FI891964A - CRYSTAL ALUMINUM PHOSPHATE COMPOSITION. - Google Patents
CRYSTAL ALUMINUM PHOSPHATE COMPOSITION. Download PDFInfo
- Publication number
- FI891964A FI891964A FI891964A FI891964A FI891964A FI 891964 A FI891964 A FI 891964A FI 891964 A FI891964 A FI 891964A FI 891964 A FI891964 A FI 891964A FI 891964 A FI891964 A FI 891964A
- Authority
- FI
- Finland
- Prior art keywords
- compositions
- ray diffraction
- diffraction pattern
- aluminium phosphate
- composition
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 11
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 title abstract 4
- 239000013078 crystal Substances 0.000 title abstract 2
- 238000002441 X-ray diffraction Methods 0.000 abstract 3
- 229940001007 aluminium phosphate Drugs 0.000 abstract 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 229910052593 corundum Inorganic materials 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- 239000002243 precursor Substances 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000002808 molecular sieve Substances 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 230000005855 radiation Effects 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 abstract 1
- 239000011135 tin Substances 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/04—Aluminophosphates [APO compounds]
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
- C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
Abstract
The invention relates to crystalline aluminium phosphate compositions with three-dimensional, microporous crystal structures, which chemical composition expressed as molar ratio is Al2O3 : 1.0 + 0.2 P2O5. Adsorption data show that the compositions can be used as molecular sieves when they have intracrystalline micropores which can admit molecules with kinetic diameters of from 3 to 14 A. These compositions have an X-ray diffraction pattern characterized by having the d spacings shown in Table 1 when measured at a two theta which is less than about 40 degrees using copper K alpha radiation. The composition can also include a structure-aligning agent. Production takes place by mixing an aluminium source, a phosphorus source and 10-100 mol water per mol Al2O3 to form a precursor mixture, mixing the precursor mixture with the structure-aligning agent to form a reaction mixture, and converting the reaction mixture under such conditions that an aluminium phosphate composition with the given X-ray diffraction pattern is formed. Metal-substituted aluminium phosphate compositions which have an X-ray diffraction pattern with the same characteristic d spacings can also be produced by also incorporating oxides of one or more metals with the oxide lattice. Metals which are suitable for substitution include silicon, magnesium, zinc, tin, zirconium, titanium, cobalt and mixtures thereof.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9080187A | 1987-08-28 | 1987-08-28 | |
| US9080187 | 1987-08-28 | ||
| US20785088 | 1988-06-15 | ||
| US07/207,850 US5374411A (en) | 1987-08-28 | 1988-06-15 | Crystalline aluminumphosphate compositions |
| US8802910 | 1988-08-24 | ||
| PCT/US1988/002910 WO1989001912A1 (en) | 1987-08-28 | 1988-08-24 | Crystalline aluminumphosphate compositions |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| FI891964A true FI891964A (en) | 1989-04-25 |
| FI891964A0 FI891964A0 (en) | 1989-04-25 |
| FI89037B FI89037B (en) | 1993-04-30 |
| FI89037C FI89037C (en) | 1993-08-10 |
Family
ID=26782637
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI891964A FI89037C (en) | 1987-08-28 | 1989-04-25 | Crystalline aluminum phosphate compositions |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0333816A4 (en) |
| JP (1) | JPH03505720A (en) |
| CN (1) | CN1018624B (en) |
| FI (1) | FI89037C (en) |
| HU (1) | HU208511B (en) |
| IL (1) | IL87606A (en) |
| RO (1) | RO104858B1 (en) |
| WO (1) | WO1989001912A1 (en) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2924089A (en) * | 1987-12-21 | 1989-07-19 | Mobil Oil Corporation | Crystalline molecular sieve |
| WO1989009748A1 (en) * | 1988-04-08 | 1989-10-19 | Mobil Oil Corporation | Synthesis of a crystalline molecular sieve |
| NZ228425A (en) * | 1988-04-08 | 1990-11-27 | Mobil Oil Corp | Method of synthesising a crystalline molecular sieve comprising oxides of aluminium and phosphorus, and other elements |
| US5013535A (en) * | 1989-04-20 | 1991-05-07 | Uop | Stabilized aluminophosphate compositions and process for preparing same |
| DD299288A5 (en) * | 1989-07-07 | 1992-04-09 | ���������������@����@�������������@�K@����������K@��������@�K@���@�K@���@M�����]k�� | PROCESS FOR PREPARING A CRYSTALLINE MOLECULAR SCREEN |
| US5208006A (en) * | 1990-05-28 | 1993-05-04 | Engelhard Corporation | Large-pored molecular sieves containing at least one octahedral site comprising titanium and at least silicon as a tetrahedral site |
| US5108727A (en) * | 1990-06-26 | 1992-04-28 | Mobil Oil Corporation | Synthesis of crystalline aluminophosphate composition |
| US5124136A (en) * | 1990-06-26 | 1992-06-23 | Mobil Oil Corporation | Synthesis of crystalline metalloluminophosphate composition |
| EP0464249B1 (en) * | 1990-07-05 | 1994-01-05 | VAW Aluminium AG | Process for the manufacture of crystalline molecular sieves with large pores |
| US5091073A (en) * | 1990-07-13 | 1992-02-25 | Mobil Oil Corp. | Crystalline molecular sieve compositions mcm-37 |
| US5104495A (en) * | 1990-12-11 | 1992-04-14 | Mobil Oil Corp. | Crystalline (metallo) aluminophosphate composition MCM-40, its synthesis and usage in hydrocarbon conversion |
| US5094828A (en) * | 1990-12-31 | 1992-03-10 | Mobil Oil Corporation | Synthesis of large-pore |
| FR2671790B1 (en) * | 1991-01-18 | 1993-04-16 | Inst Francais Du Petrole | PROCESS FOR THE PREPARATION OF ALUMINOPHOSPHATE COMPOUNDS AND SUBSTITUTED DERIVATIVES OF THE VFI STRUCTURAL TYPE INVENTION OF: JEAN-FRANCOIS JOLY, HERVE CAUFFRIEZ AND JEAN-LOUIS GUTH. |
| US5480556A (en) * | 1991-07-01 | 1996-01-02 | Ulan; Judith G. | Trapping and sealing process |
| NL1001553C2 (en) * | 1995-11-02 | 1997-05-13 | Akzo Nobel Nv | Method for the synthesis of porous ceramic materials. |
| WO2001036328A1 (en) * | 1999-11-18 | 2001-05-25 | Exxon Chemical Patents Inc. | Method for the synthesis of molecular sieves |
| US6685905B2 (en) | 2001-12-21 | 2004-02-03 | Exxonmobil Chemical Patents Inc. | Silicoaluminophosphate molecular sieves |
| WO2013158509A1 (en) * | 2012-04-16 | 2013-10-24 | Bunge Amorphic Solutions Llc | Antimicrobial chemical compositions |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4310440A (en) * | 1980-07-07 | 1982-01-12 | Union Carbide Corporation | Crystalline metallophosphate compositions |
| US4440871A (en) * | 1982-07-26 | 1984-04-03 | Union Carbide Corporation | Crystalline silicoaluminophosphates |
| US4673559A (en) * | 1983-12-19 | 1987-06-16 | Mobil Oil Corporation | Silicoaluminophosphate crystallization using hydrolysis |
-
1988
- 1988-08-24 HU HU885511A patent/HU208511B/en not_active IP Right Cessation
- 1988-08-24 JP JP63507736A patent/JPH03505720A/en active Granted
- 1988-08-24 WO PCT/US1988/002910 patent/WO1989001912A1/en not_active Application Discontinuation
- 1988-08-24 EP EP19880908535 patent/EP0333816A4/en not_active Withdrawn
- 1988-08-28 CN CN88107057A patent/CN1018624B/en not_active Expired
- 1988-08-30 IL IL87606A patent/IL87606A/en unknown
-
1989
- 1989-04-25 FI FI891964A patent/FI89037C/en not_active IP Right Cessation
- 1989-04-27 RO RO139461A patent/RO104858B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN1036376A (en) | 1989-10-18 |
| EP0333816A1 (en) | 1989-09-27 |
| JPH03505720A (en) | 1991-12-12 |
| IL87606A0 (en) | 1989-01-31 |
| FI89037C (en) | 1993-08-10 |
| EP0333816A4 (en) | 1989-12-13 |
| HU885511D0 (en) | 1990-02-28 |
| RO104858B1 (en) | 1993-04-01 |
| CN1018624B (en) | 1992-10-14 |
| FI891964A0 (en) | 1989-04-25 |
| WO1989001912A1 (en) | 1989-03-09 |
| JPH0574523B2 (en) | 1993-10-18 |
| IL87606A (en) | 1992-06-21 |
| FI89037B (en) | 1993-04-30 |
| HU208511B (en) | 1993-11-29 |
| HUT52003A (en) | 1990-06-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| BB | Publication of examined application | ||
| MM | Patent lapsed | ||
| MM | Patent lapsed |
Owner name: THE DOW CHEMICAL COMPANY |