 1986-06-11 1987-12-18 Ricoh Co Ltd 画像読取装置
JPS63119850A (ja) * 1986-11-10 1988-05-24 Matsushita Electric Ind Co Ltd 燃焼排ガス浄化用触媒
DE3713169A1 (de) * 1987-04-17 1988-11-03 Bayer Ag Verfahren und vorrichtung zur reduktion von stickoxiden
JPH0729049B2 (ja) * 1987-04-30 1995-04-05 三菱重工業株式会社 燃焼排ガス中の砒素化合物除去方法
US4867954A (en) * 1988-04-07 1989-09-19 Uop Catalytic reduction of nitrogen oxides
JPH0763631B2 (ja) * 1988-04-18 1995-07-12 トヨタ自動車株式会社 排気ガス浄化用触媒の製造方法
EP0362966B1 (en) * 1988-10-07 1994-01-12 Sakai Chemical Industry Co., Ltd., Catalysts and methods for denitrization
JP2851444B2 (ja) * 1991-01-29 1999-01-27 東ソー株式会社 排気ガス浄化方法
US5407651A (en) * 1991-02-15 1995-04-18 Tosoh Corporation Catalyst for and method of purifying exhaust gas

Also Published As

Publication number Publication date
MX9204495A (es) 1993-02-01
JPH0798133B2 (ja) 1995-10-25
AR247492A1 (es) 1995-01-31
EP0525701A1 (en) 1993-02-03
PT100750A (pt) 1993-09-30
AU2058692A (en) 1993-02-04
FI923477A (fi) 1993-02-02
KR930003955A (ko) 1993-03-22
AU645432B2 (en) 1994-01-13
NZ243726A (en) 1994-10-26
TW225481B (fi) 1994-06-21
CA2074687A1 (en) 1993-02-02
JPH05192582A (ja) 1993-08-03
ZA925779B (en) 1994-01-31
BR9202908A (pt) 1993-03-30
CN1070352A (zh) 1993-03-31
US5149512A (en) 1992-09-22
KR950008627B1 (ko) 1995-08-03

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