FI128921B - Menetelmä ja laite sivuvesijakeen käsittelemiseksi - Google Patents
Menetelmä ja laite sivuvesijakeen käsittelemiseksi Download PDFInfo
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- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
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- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/025—Thermal hydrolysis
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
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- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
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- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
- C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
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- C01B2203/06—Integration with other chemical processes
- C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
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- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1217—Alcohols
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- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1217—Alcohols
- C01B2203/1223—Methanol
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- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
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- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
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- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
- C02F2103/365—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds from petrochemical industry (e.g. refineries)
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- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
- C10G2300/1014—Biomass of vegetal origin
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- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/169—Integration of gasification processes with another plant or parts within the plant with water treatments
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Y02P20/00—Technologies relating to chemical industry
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Abstract
nullKeksintö koskee menetelmää ja laitteistoa vesisivuvirtajakeen (1), joka käsittää ainakin yhtä ei-haluttua yhdistettä ja joka on muodostettu biomassan termokemiallisessa käsittelyssä, käsittelemiseksi. Vesisivuvirtajae (1), joka käsittää ainakin yhtä ei-haluttua orgaanista yhdistettä, käsitellään reformointikäsittelyn (2) avulla orgaanisen yhdisteen konvertomiseksi ainakin vedyksi (5) ja valinnaisesti myös muiksi yhdisteiksi (6), jotka ovat valittu ryhmästä, joka käsittää orgaaniset yhdisteet, hiilivedyt, hiilidioksidin, hiilimonoksidin ja niiden yhdistelmät. Reformointikäsittelyä (2) katalysoidaan Ni/NiAl2O4 -katalyytin (3) avulla. Lisäksi keksintö koskee menetelmän käyttöä.
Claims (14)
1. Menetelmä vesisivuvirtajakeen (1), joka käsittää ainakin yhtä ei-haluttua yhdistettä ja joka on muodostettu lignoselluloosapohjaisen biomassan ter- mokemiallisessa käsittelyssä, käsittelemiseksi, tunnettu siitä, että - vesisivuvirtajae on muodostettu käsittelyssä, jossa lignoselluloosapohjainen biomassa on käsi- telty ainakin yhden prosessivaiheen avulla, joka on valittu ryhmästä, joka käsittää kaasutuksen, synteesikaasun Fischer-Tropsch (FT) -reaktion, pyrolyysin, bioöljyn jalostuksen ja niiden yhdis- telmät, - vesisivuvirtajae (1), joka käsittää ainakin yhtä ei-haluttua orgaanista yhdistettä, käsitellään reformointikäsittelyn (2) avulla orgaanisen yh- disteen konvertomiseksi ainakin vedyksi (5) ja valinnaisesti myös muiksi yhdisteiksi (6), jotka ovat valittu ryhmästä, joka käsittää orgaaniset yhdisteet, hiilivedyt, hiilidioksidin, hiilimo- noksidin ja niiden yhdistelmät, ja - reformointikäsittelyä (2) katalysoidaan Ni/NiA120. -katalyytin (3) avulla.
2. Patenttivaatimuksen 1 mukainen menetelmä, tunnettu siitä, että Ni/NiAl,0, -katalyytti (3) on Ni/NiAl,04 pintakerroskatalyytti. —
3. Patenttivaatimuksen 1 tai 2 mukainen mene- O telmä, tunnettu siitä, että Ni/NiA1,04 - AN katalyytti (3) on Ni/NiAl,0, spinelli pintakerroskata- 2 30 lyytti.
4. Jonkin patenttivaatimuksista 1 - 3 mukai- E nen menetelmä, tunnettu siitä, että Ni/Ni4A1,20, 2 katalyytti (3) muodostetaan järjestämälllä Ni/NiAl,O4 © ohuena pintakerroksena substraatin päälle. 3
5. Jonkin patenttivaatimuksista 1 - 4 mukai- nen menetelmä, tunnettu siitä, että Ni/Ni4A1,20, katalyytin Ni-pitoisuus on 8 - 15 p-%.
6. Jonkin patenttivaatimuksista 1 - 4 mukai- nen menetelmä, tunnettu siitä, että Ni/NiAl,04 - katalyytti (3) valmistetaan siten, että Ni-prekursorit impregnoidaan böhmiittikantajamateriaaliin muodosta- maan katalyyttimateriaali, katalyyttimateriaali kuiva- taan ja kalsinoidaan, ja liete, joka käsittää ainakin katalyyttimateriaalia, valmistetaan ja sekoitetaan, ja substraatti pintakerrostetaan lietteen kanssa, ja pin- takerrostettu substraatti käsitellään termisesti.
7. Jonkin patenttivaatimuksista 1 - 5 mukai- nen menetelmä, tunnettu siitä, että Ni/NiAl,04 - katalyytti (3) valmistetaan siten, että Ni-prekursorit impregnoidaan huokosimeytysimpregnoinnin avulla böhmiittikantajamateriaaliin muodostamaan katalyytti- materiaali, katalyyttimateriaali kuivataan ja kalsi- noidaan, ja liete, joka käsittää ainakin katalyyttima- teriaalia, valmistetaan ja sekoitetaan, ja substraatti pintakerrostetaan lietteen kanssa, ja pintakerrostettu substraatti kuivataan, kalsinoidaan ja käsitellään pelkistyksen avulla.
8. Jonkin patenttivaatimuksista 1 - 7 mukai- nen menetelmä, tunnettu siitä, että reformointi- käsittely (2) on vesifaasireformointi (APR). —
9. Jonkin patenttivaatimuksista 1 - 8 mukai- O nen menetelmä, tunnettu siitä, että vesifaasire- AN formointi (APR) suoritetaan 200 - 250 °C lämpötilassa = 30 ja 30 — 34 bar paineen alaisuudessa. -
10. Jonkin patenttivaatimuksista 1 - 9 mukai- a nen menetelmä, tunnettu siitä, että vesisivuvir- 2 tajae (1) käsittää 1 — 40 til-% orgaanisia yhdisteitä. ©
11. Jonkin patenttivaatimuksista 1 - 10 mu- DO 35 kainen menetelmä, tunnettu siitä, että vetyä (5) N saatetaan kierrättää termokemialliseen käsittelyyn
H,/CO -suhteen säätämiseksi tai vetykäsittelyn paran- tamiseksi.
12. Laitteisto vesisivuvirtajakeen (1), joka käsittää ainakin yhtä ei-haluttua yhdistettä ja joka on muodostettu lignoselluloosapohjaisen biomassan ter- mokemiallisessa käsittelyssä, käsittelemiseksi, tunnettu siitä, että laitteisto käsittää - ainakin yhden reformointikäsittelylaitteen (12), jossa vesisivuvirtajae (1), joka käsittää ainakin yhtä ei-haluttua orgaanista yhdistettä ja joka on muodostettu käsittelemällä lignoselluloosapoh- jaista biomassaa ainakin yhden prosessivaiheen avulla, joka on valittu ryhmästä, joka käsittää kaasutuksen, synteesikaasun Fischer-Tropsch (FT) -reaktion, pyrolyysin, bioöljyn jalostuksen ja niiden yhdistelmät, käsitellään orgaanisen yhdis- teen konvertomiseksi ainakin vedyksi (5) ja va- linnaisesti myös muiksi yhdisteiksi (6), jotka ovat valittu ryhmästä, joka käsittää orgaaniset yhdisteet, hiilivedyt, hiilidioksidin, hiilimo- noksidin ja niiden yhdistelmät, ja - Ni/NiAl,0, -katalyytin (3), joka on järjestetty reformointikäsittelylaitteen (12) sisälle kataly- soimaan reformointikäsittelvyä (2).
13. Patenttivaatimuksen 12 mukainen laitteis- to tunnettu siitä, että reformointikäsittelylai- — te (12) on vesifaasireformointi (APR) -reaktori. O
14. Jonkin patenttivaatimuksista 1 - 11 mu- N kaisen menetelmän käyttö, tunnettu siitä, että = 30 menetelmää käytetään vesifaasireformoinnissa, biopolt- N toaineiden tuotannossa, vesisivuvirtajakeen käsitte- = lyssä Fischer-Tropsch (FT) -reaktion jälkeen, vesisi- 2 vuvirtajakeen käsittelyssä bioöljyn jalostuksen jäl- © keen, vesisivuvirtajakeen käsittelyssä pyrolyysin > 35 ja/tai sen jälkiprosessin jälkeen, ainakin orgaanista yhdistettä käsittävän vesijakeen käsittelyssä, tai niiden yhdistelmissä.
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Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
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FI20176100A FI128921B (fi) | 2017-12-11 | 2017-12-11 | Menetelmä ja laite sivuvesijakeen käsittelemiseksi |
PCT/FI2018/050895 WO2019115871A1 (en) | 2017-12-11 | 2018-12-10 | Method and apparatus for treating a side water fraction |
EP18830493.5A EP3723901A1 (en) | 2017-12-11 | 2018-12-10 | Method and apparatus for treating a side water fraction |
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FI20176100A FI128921B (fi) | 2017-12-11 | 2017-12-11 | Menetelmä ja laite sivuvesijakeen käsittelemiseksi |
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FI20176100A1 FI20176100A1 (fi) | 2019-06-12 |
FI128921B true FI128921B (fi) | 2021-03-15 |
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US10005078B2 (en) * | 2016-03-16 | 2018-06-26 | Kabushiki Kaisha Toshiba | Fuel synthesis catalyst and fuel synthesis system |
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WO2019115871A1 (en) | 2019-06-20 |
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