FI126960B - Stabiloitu liima-aineformulaatio - Google Patents
Stabiloitu liima-aineformulaatio Download PDFInfo
- Publication number
- FI126960B FI126960B FI20145118A FI20145118A FI126960B FI 126960 B FI126960 B FI 126960B FI 20145118 A FI20145118 A FI 20145118A FI 20145118 A FI20145118 A FI 20145118A FI 126960 B FI126960 B FI 126960B
- Authority
- FI
- Finland
- Prior art keywords
- formulation
- polysaccharide
- mixture
- sizing
- xylan
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 96
- 238000009472 formulation Methods 0.000 title claims description 62
- 239000000853 adhesive Substances 0.000 title claims description 10
- 230000001070 adhesive effect Effects 0.000 title claims 9
- 229920001282 polysaccharide Polymers 0.000 claims description 75
- 239000005017 polysaccharide Substances 0.000 claims description 75
- 150000004804 polysaccharides Chemical class 0.000 claims description 74
- PUVAFTRIIUSGLK-UHFFFAOYSA-M trimethyl(oxiran-2-ylmethyl)azanium;chloride Chemical group [Cl-].C[N+](C)(C)CC1CO1 PUVAFTRIIUSGLK-UHFFFAOYSA-M 0.000 claims description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- 229920000189 Arabinogalactan Polymers 0.000 claims description 28
- 235000019312 arabinogalactan Nutrition 0.000 claims description 28
- 229920001221 xylan Polymers 0.000 claims description 28
- 150000004823 xylans Chemical class 0.000 claims description 27
- SATHPVQTSSUFFW-UHFFFAOYSA-N 4-[6-[(3,5-dihydroxy-4-methoxyoxan-2-yl)oxymethyl]-3,5-dihydroxy-4-methoxyoxan-2-yl]oxy-2-(hydroxymethyl)-6-methyloxane-3,5-diol Chemical compound OC1C(OC)C(O)COC1OCC1C(O)C(OC)C(O)C(OC2C(C(CO)OC(C)C2O)O)O1 SATHPVQTSSUFFW-UHFFFAOYSA-N 0.000 claims description 26
- 239000001904 Arabinogalactan Substances 0.000 claims description 26
- 239000000839 emulsion Substances 0.000 claims description 22
- 239000003153 chemical reaction reagent Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 18
- 238000006467 substitution reaction Methods 0.000 claims description 14
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 9
- 230000003197 catalytic effect Effects 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 2
- 238000000265 homogenisation Methods 0.000 claims description 2
- 238000011084 recovery Methods 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 238000004026 adhesive bonding Methods 0.000 claims 1
- 238000004513 sizing Methods 0.000 description 70
- 235000013305 food Nutrition 0.000 description 42
- 229920002472 Starch Polymers 0.000 description 35
- 239000003795 chemical substances by application Substances 0.000 description 35
- 239000000123 paper Substances 0.000 description 35
- 235000019698 starch Nutrition 0.000 description 35
- 239000008107 starch Substances 0.000 description 34
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- 239000003381 stabilizer Substances 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 125000002091 cationic group Chemical group 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- -1 alkyl ketene dimer Chemical compound 0.000 description 10
- 230000000087 stabilizing effect Effects 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 6
- 239000002585 base Substances 0.000 description 5
- 229920002678 cellulose Polymers 0.000 description 5
- 230000002209 hydrophobic effect Effects 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 235000010980 cellulose Nutrition 0.000 description 4
- 235000016709 nutrition Nutrition 0.000 description 4
- 229920000926 Galactomannan Polymers 0.000 description 3
- 229920002907 Guar gum Polymers 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 229930182830 galactose Natural products 0.000 description 3
- 239000000665 guar gum Substances 0.000 description 3
- 235000010417 guar gum Nutrition 0.000 description 3
- 229960002154 guar gum Drugs 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229940014800 succinic anhydride Drugs 0.000 description 3
- RUUHDEGJEGHQKL-UHFFFAOYSA-M 2-hydroxypropyl(trimethyl)azanium;chloride Chemical compound [Cl-].CC(O)C[N+](C)(C)C RUUHDEGJEGHQKL-UHFFFAOYSA-M 0.000 description 2
- 229920000945 Amylopectin Polymers 0.000 description 2
- 229920000856 Amylose Polymers 0.000 description 2
- 229920002488 Hemicellulose Polymers 0.000 description 2
- 238000007696 Kjeldahl method Methods 0.000 description 2
- 241000218652 Larix Species 0.000 description 2
- 244000193510 Larix occidentalis Species 0.000 description 2
- 235000008122 Larix occidentalis Nutrition 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000000433 anti-nutritional effect Effects 0.000 description 2
- PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 description 2
- 229920001222 biopolymer Polymers 0.000 description 2
- 229920006319 cationized starch Polymers 0.000 description 2
- 210000002421 cell wall Anatomy 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 125000000311 mannosyl group Chemical group C1([C@@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000009877 rendering Methods 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- 125000000969 xylosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)CO1)* 0.000 description 2
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 description 1
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 244000106483 Anogeissus latifolia Species 0.000 description 1
- 235000011514 Anogeissus latifolia Nutrition 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 description 1
- 229920001503 Glucan Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000001922 Gum ghatti Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000005590 Larix decidua Nutrition 0.000 description 1
- 229920000057 Mannan Polymers 0.000 description 1
- 229920000715 Mucilage Polymers 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- SRBFZHDQGSBBOR-IOVATXLUSA-N Xylose Natural products O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- GZCGUPFRVQAUEE-KCDKBNATSA-N aldehydo-D-galactose Chemical compound OC[C@@H](O)[C@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-KCDKBNATSA-N 0.000 description 1
- PYMYPHUHKUWMLA-VAYJURFESA-N aldehydo-L-arabinose Chemical compound OC[C@H](O)[C@H](O)[C@@H](O)C=O PYMYPHUHKUWMLA-VAYJURFESA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- AEMOLEFTQBMNLQ-WAXACMCWSA-N alpha-D-glucuronic acid Chemical compound O[C@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-WAXACMCWSA-N 0.000 description 1
- 229920006321 anionic cellulose Polymers 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 229920000617 arabinoxylan Polymers 0.000 description 1
- 150000004783 arabinoxylans Chemical class 0.000 description 1
- 238000005844 autocatalytic reaction Methods 0.000 description 1
- SRBFZHDQGSBBOR-KKQCNMDGSA-N beta-D-xylose Chemical group O[C@@H]1CO[C@@H](O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-KKQCNMDGSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000011436 cob Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 150000002243 furanoses Chemical class 0.000 description 1
- 210000001035 gastrointestinal tract Anatomy 0.000 description 1
- 235000019314 gum ghatti Nutrition 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- LUEWUZLMQUOBSB-GFVSVBBRSA-N mannan Chemical class O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](O[C@H]3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-GFVSVBBRSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical group 0.000 description 1
- NEOIUIMNEOPFEP-UHFFFAOYSA-M methyl sulfate oxiran-2-ylmethyl(tripropyl)azanium Chemical compound COS(=O)(=O)[O-].C(C1CO1)[N+](CCC)(CCC)CCC NEOIUIMNEOPFEP-UHFFFAOYSA-M 0.000 description 1
- WMDIGBAWRPJQHR-UHFFFAOYSA-M methyl sulfate triethyl(oxiran-2-ylmethyl)azanium Chemical compound COS(=O)(=O)[O-].C(C1CO1)[N+](CC)(CC)CC WMDIGBAWRPJQHR-UHFFFAOYSA-M 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- AKESJACMBIKKMG-UHFFFAOYSA-M oxiran-2-ylmethyl(tripropyl)azanium bromide Chemical compound [Br-].C(C1CO1)[N+](CCC)(CCC)CCC AKESJACMBIKKMG-UHFFFAOYSA-M 0.000 description 1
- YQFOHQBSENCNTR-UHFFFAOYSA-M oxiran-2-ylmethyl(tripropyl)azanium;chloride Chemical compound [Cl-].CCC[N+](CCC)(CCC)CC1CO1 YQFOHQBSENCNTR-UHFFFAOYSA-M 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 150000002972 pentoses Chemical class 0.000 description 1
- 229920005596 polymer binder Polymers 0.000 description 1
- 239000002491 polymer binding agent Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000013074 reference sample Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- ZVKNFWSJGKGQDB-UHFFFAOYSA-M triethyl(oxiran-2-ylmethyl)azanium;bromide Chemical compound [Br-].CC[N+](CC)(CC)CC1CO1 ZVKNFWSJGKGQDB-UHFFFAOYSA-M 0.000 description 1
- QVOJVKONBAJKMA-UHFFFAOYSA-M triethyl(oxiran-2-ylmethyl)azanium;chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC1CO1 QVOJVKONBAJKMA-UHFFFAOYSA-M 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
- D21H17/15—Polycarboxylic acids, e.g. maleic acid
- D21H17/16—Addition products thereof with hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/14—Hemicellulose; Derivatives thereof
- C08B37/143—Hemicellulose; Derivatives thereof composed by pentose units, e.g. xylose, xylan, pentosans, arabinose (not used)
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J105/00—Adhesives based on polysaccharides or on their derivatives, not provided for in groups C09J101/00 or C09J103/00
- C09J105/14—Hemicellulose; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/17—Ketenes, e.g. ketene dimers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/31—Gums
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paper (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Claims (11)
1. Stabiloitu liimaformulaatio, joka käsittää liima-aineen ja modifioidun ruuaksi kelpaamattoman polysakkaridin, jolloin ruuaksi kelpaamaton polysakkaridi käsittää ksylaanin tai arabinogalaktaanin tai niiden seoksen ja jolloin modifioitu ruuaksi kelpaamaton polysakkaridi on saatu modifioimalla ruuaksi kelpaamatonta polysakkaridia kationisesti varatulla aminoreagenssilla.
2. Patenttivaatimuksen 1 mukainen formulaatio, jolloin liima-aine on AKD tai ASA tai niiden seos.
3. Patenttivaatimuksen 1 tai 2 mukainen formulaatio, jolloin ruuaksi kelpaamattoman polysakkaridi on ksylaani tai arabinogalaktaani tai niiden seos.
4. Patenttivaatimuksen 1 mukainen formulaatio, jolloin aminoreagenssi on gly-sidyylitrimetyyliammoniumkloridi.
5. Jonkin patenttivaatimuksen 1-4 mukainen formulaatio, jolloin modifioidun ruuaksi kelpaamattoman polysakkaridin substituutioaste on 0,03-1,5.
6. Jonkin patenttivaatimuksen 1-5 mukainen formulaatio, jolloin formulaatio on dispersion, edullisesti emulsion muodossa.
7. Jonkin patenttivaatimuksen 1-6 mukainen formulaatio, jolloin modifioidun ruuaksi kelpaamattoman polysakkaridin suhde liima-aineeseen on 0,05:1.
8. Menetelmä patenttivaatimuksen 1 mukaisen stabiloidun liimaformulaation valmistamiseksi, tunnettu siitä, että liima-aine ja modifioitu ruuaksi kelpaamaton polysakkaridi saatetaan kosketuksiin vesipitoisessa liuoksessa, jolloin muodostetaan dispersio homogenisoinnilla 140-160 barn paineessa, jolloin mainittu ruuaksi kelpaamaton polysakkaridi käsittää ksylaanin tai arabinogalaktaanin tai niiden seoksen ja jolloin modifioitu ruuaksi kelpaamaton polysakkaridi on saatu modifioimalla ruuaksi kelpaamatonta polysakkaridia kationisesti varatulla aminoreagenssilla.
9. Jonkin patenttivaatimuksen 1-7 mukaisen stabiloidun liimaformulaation käyttö paperin tai paperituotteiden liimauksessa.
10. Patenttivaatimuksen 9 mukainen käyttö, jolloin stabiloidun liimaformulaation annostus selluun on 0,5-3 kg/t.
11. Menetelmä patenttivaatimuksen 1 mukaisen modifioidun ruuaksi kelpaamattoman polysakkaridin valmistamiseksi, joka menetelmä käsittää polysakkaridin funktionalisoimisen reaktiolla varatun aminoreagenssin kanssa, tunnettu siitä, että mainittu menetelmä käsittää vaiheet i) tuotetaan varatun aineen, veden ja katalyyttisen emäsmäärän seos, ja mainittua seosta sekoitetaan perusteellisesti huoneen lämpötilaa korkeammassa lämpötilassa, ja ii) lisätään mainittu ruuaksi kelpaamattoman polysakkaridi, joka käsittää ksy-laanin tai arabinogalaktaanin tai niiden seoksen, ja pieni määrä vettä vaiheen i seokseen, ja saatua seosta sekoitetaan useita tunteja vakiolämpötilassa; ja jonka jälkeen iii) pestään ja suodatetaan muodostunut varattu ruuaksi kelpaamaton polysakkaridi ennen talteenottoa.
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI20145118A FI126960B (fi) | 2014-02-06 | 2014-02-06 | Stabiloitu liima-aineformulaatio |
| EP15706493.2A EP3102736B1 (en) | 2014-02-06 | 2015-02-06 | A stabilized sizing formulation |
| ES15706493.2T ES2655819T3 (es) | 2014-02-06 | 2015-02-06 | Una composición de apresto estabilizada |
| JP2016549479A JP6376366B2 (ja) | 2014-02-06 | 2015-02-06 | 安定化サイズ製剤 |
| PT157064932T PT3102736T (pt) | 2014-02-06 | 2015-02-06 | Uma formulação de colagem estabilizada |
| US15/116,664 US10132038B2 (en) | 2014-02-06 | 2015-02-06 | Stabilized sizing formulation |
| PL15706493T PL3102736T3 (pl) | 2014-02-06 | 2015-02-06 | Stabilizowany preparat do zaklejania |
| CN201580007487.9A CN105940156B (zh) | 2014-02-06 | 2015-02-06 | 稳定化施胶制剂 |
| RU2016129033A RU2662507C2 (ru) | 2014-02-06 | 2015-02-06 | Стабилизированный проклеивающий состав |
| PCT/FI2015/050076 WO2015118228A1 (en) | 2014-02-06 | 2015-02-06 | A stabilized sizing formulation |
| BR112016017930-7A BR112016017930B1 (pt) | 2014-02-06 | 2015-02-06 | Formulação de colagem estabilizada |
| CA2938748A CA2938748C (en) | 2014-02-06 | 2015-02-06 | A stabilized sizing formulation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI20145118A FI126960B (fi) | 2014-02-06 | 2014-02-06 | Stabiloitu liima-aineformulaatio |
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| Publication Number | Publication Date |
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| FI20145118A FI20145118A (fi) | 2015-08-07 |
| FI126960B true FI126960B (fi) | 2017-08-31 |
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| Application Number | Title | Priority Date | Filing Date |
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| FI20145118A FI126960B (fi) | 2014-02-06 | 2014-02-06 | Stabiloitu liima-aineformulaatio |
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| Country | Link |
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| US (1) | US10132038B2 (fi) |
| EP (1) | EP3102736B1 (fi) |
| JP (1) | JP6376366B2 (fi) |
| CN (1) | CN105940156B (fi) |
| BR (1) | BR112016017930B1 (fi) |
| CA (1) | CA2938748C (fi) |
| ES (1) | ES2655819T3 (fi) |
| FI (1) | FI126960B (fi) |
| PL (1) | PL3102736T3 (fi) |
| PT (1) | PT3102736T (fi) |
| RU (1) | RU2662507C2 (fi) |
| WO (1) | WO2015118228A1 (fi) |
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| CN111691236B (zh) * | 2020-05-26 | 2021-12-31 | 仙鹤股份有限公司 | 一种速干型圣经纸的生产方法 |
| CN114907625B (zh) * | 2022-05-24 | 2023-07-14 | 天津科技大学 | 一种生物基防水防油剂的制备及应用 |
| CN115323824A (zh) * | 2022-07-15 | 2022-11-11 | 龙游富田造纸精化有限公司 | 一种基于复合阳离子植物胶聚合物制备akd乳液工艺 |
| WO2024134030A1 (en) * | 2022-12-21 | 2024-06-27 | Kemira Oyj | Aqueous dispersion of alkyl ketene dimer and its use |
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|---|---|---|---|---|
| US4606773A (en) * | 1984-12-10 | 1986-08-19 | Nalco Chemical Company | Emulsification of alkenyl succinic anhydride sizing agents |
| JPH02127594A (ja) * | 1988-11-02 | 1990-05-16 | Hokuetsu Paper Mills Ltd | 置換コハク酸無水物を使用して行う製紙原料のサイズ化法 |
| JP2806563B2 (ja) * | 1989-07-21 | 1998-09-30 | 日本ピー・エム・シー株式会社 | 製紙用サイズ剤組成物 |
| FR2734005B1 (fr) * | 1995-05-12 | 1997-07-18 | Roquette Freres | Composition et procede pour le collage du papier |
| US6093217A (en) | 1997-02-05 | 2000-07-25 | Akzo Nobel N.V. | Sizing of paper |
| DE1068393T1 (de) | 1998-04-06 | 2001-08-23 | Calgon Corp., Naperville | Emulgieren von einer alkenylbernsteinsäureanhydridsleimung mit einem natürlichen gummi für papierprodukte |
| WO1999055736A2 (en) | 1998-04-27 | 1999-11-04 | Larex, Inc. | Derivatives of arabinogalactan and compositions including the same |
| US6123738A (en) | 1998-08-19 | 2000-09-26 | The Dow Chemical Company | Process for the production of low color 2,3-epoxypropyltrialkylammonium halide |
| US6123760A (en) | 1998-10-28 | 2000-09-26 | Hercules Incorporated | Compositions and methods for preparing dispersions and methods for using the dispersions |
| IL137887A0 (en) | 1999-08-17 | 2001-10-31 | Nat Starch Chem Invest | Polysaccharide aldehydes prepared by oxidation method and used as strength additives in papermaking |
| RU2266995C2 (ru) * | 2000-01-11 | 2005-12-27 | Циба Спешиэлти Кемикалз Холдинг, Инк. | Способ улучшения печатных свойств и покрываемости бумаги и картона |
| EP1314822A1 (en) * | 2001-11-19 | 2003-05-28 | Akzo Nobel N.V. | Process for sizing paper and sizing composition |
| JP4379675B2 (ja) * | 2002-10-28 | 2009-12-09 | 東邦化学工業株式会社 | カチオン変性多糖類及び該物質を含む組成物 |
| TW200504265A (en) * | 2002-12-17 | 2005-02-01 | Bayer Chemicals Corp | Alkenylsuccinic anhydride surface-applied system and uses thereof |
| PL1611284T3 (pl) * | 2003-04-01 | 2012-02-29 | Akzo Nobel Nv | Dyspersja |
| DE10349727A1 (de) | 2003-10-23 | 2005-05-25 | Basf Ag | Feste Mischungen aus einem Reaktivleimungsmittel und Stärke, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE102004003261A1 (de) * | 2004-01-21 | 2005-08-18 | Basf Ag | Alkenylbernsteinsäureanhydride enthaltende wässrige Polymerdispersionen, Verfahren zu ihrer Herstellung und ihre Verwendung |
| BRPI0520060A2 (pt) * | 2005-03-03 | 2009-04-14 | Kemira Oyj | método para colagem de um produto de papel e papel |
| MY146790A (en) * | 2005-12-21 | 2012-09-28 | Akzo Nobel Nv | Sizing of paper |
| FI121811B (fi) | 2007-06-01 | 2011-04-29 | Upm Kymmene Corp | Uudet dispersiot ja menetelmä niiden valmistamiseksi |
| CL2008002019A1 (es) * | 2007-07-16 | 2009-01-16 | Akzo Nobel Chemicals Int Bv | Composicion de carga que comprende una carga, un compuesto inorganico cationico, un compuesto organico cationico y un polisacarido anionico; metodo para preparar dicha composicion; uso como aditivo para una suspension celulosica acuosa; procedimiento para producir papel; y papel. |
| FI20096326A0 (fi) * | 2009-12-15 | 2009-12-15 | Valtion Teknillinen | Modifioitu biomateriaali, sen käytöt sekä modifiointimenetelmät |
| US20120244221A1 (en) * | 2010-07-08 | 2012-09-27 | Wellesley Pharmaceuticals, Llc | Extended-release formulation for reducing the frequency of urination and method of use thereof |
| US20120135050A1 (en) * | 2010-07-08 | 2012-05-31 | Wellesley Pharmaceuticals, Llc | Extended-release formulation for reducing the frequency of urination and method of use thereof |
| US8236857B2 (en) * | 2010-07-08 | 2012-08-07 | Wellesley Pharmaceuticals, Llc | Extended-release formulation for reducing the frequency of urination and method of use thereof |
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2015
- 2015-02-06 PT PT157064932T patent/PT3102736T/pt unknown
- 2015-02-06 ES ES15706493.2T patent/ES2655819T3/es active Active
- 2015-02-06 CN CN201580007487.9A patent/CN105940156B/zh active Active
- 2015-02-06 BR BR112016017930-7A patent/BR112016017930B1/pt active IP Right Grant
- 2015-02-06 EP EP15706493.2A patent/EP3102736B1/en active Active
- 2015-02-06 WO PCT/FI2015/050076 patent/WO2015118228A1/en active Application Filing
- 2015-02-06 RU RU2016129033A patent/RU2662507C2/ru active
- 2015-02-06 PL PL15706493T patent/PL3102736T3/pl unknown
- 2015-02-06 JP JP2016549479A patent/JP6376366B2/ja active Active
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Also Published As
| Publication number | Publication date |
|---|---|
| RU2016129033A (ru) | 2018-03-14 |
| ES2655819T3 (es) | 2018-02-21 |
| FI20145118A (fi) | 2015-08-07 |
| RU2662507C2 (ru) | 2018-07-26 |
| US20160348317A1 (en) | 2016-12-01 |
| BR112016017930A2 (fi) | 2017-08-08 |
| CA2938748C (en) | 2021-05-04 |
| US10132038B2 (en) | 2018-11-20 |
| PL3102736T3 (pl) | 2018-04-30 |
| BR112016017930B1 (pt) | 2022-01-18 |
| JP6376366B2 (ja) | 2018-08-22 |
| CA2938748A1 (en) | 2015-08-13 |
| CN105940156A (zh) | 2016-09-14 |
| EP3102736A1 (en) | 2016-12-14 |
| WO2015118228A1 (en) | 2015-08-13 |
| CN105940156B (zh) | 2019-05-10 |
| JP2017505389A (ja) | 2017-02-16 |
| RU2016129033A3 (fi) | 2018-03-14 |
| EP3102736B1 (en) | 2017-11-22 |
| PT3102736T (pt) | 2018-01-30 |
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